CN110055756A - The multidimensional of silk is crosslinked solid glue method - Google Patents
The multidimensional of silk is crosslinked solid glue method Download PDFInfo
- Publication number
- CN110055756A CN110055756A CN201910373704.6A CN201910373704A CN110055756A CN 110055756 A CN110055756 A CN 110055756A CN 201910373704 A CN201910373704 A CN 201910373704A CN 110055756 A CN110055756 A CN 110055756A
- Authority
- CN
- China
- Prior art keywords
- silk
- solid glue
- multidimensional
- glue method
- bath foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of multidimensional of silk to be crosslinked solid glue method, it is characterised in that: Sericin Gumming finishing agent used is the not pickling chrome-free tanning agent TWS of Cyanuric Chloride or cyanuric chloride derivant or the production of Sichuan Ting Jiang new material limited liability company.Silk Sericin Gumming finishing agent solid glue chemical crossbond disclosed by the invention is based on covalent bond, and assist a variety of other chemical bond crosslinkings, the multidimensional cross-linked structure for being formed by spatial network is stablized, other than with good solid glue, effect of gain, moreover it is possible to assign silk certain fluffy and elastic feel.
Description
Technical field
The present invention relates to a kind of silk solid glue method, in particular to the multidimensional of a kind of silk is crosslinked solid glue method.
Background technique
Silk is a kind of animal protein material, is mainly made of silk gum and fibroin, and wherein fibroin accounts for about 3/4, and silk gum accounts for about
1/4.Silk gum and fibroin are made of 18 kinds of amino acid, the true protein containing about 97%.The fiber that silk working process arranges belongs to one
The high-grade textile of kind, chemistry and the physical characteristic of fibrous material directly affect comfort and feel of fabric dress etc.
Performance, therefore the field that always silk industry is paid close attention to is arranged to the function treatment of silk fiber.Silk gum layer in silk
Protein fibre swelling, rupture and hydrolysis easily occur in weak acid, weak base aqueous solution, therefore in traditional silk processing,
People just utilize this characteristic of silk gum to remove silk gum layer, retain fibroin layer, cause the native protein of this preciousness in this way
The waste of matter resource and its pollution to environment, therefore silk gum therein is carried out at fixation before Natural Silk Chemistry Physical Processing
Reason, is the road Bu Youzhi for solving the problems, such as this.
In recent years, the research, popularization and application of Sericin Gumming technology, not only solves this problem to a certain extent,
The functional characteristics such as silk is plentiful, thick and solid, well-pressed can also be assigned.Domestic and international Sericin Gumming finishing agent study at present mainly have chromic salts,
The types such as small molecule aldehyde, tannic acid, synthetic resin, s-triazine compound, epoxide containing Active Chlorine, it is various in style,
But all there are advantage and disadvantage to a certain extent in different properties.
Chromic salts solid glue effect spy is excellent, but itself has color, and chromic salt is easily oxidized under the conditions of high temperature, high pH
Sexavalence chromic salts with carcinogenicity is handled almost without for solid glue.
Formaldehyde is the conventional method of the solid glue early stage of development, is worked well, and formaldehydes substance highly volatile, have it is carcinogenic
Property is unfavorable for human health, and with the requirement of ecological, environmental protective silk goods, formaldehyde has been gradually backed out solid glue applied technical procedure.
Glutaraldehyde is easy xanthochromia although solid glue effect is good, is unfavorable for the processing of white and light silk, is only used for dark silk and produces
The solid glue of product is handled, and greatly limits glutaraldehyde solid glue application range.
Tannic acid lacks a certain amount of secured covalent bonding mode to silk-fibroin chemical crosslinking, the effect of crosslinking solid glue compared with
It is weak, and itself has deeper color, arranges silk with it, heavier color can be caught to silk, to the dyeability of silk
There is large effect, this method almost seldom uses.
Zhou Hongxiang etc. reports three kinds of epoxides and arranges for silk Sericin Gumming, but these three compounds are used for silkworm
During silk arranges, need to be added catalyst KSCN (noxious material), and this three kinds of substances must be in organic solvents such as isopropanols
Middle implementation solid glue also needs to wash away unreacted epoxides on silk with acetone equal solvent after processing, this method is only limitted to reality
Test room theoretical research.
