CN110028825A - A kind of super-biparental self-cleaning coating material and preparation method thereof - Google Patents
A kind of super-biparental self-cleaning coating material and preparation method thereof Download PDFInfo
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- CN110028825A CN110028825A CN201910373820.8A CN201910373820A CN110028825A CN 110028825 A CN110028825 A CN 110028825A CN 201910373820 A CN201910373820 A CN 201910373820A CN 110028825 A CN110028825 A CN 110028825A
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- 239000000463 material Substances 0.000 title claims abstract description 67
- 238000004140 cleaning Methods 0.000 title claims abstract description 47
- 239000011248 coating agent Substances 0.000 title claims abstract description 46
- 238000000576 coating method Methods 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000000126 substance Substances 0.000 claims abstract description 17
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims abstract description 14
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002243 precursor Substances 0.000 claims abstract description 12
- 238000004132 cross linking Methods 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 239000000758 substrate Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 238000001354 calcination Methods 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical group CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 claims description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- -1 Sodium alkyl benzene Chemical class 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims 1
- 150000002460 imidazoles Chemical class 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 230000009471 action Effects 0.000 abstract description 3
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 21
- 238000012360 testing method Methods 0.000 description 15
- 230000000694 effects Effects 0.000 description 9
- 239000011521 glass Substances 0.000 description 8
- 230000010148 water-pollination Effects 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical compound CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 2
- 229910021389 graphene Inorganic materials 0.000 description 2
- 230000003075 superhydrophobic effect Effects 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000012496 blank sample Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000001652 electrophoretic deposition Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of super-biparental self-cleaning coating materials and preparation method thereof.Hydrophilic radical and lipophilic group coexist in the super-biparental self-cleaning coating material；The water contact angle of the material and oily contact angle are equal to 0.Preparation method includes the following steps: that 1) class glycidol ether substance is dissolved in appropriate solvent；2) crosslinking accelerator is added；3) surfactant is added；4) stearylamine, 2~10h of stirring at normal temperature is added；5) it heats, obtains precursor liquid；6) precursor liquid is applied on cleaned substrates and carries out calcination processing, obtain super-biparental self-cleaning coating material.Super parents' coating of the invention has excellent hydrophilic and oleophilic performance, and has automatic cleaning action, has the prospect in the automatic cleaning coating material applied to solar panel.
Description
Technical field
The invention belongs to new material technology fields, and in particular to a kind of super-biparental self-cleaning coating material and its preparation side
Method.
Background technique
In recent years, surpass parents (super hydrophilic, super oleophylic) material to receive more and more attention, surpassing parents' material has from clear
It is clean, antifouling, anti-fog, so that liquid the functions such as is sprawled rapidly, as a kind of special boundary material, in catalysis, anti-corrosion, automatically cleaning etc.
Field has a wide range of applications.Common solar panel in life, with the extension of use time, dust and oil
The deposition of stain will be greatly reduced the transformation efficiency of solar panel, so as to shorten its service life, utilize super parents' material
The surface cleanness of solar panel can be improved in automatic cleaning action.Self-cleaning material is broadly divided into due to its contact angle difference
Super hydrophilic and super hydrophobic material, super hydrophilic material are special material of the contact angle less than 15 °, and super hydrophobic material is that contact angle is greater than
150 ° of material.
The useful Hummer method of super parents' material reported at present prepares graphene oxide, then prepares oxidation with hydro-thermal method
Graphene/phosphoethanolamine compound, and Hummer method is to be obtained again through strong reduction by graphite powder by Strong oxdiative, preparation process
It is complicated.Also have and super parents TiO is constructed using electrophoretic deposition2Nano-tube film, the method need to prepare electrolytic cell and electrolyte, no
It is suitble to practical large-scale production.Prepared material has certain super parents' effect in the above technology, but there are still ask as follows
Topic: (1) nanometer sized materials are easily reunited, to gradually lose self-cleaning effect；(2) preparation process is cumbersome, at high cost；
(3) oleophylic is ineffective causes oily matter to be easily adhered in surface, reduces self-cleaning effect.
The super parents that a kind of low cost, preparation method is simple to solve the above problems, the present invention provides, has excellent performance are from clear
Clean coating material and preparation method thereof, the super-biparental self-cleaning coating material of preparation, which has, is applied to solar panel automatically cleaning
The prospect of coating material.
Summary of the invention
Goal of the invention: present invention aims in view of the deficiencies of the prior art, provide a kind of super parents' automatic cleaning coating material
Material and preparation method thereof.
