CN110061416A - Semiconductor laser non-absorbing window and preparation method thereof and semiconductor laser - Google Patents

Semiconductor laser non-absorbing window and preparation method thereof and semiconductor laser Download PDF

Info

Publication number
CN110061416A
CN110061416A CN201910297034.4A CN201910297034A CN110061416A CN 110061416 A CN110061416 A CN 110061416A CN 201910297034 A CN201910297034 A CN 201910297034A CN 110061416 A CN110061416 A CN 110061416A
Authority
CN
China
Prior art keywords
diffusion
semiconductor laser
layer
absorbing window
epitaxial wafer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910297034.4A
Other languages
Chinese (zh)
Other versions
CN110061416B (en
Inventor
王俊
赵智德
程洋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Everbright Photonics Co Ltd
Original Assignee
Suzhou Everbright Photonics Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Everbright Photonics Technology Co Ltd filed Critical Suzhou Everbright Photonics Technology Co Ltd
Priority to CN201910297034.4A priority Critical patent/CN110061416B/en
Publication of CN110061416A publication Critical patent/CN110061416A/en
Application granted granted Critical
Publication of CN110061416B publication Critical patent/CN110061416B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/02Structural details or components not essential to laser action
    • H01S5/022Mountings; Housings
    • H01S5/0225Out-coupling of light
    • H01S5/02257Out-coupling of light using windows, e.g. specially adapted for back-reflecting light to a detector inside the housing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/30Structure or shape of the active region; Materials used for the active region
    • H01S5/34Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers

Landscapes

  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Optics & Photonics (AREA)
  • Semiconductor Lasers (AREA)

Abstract

The invention discloses a kind of semiconductor laser non-absorbing window and preparation method thereof and semiconductor laser, which includes: to grow diffusion source to diffusion zone what semiconductor laser device epitaxial wafer original position etching obtained;Diffusion source is diffused to diffusion zone, diffusion region is obtained;Wide band gap layer is grown on the surface of diffusion region, wide band gap layer and diffusion region form non-absorbing window.Semiconductor laser non-absorbing window preparation method provided in an embodiment of the present invention, first by the way of diffusion, so that foreign ion is diffused into semiconductor laser device epitaxial wafer, then wide-band gap material is grown on diffusion region, wide band gap layer is formed, wide band gap layer and non-absorbing window constitute non-absorbing window area.It when diffuseing to form the non-absorbing window of required thickness in the prior art, needs at a high temperature of 800 degrees Celsius or more, diffusion 10 is more than hour.The present invention is diffused in same equipment and grows wide-band gap material, reduces required diffusion depth and diffusion time when diffusion.