Liu Jin is equal by force to be reported with dichloro s-triazine reactive dye (X-type reactive dye) as sericin fixing agent (Zhejiang silk work
Institute's journal, 1994,1 phase), experiment shows that such dyestuff can be used for the fixed of silk silk gum and arrange, and can obtain good
Dyeing effect can not be processed into desirable white solid glue silk fiber, make to produce although solid glue is two-in-one with dyeing
Product color is thought arbitrarily to control, and method application is limited.
Summary of the invention
In view of the above technical problems, the purpose of the present invention is to provide a kind of multidimensional of silk to be crosslinked solid glue method, to silkworm
The non-cohesive color of silk, can obtain the pure white solid glue silk of color.
To achieve the goals above, the technical solution of the present invention is as follows: a kind of multidimensional of silk is crosslinked solid glue method, feature
Be: Sericin Gumming finishing agent used is Cyanuric Chloride or cyanuric chloride derivant or the limited public affairs of Sichuan pavilion river new material share
Take charge of the not pickling chrome-free tanning agent TWS of production.
In above scheme: the cyanuric chloride derivant is p- (the chloro- 1,3,5- triazine -2- amino of 4,6- bis-) benzene sulfonic acid
Sodium, p- (the chloro- 1,3,5- triazine -2- amino of 4,6- bis-) sodium benzoate, p- (the chloro- 1,3,5- triazine -2- oxygroup of 4,6- bis-) benzene
One of sodium sulfonate and p- (the chloro- 1,3,5- triazine -2- oxygroup of 4,6- bis-) sodium benzoate.
It operates: (1) putting into silk in 20-45 DEG C of water in accordance with the following steps, adjusted bath foam pH with organic acid
3.5-6.0 sufficiently impregnates wetting；
(2) the complete silk of immersion wetting is de- dry, the concentration for being put into 4-6 times of quality is the Sericin Gumming of 20-60g/L
In finishing agent bath foam, and bleeding agent and sodium bicarbonate is added, after impregnating 1-2h, then with lye adjusting pH value between 8-11, with
Bath foam is warming up to 60-80 DEG C of insulation reactions afterwards；
(3) after having reacted, take off dry silk, and 2-12h of pile at 20-30 DEG C, then bake at 100-120 DEG C it is dry or
Naturally dry.
According to the principles of chemistry of solid glue, we using Cyanuric Chloride and cyanuric chloride derivant [it is p- (4,6- bis- chloro- 1,
3,5- triazine -2- amino) benzene sulfonic acid sodium salt, p- (the chloro- 1,3,5- triazine -2- amino of 4,6- bis-) sodium benzoate, p- (4,6- bis-
Chloro- 1,3,5- triazine -2- oxygroup) benzene sulfonic acid sodium salt, p- (the chloro- 1,3,5- triazine -2- oxygroup of 4,6- bis-) sodium benzoate] and TWS be
Crosslink finishing agent, is dispersed in water phase, by control bath foam pH and temperature, utilizes cl radical on s-triazine ring and silk point
Ammonia on active aldehyde radical and silk molecule on existing correlation and TWS strand between the activity and temperature that amino reacts on son
The multidimensional crosslinking solid glue effect to silk is realized in reaction of base etc., since used solid glue finishing agent is to the non-cohesive color of silk
Pool can obtain the pure white solid glue silk of color.
Cyanuric Chloride adhering sericin chemical reaction mechanism is as follows:
P- (the chloro- 1,3,5- triazine -2- amino of 4,6- bis-) benzene sulfonic acid sodium salt adhering sericin chemical reaction mechanism is as follows:
P- (the chloro- 1,3,5- triazine -2- amino of 4,6- bis-) sodium benzoate adhering sericin chemical reaction mechanism is as follows:
P- (the chloro- 1,3,5- triazine -2- oxygroup of 4,6- bis-) benzene sulfonic acid sodium salt adhering sericin chemical reaction mechanism is as follows:
P- (the chloro- 1,3,5- triazine -2- oxygroup of 4,6- bis-) sodium benzoate adhering sericin chemical reaction mechanism is as follows:
TWS adhering sericin chemical reaction mechanism is as follows:
It is preferred that: the organic acid is one of formic acid, acetic acid or lactic acid.
