CN110052112A - Odor-eating cartridge - Google Patents
Odor-eating cartridge Download PDFInfo
- Publication number
- CN110052112A CN110052112A CN201910437147.XA CN201910437147A CN110052112A CN 110052112 A CN110052112 A CN 110052112A CN 201910437147 A CN201910437147 A CN 201910437147A CN 110052112 A CN110052112 A CN 110052112A
- Authority
- CN
- China
- Prior art keywords
- particle
- odor
- eating
- tourmaline
- cartridge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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Abstract
The present invention provides a kind of odor-eating cartridges, belong to adsorbent material technical field.The odor-eating cartridge includes inhaling taste material, and the suction taste material includes cocoanut active charcoal particle, tourmaline powder, tourmaline particle etc..Tourmaline powder and tourmaline particle of the invention can discharge anion, and positively charged toxic and harmful gas (such as: ammonia, ozone, formaldehyde, benzene, bacterium) particle and electrostatic particle in neutralization chamber form neutral ligand compound;Neutral ligand compound can be adsorbed and is deposited in inner tubular micropore by cocoanut active charcoal particle;The tiny particles contents parts such as indoor sulfur dioxide, nitrogen dioxide, carbon monoxide, pellet PM10, bacterium colony remains, radon gas radioactive substance part and other indoor accelerated tests are by cocoanut active charcoal granular absorption in inner tubular micropore.Odor-eating cartridge of the invention all removes indoor toxic and harmful gas particle or particle, can be realized room air and keeps purification state for a long time.
Description
Technical field
The present invention relates to adsorbent material technical field more particularly to a kind of odor-eating cartridges.
Background technique
Relevant information shows that room air pollution is 5~10 times higher than outdoor, and up to more than 500 kinds of pollutant, room air is dirty
Dye has become the inducement of a variety of diseases, and national standard " Indoor Air Quality standards " GB/T18883-2002 makes room air
At pollution, 15 kinds of main toxic and harmful gas for endangering human health are controlled.
This 15 kinds of toxic and harmful gas substances are: sulfur dioxide: the preservative of manufacture grape wine, fruit wine bleaches paper, hair
The brightening agent of silk, straw hat, dried fruit, bean vermicelli etc. is released in room air when people use these articles.Nitrogen dioxide: main
Wanting source is burning, vehicle exhaust, lightning of fuel etc..Carbon monoxide: indoor heating, tea-urn stove with fire be it is main come
Source.Carbon dioxide: fuel combustion, culinary art, biogenic emission etc. are the main sources of indoor carbon dioxide.Ammonia: indoor ammonia is main
Source is the volatilization containing urea, the substance of ammonium hydroxide in building, fitting up, and indoor organic matter rots, and sewer returns taste etc..Ozone: stone
Change the important pollution sources that burning etc. is ozone, is the photochemical product of air middle-ultraviolet lamp irradiation nitrogen oxides, duplicator illumination
Toner cartridge also generates ozone.Formaldehyde: the working process of timber, glued board, fiberboard, density board, timber floor, furniture, wall paper, wall
Paper, carpet, paint, paper, clothes, cosmetics, anticorrosion and bactericidal agent, bonding agent etc., the aquatic food that is soaked, stifling food brighten
Deng, these products all can release formaldehyde, the foam of finishing can be discharged by heat ageing, rotten etc., even suction cigarette
The formaldehyde of 0.17mg.Benzene: synthetic dyestuffs, synthetic rubber, synthetic resin, synthetic fibers, synthesis cereal, plastics, medicine, pesticide,
Photographic film, varnish, nitrocellulose lacquer, diluent, paint stripper, lubricating oil, grease, wax, celluloid, resin, artificial leather etc. are all
Volatilize benzene;Toluene: interior decoration, the adhesive of furniture, paint, coating, woodcare paint, waterproof material diluent, fuel combustion, suction
Cigarette etc. all discharges toluene.Dimethylbenzene: adhesive, paint, wallpaper, carpet, insecticide, copying machines in interior decoration, furniture etc.