Description

Semiconductor laser non-absorbing window and preparation method thereof and semiconductor laser
Technical field
The present invention relates to semiconductor laser fields, and in particular to a kind of semiconductor laser non-absorbing window and its Preparation method and semiconductor laser.
Background technique
Semiconductor laser catastrophic optics cavity surface damage (COD, Catastrophic optical damage) is limitation Semiconductor laser power output and the principal element for influencing device lifetime, COD are because impurity or dislocation etc. in Cavity surface lack Laser can be absorbed by falling into, and cause local energy excessively high, the raising of temperature will lead to the band-gap narrowing of semiconductor material, photonic absorption It is stronger, it will form vicious circle after temperature continues to increase, eventually lead to the generation of COD.Non-absorbing window structure is to utilize Material more broader than substrate material band gap forms a window region in Cavity surface, in this way in laser works due to broad-band gap Effect greatly reduces the light absorption of Cavity surface to reduce heat generation, to reach the possibility eliminating COD and occurring.
Impurity induced disordering diffusion is a kind of common method for preparing non-absorbing window area, is mainly technically characterized by leading to The mode for crossing first deposit and spread source, subsequent High temperature diffusion makes foreign atom to spreading inside semiconductor laser, realizes Quantum Well Region material mixes, to prepare non-absorbing window.By impurity induced disordering diffusion for when non-absorbing window by Farther out in diffusion quantum well radiation area of the source from device, diffusion length is long (about 3um or more), and diffusion process is again and in crystalline material Defect concentration, interface quality and diffusion parameter be closely related, required diffusion temperature is high (generally higher than 800 DEG C), diffusion time Generally also longer than 10 hours, therefore its repeatability and stability are all difficult to control;Prolonged high-temperature process also will affect device Main structure causes wave length shift and penalty.
Summary of the invention
In view of this, the embodiment of the invention provides a kind of semiconductor laser non-absorbing windows and preparation method thereof and half Conductor laser, when solving through impurity induced disordering diffusion for non-absorbing window, prolonged high-temperature process influences Device main body structure, the problem of causing wave length shift and penalty.
Technical solution proposed by the present invention is as follows:
First aspect of the embodiment of the present invention provides a kind of preparation method of semiconductor laser non-absorbing window, the preparation side Method includes: to grow diffusion source to diffusion zone what semiconductor laser device epitaxial wafer original position etching obtained;The diffusion source is expanded To diffusion zone described in being dissipated to, diffusion region is obtained;Wide band gap layer, the wide band gap layer and the expansion are grown on the surface of diffusion region It dissipates area and forms non-absorbing window.
Further, include: before semiconductor laser device epitaxial wafer grows diffusion source to diffusion zone described The upper surface deposition mask layer of the semiconductor laser device epitaxial wafer;Using lithography and etching technique, the table on the epitaxial wafer Face forms Patterned masking layer;The part of the non-cover graphics mask layer of the epitaxial wafer is subjected to etching in situ, is obtained described To diffusion region.
It further, include: selected substrate before the upper surface deposition mask layer of the semiconductor laser device epitaxial wafer; Successively grown buffer layer, lower limit layer, lower waveguide layer, Quantum Well and barrier layer, upper ducting layer, upper limiting layer over the substrate And ohmic contact layer, form the epitaxial wafer.
Further, including: by the part progress etching in situ of the non-cover graphics mask layer of the epitaxial wafer will be described The part of the non-cover graphics mask layer of epitaxial wafer formed Patterned masking layer equipment in be etched to the Quantum Well and Barrier layer interval pre-determined distance;The pre-determined distance is 0-0.3 μm.
Further, the part of the non-cover graphics mask layer of the epitaxial wafer is carried out original position etching by step and step exists Semiconductor laser device epitaxial wafer carries out in same equipment to diffusion zone growth diffusion source.
Further, described to diffuse to the diffusion source described to diffusion zone, obtaining to diffusion region includes: to have growth The semiconductor laser device epitaxial wafer in diffusion source is annealed in 600 DEG C -800 DEG C of atmosphere, wherein annealing time is small less than 1 When.
Further, it is described by the diffusion source diffuse to it is described to diffusion zone and it is described on the surface of diffusion region it is raw It include: the removal non-diffused diffusion source in diffusion region surface between long wide band gap layer.
Further, wide band gap layer is grown on the diffusion region surface, comprising: grow p-type on the surface of diffusion region and mix Miscellaneous or n-type doping wide-band gap material, the wide-band gap material and the mask layer, the upper limiting layer and ohmic contact layer shape At current barrier layer.
Second aspect of the embodiment of the present invention provides a kind of semiconductor laser non-absorbing window, and the non-absorbing window uses It is prepared by the production method of the described in any item semiconductor laser non-absorbing windows of first aspect of the embodiment of the present invention.