In above scheme: the bleeding agent is JFC.
In above scheme: in step (1), the amount of water is 8-10 times of silk quality, soaking time 1-2h.
In above scheme: in step (2), the additional amount of JFC is the 0.15-0.25% of bath foam quality；The addition of sodium bicarbonate
Amount is the 0.15-0.25% of bath foam quality.
In above scheme: lye is the sodium carbonate liquor that mass concentration is 10-20% in step (2).
In above scheme: the insulation reaction time is 2-4h in step (2).
Compared with prior art, the invention has the following advantages that
(1), it is pure white can to obtain color to the non-cohesive color of silk for silk Sericin Gumming finishing agent disclosed by the invention
Solid glue silk.
(2), silk Sericin Gumming finishing agent disclosed by the invention can under wider temperature range and weak basic condition with
Sericin combines, and is easily dispersed in water, and it is not necessary that organic solvent is added when arranging silk, operates without specially treated, institute
It states that process is simple, handles the lower production costs of silk solid glue, environmental protection.
(3), silk Sericin Gumming finishing agent solid glue chemical crossbond disclosed by the invention is based on covalent bond, and assists more
The other chemical bonds crosslinkings of kind, the multidimensional cross-linked structure for being formed by spatial network are stablized, in addition to making with good solid glue, weight gain
With outer, moreover it is possible to assign silk certain fluffy and elastic feel.
Specific embodiment
Below by embodiment, the invention will be further described:
Embodiment 1
The multidimensional of silk is crosslinked solid glue method, in accordance with the following steps:
(1) silk is put into 20 DEG C of water of 8 times of quality, bath foam pH is adjusted 3.5 with formic acid, impregnates 1h.
(2) it is de- dry that the complete silk of wetting will be impregnated, be put into the concentration of 5 times of quality as the bath foam of the Cyanuric Chloride of 20g/L
In, and JFC0.2% (in terms of bath foam quality) and sodium bicarbonate 0.2% (in terms of bath foam quality) is added, 1h is impregnated, quality is then used
The pH value of bath foam is adjusted and is stablized 8.0 by 15% soda ash solution of concentration, and bath foam is warming up to 60 DEG C and keeps 4h.
(3) the pile 2h at 20 DEG C, then naturally dry are taken off after dry silk.
Embodiment 2
The multidimensional of silk is crosslinked solid glue method, in accordance with the following steps:
(1) silk is put into 30 DEG C of water of 10 times of quality, bath foam pH is adjusted 4.5 with acetic acid, impregnates 1.5h.
(2) it will impregnate and soak that complete silk is de- dry, be put into 4 times of quality (quality of bath foam be silk quality 4 times)
In the bath foam of p- (4, the 6- bis- chloro-1,3,5-triazines -2- amino) benzene sulfonic acid sodium salt of concentration 50g/L, and be added JFC0.15% (with
Bath foam quality meter) and sodium bicarbonate 0.15% (in terms of bath foam quality), 2h is impregnated, 20% soda ash solution of mass concentration is then used
The pH value of bath foam is adjusted and is stablized 9.5, bath foam is warming up to 70 DEG C and keeps 2h.
(3) the pile 6h at 25 DEG C is taken off after dry (washing machine is de- dry) silk, then is baked at 100 DEG C dry.
Embodiment 3
The multidimensional of silk is crosslinked solid glue method, in accordance with the following steps:
(1) silk is put into 40 DEG C of water of 9 times of quality, bath foam pH is adjusted 5.0 with formic acid, impregnates 2h.
(2) will impregnate and soak that complete silk is de- dry, be put into the concentration 60g/L of 6 times of quality it is p- (4,6- bis- chloro- 1,3,
5- triazine -2- amino) sodium benzoate bath foam in, and be added JFC0.25% (in terms of bath foam quality) and sodium bicarbonate 0.25% (with
Bath foam quality meter), 2h is impregnated, then the pH value of bath foam is adjusted with 10% soda ash solution of mass concentration and is stablized 11,
Bath foam is warming up to 65 DEG C and keeps 3h.
(3) the pile 8h at 30 DEG C is taken off after dry silk, then is baked at 110 DEG C dry.
