CN110055751A - A kind of microorganism method of modifying of nano coating - Google Patents
A kind of microorganism method of modifying of nano coating Download PDFInfo
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- CN110055751A CN110055751A CN201910400969.0A CN201910400969A CN110055751A CN 110055751 A CN110055751 A CN 110055751A CN 201910400969 A CN201910400969 A CN 201910400969A CN 110055751 A CN110055751 A CN 110055751A
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/02—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined wedge-like or resilient
- A43B17/03—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined wedge-like or resilient filled with a gas, e.g. air
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/08—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined ventilated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/01—Stain or soil resistance
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of microorganism method of modifying of nano coating, shoe insole surface is immersed in 15min in the nano coating liquid that embodiment 1 obtains, bath raio 50:1, second dipping and rolling with cotton fabric respectively at room temperature, liquid carrying rate is 75%, then 50 degrees Celsius of lower prebake 30min；Then it is modified to carry out microorganism: the inventors discovered that Oenococcus Oeni can mildly be modified the nano coating, the modified wearability that can increase coating is suitble to the application of sole insole.
Description
Technical field
The present invention relates to a kind of microorganism method of modifying of nano coating, belong to field of new materials.
Background technique
Insole kind is various at present, pattern multiplicity, but in terms of its tectonic sieving in place of Shortcomings, for example has a single function, only
It is simply to play used in pad shoes, does not have any effect for deodorization, the cooling sweat etc. that disappears, outdoors movement aspect, in shoe body
Portion cooling disappear sweat effect be even more important, it is therefore necessary to pass in and out further investigation and exploitation in this respect, for formulate industry standard establish
Fixed basis.
Earlier application of the invention provide one kind can accelerate shoes inner air and outer air circulation, and have great deodorization, cooling disappear
The insole of sweat function, used technical solution is: the present invention includes insole body and air circulation system composition, and feature exists
In being connected with an air bag in: insole body and air circulation system integrally connected, the heel of insole body, air bag passes through tracheae and shoes
The stomata of pad front is connected；The air circulation system connects stomata by tracheae by air bag and constitutes；Before the insole body
Stomata is offered above portion.Generally namely insole followed by place in be arranged an air bag, in the front upper of insole
Stomata is offered, is connected between air bag and stomata by tracheae, when insole is placed in shoes in use, when heel lands, air bag
It is squeezed, the air in air bag can be discharged by tracheae by the stomata of insole front upper, be reached by rising and falling for foot
Air bag circulating exhaust, to achieve the purpose that air circulation；Do not stop ringing due to air, deodorization, cooling may be implemented
Disappear sweat function；Manufacturing the insole can be integrally formed, and keep insole durable.
Once someone used atomic deposition technique, prepared one layer of ferrous oxide on silk surface, which has certain
Hydrophobicity, the contact angle of water droplet is up to 120 degree.
The present invention further improves the material of insole, keeps its hydrophobic effect good, bears dirty, and pro-skin is comfortable, environmental protection drop
Temperature.
Summary of the invention
The object of the present invention is to provide a kind of environmental-protecting material air circulation insoles.
The present invention includes insole body 3 and air circulation system composition, it is characterised in that: insole body 3 and air circulation system
Integrally connected, an air bag 1 is connected in the heel of insole body 3, and air bag 1 passes through 4 phase of stomata of tracheae 2 and 3 front of insole body
Connection；The air circulation system connects stomata 4 by tracheae 2 by air bag 1 and constitutes；It is offered above 3 front of insole body
Stomata 4.The present invention insole followed by place in be arranged an air bag, offer stomata, air bag and gas in the front upper of insole
It is connected between hole by tracheae, when insole is placed in shoes in use, when heel lands, air bag is squeezed, can will be in air bag
Air by tracheae by insole front upper stomata be discharged, air bag circulating exhaust is reached by rising and falling for foot, to reach
To the purpose of air circulation；Do not stop ringing due to air, deodorization may be implemented, cool down the sweat function that disappears；Manufacturing should
Insole can be integrally formed, and keep insole durable.
Coating fabric is a kind of fabric handled through special process.It is exactly to utilize solvent or water by required coating micelle
(having PU glue, A/C glue, PVC, PE glue) etc. is dissolved into salivation shape, then (cylinder, scraper or roller) uniformly applies in one way
(there are cotton, terylene, the substrates such as polyamide fibre) on common cloth, then using natural evaporation or the fixation of oven temperature, makes
Web surface forms one layer of uniform covering sizing material.