The third aspect of the embodiment of the present invention provides a kind of semiconductor laser, which includes such as the embodiment of the present invention the Semiconductor laser non-absorbing window described in two aspects.
Technical solution proposed by the present invention, has the effect that
Semiconductor laser non-absorbing window provided in an embodiment of the present invention and preparation method thereof and semiconductor laser, are adopted The mode combined is grown with quantum well mixing technology and secondary epitaxy, is lured first using the impurity in quantum well mixing technology The mode for leading disordering diffusion, so that foreign ion is diffused into semiconductor laser device epitaxial wafer, then by diffusion region Wide-band gap material is grown, forms wide band gap layer, wide band gap layer and non-absorbing window together constitute non-absorbing window area.And it is existing When in technology by the impurity induced disordering non-absorbing window for diffuseing to form required thickness, need at 800 degrees Celsius or more Under high temperature, it is more than hour to spread 10, diffusion temperature is high, diffusion time is long, and repeatability and stability are all difficult to control.The present invention It is combined using two ways, wide-band gap material is diffused and grown in same equipment, the diffusion reduced when diffusion is deep Degree and diffusion time, at a high temperature of 800 degrees Celsius or more, diffusion time can solve at long-time high temperature less than 1 hour The problem of reason causes wave length shift and penalty improves the reliability of device, reduces production cost.
In addition, needing the quantum of etched features when growing to form non-absorbing window area by secondary epitaxy in the prior art Trap luminous zone, regrowth wide-band gap material, this process can generate impurity and fault in material, the luminous efficiency of influence amount trap.This hair It is bright without etching Quantum Well luminous zone, to reduce the influence of impurity and fault in material by the way of first spreading regrowth, it improves The luminous efficiency of Quantum Well.
Detailed description of the invention
It, below will be to specific in order to illustrate more clearly of the specific embodiment of the invention or technical solution in the prior art Embodiment or attached drawing needed to be used in the description of the prior art be briefly described, it should be apparent that, it is described below Attached drawing is some embodiments of the present invention, for those of ordinary skill in the art, before not making the creative labor It puts, is also possible to obtain other drawings based on these drawings.
Fig. 1 is the flow chart of the production method of semiconductor laser non-absorbing window according to an embodiment of the present invention;
Fig. 2 is the flow chart of the production method of semiconductor laser non-absorbing window according to another embodiment of the present invention;
Fig. 3 is the flow chart of the production method of semiconductor laser non-absorbing window according to another embodiment of the present invention;
Fig. 4 A to Fig. 4 G is obtained by the production method of semiconductor laser non-absorbing window according to an embodiment of the present invention Structural schematic diagram.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention In attached drawing, technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is A part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those skilled in the art are not having Every other embodiment obtained under the premise of creative work is made, shall fall within the protection scope of the present invention.
The embodiment of the present invention provides a kind of preparation method of semiconductor laser non-absorbing window, as shown in Figure 1, the preparation Method includes the following steps:
S101: what in semiconductor laser device epitaxial wafer original position, etching was obtained grows diffusion source to diffusion zone.Specifically, half The structure of conductor laser epitaxial wafer can be substrate, buffer layer, lower limit layer, lower waveguide including setting gradually from top to bottom Floor, Quantum Well and Quantum Well build area, upper ducting layer, upper limiting layer and ohmic contact layer;In the diffusion source grown with diffusion zone It can be siliceous diffusion source, be also possible to the diffusion source containing zinc, the application does not limit this.It, can when growing diffusion source With using plasma enhancing chemical vapour deposition technique (Plasma Enhanced Chemical Vapor Deposition, ) or Metalorganic chemical vapor deposition method (MOCVD, Metal-organic Chemical Vapor PECVD Deposition), the application does not limit this.
S102: diffusion source is diffused to diffusion zone, diffusion region is obtained.Specifically, growth there is into partly leading for diffusion source Body laser epitaxial wafer is annealed in 600 DEG C -800 DEG C of atmosphere, wherein annealing time was less than 1 hour.In annealing In the process, diffusion source is gradually diffused to obtain diffusion region in diffusion zone.Wherein, when diffusion source is when containing silicon diffusion source, shape At diffusion region can also play the role of electric isolation and optical confinement.
S103: growing wide band gap layer on the surface of diffusion region, and wide band gap layer and diffusion region form non-absorbing window.Specifically Ground, wide band gap layer can be the InGaP including different doping types, the materials such as AlGaAs, and the application does not limit this.
