CN110016252A - A kind of Anti- tarnishing packaging material environmental printing ink - Google Patents

A kind of Anti- tarnishing packaging material environmental printing ink Download PDF

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Publication number
CN110016252A
CN110016252A CN201910347551.8A CN201910347551A CN110016252A CN 110016252 A CN110016252 A CN 110016252A CN 201910347551 A CN201910347551 A CN 201910347551A CN 110016252 A CN110016252 A CN 110016252A
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CN
China
Prior art keywords
parts
tarnishing
packaging material
printing ink
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910347551.8A
Other languages
Chinese (zh)
Inventor
张彦粉
邹洋
李小东
王旭红
李娜
龚修端
张峻岭
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Dongguan Polytechnic
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Dongguan Polytechnic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongguan Polytechnic filed Critical Dongguan Polytechnic
Priority to CN201910347551.8A priority Critical patent/CN110016252A/en
Publication of CN110016252A publication Critical patent/CN110016252A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/103Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The present invention relates to printing material technical fields, more particularly to a kind of Anti- tarnishing packaging material environmental printing ink, raw material including following parts by weight: 3-5 parts of polysiloxanes silicone of alkyl ethylether, 2-5 parts of glycerol, 5-8 parts of octyl alconyl, 8-12 parts of organic pigment, 2-6 parts of nano silver, 15-25 parts of ethyl acetate, 10-15 parts of acrylic resin, 10-15 parts of amino resins, 15-25 parts of deionized water, 1-3 parts of auxiliary agent, polynary vinyl chloride-vinyl acetate resin 10-30 parts, 0.1-1 parts of levelling agent, 0.1-1 parts of defoaming agent, 1-5 parts of additive;Using the present invention of the printing material of the above component have many advantages, such as performance is stable, the feature of environmental protection is strong, tool is sun-proof, heat-resisting, after lamination it is non-discolouring, ink film lamination has high-intensitive pulling force and resistance to compression degree.

