CN110003659A - A kind of heat-conducting silicone grease - Google Patents

A kind of heat-conducting silicone grease Download PDF

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Publication number
CN110003659A
CN110003659A CN201910344545.7A CN201910344545A CN110003659A CN 110003659 A CN110003659 A CN 110003659A CN 201910344545 A CN201910344545 A CN 201910344545A CN 110003659 A CN110003659 A CN 110003659A
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heat
aluminum nitride
dosage
nitride powder
diamond dust
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任剑颖
杜龙心
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Sichuan Limitless Electric Technology Co Ltd
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Sichuan Limitless Electric Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/28Nitrogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/08Materials not undergoing a change of physical state when used
    • C09K5/10Liquid materials
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/08Materials not undergoing a change of physical state when used
    • C09K5/14Solid materials, e.g. powdery or granular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/28Nitrogen-containing compounds
    • C08K2003/282Binary compounds of nitrogen with aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
  • Lubricants (AREA)

Abstract

A kind of heat-conducting silicone grease, including silicone oil, aluminum nitride powder, also there is diamond dust, lauryl sodium sulfate, amino alcohol solvay-type titanate esters, diamond dust grain size specification is W5 and two kinds of W0.25, wherein the ratio of partial size W5 and W0.25 is 3:1, silicon oil dosage is 24 percent, aluminum nitride powder dosage is 50 percent, diamond dust dosage is 15 percent, lauryl sodium sulfate dosage is 10, the dosage of amino alcohol solvay-type titanate esters is 1 percent, silicone oil, the diamond dust of aluminum nitride powder and partial size W5 are as base-material, lauryl sodium sulfate, the diamond dust of amino alcohol solvay-type titanate esters and partial size W0.25 are as auxiliary material, above-mentioned each raw material reconciles through high temperature.The present invention effectively increases the thermal coefficient of finished product, ensure that integrated circuit effectively radiates in use, improves integrated circuit operation performance and reduces the probability of damage.Based on above-mentioned, so the application prospect that the present invention has had.