S101 to step S103 through the above steps, semiconductor laser non-absorbing window provided in an embodiment of the present invention Production method uses quantum well mixing skill in such a way that quantum well mixing technology and secondary epitaxy growth combine first The mode of impurity induced disordering diffusion in art is then led to so that foreign ion is diffused into semiconductor laser device epitaxial wafer It crosses and grows wide-band gap material on diffusion region, form wide band gap layer, wide band gap layer and non-absorbing window together constitute non-absorbing Window region.And when in the prior art by the impurity induced disordering non-absorbing window for diffuseing to form required thickness, it needs 800 Degree Celsius or more at a high temperature of, diffusion 10 more than hour, diffusion temperature is high, diffusion time is long, and repeatability and stability are all very It is difficult to control.The present invention is combined using two ways, and wide-band gap material is diffused and grown in same equipment, reduces expansion Diffusion depth and diffusion time when dissipating, at a high temperature of 800 degrees Celsius or more, diffusion time can solve less than 1 hour Long-time high-temperature process causes the problem of wave length shift and penalty, improves the reliability of device, reduces production cost.
In addition, needing the quantum of etched features when growing to form non-absorbing window area by secondary epitaxy in the prior art Trap luminous zone, regrowth wide-band gap material, this process can generate impurity and fault in material, influence the luminous efficiency of Quantum Well.This Invention, without etching Quantum Well luminous zone, reduces the influence of impurity and fault in material, mentions by the way of first spreading regrowth The high luminous efficiency of Quantum Well.
As a kind of optional embodiment of the embodiment of the present invention, as shown in Fig. 2, in semiconductor laser device epitaxial wafer To include the following steps: before diffusion zone growth diffusion source
S111: in the upper surface deposition mask layer of semiconductor laser device epitaxial wafer.Specifically, in semiconductor laser extension The ohmic contact layer upper surface of piece forms mask layer, and mask layer can be silicon nitride film or silicon oxide film, the thickness of mask layer Degree can control between 50-200nm, and the growth temperature of mask layer controls between 200-500 degrees Celsius, and the present invention is to this Without limitation.
S112: using lithography and etching technique, forms Patterned masking layer on extension on piece surface.Specifically, the figure The shape for changing mask layer can be bar shaped, be also possible to other shapes, the application does not limit this.
S113: the part of the non-cover graphics mask layer of epitaxial wafer is subjected to etching in situ, is obtained to diffusion region.Specifically Ground, the depth that epitaxial wafer etches in situ can control at a distance from 0-0.3 μm of Quantum Well and barrier layer interval.In addition, deposition Mask layer, Patterned masking layer and etching process in situ can carry out in same equipment.Wherein, etching in situ refers to figure Directly epitaxial wafer is performed etching in same equipment after changing mask layer.
In the embodiment of the present invention, to redeposited diffusion source after epitaxial wafer progress etching in situ and directly in extension on piece deposition Diffusion source is compared, and the diffusion source deposited after etching is closer apart from Quantum Well, and diffusion source film thickness requires to be lower.Can substantially it subtract The diffusion length of few impurity element.Etching in situ does not need etching Quantum Well, reduces compared with ex situ lithographic method simultaneously Intermediate link, so as to avoid Quantum Well because of penalty brought by impurity and fault in material.
As a kind of optional embodiment of the embodiment of the present invention, S113 is by the non-cover graphics exposure mask of the epitaxial wafer The part of layer carries out etching in situ and S101 setting same to diffusion zone growth diffusion source in semiconductor laser device epitaxial wafer Standby middle progress.Therefore, it during forming non-absorbing window, does not need epitaxial wafer and repeatedly switches process equipment, continually It is exposed in external environment, reduces influence of the introduced contaminants to device.
As a kind of optional embodiment of the embodiment of the present invention, S102 diffusion source is diffused to diffusion zone and It further includes following steps that S103, which is grown on the surface of diffusion region between wide band gap layer:
S120: the removal non-diffused diffusion source in diffusion region surface.Specifically, in removal, some acid solutions can be used It is removed using the technique of cleaning.
As a kind of optional embodiment of the embodiment of the present invention, wide band gap layer is grown on the surface of diffusion region, wherein Wide band gap layer may include the wide-band gap material of p-type doping or n-type doping, which can be InGaP or AlGaAs Equal materials, the application do not limit this.After growing wide band gap layer, wide band gap layer and mask layer, upper limiting layer and Ohmic contact Layer forms current barrier layer.
In the embodiment of the present invention, the wide band gap layer of non-absorbing window can be with flexible choice material component, doping type and dense Current barrier layer, Er Qieyou is collectively formed in degree, forbidden bandwidth etc., wide band gap layer and mask layer, upper limiting layer and ohmic contact layer In realizing current blocking using doping techniques, it is no longer necessary to the subsequent technique of ion implanting etc keeps entire technique more simplified, Reduce the possible additional impurities pollution of pilot process, improves the repeatability of technique.
As a kind of optional embodiment of the embodiment of the present invention, as shown in figure 3, semiconductor laser non-absorbing window Preparation method can using following steps carry out:
S201: in the upper surface deposition mask layer 20 of semiconductor laser device epitaxial wafer 10;Structure after S201 is as schemed Shown in 4A.