Technical solution: the purpose of the invention is achieved by the following technical solution:
The present invention provides a kind of super-biparental self-cleaning coating material, hydrophilic radical and lipophilic group are total in the material
It deposits；The water contact angle of the material and oily contact angle are equal to 0.
Preferably, the hydrophilic radical in the material is hydroxyl；Lipophilic group is aliphatic chain.
The present invention also provides the preparation methods of above-mentioned super-biparental self-cleaning coating material, include the following steps:
(1) class glycidol ether substance is dissolved in solvent；50~200mL is added in every 1mol class glycidol ether substance
Solvent；Class glycidol ether substance is a kind of substance with glycidol ether structure；
(2) crosslinking accelerator is added；0.05~1mL crosslinking accelerator is added in every 1mol class glycidol ether substance；
(3) surfactant is added；
(4) stearylamine, 2~10h of stirring at normal temperature is added；
(5) it heats, obtains precursor liquid；
(6) precursor liquid is applied on cleaned substrates, is placed in 100~150 DEG C of calcinings in Muffle furnace, obtains super parents' automatically cleaning
Coating material.
Super-biparental self-cleaning coating material of the present invention is that class glycidol ether substance and stearylamine are carried out graft reaction, is obtained
To product in existing hydrophilic radical, and have lipophilic group, so that the coating material has excellent self-cleaning effect.
Preferably, the class glycidol ether substance in step (1) is 1,4-butanediol-glycidol ether or allyl glycidyl
Glycerin ether.
Preferably, the solvent in step (1) is dehydrated alcohol, ethylene glycol, propyl alcohol or isopropanol.
Preferably, the crosslinking accelerator in the step (2) is 1- methylimidazole.
Preferably, the surfactant in the step (3) is neopelex, polyvinyl alcohol or dodecyl
Sodium sulphate.
Preferably, the surfactant additive amount in the step (3) is 0.01~2wt% of total material.In the present invention
Total material refers to including class glycidol ether substance, solvent, crosslinking accelerator, surfactant and stearylamine.
Preferably, the molar ratio of stearylamine and class glycidol ether substance is 0.01~0.18:1 in the step (4).
Preferably, the heating temperature in the step (5) is 50~80 DEG C, and heating time is 0.3~3h.
Preferably, the calcination time in the step (6) is 0.5~3h.
Super-biparental self-cleaning coating material using above method preparation has excellent super parents' performance.
The existing hydrophilic radical of super-biparental self-cleaning coating material of the present invention, and have lipophilic group, so that the coating material
Material has excellent self-cleaning effect.The super existing excellent hydrophily of parents' material has excellent lipophilicity again, so no matter right
Hydrophilic or lipophilic spot can be sprawled well, prevent spot from building up, to reach self-cleaning effect
Fruit.
Therefore, super parents' coating that the present invention obtains has excellent hydrophilic and oleophilic performance, has and is applied to solar-electricity
The prospect of pond plate automatic cleaning coating material.
The utility model has the advantages that
(1) super-biparental self-cleaning coating material preparation method of the invention is simple, at low cost, favorable reproducibility；
(2) super-biparental self-cleaning coating material hydrophilic radical and lipophilic group prepared by the present invention coexist, and have excellent
Super parents' performance；
(3) hydrophily of super-biparental self-cleaning coating material prepared by the present invention and lipophilic contact angle are equal to 0 °；
Contact angle is 0, and material can be sprawled completely on surface.For aqueous or oiliness substance, it is not easy to which adhesion deposition exists
Surface has automatic cleaning action.
Detailed description of the invention
Fig. 1 is the water contact angle test chart of blank substrate；
Fig. 2 is the hexadecane contact angle test chart of blank substrate；
Fig. 3 is the water contact angle test chart of super parents' automatic cleaning coating obtained in embodiment 1；
Fig. 4 is the hexadecane contact angle test chart of super parents' automatic cleaning coating obtained in embodiment 1；
Fig. 5 is the water contact angle test chart of super parents' automatic cleaning coating obtained in embodiment 2；
Fig. 6 is the hexadecane contact angle test chart of super parents' automatic cleaning coating obtained in embodiment 2；
Fig. 7 is the water contact angle test chart of super parents' automatic cleaning coating obtained in embodiment 3；
Fig. 8 is the hexadecane contact angle test chart of super parents' automatic cleaning coating obtained in embodiment 3.
Specific embodiment
Technical solution of the present invention is described in detail below by specific embodiments and the drawings, but protection of the invention
Range is not limited to the embodiment.