It is briefly exactly coating fabric is that coating has been added on the basis of former fabric to increase the waterproof of fabric, anti-
The functions such as fire, radix saposhnikoviae, anticorrosion, antifouling.This clothes is brighter than general clothes for beauty.After washing
The problem of falling can trust greatly.Only pay attention to when washing washing machine revolving speed hand washing if Yong not be too big strength can
With.There are many kinds of certain coatings, and what is had can allow ventilative cloth to become airtight, and some PU coatings can allow bad cloth of breathing freely
Become ventilative.
Nanometer is a kind of chemical treatment method based on nano material, nano coating cloth be with a kind of special physics and
Chemical treatment method incorporates nano raw material in face liber, to form protective layer on common fabric, increases and promoted face
The functions such as the Water-proof and oil-proof of material, antifouling, ventilative, antibacterial, environmentally friendly, fixation, can be widely applied to clothes, household textiles and
Industrial textile.
The present invention is directed to further be optimized to the material of insole, it is modified with nano coating.
Products characteristics after nanotechnology treatments:
Waterproof: untreated fabric waterproof characteristic index is 1 (completely drenched), and treated fire resistance characteristic index
For 5 (not bedewing).
Grease proofing: the grease proofing characteristic index of untreated fabric is 0, and treated grease proofing characteristic index is 6 (high
For 8).
Antifouling: the fabric after nanotechnology treatments, having in spot attachment obviously reduces.
Environmental protection: completely qualified under the requirement of all environmental protection indexs by the fabric of nanotechnology treatments.
It is ventilative: to be no more than 20% in the reduction of ventilative aspect, air permeability effect is significantly larger than other coating treatments.
Do not change sense of touch: by the fabric of nanotechnology treatments, not generating perceptible change in terms of sense of touch.
Economy and durability: tensile properties and antiwear characteristic are all significantly improved.
It is not easy to change: can to keep for a long time bright in luster, as bright as new.
It is non-toxic: any toxic reaction is not present.
It is odorless: any Additional odor is not present.
Nano coating fabric function is excellent
The common characteristic of nano coating fabric, hydrophobic oleophobic, antifouling easy cleaning, the behind of these professional terms is all said in fact
Clear a reason --- saving worry, it is dirty not to be afraid of, and wilfulness is arbitrarily worn.It will form small water on liquid splash to nano coating fabric clothing
Pearl slides, without permeating fabric；Spot dust runs into nano coating fabric clothing, is equally not easy to be adhered, even if having spot not
It is careful to make clothes dirty, also easily clean.
It is modified that the present invention carries out nano coating to shoe insole surface.
Coating solution of the present invention the preparation method is as follows:
The present invention uses tetraethyl orthosilicate for silicon source, prepares Nano particles of silicon dioxide using sol-gal process.Pass through
The pH-value for adjusting reaction process controls reaction process；It is a discovery of the invention that aqueous trehalose is added and keeps certain temperature,
Not needing ultrasonic treatment can be obtained the silicon dioxide granule of uniform particle sizes.
The coating solution the preparation method is as follows:
(1) 10ml methanol is uniformly mixed with the ammonium hydroxide of 10ml 0.05mol/L, is made each at mixed solution 1；By the positive silicon of 6ml
Acetoacetic ester and 10ml methanol after mixing, are prepared into mixed solution 2；The seaweed of the 10g/L of 2ml is added in mixed solution 1
Solution 1 is slowly added into solution 2 by sugar juice under stirring conditions, is kept for 25 degrees Celsius of constant temperature 15 minutes；It adds
The hydrochloric acid of 5ml 0.2mol/L, after stirring 15min, after the ammonium hydroxide for being 30% with concentration adjusting pH value is 9, mixed solution becomes solidifying
It is gluey；
(2) after evenly mixing by 8ml hexamethyldisilazane and 80ml n-hexane, the gel that step (1) obtains is added,
It is heated reactionization 10 hours under 80 degrees Celsius, is prepared into hydrophobization gel, reuse n-hexane and after normal propyl alcohol ingeniously washs 3 times,
The gel purified；
(3) 30ml normal propyl alcohol is added in the gel that step (2) obtain, is uniformly mixed, added and 90ml is being added just
Heptane after 0 degree Celsius of lower natural subsidence 48h, separates upper liquid, the soybean protein that 1ml 10g/L is added is molten after mixing evenly
Liquid stirs evenly, and obtains nano coating liquid.
