CN110045058A - Hydrogen fluoride content test method in electrolyte - Google Patents
Hydrogen fluoride content test method in electrolyte Download PDFInfo
- Publication number
- CN110045058A CN110045058A CN201810045055.2A CN201810045055A CN110045058A CN 110045058 A CN110045058 A CN 110045058A CN 201810045055 A CN201810045055 A CN 201810045055A CN 110045058 A CN110045058 A CN 110045058A
- Authority
- CN
- China
- Prior art keywords
- electrolyte
- titrant
- measured
- hydrogen fluoride
- titration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/16—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using titration
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/16—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using titration
- G01N31/162—Determining the equivalent point by means of a discontinuity
- G01N31/164—Determining the equivalent point by means of a discontinuity by electrical or electrochemical means
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
Hydrogen fluoride content test method in a kind of electrolyte provided by the invention, solution is configured to as titrant using trihydroxy aminomethane (Tris) and organic solvent, the titrant is instilled in electrolyte to be measured and is titrated, hydrogen fluoride content in electrolyte to be measured is calculated by the reacting dose of Tris after judgement arrival titration end-point.Wherein titrant can be added in alcoholic solution by Tris powder or particle etc. and be formulated directly into required concentration, without adding water, will not be reacted with electrolyte and be generated additional hydrogen fluoride；And Tris alcoholic solution stable chemical performance, it is unlikely to deteriorate, it is fixed without titration advance rower every time, reduce manual operation error caused by calibration process.Test method of the present invention has the characteristics that quick, accurate, operating error is small.
Description
Technical field
The present invention relates to detection technique fields, in particular to the test method of hydrogen fluoride content in electrolyte.
Background technique
Hydrogen fluoride has very strong corrosivity in electrolyte, and content increases, capacity, cycle life and the safety of battery
It can be remarkably decreased, when its content goes beyond the limit of value, battery will be destroyed completely, therefore how accurately detect fluorine in electrolyte
Changing hydrogen content is the premise for improving battery and security performance.And existing titrant mostly uses highly basic alcoholic solution that water is added to match
System, water is reacted with electrolyte generates hydrogen fluoride, influences the accuracy of testing result.
Summary of the invention
In view of the foregoing, it is necessary to hydrogen fluoride content test method in a kind of improved electrolyte be provided, had fast
Speed, the features such as accurate, operating error is small.
Technical solution provided by the invention are as follows: hydrogen fluoride content test method in a kind of electrolyte, using trihydroxy amino
Methane (Tris- (hydroxymethyl) aminomethane, abbreviation Tris) and organic solvent are configured to solution as titration
The titrant is instilled in electrolyte to be measured and is titrated by agent, passes through the reaction meter of Tris after judgement arrival titration end-point
Calculate hydrogen fluoride content in electrolyte to be measured.
Further, the determination method of titration end-point includes being existed by electrolyte to be measured after measurement potential jump point or titration
The color of discoloration terminal is presented under indicator effect to determine.
Further, when by measurement potential jump point to determine titration end-point, comprising the following steps:
Electrolyte to be measured is packed into titration cell, the titrant is pipetted to buret, electrode is placed in electrolyte to be measured,
Start to titrate；
It is to be measured measure potential jump point after, according to the reacting dose of Tris, electrolyte quality to be measured, chemical reaction metering than meter
Calculate hydrogen fluoride content in electrolyte to be measured.
Further, when by under indicator acts on present discoloration terminal color to determine titration end-point when, including
Following steps:
Diluent is weighed, indicator is added, is uniformly mixed；
Electrolyte to be measured is instilled, is uniformly mixed, and is recorded of poor quality before and after instilling electrolyte to be measured；
The titrant is instilled, when the color for being within a certain period of time in titration end-point does not subside, terminates and titrates and record
It instills of poor quality before and after the titrant；
It is fluorinated according to the reacting dose of Tris, electrolyte quality to be measured, chemical reaction metering than calculating in electrolyte to be measured
Hydrogen content.