Reference examples 1:
There is excellent super parents' effect in order to illustrate prepared coating, spy is provided with blank sample, i.e., does not apply
The blank substrate (clean glass slide) of layer, contact angle test result is as depicted in figs. 1 and 2, and Fig. 1 is that the water of blank substrate contacts
Angle test chart, Fig. 2 are the hexadecane contact angle test chart of blank substrate.Contact angle tester is that Chengde is limited at favour testing machine
The JGW-360A contact angle tester of company, 2 μ L of droplet size.
Fig. 1 and Fig. 2 respectively with water and hexadecane in the hydrophily of the contact angle reflection coating on clean glass slide surface and
It is lipophilic.The contact angle of Fig. 1 is 89 °, and the contact angle of Fig. 2 is 40 °.
Embodiment 1
A kind of preparation method of super-biparental self-cleaning coating material, includes the following steps:
(1) 1mol 1,4- butanediol-glycidol ether is taken to be dissolved in 50mL dehydrated alcohol.
(2) 0.5mL 1- methylimidazole is instilled.
(3) neopelex of the total material 1wt% of Zhan is added.
(4) it is 0.1:1 according to stearylamine and 1,4-butanediol-glycidol ether molar ratio, stearylamine, stirring at normal temperature is added
6h。
(5) 70 DEG C of heating 0.5h, obtain precursor liquid.
(6) precursor liquid is applied in clean glass slide, is placed in 120 DEG C of calcining 1h in Muffle furnace.
The super-biparental self-cleaning coating material obtained by above step, contact angle test result is as shown in Figure 3 and Figure 4,
Fig. 3 is aqueous solution, and Fig. 4 is hexadecane solution.Fig. 3 and Fig. 4 contact with water with hexadecane on clean glass slide surface respectively
The hydrophily and lipophilicity of angle reflection coating.The contact angle of Fig. 3 is 0 °, and the contact angle of Fig. 2 is 0 °.
Embodiment 2
A kind of preparation method of super-biparental self-cleaning coating material, includes the following steps:
(1) 1mol 1,4- butanediol-glycidol ether is taken to be dissolved in 100mL ethylene glycol.
(2) 1mL 1- methylimidazole is instilled.
(3) polyvinyl alcohol of the total material 0.01wt% of Zhan is added.
(4) it is 0.18:1 according to stearylamine and 1,4-butanediol-glycidol ether molar ratio, stearylamine is added, room temperature stirs
Mix 2h.
(5) 80 DEG C of heating 2h, obtain precursor liquid.
(6) precursor liquid is applied in clean glass slide, is placed in 150 DEG C of calcining 0.5h in Muffle furnace.
The super-biparental self-cleaning coating material obtained by above step, contact angle test result is as shown in Figure 5 and Figure 6,
Fig. 5 is aqueous solution, and Fig. 6 is hexadecane solution.Fig. 5 and Fig. 6 contact with water with hexadecane on clean glass slide surface respectively
The hydrophily and lipophilicity of angle reflection coating.The contact angle of Fig. 5 is 0 °, and the contact angle of Fig. 6 is 0 °.
Embodiment 3
A kind of preparation method of super-biparental self-cleaning coating material, includes the following steps:
(1) 1mol allyl glycidyl ether is taken to be dissolved in 200mL dehydrated alcohol.
(2) 0.05mL 1- methylimidazole is instilled.
(3) lauryl sodium sulfate of the total material 2wt% of Zhan is added.
(4) it is 0.01:1 according to stearylamine and allyl glycidyl ether molar ratio, stearylamine, stirring at normal temperature 10h is added.
(5) 50 DEG C of heating 3h, obtain precursor liquid.
(6) precursor liquid is applied in clean glass slide, is placed in 100 DEG C of calcining 3h in Muffle furnace.
The super-biparental self-cleaning coating material obtained by above step, contact angle test result is as shown in Figure 7 and Figure 8,
Fig. 7 is aqueous solution, and Fig. 8 is hexadecane solution.Fig. 7 and Fig. 8 contact with water with hexadecane on clean glass slide surface respectively
The hydrophily and lipophilicity of angle reflection coating.The contact angle of Fig. 7 is 0 °, and the contact angle of Fig. 8 is 0 °.
Super parents effect of the super parents' material that the present invention prepares in numerous experiments is all consistent, surpasses parents' material
Water contact angle and oily contact angle are equal to 0, the favorable reproducibility of preparation method of the present invention.Super parents' automatically cleaning prepared by the present invention applies
The hydrophily of layer material and lipophilic contact angle are equal to 0 °, and existing excellent hydrophily has excellent lipophilicity again；Contact
Angle is 0, and material can be sprawled completely on surface.For aqueous or oiliness substance, it is not easy to adhesion deposition on surface,
Prevent spot from building up, to reach self-cleaning effect.
As described above, must not be explained although the present invention has been indicated and described referring to specific preferred embodiment
For the limitation to invention itself.It without prejudice to the spirit and scope of the invention as defined in the appended claims, can be right
Various changes can be made in the form and details for it.
Claims (10)
1. a kind of super-biparental self-cleaning coating material, which is characterized in that hydrophilic radical and lipophilic group coexist in the material；Institute
The water contact angle and oily contact angle for stating material are equal to 0.
2. super-biparental self-cleaning coating material according to claim 1, which is characterized in that the hydrophilic radical in the material
For hydroxyl；Lipophilic group is aliphatic chain.
3. the preparation method of super-biparental self-cleaning coating material according to claim 1 or 2, which is characterized in that including such as
Lower step:
(1) class glycidol ether substance is dissolved in solvent；50~200mL solvent is added in every 1mol class glycidol ether substance；
(2) crosslinking accelerator is added；0.05~1mL crosslinking accelerator is added in every 1mol class glycidol ether substance；
(3) surfactant is added；
(4) stearylamine, 2~10h of stirring at normal temperature is added；
(5) it heats, obtains precursor liquid；
(6) precursor liquid is applied on cleaned substrates, 100~150 DEG C of calcinings obtain super-biparental self-cleaning coating material.
4. preparation method according to claim 3, which is characterized in that the class glycidol ether substance in step (1) is 1,
4- butanediol-glycidol ether or allyl glycidyl ether.
5. preparation method according to claim 3, which is characterized in that the solvent in step (1) is dehydrated alcohol, second two
Alcohol, propyl alcohol or isopropanol.
6. preparation method according to claim 3, which is characterized in that the crosslinking accelerator in the step (2) is 1- first
Base imidazoles.
7. preparation method according to claim 3, which is characterized in that the surfactant in the step (3) is 12
Sodium alkyl benzene sulfonate, polyvinyl alcohol or lauryl sodium sulfate.
8. preparation method according to claim 3, which is characterized in that the surfactant additive amount in the step (3)
For 0.01~2wt% of total material.
9. preparation method according to claim 3, which is characterized in that stearylamine and class glycidol in the step (4)
The molar ratio of ether substance is 0.01~0.18:1.
10. preparation method according to claim 3, which is characterized in that the heating temperature in the step (5) is 50~80
DEG C, heating time is 0.3~3h.
Priority Applications (1)
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| CN201910373820.8A CN110028825A (en) | 2019-05-07 | 2019-05-07 | A kind of super-biparental self-cleaning coating material and preparation method thereof |
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| CN201910373820.8A CN110028825A (en) | 2019-05-07 | 2019-05-07 | A kind of super-biparental self-cleaning coating material and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1328102A (en) * | 2001-06-08 | 2001-12-26 | 成都茵地乐电源科技有限公司 | Water adhesive for electrode material of secondary lithium ion battery and its preparing process |
| CN101724342A (en) * | 2009-12-17 | 2010-06-09 | 复旦大学 | Super-biparental self-cleaning coating material and preparation method thereof |
| CN102295914A (en) * | 2010-06-28 | 2011-12-28 | 上海万森水处理有限公司 | Multifunctional hydrophobic lacquer protecting agent containing amphiphile for auto detailing |
| CN109294394A (en) * | 2018-09-21 | 2019-02-01 | 华东理工大学 | A kind of superhydrophilic self-cleaning epoxy coating and the preparation method and application thereof |
-
2019
- 2019-05-07 CN CN201910373820.8A patent/CN110028825A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1328102A (en) * | 2001-06-08 | 2001-12-26 | 成都茵地乐电源科技有限公司 | Water adhesive for electrode material of secondary lithium ion battery and its preparing process |
| CN101724342A (en) * | 2009-12-17 | 2010-06-09 | 复旦大学 | Super-biparental self-cleaning coating material and preparation method thereof |
| CN102295914A (en) * | 2010-06-28 | 2011-12-28 | 上海万森水处理有限公司 | Multifunctional hydrophobic lacquer protecting agent containing amphiphile for auto detailing |
| CN109294394A (en) * | 2018-09-21 | 2019-02-01 | 华东理工大学 | A kind of superhydrophilic self-cleaning epoxy coating and the preparation method and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| SIDA FU等: "Amphibious superamphiphilic fabrics with self-healing underwater superoleophilicity", 《MATERIALS HORIZONS》 * |
| 郑忠等: "《表面活性剂的物理化学原理》", 30 April 1997, 华南理工大学出版社 * |
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