Embodiment 4
The multidimensional of silk is crosslinked solid glue method, in accordance with the following steps:
(1) silk is put into 35 DEG C of water of 10 times of quality, bath foam pH is adjusted 6 with lactic acid, impregnates 1h.
(2) will impregnate and soak that complete silk is de- dry, be put into the concentration 55g/L of 5 times of quality it is p- (4,6- bis- chloro- 1,3,
5- triazine -2- oxygroup) benzene sulfonic acid sodium salt bath foam in, and be added JFC0.2% (in terms of bath foam quality) and sodium bicarbonate 0.25% (with
Bath foam quality meter), 1.5h is impregnated, then the pH value of bath foam is adjusted and stablized with 20% soda ash solution of mass concentration
10, bath foam is warming up to 80 DEG C and keeps 2h.
(3) the pile 10h at 25 DEG C is taken off after dry silk, then is baked at 120 DEG C dry.
Embodiment 5
The multidimensional of silk is crosslinked solid glue method, in accordance with the following steps:
(1) silk is put into 45 DEG C of water of 9 times of quality, bath foam pH is adjusted 5.0 with acetic acid, impregnates 2h.
(2) will impregnate and soak that complete silk is de- dry, be put into the concentration 50g/L of 5 times of quality it is p- (4,6- bis- chloro- 1,3,
5- triazine -2- oxygroup) sodium benzoate bath foam in, and JFC0.2% (in terms of bath foam quality) and sodium bicarbonate 0.2% is added (with bath
Liquid quality meter), 1.5h is impregnated, then the pH value of bath foam is adjusted with the soda ash solution of mass concentration 15% and is stablized 9.0, it will
Bath foam is warming up to 75 DEG C and keeps 3h.
(3) the pile 4h at 25 DEG C is taken off after dry silk, then is baked at 100 DEG C dry.
Embodiment 6
The multidimensional of silk is crosslinked solid glue method, in accordance with the following steps:
(1) silk is put into 20 DEG C of water of 8 times of quality, bath foam pH is adjusted 4.0 with lactic acid, impregnates 1h.
(2) it is de- dry that the complete silk of wetting will be impregnated, be put into the TWS bath foam of the concentration 40g/L of 5 times of quality, and be added
JFC0.2% (in terms of bath foam quality) and sodium bicarbonate 0.2% (in terms of bath foam quality) impregnate 2h, then dense with quality within 4h
The pH value of bath foam is gradually adjusted and is stablized 8.5 by 15% soda ash solution of degree, and bath foam is warming up to 65 DEG C and keeps 4h.
(3) the pile 4h at 30 DEG C, then naturally dry again are taken off after dry silk.
The present invention is not limited to the above embodiment, it will be understood by those skilled in the art that: do not departing from the present invention
Principle and objective in the case where a variety of change, modification, replacement and modification, the scope of the present invention can be carried out to these embodiments
It is defined by the claims and their equivalents.
Claims (9)
1. the multidimensional of silk a kind of is crosslinked solid glue method, it is characterised in that: Sericin Gumming finishing agent used be Cyanuric Chloride or
Cyanuric chloride derivant or the not pickling chrome-free tanning agent TWS of Sichuan Ting Jiang new material limited liability company production.
2. the multidimensional of silk is crosslinked solid glue method according to claim 1, it is characterised in that: the cyanuric chloride derivant is
P- (the chloro- 1,3,5- triazine -2- amino of 4,6- bis-) benzene sulfonic acid sodium salt, p- (the chloro- 1,3,5- triazine -2- amino of 4,6- bis-) benzoic acid
Sodium, p- (the chloro- 1,3,5- triazine -2- oxygroup of 4,6- bis-) benzene sulfonic acid sodium salt and p- (the chloro- 1,3,5- triazine -2- oxygroup of 4,6- bis-) benzene
One of sodium formate.