S202: using lithography and etching technique, forms Patterned masking layer 21 in 10 upper surface of epitaxial wafer;After S202 Structure it is as shown in Figure 4 B.
S203: the part of the non-cover graphics mask layer of epitaxial wafer 10 is subjected to etching in situ, is generated on bar shaped epitaxial wafer Surface 11, obtains to diffusion region;Structure after S203 is as shown in Figure 4 C.
S204: diffusion source 30 is grown to diffusion zone in semiconductor laser device epitaxial wafer 10;Structure after S204 As shown in Figure 4 D.
S205: diffusion source 30 is diffused to diffusion zone, obtains diffusion region 40;Structure such as Fig. 4 E institute after S205 Show.
S206: the removal non-diffused diffusion source in diffusion region surface;Structure after S206 is as illustrated in figure 4f.
S207: growing wide band gap layer 50 on the surface of diffusion region, and wide band gap layer 50 and diffusion region 40 form non-absorbing window. Structure after S207 is as shown in Figure 4 G.
In the embodiment of the present invention, above-mentioned steps S201 to step S207 and the process for forming semiconductor laser device epitaxial wafer It can be carried out in same equipment, not need epitaxial wafer and repeatedly switch process equipment, be continually exposed in external environment, Reduce influence of the introduced contaminants to device, wherein the different process in above-mentioned steps can be in the differential responses of same equipment It is carried out in room.
The embodiment of the present invention also provides a kind of semiconductor laser non-absorbing window, which uses above-mentioned implementation The production method preparation for the semiconductor laser non-absorbing window that example provides.
Semiconductor laser non-absorbing window provided in an embodiment of the present invention uses quantum well mixing technology and secondary outer Prolong the mode that growth combines, first by the way of the impurity induced disordering diffusion in quantum well mixing technology, so that miscellaneous Matter ion is diffused into semiconductor laser device epitaxial wafer, then by growing wide-band gap material on diffusion region, forms broad stopband Layer, wide band gap layer and non-absorbing window together constitute non-absorbing window area.And in the prior art by impurity induced disordering It when diffuseing to form the non-absorbing window of required thickness, needs at a high temperature of 800 degrees Celsius or more, it is more than hour to spread 10, Repeatability and stability are all difficult to control.The present invention is combined using two ways, is diffused and is grown in same equipment Wide-band gap material reduces diffusion depth when diffusion and diffusion time, at a high temperature of 800 degrees Celsius or more, diffusion time It can solve the problems, such as that long-time high-temperature process caused wave length shift and penalty less than 1 hour, and improve the reliable of device Property, reduce production cost.
In addition, needing the quantum of etched features when growing to form non-absorbing window area by secondary epitaxy in the prior art Trap luminous zone, regrowth wide-band gap material, this process can generate impurity and fault in material, influence the luminous efficiency of Quantum Well.This Invention, without etching Quantum Well luminous zone, reduces the influence of impurity and fault in material, mentions by the way of first spreading regrowth The high luminous efficiency of Quantum Well.
The embodiment of the present invention also provides a kind of semiconductor laser, which includes provided by the above embodiment Semiconductor laser non-absorbing window.
Semiconductor laser provided in an embodiment of the present invention, including non-absorbing window area, can eliminate semiconductor laser Catastrophic optics cavity surface damage, and the preparation of non-absorbing window uses quantum well mixing technology and secondary epitaxy growth combines Mode, first by the way of the impurity induced disordering diffusion in quantum well mixing technology, so that foreign ion is diffused into In semiconductor laser device epitaxial wafer, then by growing wide-band gap material on diffusion region, form wide band gap layer, wide band gap layer and Non-absorbing window together constitutes non-absorbing window area.And required thickness is diffuseed to form by impurity induced disordering in the prior art It when the non-absorbing window of degree, needs at a high temperature of 800 degrees Celsius or more, diffusion 10 is more than hour, repeatability and stability All it is difficult to control.The present invention is combined using two ways, and wide-band gap material is diffused and grown in same equipment, is reduced Diffusion depth and diffusion time when diffusion, at a high temperature of 800 degrees Celsius or more, diffusion time can solve less than 1 hour The problem of long-time high-temperature process causes wave length shift and penalty improves the reliability of device, reduces production cost.
In addition, needing the quantum of etched features when growing to form non-absorbing window area by secondary epitaxy in the prior art Trap luminous zone, regrowth wide-band gap material, this process can generate impurity and fault in material, influence the luminous efficiency of Quantum Well.This Invention, without etching Quantum Well luminous zone, reduces the influence of impurity and fault in material, mentions by the way of first spreading regrowth The high luminous efficiency of Quantum Well.
Although being described in conjunction with the accompanying the embodiment of the present invention, those skilled in the art can not depart from the present invention Spirit and scope in the case where make various modifications and variations, such modifications and variations are each fallen within by appended claims institute Within the scope of restriction.