Further, the concentration of the titrant is 0.0003-0.5mol/L.
Further, the organic solvent is one of methanol, ethyl alcohol, isopropanol or combination.
Further, the indicator is bromthymol blue.
Further, the diluent is one of methanol, ethyl alcohol, isopropanol or combination.
It further, include the proving operation of the titrant before titration, for correcting the concentration of the titrant, specifically
Step are as follows:
The solution of known acid concentration is added in the titrant and is tested；
By measuring potential jump or indicator in the color discriminating test terminal of discoloration terminal, root after test terminal is reached
The concentration than measuring the titrant is measured according to the reacting dose of the solution, the titrant quality, chemical reaction；
Judge the measured value of the titrant concentration whether in setting range；
When measured value is in setting range, progress next step titration operation, the adjustment titrant concentration on the contrary is surveyed again
Examination.
Further, when by measurement potential jump point come discriminating test terminal, comprising the following steps:
The titrant to be measured is packed into titration cell, the solution is pipetted to buret, electrode is placed in institute to be measured
It states in titrant, starts titration test；
It is to be measured measure potential jump point after, according to the reacting dose of titrant to be measured, solution quality to be measured, chemical reaction measure
Than the concentration for obtaining the titrant.
Further, when by under indicator acts on present discoloration terminal color come discriminating test terminal when, including
Following steps:
Diluent is weighed, indicator is added, is uniformly mixed；
The titrant to be measured is instilled, is uniformly mixed, and is recorded of poor quality before and after instilling the titrant to be measured；
The solution is instilled, when not subsiding in the color of test terminal within a certain period of time, terminates and titrates and record drop
Enter of poor quality before and after the solution；
According to the reacting dose of the solution, the titrant quality to be measured, chemical reaction metering than obtaining the titrant
Concentration.
Compared with prior art, hydrogen fluoride content test method in electrolyte provided by the invention, using trihydroxy amino
Methane (Tris) and organic solvent are configured to solution as titrant, are sentenced by measurement potential change or indicator color change
Determine terminal, hydrogen fluoride content in electrolyte is calculated by the reacting dose of Tris after titration.Wherein titrant can pass through city
Purchase Tris powder or particle etc., which are added in alcoholic solution, is formulated directly into required concentration, without adding water, will not occur with electrolyte anti-
Additional hydrogen fluoride should be generated；And Tris alcoholic solution stable chemical performance, it is unlikely to deteriorate, it is fixed without titration advance rower every time,
Reduce manual operation error caused by calibration process.To sum up, this method has the characteristics that quick, accurate, operating error is small.
Detailed description of the invention
The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.
Fig. 1 is the chemical principle figure of Tris alcoholic solution and hydrogen fluoride of the invention.
Description of symbols:
The embodiment of the present invention that the following detailed description will be further explained with reference to the above drawings.
Specific embodiment
In order to be more clearly understood that the above objects, features, and advantages of the embodiment of the present invention, with reference to the accompanying drawing and
The present invention will be described in detail for specific embodiment.It should be noted that in the absence of conflict, the embodiment party of the application
Feature in formula can be combined with each other.
Embodiment in the following description, numerous specific details are set forth in order to facilitate a full understanding of the present invention, described reality
Applying mode is only some embodiments of the invention, rather than whole embodiments.Based on the embodiment in the present invention, originally
Field those of ordinary skill every other embodiment obtained without making creative work, belongs to this hair
The range of bright embodiment protection.
Unless otherwise defined, all technical and scientific terms used herein and the technology for belonging to the embodiment of the present invention
The normally understood meaning of the technical staff in field is identical.Term as used herein in the specification of the present invention is intended merely to
The purpose of specific embodiment is described, it is not intended that in the limitation embodiment of the present invention.