Description

A kind of Anti- tarnishing packaging material environmental printing ink
Technical field
The present invention relates to printing material technical fields, more particularly to a kind of Anti- tarnishing packaging material environmental printing oil Ink.
Background technique
Ink is by chromoplast (such as pigment, dyestuff), link stuff, fills out and (fill) the uniform of the material compositions such as material, additional material Mixture;It can be carried out printing, and dry in printed body;It is to have color, the pulpous state adherent with certain fluidity.Cause This, color (form and aspect), body bone (rheological properties such as dilute thick, fluidity) and drying property are three most important performances of ink. There are many their type, and physical property is also different, and some is very thick, very viscous;And some is quite dilute.Some is connected with vegetable oil work Ramming material;Some resins and solvent or water etc. make link stuff.These be all according to the object i.e. stock of printing, printing process, The type of printing plate and drying means etc. determine.
Ink is the substance that graph text information is used to form in printing process, thus ink in press act on it is not insignificant, It directly determines the contrast of image, color, clarity etc. on printed matter.In press we it should be understood that ink composition and oil The classification of ink.
Ink should have chromatic colour, good printing adaptability, suitable rate of drying.In addition, should also have one The application index of fixed solvent resistant, acid, alkali, water, light, heat etc..Increasingly with printing, paper and other requirements etc. Height also increases to the technical conditions of ink requirements.Such as the high speed multicolour press and assorted rotary press in modern age, it is desirable that Even speed was dry faster with several seconds for ink.Glass lament and gold, silver lament, art paper require the ink for having light.Print plastics Film, it is desirable that be well combined with plastic foil;Or the ink being attached together is bonded with plastic foil to the maximum extent.Print specialty printing Product, it is desirable that use photosensitive ink etc..
In the prior art, Chinese Patent Application No. CN201610721392.X discloses a kind of dedicated ring of Packaging Box Protect printing ink, Shortcomings are that fastness effect is poor, entire compression degree use intensity etc. using poor, because This needs to improve this.
Summary of the invention
To solve the above problems, the present invention provides and a kind of has that performance is stable, the feature of environmental protection is strong, tool is sun-proof, heat-resisting, after lamination The advantages that non-discolouring, ink film lamination have the Anti- tarnishing packaging material of high-intensitive pulling force and resistance to compression degree environmental printing oil Ink.
The technical scheme adopted by the invention is that: a kind of Anti- tarnishing packaging material environmental printing ink, including it is following heavy The raw material of part is measured,
3-5 parts of polysiloxanes silicone of alkyl ethylether,
2-5 parts of glycerol,
5-8 parts of octyl alconyl,
8-12 parts of organic pigment,
2-6 parts of nano silver,
15-25 parts of ethyl acetate,
10-15 parts of acrylic resin,
10-15 parts of amino resins,
15-25 parts of deionized water,
1-3 parts of auxiliary agent,
Polynary vinyl chloride-vinyl acetate resin 10-30 parts,
0.1-1 parts of levelling agent,
0.1-1 parts of defoaming agent,
1-5 parts of additive.
Further improvement of these options is the raw material including following parts by weight,
3-5 parts of polysiloxanes silicone of alkyl ethylether,
2-5 parts of glycerol,
5-8 parts of octyl alconyl,
8-12 parts of organic pigment,
2-6 parts of nano silver,
10-15 parts of ethyl acetate,
2-5 parts of acrylic resin,
15-25 parts of deionized water,
1-3 parts of auxiliary agent,
Polynary vinyl chloride-vinyl acetate resin 10-20 parts,
20-50 parts of solvent,
0.1-1 parts of levelling agent,
0.1-1 parts of defoaming agent,
1-5 parts of additive.
Further improvement of these options is the raw material including following parts by weight, the poly- silicon of alkyl ethylether polysiloxanes 4 parts of ketone,
2 parts of glycerol,
5 parts of octyl alconyl,
10 parts of organic pigment,
2 parts of nano silver,
15 parts of ethyl acetate,
10 parts of acrylic resin,
10 parts of amino resins,
15 parts of deionized water,
2 parts of auxiliary agent,
20 parts of polynary vinyl chloride-vinyl acetate resin,
5 parts of additive.
Further improvement of these options be further include parts by weight be 5-15 parts of metallic pigments, the metallic pigments For the metallic with lamellar morphology, the metallic pigments are pearl powder, silver powder, silver paste, bronze, silver paste, aluminium powder, copper gold The combination of one or more of powder, stainless steel powder, nickel powder, zinc powder, iron powder.
Further improvement of these options is that the solvent is ethyl alcohol, normal propyl alcohol, isopropanol, benzyl carbinol, butanol, second The mixing of one or more of glycol, polyethylene glycol, isooctanol, silicone oil, ethyl linoleate or eleostearic acid methyl esters.
Further improvement of these options is that the auxiliary agent is made from the following raw materials in parts by weight: silane coupling agent 5- 15 parts, 3-8 parts of tri (propylene glycol) diacrylate, 5-15 parts of beautiful jade, 1-2 parts of methacrylic acid, TAC1-2 parts of crosslinking agent, second 15-30 parts of alcohol.
Further improvement of these options is that the levelling agent is polyether-modified dimethyl silicone polymer, fluorine carbon changes One of property polyacrylate solution, alkylbenzene modified dimethyl polysiloxane, silicone diacrylate.
Further improvement of these options is, defoaming agent be polysiloxanes, dimethyl silicone polymer, tributyl phosphate, One of polyether-modified silicon.