Claims (10)

1. a kind of preparation method of semiconductor laser non-absorbing window characterized by comprising
Diffusion source is grown to diffusion zone what the etching in situ of semiconductor laser device epitaxial wafer obtained;
The diffusion source is diffused to described to diffusion zone, obtains diffusion region;
Wide band gap layer is grown on the surface of diffusion region, the wide band gap layer and the diffusion region form non-absorbing window.
2. the preparation method of semiconductor laser non-absorbing window according to claim 1, which is characterized in that it is described Semiconductor laser device epitaxial wafer to diffusion zone growth diffusion source before include:
In the upper surface deposition mask layer of the semiconductor laser device epitaxial wafer;
Using lithography and etching technique, Patterned masking layer is formed in the epitaxial wafer upper surface;
The part of the non-cover graphics mask layer of the epitaxial wafer is subjected to etching in situ, is obtained described to diffusion region.
3. the preparation method of semiconductor laser non-absorbing window according to claim 2, which is characterized in that described half Include: before the upper surface deposition mask layer of conductor laser epitaxial wafer
Selected substrate;
Successively grown buffer layer, lower limit layer, lower waveguide layer, Quantum Well and barrier layer, upper ducting layer, the upper limit over the substrate Preparative layer and ohmic contact layer form the epitaxial wafer.
4. the preparation method of semiconductor laser non-absorbing window according to claim 3, which is characterized in that will be described outer The part for prolonging the non-cover graphics mask layer of piece carries out etching in situ and includes:
The part of the non-cover graphics mask layer of the epitaxial wafer is etched to and institute in the equipment for forming Patterned masking layer State Quantum Well and barrier layer interval pre-determined distance;The pre-determined distance is 0-0.3 μm.
5. according to the preparation method of semiconductor laser non-absorbing window described in claim 2-4 any one, feature exists In,
The part of the non-cover graphics mask layer of the epitaxial wafer is carried out etching and step in situ in semiconductor laser by step Epitaxial wafer carries out in same equipment to diffusion zone growth diffusion source.
6. the preparation method of semiconductor laser non-absorbing window according to claim 1, which is characterized in that described by institute It states diffusion source and diffuses to described to diffusion zone, obtain to diffusion region and include:
There is the semiconductor laser device epitaxial wafer in diffusion source to anneal in 600 DEG C -800 DEG C of atmosphere growth, wherein to move back The fiery time was less than 1 hour.
7. the preparation method of semiconductor laser non-absorbing window according to claim 1, which is characterized in that incited somebody to action described The diffusion source diffuses to described to diffusion zone and described grown between wide band gap layer on the surface of diffusion region includes:
Remove the non-diffused diffusion source in diffusion region surface.
8. the preparation method of semiconductor laser non-absorbing window according to claim 1, which is characterized in that in the expansion It dissipates and grows wide band gap layer on area surface, comprising:
The wide-band gap material of p-type doping or n-type doping, the wide-band gap material and the exposure mask are grown on the surface of diffusion region Layer, the upper limiting layer and ohmic contact layer form current barrier layer.
9. a kind of semiconductor laser non-absorbing window, which is characterized in that the non-absorbing window uses such as claim 1-8 The preparation method of described in any item semiconductor laser non-absorbing windows makes.
10. a kind of semiconductor laser, which is characterized in that including the non-absorbing window of semiconductor laser as claimed in claim 9 Mouthful.
CN201910297034.4A 2019-04-12 2019-04-12 Non-absorption window of semiconductor laser, preparation method thereof and semiconductor laser Active CN110061416B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910297034.4A CN110061416B (en) 2019-04-12 2019-04-12 Non-absorption window of semiconductor laser, preparation method thereof and semiconductor laser