Electrolyte in an embodiment of the present invention is one of critical material of battery, and its role is between positive and negative electrode
Play a part of to conduct ion.Such as electrolyte generally by the organic solvent of high-purity, electrolyte lithium salt etc., make by production in lithium battery
Standby process is also easy to produce hydrogen fluoride, and hydrogen fluoride itself has very strong corrosivity, to the capacity of battery, cycle life and safety
Can have a significant impact, need its content of strict control.Mostly use highly basic alcoholic solution that water is added to prepare for existing titrant, water and electrolysis
Liquid reaction generates hydrogen fluoride, influences the deficiency of testing result accuracy, proposes a kind of improved titrant, i.e. trihydroxy amino first
Alkane (Tris) alcoholic solution, anhydrous can prepare, and reacting for 1:1 stoichiometric ratio occurs with hydrogen fluoride, as shown in Figure 1, wherein N3-
With the H in hydrogen fluoride+Form coordinate bond, while F-It is coexisted with ionic bond and coordinate bond, to realize the accurate inspection of hydrogen fluoride content
It surveys.
Embodiment one:
Hydrogen fluoride content test method in a kind of electrolyte is configured using trihydroxy aminomethane (Tris) and organic solvent
At solution as titrant, the titrant is instilled in electrolyte to be measured and is titrated, determines to pass through after reaching titration end-point
The reacting dose of Tris calculates hydrogen fluoride content in electrolyte to be measured, wherein the determination method of titration end-point includes by measurement electricity
The color of discoloration terminal is presented under indicator effect to determine in electrolyte to be measured after position catastrophe point or titration.
In the above method, the organic solvent is ethyl alcohol.
In the above method, titration end-point is determined by measurement potential jump point, specifically includes the following steps:
(1) the Tris alcoholic solution that compound concentration is ρ mol/L is titrant；
(2) readiness potential titration apparatus, the instrument include titration cell, buret, reference electrode and indicator electrode etc., ensure
Instrument normal use；
(3) titrant is pipetted into buret, the suitable height of installation buret to bracket；
(4) electrolyte to be measured that quality is M1g is packed into titration cell, the upper liquid level of electrolyte to be measured is located at titration cell upper end
Mouthful or less at 1/3, magnetic agitation switch is opened, for being stirred solution；
(5) reference electrode and indicator electrode are inserted into electrolyte to be measured, start potentiometric recorder, open titration pipe valve,
Start to titrate；
(6) potential jump point being measured to potentiometric recorder and reaching titration end-point, titration is automatically stopped；
(7) it is calculated according to the reactant accumulated amount EP1 (ml) of consumption Tris, electrolyte quality (g), chemical reaction metering ratio
Hydrogen fluoride content is HF/ppm in electrolyte to be measured.
Calculation formula are as follows: HF/ppm=EP1* ρ * MHF*103/M1
Wherein: MHFUnit be g/mol.
Embodiment two:
Hydrogen fluoride content test method in a kind of electrolyte is configured using trihydroxy aminomethane (Tris) and organic solvent
At solution as titrant, the titrant is instilled in electrolyte to be measured and is titrated, determines to pass through after reaching titration end-point
The reacting dose of Tris calculates hydrogen fluoride content in electrolyte to be measured.Wherein, the determination method of titration end-point includes by measurement electricity
The color of discoloration terminal is presented under indicator effect to determine in electrolyte to be measured after position catastrophe point or titration.
In the above method, the organic solvent is isopropanol.
In the above method, titration end-point is determined by the way that the color of discoloration terminal is presented in the case where indicator acts on, it is specific to wrap
Include following steps:
(1) the Tris alcoholic solution that compound concentration is ρ 2mol/L is titrant；
(2) titrant in step (1) carries out proving operation:
A. the Tris alcoholic solution in above-mentioned (1) is placed in conical flask；
B. use known acid concentration for H0The solution of/ppm washs buret 2~3 times, pipettes the solution and buret is added simultaneously
Adjustment start index position is " 0 " position；
C. using the concentration of the indicator titration method measurement Tris alcoholic solution, 5 measurement result average value ρ are taken
3mol/L compares the setting value and measured value of titrant concentration, as 0.95* ρ 2≤ρ, 3≤1.05* ρ 2, carries out next step titration
Operation；Otherwise adjustment Tris alcoholic solution concentration ρ 2, re-scales.