3. the multidimensional of silk according to claim 1 or claim 2 is crosslinked solid glue method, which is characterized in that operate in accordance with the following steps:
(1) silk is put into 20-45 DEG C of water, bath foam pH is adjusted in 3.5-6.0 with organic acid, sufficiently impregnates wetting；
(2) it is de- dry that the complete silk of wetting will be impregnated, the concentration of 4-6 times of quality is put into and is arranged for the Sericin Gumming of 20-60g/L
In agent bath foam, and bleeding agent and sodium bicarbonate is added, it is subsequent to incite somebody to action after impregnating 1-2h, then with lye adjusting pH value between 8-11
Bath foam is warming up to 60-80 DEG C of insulation reactions；
(3) after having reacted, dry silk, and 2-12h of pile at 20-30 DEG C are taken off, then bakes dry or nature at 100-120 DEG C
It dries.
4. according to claim 3 silk multidimensional be crosslinked solid glue method, it is characterised in that: the organic acid be formic acid,
One of acetic acid or lactic acid.
5. the multidimensional of silk is crosslinked solid glue method according to claim 4, it is characterised in that: the bleeding agent is JFC.
6. the multidimensional of silk is crosslinked solid glue method according to claim 5, it is characterised in that: in step (1), the amount of water is silkworm
8-10 times of yarn quality, soaking time 1-2h.
7. the multidimensional of silk is crosslinked solid glue method according to claim 6, it is characterised in that: in step (2), the addition of JFC
Amount is the 0.15-0.25% of bath foam quality；The additional amount of sodium bicarbonate is the 0.15-0.25% of bath foam quality.
8. the multidimensional of silk is crosslinked solid glue method according to claim 7, it is characterised in that: lye is quality in step (2)
Concentration is the sodium carbonate liquor of 10-20%.
9. the multidimensional of silk is crosslinked solid glue method according to claim 8, it is characterised in that: in step (2) when insulation reaction
Between be 2-4h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910373704.6A CN110055756B (en) | 2019-05-07 | 2019-05-07 | Multi-dimensional crosslinking glue fixing method for silk |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910373704.6A CN110055756B (en) | 2019-05-07 | 2019-05-07 | Multi-dimensional crosslinking glue fixing method for silk |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110055756A true CN110055756A (en) | 2019-07-26 |
| CN110055756B CN110055756B (en) | 2022-02-18 |
Family
ID=67322334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910373704.6A Active CN110055756B (en) | 2019-05-07 | 2019-05-07 | Multi-dimensional crosslinking glue fixing method for silk |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110055756B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111335028A (en) * | 2020-03-27 | 2020-06-26 | 席敏皓 | Glue-fixing production method for steam filature |
| CN113463386A (en) * | 2021-08-18 | 2021-10-01 | 浙江丝绸科技有限公司 | Machine-washable gray-damage-proof real silk or silk-containing fabric |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04202855A (en) * | 1990-11-30 | 1992-07-23 | Seiren Co Ltd | Modifying processing of synthetic yarn |
| CN1072741A (en) * | 1991-11-30 | 1993-06-02 | 浙江丝绸工学院 | A kind of processing technology of short-fibre silk of cocoon garment |
| WO1999007934A1 (en) * | 1997-08-07 | 1999-02-18 | Kanehisa Inc. | Method of production of woven/knitted fabrics using sericin fixation yarn and woven/knitted fabric produced by the method |
| JP2002302874A (en) * | 2001-03-30 | 2002-10-18 | Kanehisa:Kk | Method for reforming and finishing fiber material by utilizing silk protein |
| CN102558078A (en) * | 2011-12-27 | 2012-07-11 | 苏州大学 | Cyanuric chloride derivative as well as preparation method and application in anti-wrinkle finishing agent of cyanuric chloride derivative and finishing method of pure silk fabric |
| CN104195819A (en) * | 2014-08-06 | 2014-12-10 | 浙江理工大学 | Natural silk anti-crease agent and preparation method and application thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4202855B2 (en) * | 2003-07-25 | 2008-12-24 | 株式会社日立メディコ | Magnetic resonance imaging system |