Further improvement of these options is, the additive be one of polyethylene, polypropylene, polystyrene or Several combinations.
The beneficial effects of the present invention are:
The raw material of following parts by weight, 3-5 parts of polysiloxanes silicone of alkyl ethylether, 2-5 parts of glycerol, 5-8 parts of octyl alconyl, 8-12 parts of organic pigment, 2-6 parts of nano silver, 15-25 parts of ethyl acetate, 10-15 parts of acrylic resin, 10-15 parts of amino resins, 15-25 parts of deionized water, 1-3 parts of auxiliary agent, polynary vinyl chloride-vinyl acetate resin 10-30 parts, 0.1-1 parts of levelling agent, 0.1-1 parts of defoaming agent, add Add 1-5 parts of agent;Using the environmental printing ink of said components, chromatic flicker is beautiful, and the ink is suitable for large area silk screen Printing has many advantages, such as that performance is stable, the feature of environmental protection is strong, tool is sun-proof, heat-resisting, non-discolouring after lamination, and ink film lamination has high intensity Pulling force and resistance to compression degree, the ink it is resistance to have excellent anti-aging property.
We's invention effectively reduces the metachromatism that packaging material is occurred by such environmental effects, product with stable quality; The solvent low toxic and environment-friendly of use, be free of benzene, ketones solvent, other raw materials be also it is nontoxic to human body and environment or it is less toxic at Point;Possess excellent printing adaptability, and film forming speed is fast, not crystallization, coating is heat-resisting weather-proof, strong covering power, long service life.
Specific embodiment
The present invention is further illustrated below.
Embodiment 1
Anti- tarnishing packaging material environmental printing ink, the raw material including following parts by weight,
It 3-5 parts of polysiloxanes silicone of alkyl ethylether, 2-5 parts of glycerol, 5-8 parts of octyl alconyl, 8-12 parts of organic pigment, receives 2-6 parts of silver of rice, 15-25 parts of ethyl acetate, 10-15 parts of acrylic resin, 10-15 parts of amino resins, 15-25 parts of deionized water, 1-3 parts of auxiliary agent, polynary vinyl chloride-vinyl acetate resin 10-30 parts, 0.1-1 parts of levelling agent, 0.1-1 parts of defoaming agent, 1-5 parts of additive, in use The environmental printing ink of component is stated, chromatic flicker is beautiful, and the ink is suitable for large area silk-screen printing, has performance steady Calmly, the advantages that feature of environmental protection is strong, tool is sun-proof, heat-resisting, non-discolouring after lamination.
Embodiment 2
Anti- tarnishing packaging material environmental printing ink, the raw material including following parts by weight,
It 3-5 parts of polysiloxanes silicone of alkyl ethylether, 2-5 parts of glycerol, 5-8 parts of octyl alconyl, 8-12 parts of organic pigment, receives 2-6 parts of silver of rice, 10-15 parts of ethyl acetate, 2-5 parts of acrylic resin, 15-25 parts of deionized water, 1-3 parts of auxiliary agent, polynary chlorine vinegar 10-20 parts of resin, 20-50 parts of solvent, 0.1-1 parts of levelling agent, 0.1-1 parts of defoaming agent, 1-5 parts of additive, using said components Environmental printing ink, chromatic flicker is beautiful, and the ink is suitable for large area silk-screen printing, after having sun-proof, heat-resisting, lamination The advantages that non-discolouring, ink film lamination have high-intensitive pulling force and resistance to compression degree.
Embodiment 3
Anti- tarnishing packaging material environmental printing ink, the raw material including following parts by weight,
4 parts of silicone of alkyl ethylether polysiloxanes, 2 parts of glycerol, 5 parts of octyl alconyl, 10 parts of organic pigment, 2 parts of nano silver, 15 parts of ethyl acetate, 10 parts of acrylic resin, 10 parts of amino resins, 15 parts of deionized water, 2 parts of auxiliary agent, polynary vinyl chloride-vinyl acetate resin 20 Part, 5 parts of additive, using the environmental printing ink of said components, chromatic flicker is beautiful, and the ink is suitable for large area silk Wire mark brush has many advantages, such as that performance is stable, the feature of environmental protection is strong, tool is sun-proof, heat-resisting, non-discolouring after lamination, and ink film lamination has high-strength The pulling force and resistance to compression degree of degree, the resistance to of the ink have excellent anti-aging property.
Embodiment 4
It further include the metallic pigments that parts by weight are 5-15 parts, the metallic pigments are the metallic with lamellar morphology, The metallic pigments are pearl powder, silver powder, silver paste, bronze, silver paste, aluminium powder, Cu-Zn alloy powder, stainless steel powder, nickel powder, zinc powder, iron powder One or more of combination.
Embodiment 5
Solvent is ethyl alcohol, normal propyl alcohol, isopropanol, benzyl carbinol, butanol, ethylene glycol, polyethylene glycol, isooctanol, silicone oil, sub- oil The mixing of one or more of acetoacetic ester or eleostearic acid methyl esters.
Auxiliary agent is made from the following raw materials in parts by weight: 5-15 parts of silane coupling agent, tri (propylene glycol) diacrylate 3-8 Part, 5-15 parts of beautiful jade, 1-2 parts of methacrylic acid, TAC1-2 parts of crosslinking agent, 15-30 parts of ethyl alcohol.
Embodiment 6
Levelling agent is polyether-modified dimethyl silicone polymer, fluorine-carbon modified polyacrylate solution, alkylbenzene are modified poly- One of dimethyl siloxane, silicone diacrylate.
Defoaming agent is one of polysiloxanes, dimethyl silicone polymer, tributyl phosphate, polyether-modified silicon.
Additive is the combination of one or more of polyethylene, polypropylene, polystyrene.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention Protect range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.