(3) diluent is weighed into beaker, indicator is added, and is uniformly mixed；
(4) electrolyte to be measured is instilled, is uniformly mixed, M2 of poor quality before and after instilling electrolyte to be measured is weighed up；
(5) instilling density is ρsG/mL Tris alcoholic solution does not disappear to titrate in titration end-point color and half a minute
When moving back, titration is terminated, weighs up the m2 of poor quality instilled before and after Tris alcoholic solution；
(6) hydrogen fluoride content in electrolyte is calculated according to the reacting dose of Tris, electrolyte quality, chemical reaction metering ratio
HF/ppm。
Calculation formula are as follows: HF/ppm=m2* ρ 2*MHF*103/M2
Wherein: MHFUnit be g/mol.
In the above method, the diluent is ethyl alcohol.
In the above method, the indicator is bromthymol blue.
In other embodiments, the organic solvent can be methanol, or the combination for methanol, ethyl alcohol, isopropanol
Object, or other similar organic solvent；The diluent can for methanol, ethyl alcohol, in isopropanol any one or
Combination.The proving operation can carry out one or many in 2 times or more titration, and the titration process being repeatedly spaced can also be with
Without proving operation.The vessel of the filling solutions such as beaker, conical flask are also possible to other containers such as wide-mouth bottle, volumetric flask, herein
Without limitation.
Test method of the present invention can realize the purpose of quick, accurate detection hydrogen fluoride content, and Tris alcoholic solution can
It is directly convenient with anhydrous preparation, it avoids generating additional hydrogen fluoride with electrolyte lithium salts, test accuracy is high.
Embodiment of above is only to illustrate the technical solution of the embodiment of the present invention rather than limits, although referring to above preferable
The embodiment of the present invention is described in detail in embodiment, those skilled in the art should understand that, it can be to this hair
The technical solution of bright embodiment is modified or equivalent replacement should not all be detached from the embodiment of the present invention technical solution spirit and
Range.
Claims (9)
1. hydrogen fluoride content test method in a kind of electrolyte, it is characterised in that: using trihydroxy aminomethane (Tris) and have
Solvent is configured to solution as titrant, and the titrant is instilled in electrolyte to be measured and is titrated, and determines to reach titration
Hydrogen fluoride content in electrolyte to be measured is calculated by the reacting dose of Tris after terminal.
2. hydrogen fluoride content test method in electrolyte according to claim 1, it is characterised in that: the judgement of titration end-point
Method includes that the color of discoloration terminal is presented under indicator effect by electrolyte to be measured after measurement potential jump point or titration
To determine.
3. hydrogen fluoride content test method in electrolyte according to claim 2, it is characterised in that: when by measuring current potential
Catastrophe point is come when determining titration end-point, comprising the following steps:
Electrolyte to be measured is packed into titration cell, the titrant is pipetted to buret, electrode is placed in electrolyte to be measured, is started
Titration；
It is to be measured measure potential jump point after, according to the reacting dose of Tris, electrolyte quality to be measured, chemical reaction metering than obtain to
Survey hydrogen fluoride content in electrolyte.
4. hydrogen fluoride content test method in electrolyte according to claim 2, it is characterised in that: when by indicator
The lower color that discoloration terminal is presented of effect is come when determining titration end-point, comprising the following steps:
Diluent is weighed, indicator is added, is uniformly mixed；
Electrolyte to be measured is instilled, is uniformly mixed, and is recorded of poor quality before and after instilling electrolyte to be measured；
The titrant is instilled, when the color for being within a certain period of time in titration end-point does not subside, terminates and titrates and record instillation
It is of poor quality before and after the titrant；
Contained according to the reacting dose of Tris, electrolyte quality to be measured, chemical reaction metering than calculating hydrogen fluoride in electrolyte to be measured
Amount.