All discharge dimethylbenzene.Benzo [a] pyrene: flue gas that the burnings such as all kinds of carbon blacks and coal, petroleum generate, smoke from cigarette, in vehicle exhaust,
Unsuitable fried, barbecue in food chain, benzo [a] pyrene content is higher in smoked foods.Pellet PM10: interior can
Sucking particulate matter is mainly derived from outdoor floating dust, domestic kitchens non-complete combustion of fuel and oil smoke etc., building thermal insulation material
Asbestos long-term ageing abrasion, raising pet, animal, birds fur particle be diffused into interior, can also generate pellet,
The optimal living space of the mankind should for its pellet, be got over from the ground within 20 meters from the ground, preferably 10 meters
The diameter of nearly pellet is bigger, and the probability of human body sucking is also just smaller.It is known that the weight of toxic gas is very
It is small, mixed substantially with air, it is easy to sucked by human body, then, for our mankind, the space lived from
Ground is higher, and pellet is also bigger to the harmful effect of human body.But with the growth of human population, urban human
The height of the increase of mouth density, office and house the more is built the more high, and skyscraper is in a compact mass, and pellet is with building
Raising and increase.TVOC total volatile organism: participating in the organic compound of atmospheric photochemical reaction, and main source is: combustion
The combustion products such as coal and natural gas, the smog of smoking, heating and culinary art etc., coating, paint, adhesive, wallpaper and other decorations
Product, ink, correction fluid, office appliance, furniture, carpet, synthetic fiber curtain, household electrical appliance, the glue of footwear, fragrant toys, washing
Discharge of agent, detergent, spray, fabric softener, cosmetics, human body itself etc. can all generate volatile organic compounds.
Radon: construction material is main source of Indoor Niton, such as granite lithotome, brick sand, cement and gypsum etc.Radon gas can be with
The crack linked by cement flooring with wall, the crack on ground, the duck eye of brick cavity wall, basement or connect cellar with soil
Other contact areas of touching, cesspit and sewer, return taste etc. when water closet rushes.Total plate count: the humidity of construction material,
The humidity of air conditioner, humidifier, washing machine, vegetable sink etc. multiplies bacterium, forms colloidal sol and propagates in air, crisis food and
Water.Electrostatic: indoor many electrical equipments such as television set, computer, mobile phone, air conditioner, electric heater, hair dryer etc. use Shi Douhui
Release electrostatic;Anion in air is consumed, and keeps indoor cation relatively more, people breathe when intake to it is intracorporal compared with
More is cation, and cation is made of hydrogen ion, and when internal hydrogen ion concentration improves, the liquid such as blood will tend to acid
Property, intracorporal acidification hinders smoothly metabolism, weak cell function, accelerated ageing, immunity is caused to reduce and draw
Play various diseases.
In short, having plenty of fuel combustion can pass through caused by culinary art, smoking etc. in these indoor toxic and harmful gas
Smoke exhaust ventilator, ventilating fan, windowing etc. force exhaust method largely to exclude it;And have plenty of construction material, finishing material,
What ornament materials, furniture, carpet, curtain, household electrical appliances, clothes, tool, toy, liquid detergent etc. at every moment distributed, their properties are not
Together, producing method is different, also different to the extent of injury of people, and some endangers the eyes of people, some by skin, respiratory tract into
Enter human body, endangers the respiratory tract, internal organs, blood of people.In these toxic and harmful gas, has plenty of a kind of poisonous and harmful gas
Body generates a variety of harm, has plenty of the harm that a variety of toxic and harmful gas generate a kind of superposition.They are all poisonous and hazardous gas
Body particle or particle will carry out comprehensive treatment to them, room air made to keep pure and fresh.
The method of toxic and harmful gas includes ventilation method in existing decontamination chamber: ventilation method needs 2~3 years time could
The toxicity and peculiar smell of interior decoration are reduced, can also endlessly have new toxic and harmful gas to release in life later,
And summer air-conditioning and winter heating all influence windowing ventilation.Plant removes method: mainly grow flowers and nurse the grass absorption, utilizes photosynthesis
Part harmful substance is absorbed, at no photosynthetic night, also to absorb oxygen, releases carbon dioxide, and plant absorption
The amount of harmful substance is extremely limited, and effect is little.Eliminating smell agent removes method: mainly sprinkling air freshener, only with one kind
Fragrance taste masks peculiar smell, practical not remove toxic and harmful gas.Photoelectricity taste removal method: high energy ozone UV ultraviolet is utilized
Poisonous and harmful substance is eliminated in irradiation, but the ultraviolet light and ozone that generate all are secondary pollutions, and family is not easy to use.Anion hair
Raw device: anion generator is opened the oxygen molecule in air by transmitting high-voltage corona, allow an oxygen atom with it is poisonous and harmful
The cation particle conglomeration of gas settles, meanwhile, another oxygen atom and oxygen molecule are combined into ozone, easily cause secondary pollution.