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910297034.4A CN110061416B (en) 2019-04-12 2019-04-12 Non-absorption window of semiconductor laser, preparation method thereof and semiconductor laser

Publications (2)

Publication Number Publication Date
CN110061416A true CN110061416A (en) 2019-07-26
CN110061416B CN110061416B (en) 2020-04-10

Family

ID=67318955

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910297034.4A Active CN110061416B (en) 2019-04-12 2019-04-12 Non-absorption window of semiconductor laser, preparation method thereof and semiconductor laser

Country Status (1)

Country Link
CN (1) CN110061416B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114389152A (en) * 2022-01-13 2022-04-22 中国科学院半导体研究所 Epitaxial growth method of semiconductor laser

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5764669A (en) * 1995-07-05 1998-06-09 Mitsubishi Denki Kabushiki Kaisha Semiconductor laser including disordered window regions
US20020146866A1 (en) * 2001-04-06 2002-10-10 Sanyo Electric Co., Ltd. Nitride-based semiconductor laser device and method of fabricating the same
CN1426142A (en) * 2001-12-10 2003-06-25 Lg电子株式会社 Semiconductor laser device and its producing method
CN1663088A (en) * 2002-06-26 2005-08-31 阿莫诺公司 Nitride semiconductor laser device and a method for improving its performance
CN104158087A (en) * 2014-05-29 2014-11-19 北京工业大学 Cycle annealing method based on InGaAs/AlGaAs quantum well intermixing
CN104752954A (en) * 2015-03-23 2015-07-01 西安理工大学 Semiconductor laser manufactured by mixed zinc oxide quantum well and manufacturing method of semiconductor laser