Shoe insole surface is immersed in 15min in the nano coating liquid that embodiment 1 obtains with cotton fabric respectively at room temperature, is bathed
Than for 50:1, second dipping and rolling, liquid carrying rate 75%, then 50 degrees Celsius of lower prebake 30min；
Then it is modified to carry out microorganism:
The inventors discovered that Oenococcus Oeni can mildly be modified the nano coating, it is modified to increase coating
Wearability is suitble to the application of sole insole.
Oenococcus Oeni is nontoxic, through detecting, due to fermentation medium (i.e. nano coating liquid) and may be not suitable for, in sprinkling bacterium
Reaction is just automatically stopped after liquid after 10min, it is subsequent to be inactivated automatically in processing and drying course in methanol solution.
After prebake, it is modified to carry out Oenococcus Oeni:
Oenococcus Oeni commercially available can obtain.
Oenococcus Oeni is prepared into 106The bacterium solution of CFU/ml on the fabric after bacterium solution to be uniformly sprayed on to prebake, is kept
37 degrees Celsius, handle 10min；
Fabric is put into again in 75% methanol solution and handles 10min, taken out and dry 30min under 50 degrees Celsius of fabric, most
Washing is dried afterwards, obtains coating fabric not soluble in water.
Detailed description of the invention:
Fig. 1 is Shoe-pad structure simplified schematic diagram of the present invention.
Fig. 2 is the film stereoscan photograph that coating solution of the present invention is formed.
Fig. 3 is the electron-microscope scanning figure after microorganism of the present invention is coating modified.
Fig. 4 is the electron-microscope scanning figure without microorganism after coating modified.
Specific embodiment
The embodiment of the present invention is described below in detail, described the examples are only for explaining the invention, and should not be understood as pair
Limitation of the invention.
Specific embodiments of the present invention are as described below.
Embodiment 1 prepares nano coating liquid
The present invention includes insole body 3 and air circulation system composition, it is characterised in that: insole body 3 and air circulation system
Integrally connected, an air bag 1 is connected in the heel of insole body 3, and air bag 1 passes through 4 phase of stomata of tracheae 2 and 3 front of insole body
Connection；The air circulation system connects stomata 4 by tracheae 2 by air bag 1 and constitutes；It is offered above 3 front of insole body
Stomata 4.The present invention insole followed by place in be arranged an air bag, offer stomata, air bag and gas in the front upper of insole
It is connected between hole by tracheae, when insole is placed in shoes in use, when heel lands, air bag is squeezed, can will be in air bag
Air by tracheae by insole front upper stomata be discharged, air bag circulating exhaust is reached by rising and falling for foot, to reach
To the purpose of air circulation；Do not stop ringing due to air, deodorization may be implemented, cool down the sweat function that disappears；Manufacturing should
Insole can be integrally formed, and keep insole durable.
It is modified that the present invention carries out nano coating to shoe insole surface.
The present invention uses tetraethyl orthosilicate for silicon source, prepares Nano particles of silicon dioxide using sol-gal process.Pass through
The pH-value for adjusting reaction process controls reaction process；It is a discovery of the invention that aqueous trehalose is added and keeps certain temperature,
Not needing ultrasonic treatment can be obtained the silicon dioxide granule of uniform particle sizes.
The coating solution the preparation method is as follows:
(1) 10ml methanol is uniformly mixed with the ammonium hydroxide of 10ml 0.05mol/L, is made each at mixed solution 1；By the positive silicon of 6ml
Acetoacetic ester and 10ml methanol after mixing, are prepared into mixed solution 2；The seaweed of the 10g/L of 2ml is added in mixed solution 1
Solution 1 is slowly added into solution 2 by sugar juice under stirring conditions, is kept for 25 degrees Celsius of constant temperature 15 minutes；It adds
The hydrochloric acid of 5ml 0.2mol/L, after stirring 15min, after the ammonium hydroxide for being 30% with concentration adjusting pH value is 9, mixed solution becomes solidifying
It is gluey；
(2) after evenly mixing by 8ml hexamethyldisilazane and 80ml n-hexane, the gel that step (1) obtains is added,
It is heated reactionization 10 hours under 80 degrees Celsius, is prepared into hydrophobization gel, reuse n-hexane and after normal propyl alcohol ingeniously washs 3 times,
The gel purified；
(3) 30ml normal propyl alcohol is added in the gel that step (2) obtain, is uniformly mixed, added and 90ml is being added just
Heptane after 0 degree Celsius of lower natural subsidence 48h, separates upper liquid, the soybean protein that 1ml 10g/L is added is molten after mixing evenly
Liquid stirs evenly, and obtains nano coating liquid.