Claims (9)

1. a kind of Anti- tarnishing packaging material environmental printing ink, it is characterised in that: the raw material including following parts by weight,
3-5 parts of polysiloxanes silicone of alkyl ethylether,
2-5 parts of glycerol,
5-8 parts of octyl alconyl,
8-12 parts of organic pigment,
2-6 parts of nano silver,
15-25 parts of ethyl acetate,
10-15 parts of acrylic resin,
10-15 parts of amino resins,
15-25 parts of deionized water,
1-3 parts of auxiliary agent,
Polynary vinyl chloride-vinyl acetate resin 10-30 parts,
0.1-1 parts of levelling agent,
0.1-1 parts of defoaming agent,
1-5 parts of additive.
2. a kind of Anti- tarnishing packaging material environmental printing ink according to claim 1, it is characterised in that: including following The raw material of parts by weight,
3-5 parts of polysiloxanes silicone of alkyl ethylether,
2-5 parts of glycerol,
5-8 parts of octyl alconyl,
8-12 parts of organic pigment,
2-6 parts of nano silver,
10-15 parts of ethyl acetate,
2-5 parts of acrylic resin,
15-25 parts of deionized water,
1-3 parts of auxiliary agent,
Polynary vinyl chloride-vinyl acetate resin 10-20 parts,
20-50 parts of solvent,
0.1-1 parts of levelling agent,
0.1-1 parts of defoaming agent,
1-5 parts of additive.
3. a kind of Anti- tarnishing packaging material environmental printing ink according to claim 1, it is characterised in that: including following The raw material of parts by weight,
4 parts of silicone of alkyl ethylether polysiloxanes,
2 parts of glycerol,
5 parts of octyl alconyl,
10 parts of organic pigment,
2 parts of nano silver,
15 parts of ethyl acetate,
10 parts of acrylic resin,
10 parts of amino resins,
15 parts of deionized water,
2 parts of auxiliary agent,
20 parts of polynary vinyl chloride-vinyl acetate resin,
5 parts of additive.
4. a kind of Anti- tarnishing packaging material environmental printing ink according to claim 1, it is characterised in that: further include weight The metallic pigments that part is 5-15 parts are measured, the metallic pigments are the metallic with lamellar morphology, and the metallic pigments are pearl One or more of light powder, silver powder, silver paste, bronze, silver paste, aluminium powder, Cu-Zn alloy powder, stainless steel powder, nickel powder, zinc powder, iron powder Combination.
5. a kind of Anti- tarnishing packaging material environmental printing ink according to claim 2, it is characterised in that: the solvent For ethyl alcohol, normal propyl alcohol, isopropanol, benzyl carbinol, butanol, ethylene glycol, polyethylene glycol, isooctanol, silicone oil, ethyl linoleate or tung oil The mixing of one or more of sour methyl esters.
6. a kind of Anti- tarnishing packaging material environmental printing ink according to claim 1, it is characterised in that: the auxiliary agent It is made from the following raw materials in parts by weight: 5-15 parts of silane coupling agent, 3-8 parts of tri (propylene glycol) diacrylate, beautiful jade 5-15 Part, 1-2 parts of methacrylic acid, TAC1-2 parts of crosslinking agent, 15-30 parts of ethyl alcohol.
7. a kind of Anti- tarnishing packaging material environmental printing ink according to claim 1, it is characterised in that: the levelling Agent be polyether-modified dimethyl silicone polymer, fluorine-carbon modified polyacrylate solution, alkylbenzene modified dimethyl polysiloxane, One of silicone diacrylate.
8. a kind of Anti- tarnishing packaging material environmental printing ink according to claim 1, it is characterised in that: the defoaming Agent is one of polysiloxanes, dimethyl silicone polymer, tributyl phosphate, polyether-modified silicon.
9. a kind of Anti- tarnishing packaging material environmental printing ink according to claim 1, it is characterised in that: the addition Agent is the combination of one or more of polyethylene, polypropylene, polystyrene.
CN201910347551.8A 2019-04-28 2019-04-28 A kind of Anti- tarnishing packaging material environmental printing ink Pending CN110016252A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910347551.8A CN110016252A (en) 2019-04-28 2019-04-28 A kind of Anti- tarnishing packaging material environmental printing ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910347551.8A CN110016252A (en) 2019-04-28 2019-04-28 A kind of Anti- tarnishing packaging material environmental printing ink

Publications (1)

Publication Number Publication Date
CN110016252A true CN110016252A (en) 2019-07-16

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Family Applications (1)

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Country Status (1)

Country Link
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104263070B (en) * 2014-09-03 2016-05-11 安徽雅美油墨有限公司 One brightens durable composite environmental-friendly printing-ink
CN107674496A (en) * 2017-08-25 2018-02-09 惠州德斯坤实业有限公司 A kind of smart card screen printing ink
CN107778982A (en) * 2016-08-25 2018-03-09 天津市有为印刷包装有限公司 A kind of Packaging Box special environment protection printing-ink and preparation method thereof
JP2018193543A (en) * 2018-04-16 2018-12-06 株式会社セイコーアドバンス Insulating printing ink for light shielding and insulating member

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104263070B (en) * 2014-09-03 2016-05-11 安徽雅美油墨有限公司 One brightens durable composite environmental-friendly printing-ink
CN107778982A (en) * 2016-08-25 2018-03-09 天津市有为印刷包装有限公司 A kind of Packaging Box special environment protection printing-ink and preparation method thereof
CN107674496A (en) * 2017-08-25 2018-02-09 惠州德斯坤实业有限公司 A kind of smart card screen printing ink
JP2018193543A (en) * 2018-04-16 2018-12-06 株式会社セイコーアドバンス Insulating printing ink for light shielding and insulating member

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Application publication date: 20190716

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