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5764669A (en) * 1995-07-05 1998-06-09 Mitsubishi Denki Kabushiki Kaisha Semiconductor laser including disordered window regions
US20020146866A1 (en) * 2001-04-06 2002-10-10 Sanyo Electric Co., Ltd. Nitride-based semiconductor laser device and method of fabricating the same
CN1426142A (en) * 2001-12-10 2003-06-25 Lg电子株式会社 Semiconductor laser device and its producing method
CN1663088A (en) * 2002-06-26 2005-08-31 阿莫诺公司 Nitride semiconductor laser device and a method for improving its performance
CN104158087A (en) * 2014-05-29 2014-11-19 北京工业大学 Cycle annealing method based on InGaAs/AlGaAs quantum well intermixing
CN104752954A (en) * 2015-03-23 2015-07-01 西安理工大学 Semiconductor laser manufactured by mixed zinc oxide quantum well and manufacturing method of semiconductor laser

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114389152A (en) * 2022-01-13 2022-04-22 中国科学院半导体研究所 Epitaxial growth method of semiconductor laser
CN114389152B (en) * 2022-01-13 2023-10-13 中国科学院半导体研究所 Epitaxial growth method of semiconductor laser

Also Published As

Publication number Publication date
CN110061416B (en) 2020-04-10

Similar Documents

Publication Publication Date Title
CN106207752B (en) A kind of Si based high-power laser and preparation method thereof
CN111564756B (en) Silicon-based non-phosphorus laser and preparation method thereof
Oh et al. Control of crack formation for the fabrication of crack-free and self-isolated high-efficiency gallium arsenide photovoltaic cells on silicon substrate
US11830961B2 (en) Silicon nitride hard mask for epitaxial germanium on silicon
US9948064B2 (en) Method of manufacturing semiconductor device, and semiconductor device
CN104485578A (en) Transistor laser, and manufacturing method thereof
CN110061416A (en) Semiconductor laser non-absorbing window and preparation method thereof and semiconductor laser
US20210288471A1 (en) Vertical-Cavity Surface-Emitting Device with Epitaxial Index Guide
CN111785818B (en) GaN fundamental waveguide device based on porous lower cladding layer and preparation method and application thereof
CN100349338C (en) Buried heterostructure semiconductor optical device with blue shift effect of wavelengh, and method
JP3659361B2 (en) Semiconductor laser device and manufacturing method thereof
CN110086080B (en) Non-absorption window of semiconductor laser, preparation method thereof and semiconductor laser
US7456040B2 (en) Method for producing semiconductor optical device
RU2324999C2 (en) Method of quantum wells mixing within semiconductor device and semiconductor device structure made according to this method
JPH11354886A (en) Semiconductor laser and its manufacturing method
CN1496579A (en) Method of manufacturing optical devices and related improvements
KR950011998B1 (en) Manufacturing method of semiconductor laser diode
JPS63164288A (en) Manufacture of semiconductor laser device
KR20010019358A (en) Method for fabricating a III-nitride compound semiconductor
JP2024117750A (en) Germanium semiconductor device and its manufacturing method
KR20170086907A (en) Method for selective doping of semiconductor device
CN116666214A (en) Semiconductor structure and preparation method thereof
KR0146711B1 (en) Method of inactivation for surface radiation laser diode
WO2024155335A2 (en) Ultraviolet laser diode on a nano-porous aluminum gallium nitride template
KR950006987B1 (en) Semiconductor laser diode manufacturing method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CP03 Change of name, title or address

Address after: 215163 No.2 workshop-1-102, No.2 workshop-2-203, zone a, industrial square, science and Technology City, No.189 Kunlunshan Road, high tech Zone, Suzhou City, Jiangsu Province

Patentee after: Suzhou Changguang Huaxin Optoelectronic Technology Co.,Ltd.

Address before: 215163 Building 2, No.189, Kunlunshan Road, high tech Zone, Suzhou City, Jiangsu Province

Patentee before: SUZHOU EVERBRIGHT PHOTONICS TECHNOLOGY Co.,Ltd.

CP03 Change of name, title or address