The film stereoscan photograph that coating solution of the present invention is formed is as shown in Fig. 2.
2 dip-coating shoe pad fabric of embodiment is modified
Shoe insole surface is immersed in 15min in the nano coating liquid that embodiment 1 obtains with cotton fabric at room temperature, bath raio is
50:1, second dipping and rolling, liquid carrying rate 75%, then 50 degrees Celsius of lower prebake 30min；
Then it is modified to carry out microorganism:
The inventors discovered that Oenococcus Oeni can mildly be modified the nano coating, it is modified to increase coating
Wearability is suitble to the application of sole insole.
Oenococcus Oeni is nontoxic, through detecting, due to fermentation medium (i.e. nano coating liquid) and may be not suitable for, in sprinkling bacterium
Reaction is just automatically stopped after liquid after 10min, it is subsequent to be inactivated automatically in processing and drying course in methanol solution.
After prebake, it is modified to carry out Oenococcus Oeni:
Oenococcus Oeni commercially available can obtain.
Oenococcus Oeni is prepared into 106The bacterium solution of CFU/ml on the fabric after bacterium solution to be uniformly sprayed on to prebake, is kept
37 degrees Celsius, handle 10min；
Fabric is put into again in 75% methanol solution and handles 10min, taken out and dry 30min under 50 degrees Celsius of fabric, most
Washing is dried afterwards, obtains coating fabric not soluble in water.
More coarse coating is obtained, electron-microscope scanning figure is as shown in Figure 3.
Comparative example is modified without using microorganism:
Cotton fabric is immersed in 15min in the nano coating liquid that embodiment 1 obtains, bath raio 50:1 respectively at room temperature,
Second dipping and rolling, liquid carrying rate 75%, then 50 degrees Celsius of lower prebake 30min；Fabric is put into again in 75% methanol solution
10min is handled, takes out and dries 30min under 50 degrees Celsius of fabric, finally washing is dried, and obtains coating fabric not soluble in water.
More smooth coating is obtained, electron-microscope scanning figure is as shown in Figure 4.
As it can be seen that microorganism is modified, the pattern of coating becomes more coarse.
Hydrophobic performance is characterized:
The modified static contact angle (°) of microorganism: 167；
The static contact angle (°) of comparative example: 150；
It can be seen that modified hydrophobicity increases.
The mechanical performance of nano coating is always a problem in wetting field.
After shoe insole surface after coating treatment does straight reciprocating motion on 1500 mesh sand paper with cotton fabric weight bearing 600g, fortune
After dynamic 300cm, fabric starts breakage occur, at this time:
The modified static contact angle (°) of microorganism: 160；
The static contact angle (°) of comparative example: 128.
As it can be seen that microorganism is modified, the abrasion-resistance of nano coating is greatly improved, and is very suitable for the use of insole.
It should be noted that the foregoing is merely preferred specific embodiment of the invention, if conception under this invention institute
It changes, the function generated, it, should all be within the scope of the invention when the spirit still covered without departing from specification.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show
The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example
Point is included at least one embodiment or example of the invention.In the present specification, schematic expression of the above terms are not
Centainly refer to identical embodiment or example.Moreover, particular features, structures, materials, or characteristics described can be any
One or more embodiment or examples in can be combined in any suitable manner.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that: not
A variety of change, modification, replacement and modification can be carried out to these embodiments in the case where being detached from the principle of the present invention and objective, this
The range of invention is defined by the claims and their equivalents.
Claims (5)
1. a kind of microorganism method of modifying of nano coating, it is characterised in that:
Shoe insole surface is coated by cotton fabric, and shoe insole surface is immersed in 15min in nano coating liquid with cotton fabric at room temperature, bath
Than for 50:1, second dipping and rolling, liquid carrying rate 75%, then 50 degrees Celsius of lower prebake 30min；Then the micro- life of Oenococcus Oeni is carried out
Object is modified.