5. hydrogen fluoride content test method in electrolyte according to claim 1, it is characterised in that: the titrant it is dense
Degree is 0.0003-0.5mol/L.
6. hydrogen fluoride content test method in electrolyte according to claim 1, it is characterised in that: the organic solvent is
One of methanol, ethyl alcohol, isopropanol or combination.
7. hydrogen fluoride content test method in electrolyte according to claim 4, it is characterised in that: the indicator is bromine
Thymol blue.
8. hydrogen fluoride content test method in electrolyte according to claim 4, it is characterised in that: the diluent is first
One of alcohol, ethyl alcohol, isopropanol or combination.
9. hydrogen fluoride content test method in electrolyte according to claim 3 or 4, it is characterised in that: include before titration
The proving operation of the titrant, for correcting the concentration of the titrant, specific steps are as follows:
The solution of known acid concentration is added in the titrant and is tested；
By measuring potential jump point or indicator in the color discriminating test terminal of discoloration terminal, basis after test terminal is reached
The concentration than measuring the titrant is measured in the reacting dose of the solution, the titrant quality, chemical reaction；
Judge the measured value of the titrant concentration whether in setting range；
When measured value is in setting range, progress next step titration operation, the adjustment titrant concentration on the contrary is retested.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810045055.2A CN110045058A (en) | 2018-01-17 | 2018-01-17 | Hydrogen fluoride content test method in electrolyte |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810045055.2A CN110045058A (en) | 2018-01-17 | 2018-01-17 | Hydrogen fluoride content test method in electrolyte |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110045058A true CN110045058A (en) | 2019-07-23 |
Family
ID=67273564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810045055.2A Pending CN110045058A (en) | 2018-01-17 | 2018-01-17 | Hydrogen fluoride content test method in electrolyte |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110045058A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112255222A (en) * | 2020-10-19 | 2021-01-22 | 厦门海辰新能源科技有限公司 | Composition, application thereof and screening method of electrolyte |
| CN113495118A (en) * | 2021-07-07 | 2021-10-12 | 远景动力技术(江苏)有限公司 | Method and device for testing electrolyte consumption |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1423127A (en) * | 2001-12-04 | 2003-06-11 | 比亚迪股份有限公司 | Nonaqueous titration determination method of hydrogen fluoride in electrolyte of lithium ion cell |
| CN1614406A (en) * | 2004-11-29 | 2005-05-11 | 华南师范大学 | Quantitatively analyzing method for fluohydric acid in lithium ion battery electrolyte |
| CN1632558A (en) * | 2004-12-31 | 2005-06-29 | 中国海洋大学 | Process for determining hydrogen fluoride in lithium ion cell electrolyte |
| US20130168264A1 (en) * | 2011-12-28 | 2013-07-04 | Soulbrain Co., Ltd. | Method for Measuring HF Content in Lithium Secondary Battery Electrolyte and Analytical Reagent Composition Used in the Same |
| CN105158407A (en) * | 2015-10-09 | 2015-12-16 | 天津市捷威动力工业有限公司 | Method for measuring HF content of electrolyte containing LiBOB |
-
2018
- 2018-01-17 CN CN201810045055.2A patent/CN110045058A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1423127A (en) * | 2001-12-04 | 2003-06-11 | 比亚迪股份有限公司 | Nonaqueous titration determination method of hydrogen fluoride in electrolyte of lithium ion cell |
| CN1614406A (en) * | 2004-11-29 | 2005-05-11 | 华南师范大学 | Quantitatively analyzing method for fluohydric acid in lithium ion battery electrolyte |
| CN1632558A (en) * | 2004-12-31 | 2005-06-29 | 中国海洋大学 | Process for determining hydrogen fluoride in lithium ion cell electrolyte |