Physisorphtion: only a part of poisonous and harmful granular absorption is arrived by putting absorption, this methods such as active carbon, suction taste stick
Active carbon is inhaled in the tubular macroporous of adsorbent materials such as taste stick, full when being adsorbed onto there is no change poisonous and harmful substance itself
When with state, desorption can be generated, the poisonous and harmful substance for being adsorbed onto activated carbon surface can be re-released into air;By applying
Be added a small amount of negative ion powder in material, neutralize the toxic and harmful gas cation particle in air, form complex compound sedimentation, bear from
Sub- powder is the artificial synthesized mixture containing rare earth element, has radioactive pollution.Adsorbed using sepiolite: sepiolite is by snake
Line rock alteration, and serpentinite is the main component of asbestos, must not recur asbestos influences the tragedy of human health;It is applying
In material be added partial electric mountain flour purify air, since tourmaline powder is transparent or semitransparent crystal, in coating it is main at
It point is lotion, water and titanium dioxide, in good coating composition, for emulsion content 50~65%, paint film just has the exquisiteness of skin
The contrast ratio of sense, the contrast ratio 92% of qualified product covering power, high-class product is greater than 96%, and needing to be added 15~20% has covering power
Titanium dioxide can just be met the requirements, so that coating composition accounting reaches 65~85%, the water for further needing exist for 15~25% will for this meeting
Titanium dioxide modulation is slurried and scatter, and tourmaline powder is added in not extra space, and tourmaline powder is transparent or semitransparent
How many titanium dioxide do not replaced without covering power for crystal grain, this additive amount that will lead to tourmaline powder is restricted, on a small quantity
Tourmaline powder radiation anion in and harmful substance, form neutral complex compound, partial size very little is suspended in the form of floating dust
The concentration of the interior space, PM10 does not reduce, so that coating is difficult to realize the purpose of indoor air purification.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of odor-eating cartridge, odor-eating cartridge provided by the invention can will be indoor
Toxic and harmful gas in air efficiently removes, and achievees the purpose that indoor air purification.
In order to achieve the above-mentioned object of the invention, the present invention the following technical schemes are provided:
The present invention provides a kind of odor-eating cartridges, including inhale taste material, packing inside bag and external packing box, the external packing box table
Face is provided with stomata;The taste material of inhaling is by including that the raw material of following weight percent is prepared: cocoanut active charcoal particle 10
~90%, tourmaline powder 5~30%, tourmaline particle 5~60%, acrylic emulsion 4~10%, water 1~4%.
Preferably, the packing inside bag is sewed by non-woven fabrics;The Unit Weight of the non-woven fabrics be 20~100 grams/
Square metre.
Preferably, the external packing box includes subiculum part and upper cover part, and the upper cover part covers on the lower supporting portion
On point.
Preferably, the partial size of the cocoanut active charcoal particle is 10~60 mesh.
Preferably, the partial size of the tourmaline particle is 10~60 mesh.
Preferably, the partial size of the tourmaline powder is 800~20000 mesh.
Preferably, the solid content of the acrylic emulsion is 50~55%.
Preferably, it is described inhale taste material preparation method the following steps are included:
After acrylic emulsion, water and tourmaline particle are mixed, tourmaline powder is added and is mixed and dried, obtains just mixing;
The just mixing is mixed with cocoanut active charcoal particle, obtains inhaling taste material.
Preferably, the mixing carries out under stirring conditions, and the revolving speed of the stirring is 50~80r/min.
The present invention provides a kind of odor-eating cartridges, including inhale taste material, packing inside bag and external packing box, the external packing box table
Face is provided with stomata;The taste material of inhaling is by including that the raw material of following weight percent is prepared: cocoanut active charcoal particle 10
~90%, tourmaline powder 5~30%, tourmaline particle 5~60%, acrylic emulsion 4~10%, water 1~4%.
Suction taste material in odor-eating cartridge of the present invention is prepared by raw materials such as tourmaline powder, tourmaline particle and cocoanut active charcoals
It obtains.Wherein tourmaline powder and tourmaline particle can discharge anion for a long time, positively charged poisonous and harmful in neutralization chamber
Gas (for example, ammonia, ozone, formaldehyde, benzene,toluene,xylene, benzo [a] pyrene, total volatile organism TVOC, bacterium) grain
Son and electrostatic particle form neutral ligand compound;And cocoanut active charcoal particle can adsorb neutral ligand compound and retain
In internal tubular macroporous, and it will not be desorbed and leave;Indoor sulfur dioxide, nitrogen dioxide, carbon monoxide, carbon dioxide,
The tiny particles contents parts such as pellet PM10, bacterium colony remains, radon gas (222Rn) radioactive substance part and other interiors
Particulate matter is adsorbed in inner tubular micropore by cocoanut active charcoal grain fraction.Odor-eating cartridge of the invention is by inhaling in taste material
Cocoanut active charcoal particle and tourmaline collective effect, indoor toxic and harmful gas particle or particle are all removed, Neng Goushi
Existing room air keeps purification state for a long time, realizes the synthesis Long term control of indoor toxic and harmful gas.
Detailed description of the invention
Fig. 1 is the perspective view of odor-eating cartridge;
Fig. 2 is the side surface part schematic diagram of odor-eating cartridge upper cover part;
Fig. 3 is the top perspective view of odor-eating cartridge subiculum part;
Fig. 4 is the perspective bottom view of odor-eating cartridge subiculum part.
Specific embodiment
The present invention provides a kind of odor-eating cartridges, including inhale taste material, packing inside bag and external packing box, the external packing box table
Face is provided with stomata;The taste material of inhaling is by including that the raw material of following weight percent is prepared: cocoanut active charcoal particle 10
~90%, tourmaline powder 5~30%, tourmaline particle 5~60%, acrylic emulsion 4~10%, water 1~4%.
In the present invention, the suction taste material is placed in packing inside bag, is placed in equipped with the packing inside bag for inhaling taste material described
In external packing box.
Odor-eating cartridge provided by the invention includes packing inside bag;The packing inside bag is preferably sewed by non-woven fabrics;It is described
The Unit Weight of non-woven fabrics is preferably 20~100 grams/m, further preferably 40~80 grams/m, more preferably 50
~60 grams/m.
Odor-eating cartridge provided by the invention includes external packing box;The external packing box surface is provided with stomata.In the present invention,
The external packing box preferably includes subiculum part and upper cover part, and the upper cover part covers on the subiculum part;The suction
The perspective view of taste box is as indicated with 1.By taking the odor-eating cartridge of cuboid as an example, in conjunction with Fig. 2, Fig. 3 and Fig. 4 to the structure of odor-eating cartridge
It is described in detail.
In the present invention, the upper cover part includes upper top and side surface part, and the upper top is not provided with stomata;On described
The side surface part schematic diagram of cover is as shown in Figure 2;Upper cover part side surface part is provided with stomata in Fig. 2.
Fig. 3 is the top perspective view of odor-eating cartridge subiculum part;Wherein 1 is backing portion, and 2 be support portion.In the present invention, institute
Stating lower supporting portion point includes support portion (in Fig. 32 shown in) and backing portion (in Fig. 31 shown in).In the present invention, the backing
The middle part protrusion in portion, raised position open up stomata;The perspective bottom view of the subiculum part in the backing portion with protrusion, such as Fig. 4 institute
Show.
In the present invention, the upper cover part of the external packing box is highly preferred consistent with subiculum part.The present invention is to institute
The shape and size for stating upper cover part and subiculum part are not specifically limited, arbitrary shape and size, as long as can make
Cover and the matching of subiculum part;In the present invention, the volume of the external packing box is preferably 0.001~1m3, further
Preferably 0.003~0.1m3, more preferably 0.005~0.01m3。
The upper top of the upper cover part of external packing box of the invention is sealing, can prevent depositing dust from falling into odor-eating cartridge,
Improve odor-eating cartridge adsorbance;And external packing box upper cover part and subiculum part be it is dismountable, replacement is equipped with inhaling taste material
Packing inside bag is easier, and can achieve the purpose that saving, environmental protection.It is commonly stored up in addition, the external packing box is also used as day
Object box or document case are used;When the external packing box is used as daily storage box or document case used time, the size of the external packing box
It is preferred that are as follows: overall dimensions are 320mm × 230mm × 80mm, interior empty having a size of 310mm × 220mm × 55mm, are greater than a packet A4 paper
Size.
Odor-eating cartridge provided by the invention includes inhaling taste material;The suction taste material is by the raw material including following weight percent
It is prepared: cocoanut active charcoal particle 10~90%, tourmaline powder 5~30%, tourmaline particle 5~60%, propylene yogurt
Liquid 4~10%, water 1~4%.
Prepare suction taste material of the invention raw material include weight percent be 10~90% cocoanut active charcoal particle, it is excellent
It is selected as 50~80%, further preferably 65~75%.In the present invention, the partial size of the cocoanut active charcoal particle is preferably 10
~60 mesh, further preferably 20~40 mesh.The present invention is not specifically limited the source of the cocoanut active charcoal particle, uses
Commercial product well known to those skilled in the art.In a specific embodiment of the present invention, the cocoanut active charcoal particle
Macropore diameter is preferably 5~10 μm, and transitional pore aperture is preferably 5000~5nm, and micropore size is preferably smaller than 2~5nm;The coconut palm
Shell active carbon inner tubular macropore diameter is slightly larger than the diameter of toxic and harmful gas particle (such as pellet PM10), can
Adsorb the biggish toxic and harmful gas of partial size;Meanwhile the transition aperture having and micropore size can adsorb having compared with small particle
Malicious pernicious gas particle, enables cocoanut active charcoal to adsorb most of toxic and harmful gas, has excellent adsorption effect.This
The further preferred cocoanut active charcoal particle with 20~40 mesh of invention, specific surface area reach 900~1700m2/ g, internal voids hair
It reaches, density is small, and the duality with physical absorption and chemisorption can adsorb the venomous injurant in gas phase and liquid phase simultaneously
Matter effectively purifies the air of a room.
The cocoanut active charcoal granular mass that the present invention uses is lighter, and specific surface area is larger, is better than stalk active carbon, such as rice
Shell charcoal or bamboo charcoal, charcoal etc., better than beast bone, blood charcoal etc., better than coaly activated carbon.Cocoanut active charcoal particle is small molecule gap
Structure, different from the macromolecular gap structure of coaly activated carbon, cocoanut active charcoal specific grain surface product is big, activity is high, micropore hair
It reaches, adsorbs floating dust and tiny toxic and harmful gas particle ability is strong.Cocoanut active charcoal particle is broken by sheet cocoanut active charcoal
It is broken to form, it is not the particle binded again after crushing, so that cocoanut active charcoal is obtained internal capillary hole and directly contacted with air, convenient for inhales
Attached floating dust and particle.
On the basis of the weight percent of cocoanut active charcoal particle, the raw material for preparing suction taste material of the invention includes weight
The tourmaline powder that percentage is 5~30%, preferably 5~20%, further preferably 6~10%.In the present invention, described
The partial size of tourmaline powder is preferably 800~20000 mesh, preferred 1250~3000 mesh.In the present invention, the tourmaline
Chemical general formula be NaR3AI6Si6O18[BO3]3(OH, F)4, mainly by SiO2、TiO2、CaO、K2O、LiO、Al2O3、B2O3、
MgO、Na2O、Fe2O3, FeO, MnO and P2O5Composition, is the rock containing combined oxygen.Tourmaline in addition to direct releasing negative oxygen ion,
Also containing the microelements such as aluminium, sodium, iron, magnesium, lithium, all it is easy to lose electronics, outermost electron detachment metallic atom, transition is electrical
The potential barrier on stone crystal surface layer is in the air, and by the oxygen in air, (since the outer-shell electron of oxygen atom is 6, the electronegativity of oxygen is very
Height, atomic radius is smaller, and the ability for obtaining electronics is stronger) it is obtained, free negative oxygen ion is formed, is directly discharged with tourmaline
Negative oxygen ion be collectively formed free negative oxygen ion, in air, the negative oxygen ion of diameter very little is under electric field action for floating
Higher migration velocity is obtained, negative oxygen ion, which can make an initiative sally, captures granule micronic dust positively charged in air.The present invention selects
Mesh number is higher, that is, the lesser tourmaline powder of partial size, is the tourmaline since the total surface area of the small unit volume of partial size is big
Crystal surface area increases, and the potential barrier on transition tourmaline crystal surface layer increases to aerial probability, and the negative ion amount of release increases,
The tourmaline anion burst size of 100 mesh is 200/cm3, the tourmaline anion burst size about 400/cm of 325 mesh3, 1250
Purpose tourmaline anion burst size is up to 800/cm3.The present invention utilizes the piezoelectric effect and pyroelectric effect of tourmaline, utilizes electricity
Gas stone can discharge the characteristic of anion, so that toxic and harmful gas and the anion of tourmaline release form complex,
To eliminate the polarity and free radical of toxic and harmful gas, it is deposited in it in inner tubular micropore of cocoanut active charcoal particle,
Loss of polarity will not be desorbed and leave, and realize effectively removing for indoor toxic and harmful gas.
On the basis of the weight percent of cocoanut active charcoal particle, the raw material for preparing suction taste material of the invention includes weight
The tourmaline particle that percentage is 5~60%, preferably 10~30%, further preferably 15~25%.In the present invention, institute
The partial size for stating tourmaline particle is preferably 10~60 mesh, further preferably 20~40 mesh.The present invention utilizes tourmaline particle energy
The characteristic for enough discharging anion, is continuously replenished in outer layer tourmaline powder shell, then be discharged into interior, so that poisonous and harmful gas
Body and the anion of tourmaline release, which form complex, makes it to eliminate the polarity and free radical of toxic and harmful gas
It is deposited in the inner tubular micropore of cocoanut active charcoal particle, and will not be desorbed and leave, realize indoor toxic and harmful gas
It effectively removes.
On the basis of the weight percent of cocoanut active charcoal particle, the raw material for preparing suction taste material of the invention includes weight
The acrylic emulsion that percentage is 4~10%, preferably 6~8%.In the present invention, the solid content of the acrylic emulsion is excellent
It is selected as 50~55%, further preferably 51~54%.The present invention is not specifically limited the source of the acrylic emulsion, adopts
With commercial product well known to those skilled in the art.In the present invention, when the acrylic emulsion forms a film, by tourmaline powder
End is adhered to the outer surface of tourmaline particle, forms shelly-shaped tourmaline particle, discharges anion.
On the basis of the weight percent of cocoanut active charcoal particle, the raw material for preparing suction taste material of the invention includes weight
The water that percentage is 1~4%, preferably 2~3%.The present invention utilizes water and acrylic emulsion collective effect, by tourmaline powder
It is adhered to tourmaline particle surface, after moisture evaporation drying forms a film, shelly-shaped tourmaline particle is formed, discharges anion.
In the present invention, the preparation method for inhaling taste material preferably includes following steps:
After acrylic emulsion, water and tourmaline particle are mixed, tourmaline powder is added and is mixed and dried, obtains just mixing;
The just mixing is mixed with cocoanut active charcoal particle, obtains inhaling taste material.
After the present invention mixes acrylic emulsion, water and tourmaline particle, tourmaline powder is added and is mixed and dried, obtains
First mixing.
In the present invention, the evaporation drying film forming, the present invention are not specifically limited evaporation drying film formation time, as long as
Can in its natural state by acrylic emulsion water and weight percent be 1~4% water evaporation drying and forming-film.
Tourmaline powder is uniformly attached to tourmaline particle outer layer by acrylic emulsion and water by the present invention, is formed electrical
The film forming shell of stone powder and acrylic emulsion composition is wrapped in tourmaline particle;When acrylic emulsion forms a film, by propylene yogurt
Moisture and additional moisture in liquid evaporate, and obtain the first mixing in drying regime.
After obtaining just mixing, the present invention mixes the just mixing with cocoanut active charcoal particle, obtains inhaling taste material.
In the present invention, preparation is inhaled mixing involved in taste materials process and is preferably carried out under stirring conditions, described
The revolving speed of stirring is preferably 50~80r/min, further preferably 60~70r/min.Mixing of the invention uniformly mixes raw material
It closes, improves the odor-absorbing energy for inhaling taste material.
Odor-eating cartridge provided by the invention can be used in the middle toxic and harmful gas that purifies the air of a room.In the present invention, described
Interior refers to the interior in this field in universal significance, the interior of forced ventilation condition specially can be achieved.
According to the production of people's actual life habit and the main toxic and harmful gas in 15 kinds of interior of current national regulation control
Raw and source mode, does three hypothesis.
Assuming that one: assuming that indoor toxic and harmful gas exceeded 30%, opens door and window ventilation, indoor air quality is made to reach state
Family's quality control standard, has new toxic and harmful gas to release in second day, and exceeded 30% again, and it is up to standard to divulge information, i.e. room
The interior toxic and harmful gas for generating 30% national quality control standard new daily.With indoor 1 square metre of area, 3 meters of clear height are calculated,
Sulfur dioxide 164.25mg, nitrogen dioxide 78.84mg, carbon monoxide 3285mg are generated within 1 year, carbon dioxide 424.75g (takes
Atmospheric density is 1.293g/L), ammonia 65.7mg, ozone 52.56mg, formaldehyde 32.85mg, benzene 36.14mg, toluene 65.7mg,
Dimethylbenzene 65.7mg, benzo [a] pyrene 328.5mg, pellet PM10 49.28mg, total volatile organism TVOC
197.1mg, annual every square metre of total generation toxic and harmful gas 429171.62mg, wherein carbon monoxide 3285mg, Zhan are always toxic
The 0.76543% of pernicious gas;The 98.96973% of the total toxic and harmful gas of carbon dioxide 424750mg, Zhan, carbon monoxide, two
The 99.73516% of the total toxic and harmful gas of carbonoxide Zhan;Other 11 toxic and harmful gas generate the substance of 1136.62mg, account for
The 0.26484% of total toxic and harmful gas;In addition, annual every square metre will also have 13.14 ten thousand Kenenisa Bekele radon 222Rn radioactivity
Atomic decay;There are 37.38 ten thousand bacteria colonies to generate unit to be formed.
Assuming that two: in view of carbon monoxide be mainly carbon-containing fuel burning generate intermediate product, such as home interior one
Caused by carbonoxide is mainly gas-cooker, culinary art, general people will use exhaust system or open the window when using gas-cooker
Ventilation, will be greatly reduced the amount retained of carbon monoxide;Caused by carbon dioxide is mainly also fuel combustion, culinary art, there are also one
Point be the mankind or biogenic emission, it is assumed that fuel combustion, culinary art etc. cause the yield of carbon monoxide, carbon dioxide, mainly by
Smoke exhaust ventilator etc. forces exhaust system or door and window ventilation discharge outdoor, the part of the mankind or biogenic emission and other interiors are toxic has
Evil gas is administered together, it is assumed that two be carbon monoxide, carbon dioxide forced discharge 90%, annual every square metre of discharge
385232mg retains 10%, annual every square metre of retention 42804mg, annual every square metre of total generation toxic and harmful gas
43941mg, the 42804mg that wherein carbon monoxide, carbon dioxide are retained account for annual every square metre total generation toxic and harmful gas
97.41%, other 11 toxic and harmful gas account for 2.59%.It is that a converting standard uses list by 100 square metres of usable floor areas
Member, it is total to generate toxic and harmful gas 2.197kg by the 5th year.
Assuming that three: cocoanut active charcoal at most adsorbable other particles less than oneself internal capillary diameter are close to or up to it
Itself quality 60%, it is contemplated that the unfavorable factors such as manufacture, construct, using, influencing the adsorption capacity of active carbon, it is assumed that press active carbon
30% measuring and calculating of sole mass is adsorbed, 100 square metres of 5 years absorption 2.197kg toxic and harmful gas particles need active carbon
7.32kg。
In short, being assumed by three above, it is assumed that the toxic of 30% part that active carbon absorbs national standard daily has
Evil gas, absorbs 5 years;Assuming that the carbon monoxide, the carbon dioxide that are generated when people's burning, culinary art it is most of by smoke exhaust ventilator, open
The part of the pressures such as window discharge, the mankind and biogenic emission is tightly held by activated carbon;Assuming that the adsorbable own wt of cocoanut active charcoal
30% toxic and harmful gas.Under assumed condition, high 100 square metres of 5 years 3 meters of layers indoor converting standard surface elemants
(300m3), need the cocoanut active charcoal of 7.32kg to adsorb the toxic and harmful gas particle or particle of 2.197kg, i.e. converting standard
Surface elemant needs 7.32kg cocoanut active charcoal, and 100 square metres of usable floor area units of converting standard need 8.13~73.2kg institute
It states suction taste material and the odor-eating cartridge poisonous and harmful gas in purifying the air of a room is realized by above hypothesis and quantum chemical method
Quantization application in body.
By assuming that quantization indoor total toxic and harmful gas particle or mass particle, the release of mating electrical stone component are negative
The total requiremants of ion, active carbon particle component absorption toxic and harmful gas particle or particle within the time of a fixed length, guarantees
Under assumed condition, within the time of a fixed length, completes to capture, toxic particle in adsorption chamber, floating dust particle, electrostatic particle, put
The amount of the total toxic and harmful gas particle of four class of penetrating property particle or particle.It realizes under assumed condition, in the time of a fixed length, needs
The total toxic and harmful gas mass particle to be adsorbed, determines the dosage of total active carbon particle component, determines that unit area is total
Suction taste material utilization amount further according to the subregion in relative closure space in unit area, the odor-eating cartridge dosage of each subregion is set, it is real
It applies distribution to put, achievees the purpose that quantify comprehensive purifying room air.
Odor-eating cartridge provided by the invention can be used for toxic and harmful gas in purification confined space.In the present invention, described
Confined space refers specifically to can not achieve force ventilated space.Odor-eating cartridge is used for confined space by the present invention, can use increasing
Add odor-eating cartridge quantity or reduce the method for the odor-eating cartridge operational support time limit, realizing that the interior of odor-eating cartridge absorption confined space is toxic has
Evil gas particle, such as it is applied to basement, tunnel, vehicle, ship, submarine confined space, purify air.
A kind of suction taste material provided by the invention and preparation method thereof and a kind of odor-eating cartridge are carried out below with reference to embodiment
Detailed description, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
By weight percentage, the suction taste material is prepared by following raw material: acrylic emulsion (solid content 52%)
6%, 20~40 mesh cocoanut active charcoal particles 70%, water 2%, 2000 mesh tourmaline powders 8%, 20~40 mesh tourmaline particles
14%.
The preparation method for inhaling taste material, comprising the following steps:
It by acrylic emulsion, water, tourmaline particle, is mixed evenly under the conditions of 60r/min, then by tourmaline powder
It is slowly added to, the graininess of dispersion is mixed evenly into, form a film to obtain just mixing in nature evaporation drying;
First mixing is uniformly mixed with cocoanut active charcoal particle, obtains inhaling taste material.
2kg is inhaled in taste material loading non-woven fabrics venting bags and is sealed, is put into external packing box;The external form of the external packing box
Having a size of 320mm × 230mm × 80mm, product is detected, is packed, is entered having a size of 310mm × 220mm × 55mm by interior sky
Library or factory mark bulk density and activated carbon content, obtain odor-eating cartridge.
Every odor-eating cartridge cocoanut active charcoal containing 1.4kg particle in the embodiment, by aforementioned 100 square metres of usable floor areas 5 years
The cocoanut active charcoal for needing 7.32kg needs six odor-eating cartridges, absorbs 2.197kg toxic and harmful gas particle, every odor-eating cartridge
Absorb 0.37kg toxic and harmful gas particle;Such as packing inside bag and external packing box weight 0.2kg, i.e. odor-eating cartridge work's weight
2.20kg, failure period are that weight reaches 2.57kg, i.e., at this time the active carbon in odor-eating cartridge close to adsorption saturation.Odor-eating cartridge uses
In skyscraper, to increase by increasing for height;Using to the interiors such as submarine, confined space, vehicle, according to there is toxic gas
The usage amount of the burst size adjustment odor-eating cartridge of body.
Comparative example 1
By weight percentage, the suction taste material is prepared by following raw material: acrylic emulsion (solid content 52%)
8%, 20~40 mesh bamboo charcoal particles 66%, water 1%, 800 mesh tourmaline powders 10%, 20~40 mesh quartz sand particles 15%.
The preparation method for inhaling taste material, comprising the following steps:
Acrylic emulsion, water and quartz sand particle are mixed evenly under the conditions of 80r/min, then by tourmaline powder
It is slowly added to, the graininess of dispersion is mixed evenly into, it is dry, obtain just mixing;
First mixing is uniformly mixed with bamboo charcoal particle, obtains inhaling taste material.
2.5kg is inhaled in taste material loading non-woven fabrics venting bags and is sealed, is put into external packing box;The external packing box and reality
It is identical to apply 1 size of example, product is detected, pack, be put in storage or is dispatched from the factory, marks bulk density and activated carbon content, obtains odor-eating cartridge.
Obtained odor-eating cartridge is lower relative to the adsorption capacity of embodiment 1;This is because specific surface area is not so good as coconut husk inside bamboo charcoal particle
Active carbon is big, and internal capillary is relatively large in diameter, and the mesh number of tourmaline is smaller, discharges the negligible amounts of anion, thus adsorption capacity compared with
Difference;But cost can reduce very much.
Comparative example 2
By weight percentage, the suction taste material is prepared by following raw material: acrylic emulsion (solid content 52%)
4%, 20~40 mesh coaly activated carbon particles 72%, water 4%, 325 mesh tourmaline powders 10%, 20~40 mesh quartz sand particles
10%.
The preparation method for inhaling taste material, comprising the following steps:
Acrylic emulsion, water and quartz sand particle are mixed evenly under the conditions of 70r/min, then by tourmaline powder
It is slowly added to, the graininess of dispersion is mixed evenly into, it is dry, obtain just mixing;
First mixing is uniformly mixed with coaly activated carbon particle, obtains inhaling taste material.
3kg is inhaled in taste material loading non-woven fabrics venting bags and is sealed, is put into external packing box;The packing box size and reality
It is identical to apply example 1;Product is detected, packed, be put in storage or is dispatched from the factory, bulk density and activated carbon content is marked, obtains odor-eating cartridge, obtain
Odor-eating cartridge it is lower relative to the adsorption capacity of embodiment 1, cost can reduce more, and such odor-eating cartridge can adsorb a large amount of drop
Dirt bulky grain makes odor-eating cartridge lose adsorption function quickly by coaly activated carbon internal capillary adsorption saturation.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (9)
1. a kind of odor-eating cartridge, including inhale taste material, packing inside bag and external packing box, which is characterized in that the external packing box surface
It is provided with stomata;The taste material of inhaling is by including that the raw material of following weight percent is prepared: cocoanut active charcoal particle 10~
90%, tourmaline powder 5~30%, tourmaline particle 5~60%, acrylic emulsion 4~10%, water 1~4%.
2. odor-eating cartridge according to claim 1, which is characterized in that the packing inside bag is sewed by non-woven fabrics;It is described
The Unit Weight of non-woven fabrics is 20~100 grams/m.
3. odor-eating cartridge according to claim 1 or 2, which is characterized in that the external packing box includes subiculum part and upper cover
Part, the upper cover part cover on the subiculum part.
4. odor-eating cartridge according to claim 1, which is characterized in that the partial size of the cocoanut active charcoal particle is 10~60
Mesh.
5. odor-eating cartridge according to claim 1, which is characterized in that the partial size of the tourmaline particle is 10~60 mesh.
6. odor-eating cartridge according to claim 1, which is characterized in that the partial size of the tourmaline powder is 800~20000
Mesh.
7. odor-eating cartridge according to claim 1, which is characterized in that the solid content of the acrylic emulsion is 50~55%.
8. odor-eating cartridge described according to claim 1 or 4 or 5 or 6 or 7, which is characterized in that the preparation method for inhaling taste material
The following steps are included:
After acrylic emulsion, water and tourmaline particle are mixed, tourmaline powder is added and is mixed and dried, obtains just mixing;
The just mixing is mixed with cocoanut active charcoal particle, obtains inhaling taste material.
9. odor-eating cartridge according to claim 8, which is characterized in that the mixing carries out under stirring conditions,
The revolving speed of the stirring is 50~80r/min.
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CN109651906A (en) * | 2018-12-26 | 2019-04-19 | 天津市朗威柏丽科技有限公司 | A kind of suction taste coating and its preparation method and application |
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CN2690822Y (en) * | 2004-01-18 | 2005-04-06 | 关君正 | Deodorizing freshness keeper for refrigerator |
CN1990385A (en) * | 2005-12-27 | 2007-07-04 | 上海沪正纳米科技有限公司 | Tourmaline nano metal oxide and preparation method thereof |
US20090065732A1 (en) * | 2007-09-11 | 2009-03-12 | Jen-Taut Yeh | Composite powder with a high efficiency of releasing anions, and its attached substance and manufacturing method |
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