2. method described in claim 1, it is characterised in that:
The nano coating liquid the preparation method is as follows:
(1) 10ml methanol is uniformly mixed with the ammonium hydroxide of 10ml0.05mol/L, is made each at mixed solution 1；By the positive silicic acid second of 6ml
Ester and 10ml methanol after mixing, are prepared into mixed solution 2；The trehalose that the 10g/L of 2ml is added in mixed solution 1 is molten
Solution 1 is slowly added into solution 2 by liquid under stirring conditions, is kept for 25 degrees Celsius of constant temperature 15 minutes；It adds
The hydrochloric acid of 5ml0.2mol/L, after stirring 15min, after the ammonium hydroxide for being 30% with concentration adjusting pH value is 9, mixed solution becomes solidifying
It is gluey；
(2) after evenly mixing by 8ml hexamethyldisilazane and 80ml n-hexane, the gel that step (1) obtains is added, is taken the photograph 80
It is heated reactionization 10 hours under family name's degree, is prepared into hydrophobization gel, reuse n-hexane and after normal propyl alcohol ingeniously washs 3 times, obtained
The gel of purifying；
(3) 30ml normal propyl alcohol is added in the gel that step (2) obtain, is uniformly mixed, added and 90ml normal heptane is added,
After mixing evenly, after 0 degree Celsius of lower natural subsidence 48h, upper liquid is separated, the soy bean proteinous soln stirring of 1ml10g/L is added
Uniformly, nano coating liquid is obtained.
Shoe insole surface is immersed in 15min in the nano coating liquid that embodiment 1 obtains with cotton fabric respectively at room temperature, bath raio is
50:1, second dipping and rolling, liquid carrying rate 75%, then 50 degrees Celsius of lower prebake 30min.
3. method as claimed in claim 2, it is characterised in that:
Nano coating carries out the modified step of microorganism:
Oenococcus Oeni is prepared into bacterium solution, is handled on the fabric after bacterium solution to be uniformly sprayed on to prebake；
Fabric is put into again in 75% methanol solution and handles 10min, taken out and dry 30min, last water under 50 degrees Celsius of fabric
It washes and dries, obtain coating fabric not soluble in water.
4. method as claimed in claim 3, it is characterised in that:
The Oenococcus Oeni is prepared into 106The bacterium solution of CFU/ml.
5. method as claimed in claim 4, it is characterised in that:
It on fabric after bacterium solution to be uniformly sprayed on to prebake, is kept for 37 degrees Celsius, handles 10min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910400969.0A CN110055751B (en) | 2019-05-15 | 2019-05-15 | Microbial modified air circulation insole with nano coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910400969.0A CN110055751B (en) | 2019-05-15 | 2019-05-15 | Microbial modified air circulation insole with nano coating |
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| CN110055751A true CN110055751A (en) | 2019-07-26 |
| CN110055751B CN110055751B (en) | 2020-05-19 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201365604Y (en) * | 2008-12-24 | 2009-12-23 | 瞿成圣 | Nano breathing insole |
| CN102953268A (en) * | 2012-11-02 | 2013-03-06 | 陕西科技大学 | Super oleophilic and super hydrophobic oil-water separation terylene textile preparation method |
| CN103478986A (en) * | 2013-08-20 | 2014-01-01 | 杭州希而胜体育用品有限公司 | Air circulation insole |
| CN109265745A (en) * | 2018-09-11 | 2019-01-25 | 山西山明环保科技有限公司 | A kind of modified montmorillonoid, preparation method and composite material |
-
2019
- 2019-05-15 CN CN201910400969.0A patent/CN110055751B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201365604Y (en) * | 2008-12-24 | 2009-12-23 | 瞿成圣 | Nano breathing insole |
| CN102953268A (en) * | 2012-11-02 | 2013-03-06 | 陕西科技大学 | Super oleophilic and super hydrophobic oil-water separation terylene textile preparation method |
| CN103478986A (en) * | 2013-08-20 | 2014-01-01 | 杭州希而胜体育用品有限公司 | Air circulation insole |
| CN109265745A (en) * | 2018-09-11 | 2019-01-25 | 山西山明环保科技有限公司 | A kind of modified montmorillonoid, preparation method and composite material |
Non-Patent Citations (1)
| Title |
|---|
| 李华: "《葡萄酒微生物学》", 30 September 2003 * |
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| CN110055751B (en) | 2020-05-19 |
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