| US20130168264A1 (en) * | 2011-12-28 | 2013-07-04 | Soulbrain Co., Ltd. | Method for Measuring HF Content in Lithium Secondary Battery Electrolyte and Analytical Reagent Composition Used in the Same |
| CN105158407A (en) * | 2015-10-09 | 2015-12-16 | 天津市捷威动力工业有限公司 | Method for measuring HF content of electrolyte containing LiBOB |
Non-Patent Citations (4)
| Title |
|---|
| 徐宝荣 等: "《分析化学》", 31 July 2009, 北京：中国农业出版社 * |
| 谢鹏: "酸标准溶液标定方法改进探讨", 《广东轻工职业技术学院学报》 * |
| 陈克平: "用THAM替代Na2CO3电位滴定标定酸浓度探讨", 《中国石油和化工标准与质量》 * |
| 陈耀祖: "《有机分析》", 30 September 1981, 北京：高等教育出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112255222A (en) * | 2020-10-19 | 2021-01-22 | 厦门海辰新能源科技有限公司 | Composition, application thereof and screening method of electrolyte |
| CN113495118A (en) * | 2021-07-07 | 2021-10-12 | 远景动力技术(江苏)有限公司 | Method and device for testing electrolyte consumption |
| CN113495118B (en) * | 2021-07-07 | 2024-02-27 | 远景动力技术(河北)有限公司 | Method and device for testing consumption of electrolyte |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Johnson et al. | Coulometric TCO2 analyses for marine studies; an introduction | |
| CN103645226A (en) | Method for detecting free acids in boracic lithium salt and electrolyte of boracic lithium salt | |
| CN105242002A (en) | System and method for automatically detecting oleic acid value | |
| CN110261464A (en) | The method of free acid content in lithium hexafluoro phosphate product is quickly measured in non-aqueous system | |
| CN105388127A (en) | Online detecting method and system for concentration of all ions of all-vanadium redox flow battery | |
| CN102288726B (en) | Method for determining acidity of vanadium redox battery electrolyte by virtue of pH titration quantitative determination and application thereof | |
| CN108666600A (en) | A kind of all-vanadium flow battery SOC detection methods measured based on heat chemistry | |
| CN110045058A (en) | Hydrogen fluoride content test method in electrolyte | |
| CN106198453A (en) | The online test method of the chief and vice reaction ratio of a kind of all-vanadium flow battery and device | |
| CN103913458A (en) | Detection method for trace free acid in electrolyte lithium salt | |
| Wang et al. | Standard operating protocol for ion-exchange capacity of anion exchange membranes | |
| CN102937614A (en) | Method for analyzing content of free fluorin in lithium ion battery electrolyte salt LiBF4 | |
| Chapman | A simple conductimetric soil respirometer for field use | |
| CN111505200A (en) | Method for detecting trace free acid in electrolyte additive | |
| CN113281457A (en) | Method for rapidly determining content of free acid in lithium hexafluorophosphate electrolyte through low-temperature linear titration | |
| CN103235085A (en) | Method for rapidly determining volatile fatty acid concentration in anaerobic reactor | |
| CN109612978B (en) | Lithium ion battery electrode diaphragm lithium supplement amount detection method | |
| CN103868910A (en) | Method for detecting ingredients of vanadyl sulfate product | |
| CN112415077A (en) | All-vanadium redox flow battery electrolyte detection method and detection device | |
| CN112147203A (en) | Method and system for measuring concentration of ferrous iron in electrolyte of Fe/Cr flow battery | |
| WO2009123496A1 (en) | Method and device for measuring impurities in oil and petroleum products | |
| CN107449772B (en) | Method for detecting impurities in electrolyte of flooded lead-acid storage battery | |
| CN117476974A (en) | Real-time detection compensation method and system for all-vanadium redox flow battery | |
| CN109900684A (en) | A kind of measuring method of lithium salt in lithium ion battery electrolyte content | |
| CN113311051A (en) | Method for rapidly determining content of free acid in lithium hexafluorophosphate electrolyte by coulometric titration digital end point method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190723 |