-
2019
- 2019-05-07 CN CN201910373704.6A patent/CN110055756B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04202855A (en) * | 1990-11-30 | 1992-07-23 | Seiren Co Ltd | Modifying processing of synthetic yarn |
| CN1072741A (en) * | 1991-11-30 | 1993-06-02 | 浙江丝绸工学院 | A kind of processing technology of short-fibre silk of cocoon garment |
| WO1999007934A1 (en) * | 1997-08-07 | 1999-02-18 | Kanehisa Inc. | Method of production of woven/knitted fabrics using sericin fixation yarn and woven/knitted fabric produced by the method |
| JP2002302874A (en) * | 2001-03-30 | 2002-10-18 | Kanehisa:Kk | Method for reforming and finishing fiber material by utilizing silk protein |
| CN102558078A (en) * | 2011-12-27 | 2012-07-11 | 苏州大学 | Cyanuric chloride derivative as well as preparation method and application in anti-wrinkle finishing agent of cyanuric chloride derivative and finishing method of pure silk fabric |
| CN104195819A (en) * | 2014-08-06 | 2014-12-10 | 浙江理工大学 | Natural silk anti-crease agent and preparation method and application thereof |
Non-Patent Citations (5)
| Title |
|---|
| 俞力栋 等: ""对-(4,6-二氯-1,3,5-三嗪-2-氧基)苯磺酸钠的合成及其鞣革性能"", 《精细化工》 * |
| 刘今强 等: ""三官能团交联剂对蚕丝丝胶的固着"", 《纺织学报》 * |
| 刘今强 等: ""二氯均三嗪活性染料对蚕丝丝胶的固着作用"，刘今强 等，《浙江丝绸工学院学报》，第11卷，第1期，第24-28页", 《浙江丝绸工学院学报》 * |
| 李朝辉 等: ""黄牛汽车座垫革不浸酸白鞣工艺探讨"", 《皮革与化工》 * |
| 汪钊: ""醛类化合物对蚕丝的化学改性及其对丝纤维特性的影响研究"，汪钊，《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》，第 11 期，第B024-18页", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111335028A (en) * | 2020-03-27 | 2020-06-26 | 席敏皓 | Glue-fixing production method for steam filature |
| CN111335028B (en) * | 2020-03-27 | 2022-09-27 | 席敏皓 | Glue-fixing production method for steam filature |
| CN113463386A (en) * | 2021-08-18 | 2021-10-01 | 浙江丝绸科技有限公司 | Machine-washable gray-damage-proof real silk or silk-containing fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110055756B (en) | 2022-02-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104695239B (en) | A kind of colouring method of aramid fiber | |
| CN103998660B (en) | The technique for improving yarn weavability | |
| CN101871167B (en) | Preparation method of antibacterial cellulose fabric | |
| JPS60134080A (en) | Improvement in dyeability of fiber material, cationic fiber reactive product and its producton | |
| CN104727165A (en) | Process of dyeing silk fabric | |
| CN110055756A (en) | The multidimensional of silk is crosslinked solid glue method | |
| CN104746365A (en) | Salt-free dyeing process for natural silk fabric | |
| CN113355914B (en) | Lignin-containing wool fabric shrink-proof finishing liquid and preparation method and application thereof | |
| CN104762828A (en) | Direct dyeing process for chemical fiber | |
| US20230071562A1 (en) | Pad-dry cationization of textiles | |
| EP1612323B1 (en) | Method for modifying fibers and modified fibers | |
| SU1035108A1 (en) | Method for dyeing materials from cellulose fibers with anionic dyes | |
| CN103703180A (en) | Binder and process for producing fabrics containing cyclodextrins fixed by the binder | |
| CN105544202A (en) | Method for improving hygienic property and dyeing property of polyamide superfine fiber synthetic leather | |
| US20230089849A1 (en) | Pad-steam cationization of textiles | |
| JP4089083B2 (en) | Antibacterial fiber structure | |
| CN107151922A (en) | A kind of mill flower process of Waterproof Breathable type pure cotton cloth | |
| JPS5940957B2 (en) | Surface treatment method for dyed cationized cellulose fibers | |
| Gopalakrishnan et al. | Low impact reactive dyeing methods for cotton for sustainable manufacturing | |
| CN115821606B (en) | Auxiliary agent for improving wet rubbing fastness of indigo jean, preparation method and dyeing process thereof | |
| US2442973A (en) | Treatment of textile material with alkaline cellulose zincate solutions | |
| JPH07300772A (en) | Method for processing silk fibroin | |
| CN111335028B (en) | Glue-fixing production method for steam filature | |
| JPH11158785A (en) | Dyeing method | |
| JPH10212671A (en) | Cellulosic fiber and crosslinking modification of structural material of the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |