CN110017124A - Coal-bed gas enhanced gas extraction method and extraction system based on phase-change heat-storage material - Google Patents

Coal-bed gas enhanced gas extraction method and extraction system based on phase-change heat-storage material Download PDF

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Publication number
CN110017124A
CN110017124A CN201910162956.4A CN201910162956A CN110017124A CN 110017124 A CN110017124 A CN 110017124A CN 201910162956 A CN201910162956 A CN 201910162956A CN 110017124 A CN110017124 A CN 110017124A
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China
Prior art keywords
gas
phase
coal seam
coal
storage material
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CN201910162956.4A
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Chinese (zh)
Inventor
柳先锋
王泽鹏
聂百胜
张亮
曾梦茹
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Chongqing University
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Chongqing University
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Priority to CN201910162956.4A priority Critical patent/CN110017124A/en
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    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/006Production of coal-bed methane
    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/24Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21FSAFETY DEVICES, TRANSPORT, FILLING-UP, RESCUE, VENTILATION, OR DRAINING IN OR OF MINES OR TUNNELS
    • E21F7/00Methods or devices for drawing- off gases with or without subsequent use of the gas for any purpose

Abstract

The invention discloses a kind of coal-bed gas enhanced gas extraction method and its system based on phase-change heat-storage material, pumping method include drilling, establish extraction system, heating coal seam and exploitation four steps of gas;Extraction system includes storage silo and meter, and storage silo is connected with meter, and the conveying steel pipe for protruding into coal seam is connected on meter;It further include gas pipe network, gas pipe is connected with the gas drainage pipe for protruding into coal seam on the net;Storage silo is used to store phase-change heat-storage material, and meter is used to carry out traffic statistics and display to the phase-change heat-storage material of conveying, and temperature controlled situation is carried out quantization grasp.The invention has the advantages that being heated using phase-change heat-storage material heat release to coal seam, to be maintained at certain temperature range, the moisture evaporation inside coal seam is helped, the flow channel of gas is dredged, while also accelerating the flowing diffusion of gas, production efficiency is improved, the risk of exploitation is avoided.

Description

Coal-bed gas enhanced gas extraction method and extraction system based on phase-change heat-storage material
Technical field
The invention belongs to gas production technical field, in particular to a kind of coal-bed gas based on phase-change heat-storage material is strong Change pumping method and extraction system.
Background technique
Coal is the main body energy in China, and the Gas Disaster with coal mining association is always to restrict Safety of Coal Mine Production A great problem.With being continuously increased for mining depth and mining rate, fire damp outburst amount is increasing, gas overpressure frequency limit Hair, Gas Outburst and gas explosion risk are got worse.Efficient draining coal seam gas is that the essence of prevention and treatment Gas Disaster is done Method.
In terms of the anti-reflection reinforcing gas drainage in coal seam, common gas govenance mainly includes standing both at home and abroad And hydraulic fracturing.Both the above can promote gas drainage to a certain extent, but generally existing coverage is small, function and effect Limited problem is unable to satisfy coal production needs.Wherein, standing is also easy to that a large amount of gas is induced to discharge suddenly, causes Gas secondary disaster;After hydraulic fracturing fracturing coal body, large quantity of moisture is remained in coal, thus can block Gas Flow channel, is stopped Desorption of mash gas, seepage flow, diffusion, are unfavorable for gas drainage, and Gas Disaster is also difficult to be effectively prevented.Therefore, for existing watt The deficiency of this extraction technology is badly in need of a kind of novel gas pumping method, greatly improves gas pumping effect, to meet coal mine peace Full production needs.
The presence of substance has had been generally acknowledged that tri-state, and substance changes to another state phase transformation from a kind of state.Phase transformation Form has following four: (1) solid-liquid phase change;(2) liquid-vapour phase becomes;(3) solid-vapour phase becomes;(4) solid-solid phase-change.Phase transition process In with energy absorption or release, we can absorb and release phenomenon using have energy in phase transition process, utilize phase Become material and carrys out storage energy.
There are many phase-changing energy storage materials, is such as applied by Shanghai University Of Engineering Science, Patent No. ZL201510742887.6, entitled a kind of composite phase-change energy storage material and preparation method thereof provide for one of which, for another example Applied by Shenyang Chemical Engineering Inst. Co., Ltd, Patent No. ZL201510259828.3, a kind of entitled improved silica Shape-stabilized phase change energy storage and preparation method thereof provides one kind again.
Summary of the invention
In view of influencing in the prior art, coal seam range is small, function and effect are limited, secondary disaster and blocking Gas Flow are logical The problem of road, the present invention provide a kind of coal-bed gas enhanced gas extraction method based on phase-change heat-storage material, technology to be solved Problem increases the coverage to coal seam, and secondary disaster caused by avoiding gas from discharging suddenly avoids Gas-Flow in blocking coal seam Dynamic channel, and then gas pumping effect is increased substantially, to meet Safety of Coal Mine Production needs.
An object of the present invention is to provide a kind of coal-bed gas enhanced gas extraction method based on phase-change heat-storage material, packet Include following steps:
1) drill: a gas drainage hole of constructing in coal seam is constructed a coal again in the bottom end in the gas drainage hole Layer preheating gate;
2) it establishes extraction system: being provided with the storage silo for storing phase-change heat-storage material outside the coal seam, the storage Storehouse, which is connected, conveying steel pipe, and the conveying steel pipe is extend into inside the coal seam preheating gate, is additionally provided with gas outside the coal seam Pipe network, the gas pipe are connected with gas drainage pipe on the net, which extend into gas drainage hole;Extraction system connects After the completion of connecing, gas drainage hole is sealed with hole packer;
3) it heats coal seam: phase-change heat-storage material being inputted into coal seam preheating gate by storage silo and conveying steel pipe, utilizes phase The temperature of change heat storage material is higher than the temperature in the coal seam to heat to the coal seam;
4) it exploits gas: keeping the connection of gas drainage pipe to gas pipe network unobstructed, gas in the coal seam passes through watt This drainage holes is flowed into gas drainage pipe, and enters gas pipe network.
Gas pumping method provided in the present invention, basic principle are using phase-change heat-storage material, by the phase-change thermal storage Material is circulated into coal seam, and since the temperature of the phase-changing energy storage material is higher, phase transformation can be generated by encountering the lower coal seam of temperature, And heat is released, coal seam is heated.After coal seam absorbs heat, temperature is increased, and regional coal-seam temperature is controlled in a certain range It is interior, the original moisture in coal seam is evaporated, gas migration channel has been discongested;In addition, gas molecular thermalmotion under thermogenic action Enhance, it is free state gas that the ADSORPTION STATE gas in coal seam, which constantly desorbs, and desorption of mash gas diffusion rate is accelerated, and by coal Crack flows to gas drainage hole, and fire damp pipe network is reached after gas drainage pipe, carries out gas drainage.
Further, the length in the gas drainage hole is 30m-50m.
Further, the diameter in the gas drainage hole is 110mm-140mm.
Further, the length of the coal seam preheating gate is 40m-60m.
Further, the diameter of the coal seam preheating gate is 25mm-55mm.
Further, the phase-change heat-storage material passes through meter during transportation and conveying capacity is measured and shown, Power is provided to conveying by delivery pump, and controls flow, and then control the temperature in the coal seam.
Temperature in coal seam is controlled with realizing by the control to phase-change heat-storage material flow, temperature control is existed In suitable range, it is conducive to evaporation water, dredges gas migration channel, while enhancing the warm-up movement of gas molecule.
Further, the temperature in temperature field is controlled at 55 DEG C -60 DEG C in the coal seam.
The second object of the present invention is to provide a kind of extraction that coal-bed gas enhanced gas extraction is carried out for phase-change heat-storage material System, including storage silo and meter, the storage silo are connected with meter, and are connected on the meter and are protruded into coal seam Conveying steel pipe;
It further include gas pipe network, the gas pipe is connected with the gas drainage pipe for protruding into coal seam on the net.
Storage silo is used to store phase-change heat-storage material, and meter is used to carry out flow system to the phase-change heat-storage material of conveying Meter and display, carry out quantization grasp for temperature controlled situation.
Further, delivery pump is provided on the conveying steel pipe.
Further, valve is provided on the gas drainage pipe.
The utility model has the advantages that present inventive concept is novel, ingenious in design and structurally reasonable, using phase-change heat-storage material heat release to coal Layer is heated, and to be maintained at certain temperature range, is helped the moisture evaporation inside coal seam, is dredged the flow channel of gas, The flowing diffusion for also accelerating gas simultaneously, improves production efficiency, avoids the risk of exploitation.
Detailed description of the invention
Fig. 1 is positive structure diagram of the present invention.
Specific embodiment
Present invention will be further explained below with reference to the attached drawings and examples:
Embodiment one
A kind of coal-bed gas enhanced gas extraction method based on phase-change heat-storage material as shown in Figure 1, it is characterised in that including Following steps:
1) drill: a gas drainage hole 5 of constructing in coal seam 7, the length in gas drainage hole 5 are 30m-50m, gas The diameter of drainage holes 5 is 110mm-140mm, is constructed again a coal seam preheating gate 11 in the bottom end in gas drainage hole 5, coal seam is pre- The length of hot hole 11 is 40m-60m, and the diameter of coal seam preheating gate 11 is 25mm-55mm;
2) it establishes extraction system: being provided with the storage silo 1 for storing phase-change heat-storage material, the storage silo outside coal seam 7 1 connection has conveying steel pipe 6, and the conveying steel pipe 6 is extend into inside coal seam preheating gate 11, and gas pipe network is additionally provided with outside coal seam 7 10, gas drainage pipe 8 is connected on the gas pipe network 10, which extend into gas drainage hole 5;Extraction system After the completion of connection, gas drainage hole 5 is sealed with hole packer 4;
3) it heats coal seam: phase-change heat-storage material is inputted into coal seam preheating gate 11 by storage silo 1 and conveying steel pipe 6, benefit It is higher than the temperature in coal seam 7 with the temperature of phase-change heat-storage material to heat to the coal seam 7;
4) exploit gas: keeping gas drainage pipe 8 unobstructed to the connection of gas pipe network 10, gas in coal seam 7 by watt This drainage holes 5 is flowed into gas drainage pipe 8, and enters gas pipe network 10.
In the specific implementation process, as a kind of perferred technical scheme, phase-change heat-storage material passes through during transportation Meter 2 is measured and is shown to conveying capacity, provides power by 3 pairs of conveyings of delivery pump, and control flow, and then control Temperature in coal seam 7.The temperature in temperature field is controlled at 55 DEG C -60 DEG C in coal seam 7.
In the specific implementation process, used phase-change heat-storage material is inorganic salts energy storage materials of phase change to the present embodiment, main Wanting ingredient is stearic acid and titanium dioxide, other are conventional additives, wherein stearic accounting is 25%, is formed by nothing Machine salt energy storage materials of phase change fusing point is 53.84 DEG C, latent heat of fusion 47.82kJ/kg, and freezing point is 53.31 DEG C, latent heat of solidification For 46.60kJ/kg, there is good stability.
Basic principle in the present invention is that the phase-change heat-storage material is circulated into coal seam using phase-change heat-storage material, by Higher in the temperature of the phase-changing energy storage material, phase transformation can be generated by encountering the lower coal seam of temperature, and release heat, to coal seam into Row heating.After coal seam absorbs heat, temperature is increased, and regional coal-seam temperature controls in a certain range, makes the initial condition in coal seam Divide evaporation, discongests gas migration channel.In addition, gas molecular thermalmotion under thermogenic action enhances, the ADSORPTION STATE in coal seam It is free state gas that gas, which constantly desorbs, and desorption of mash gas diffusion rate is accelerated, and flows to gas drainage hole by crack in coal, Reach fire damp pipe network after gas drainage pipe, realizes coal-bed gas enhanced gas extraction.
As shown in Figure 1, being specifically to bore gas drainage hole 5 in coal seam 7 to carry out the extraction of gas, at 5 bottom of gas drainage hole Coal seam preheating gate 11 is bored in portion, and phase-change heat-storage material is circulated into the coal seam preheating gate 11 by conveying steel pipe 6, carries out coal The preheating of layer.The coal seam being heated can volatilize methane gas, enter in the thicker gas drainage hole 5 of diameter, then pass through Gas drainage pipe 8 carries out gas drainage, and the gas of extraction enters 10 the inside of gas pipe network, conveys outward.
Embodiment two
As shown in Figure 1, a kind of extraction system for carrying out coal-bed gas enhanced gas extraction for phase-change heat-storage material, has and deposits Warehouse 1 and meter 2, storage silo 1 are connected with meter 2, and the conveying steel pipe 6 for protruding into coal seam 7 is connected on meter 2.Also Including gas pipe network 10, the gas drainage pipe 8 for protruding into coal seam 7 is connected on gas pipe network 10.It is provided on conveying steel pipe 6 defeated Send pump 3.Valve 9 is provided on gas drainage pipe 8.
In the present embodiment, storage silo 1 is used to change heat storage material of pretending, and meter 2 is used to show the phase transformation storage actually passed through Hot material flow, conveying steel pipe 6 are used to convey phase-change heat-storage material, and gas pipe network 10 is used to the device in Gas of conveying exploitation outward Body, gas drainage pipe 8 are used to mash gas extraction, and delivery pump 3 is used to provide power to the conveying of gas, and valve 9 is used as mash gas extraction Switch.
The preferred embodiment of the present invention has been described in detail above.It should be appreciated that those skilled in the art without It needs creative work according to the present invention can conceive and makes many modifications and variations.Therefore, all technologies in the art Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea Technical solution, all should be within the scope of protection determined by the claims.

Claims (10)

1. a kind of coal-bed gas enhanced gas extraction method based on phase-change heat-storage material, it is characterised in that include the following steps:
1) drill: a gas drainage hole (5) of constructing in coal seam (7) constructs one in the bottom end of the gas drainage hole (5) again A coal seam preheating gate (11);
2) it establishes extraction system: being provided with the storage silo (1) for storing phase-change heat-storage material outside the coal seam (7), this is deposited Warehouse (1) connection has conveying steel pipe (6), and the conveying steel pipe (6) extend into coal seam preheating gate (11) inside, the coal seam (7) gas pipe network (10) are additionally provided with outside, are connected with gas drainage pipe (8) on the gas pipe network (10), the gas drainage pipe (8) It extend into gas drainage hole (5);After the completion of extraction system connection, gas drainage hole (5) are sealed with hole packer (4);
3) it heats coal seam: phase-change heat-storage material is inputted into coal seam preheating gate (11) by storage silo (1) and conveying steel pipe (6), It is higher than the temperature of the coal seam (7) using the temperature of phase-change heat-storage material to heat to the coal seam (7);
4) it exploits gas: keeping the connection of gas drainage pipe (8) to gas pipe network (10) unobstructed, the gas in the coal seam (7) Gas drainage pipe (8) are flowed by gas drainage hole (5), and enter gas pipe network (10).
2. the coal-bed gas enhanced gas extraction method based on phase-change heat-storage material as described in claim 1, it is characterised in that: in institute It states in drill process, driller's length of the gas drainage hole (5) is 30m-50m.
3. the coal-bed gas enhanced gas extraction method based on phase-change heat-storage material as claimed in claim 2, it is characterised in that: in institute It states in drill process, driller's diameter of the gas drainage hole (5) is 110mm-140mm.
4. the coal-bed gas enhanced gas extraction method based on phase-change heat-storage material as described in claim 1, it is characterised in that: in institute It states in drill process, driller's length of the coal seam preheating gate (11) is 40m-60m.
5. the coal-bed gas enhanced gas extraction method based on phase-change heat-storage material as claimed in claim 4, it is characterised in that: in institute It states in drill process, driller's diameter of the coal seam preheating gate (11) is 25mm-55mm.
6. the coal-bed gas enhanced gas extraction method based on phase-change heat-storage material as described in claim 1, it is characterised in that: in coal In layer heating steps, the phase-change heat-storage material passes through meter (2) during transportation and conveying capacity is measured and shown, Power is provided to conveying by delivery pump (3), and controls flow, and then control the temperature in the coal seam (7).
7. the coal-bed gas enhanced gas extraction method based on phase-change heat-storage material as claimed in claim 6, it is characterised in that: described The temperature in coal seam (7) interior temperature field is controlled at 55 DEG C -60 DEG C.
8. a kind of extraction system for carrying out coal-bed gas enhanced gas extraction for phase-change heat-storage material, it is characterised in that: including storage Storehouse (1) and meter (2), the storage silo (1) is connected with meter (2), and is connected on the meter (2) and is protruded into coal seam (7) conveying steel pipe (6);
Further include gas pipe network (10), the gas drainage pipe (8) for protruding into coal seam (7) is connected on the gas pipe network (10).
9. a kind of extraction system that coal-bed gas enhanced gas extraction is carried out for phase-change heat-storage material as claimed in claim 8, It is characterized in that: being provided with delivery pump (3) on the conveying steel pipe (6).
10. a kind of extraction system that coal-bed gas enhanced gas extraction is carried out for phase-change heat-storage material as claimed in claim 9, It is characterized in that: being provided with valve (9) on the gas drainage pipe (8).
CN201910162956.4A 2019-03-05 2019-03-05 Coal-bed gas enhanced gas extraction method and extraction system based on phase-change heat-storage material Pending CN110017124A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105201481A (en) * 2015-10-17 2015-12-30 山西晋煤集团技术研究院有限责任公司 Liquid CO2 phase transition multipoint fracturing and permeability increasing method
CN205593878U (en) * 2016-05-09 2016-09-21 华北科技学院 Coal body heating methane desorption experimental apparatus
US20170137704A1 (en) * 2013-08-19 2017-05-18 Baker Hughes Incorporated Apparatus and Methods for Stimulating Reservoirs Using Fluids Containing Nano/Micro Heat Transfer Elements
CN106894799A (en) * 2017-04-26 2017-06-27 华北科技学院 A kind of device and method of utilization supercritical carbon dioxide displacement coal-bed gas
CN106948816A (en) * 2017-03-21 2017-07-14 太原理工大学 Automatic energy storage high pressure fluid injection CO2Phase conversion pulse coal and rock fracturing method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170137704A1 (en) * 2013-08-19 2017-05-18 Baker Hughes Incorporated Apparatus and Methods for Stimulating Reservoirs Using Fluids Containing Nano/Micro Heat Transfer Elements
CN105201481A (en) * 2015-10-17 2015-12-30 山西晋煤集团技术研究院有限责任公司 Liquid CO2 phase transition multipoint fracturing and permeability increasing method
CN205593878U (en) * 2016-05-09 2016-09-21 华北科技学院 Coal body heating methane desorption experimental apparatus
CN106948816A (en) * 2017-03-21 2017-07-14 太原理工大学 Automatic energy storage high pressure fluid injection CO2Phase conversion pulse coal and rock fracturing method
CN106894799A (en) * 2017-04-26 2017-06-27 华北科技学院 A kind of device and method of utilization supercritical carbon dioxide displacement coal-bed gas

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
《能源百科全书》编辑委员会: "《能源百科全书》", 31 January 1997, 中国大百科全书出版社 *
刘文革: "《煤矿瓦斯防治管理和技术》", 30 June 2017, 煤炭工业出版社 *
杨涛 等: "煤层钻孔升温提高瓦斯抽放效率的新思路", 《煤炭技术》 *
王立久 等: "《新型屋面材料》", 31 October 2012, 中国建材工业出版社 *

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Application publication date: 20190716