Description

A kind of heat-conducting silicone grease
Technical field
The present invention relates to electronic device auxiliary material field, especially a kind of heat-conducting silicone grease.
Background technique
Temperature rise can be generated in the work such as relatively high power integrated circuit, therefore in practical application, relatively high power integrated circuit one As need using cooling fin and radiator fan, the heat generated for its work radiates, and then guarantees its normal working performance, Also it is unlikely to damage because temperature rise is excessively high.For example normal temperature can guarantee its normal work at 75 DEG C or less to computer CPU at work Make, temperature is more than 80 DEG C or more and is easy to cause computer crash or automatic shutdown, or even because temperature is excessively high cause CPU burn to User brings larger economic loss;Under actual conditions, cpu temperature is lower, and work runnability is higher, otherwise performance is poorer;Cause This computer CPU is provided with cooling fin and radiator fan as CPU heat dissipation.Since manufacturing process limits, it is impossible to accomplish CPU shell table Face and the absolute mirror surface of spreader surface, in order to guarantee cooling fin heating surface and CPU surface of shell be effectively bonded it is thermally conductive, therefore It needs to spread heat-conducting silicone grease between the surface of shell of CPU and the binding face of cooling fin, guarantees leakproofness between the two, and lead to Heat-conducting silicone grease is crossed to distribute the heat walking guide that CPU is generated through cooling fin and radiator fan.
Existing heat-conducting silicone grease mainly includes that (main Heat Conduction Material, there are also use and aluminium nitride for Heat Conduction Material aluminum nitride powder The boron nitride that mealiness can approach) and the composition such as silicone oil, limit by its composition material, although existing heat-conducting silicone grease aluminum nitride powder tool There are very low specific heat capacity (22.87J/(kg. DEG C of specific data), has the characteristics that temperature rise is fast, but its thermal coefficient only has The left and right 300W/ (mK), since the aluminum nitride powder content of heat-conducting silicone grease typically constitutes from the percentage of all material on 60 percent left side Right (excessively will lead to end properties variation, mobility is small, can not effectively be bonded the surface of CPU and cooling fin), the conducts such as silicone oil Basic material thermal coefficient is lower, therefore the thermal coefficient gross data of finished product heat-conducting silicone grease only has 180W/ (mK), actual conditions It is, since the aluminum nitride powder partial size that existing heat-conducting silicone grease uses is minimum, to be applied to after thermally conductive sheet lower end and the upper end CPU, nitrogen Changing can not effectively contact between aluminium powder grain and aluminium nitride powder, be also impossible to effectively between thermally conductive sheet lower end and the upper end CPU Contact, thermal resistance thus can be generated between aluminium nitride powder and aluminium nitride powder (namely can not effectively transmit heat between gap Amount), actual thermal conductivity only has the left and right 1-5W/ (mK), therefore effectively CPU can not be made to cool down, this is also that existing CPU etc. can not be real The main reason for existing overclocking.And existing heat-conducting silicone grease is limited since proportion forms, and after heat effect, is easy to appear viscosity Situations such as being lower causes heat-conducting silicone grease after smearing to flow out between CPU and the surface of cooling fin or aluminum nitride powder is out of silicone grease It is precipitated, it is even more impossible to guarantee the effect of heat dissipation in this way.
Summary of the invention
In order to overcome existing heat-conducting silicone grease because constituent limits, it is poor that there are thermal conductivitys, can not effectively be relatively high power collection It is thermally conductive at circuit and then the drawbacks of effectively radiate through cooling fin, radiator fan, the present invention provides use partial size for W5's or so Lauryl sodium sulfate, amino alcohol solvay-type metatitanic acid is added as thermally conductive main material in diamond dust and aluminum nitride powder In conjunction with the finished product that silicone grease forms the reunion and fusion of a variety of materials can be not only effectively ensured, and increase the sticky of finished product in ester Degree, and combination aluminum nitride powder specific heat capacity is low, temperature rise is fast, the big spy of bortz powder thermal coefficient (thermal coefficient is in 2000W/mK) Point, after smearing, partial size is that the diamond dust of W5 or so can effectively be bonded the shell upper end radiating surface and radiating copper of integrated circuit (for the radiator mirror surface that in the prior art, object finely polishes at present in W5 or so, partial size is the gold of W5 or so between the lower end of piece Hard rock powder can be effectively bonded between the shell upper end radiating surface of integrated circuit and the lower end of radiating copper sheet), integrated circuit generates Heat efficiency act on aluminum nitride powder, aluminum nitride powder temperature rise transfers heat to bortz powder in time fastly, and then leads with height The bortz powder of heating rate can effectively transfer heat to radiating copper sheet, and bortz powder dosage is 20 or so percent, due to gold Emery partial size and cooling fin, integrated circuit shell radiating surface gap close to consistent, can effective, thermal conductivity at least exists 300W/(mK), the thermal coefficient for thus effectively increasing finished product ensure that integrated circuit effectively radiates in use, improve collection At circuit working performance and a kind of heat-conducting silicone grease for reducing damage probability.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of heat-conducting silicone grease, including silicone oil, aluminum nitride powder, it is characterised in that also have diamond dust, lauryl sodium sulfate, Amino alcohol solvay-type titanate esters, diamond dust grain size specification are W5 and two kinds of W0.25, wherein the ratio of partial size W5 and W0.25 For 3:1, silicon oil dosage is 24 percent, aluminum nitride powder dosage is 50 percent, diamond dust dosage is percent 15, lauryl sodium sulfate dosage is 10, the dosage of amino alcohol solvay-type titanate esters is 1 percent, silicone oil, The diamond dust of aluminum nitride powder and partial size W5 are as base-material, lauryl sodium sulfate, amino alcohol solvay-type titanate esters and partial size The diamond dust of W0.25 reconciles as auxiliary material, above-mentioned each raw material through high temperature.
In the heat-conducting silicone grease preparation, first silicone oil is poured into the thermostatic container of process equipment, in thermostatic container in temperature After being raised to 80 DEG C or so, constant temperature in thermostatic container is kept, partial size W5 and W0.25 is then successively added in thermostatic container respectively Bortz powder and aluminum nitride powder start the rabbling mechanism of process equipment, and rabbling mechanism is stirred continuously material in thermostatic container, interval After ten minutes, after above-mentioned material stirs, stopping is stirred into next process.
After the bortz powder and aluminum nitride powder, silicone oil material stir, lauryl sodium sulfate, amino alcohol Solvay-type titanate esters are added in material, and continue to guarantee the temperature of thermostatic container, open the rabbling mechanism of process equipment, blender Structure is stirred continuously silicone oil in thermostatic container, aluminum nitride powder, diamond dust, lauryl sodium sulfate, amino alcohol solvay-type metatitanic acid Ester material, after twenty minutes, after above-mentioned material stirs, material just obtains finished product after stopping stirring cooling at interval, at The laggard marketing of product packaging is sold.
In the rabbling mechanism whipping process of the process equipment, agitating shaft stirs for a period of time, counterclockwise according to clockwise Stir a period of time stirring sequence be stirred, fully ensure that stirring after material it is uniform.
The medicine have the advantages that the present invention is in use, be uniformly applied to finished product the shell upper end heat dissipation of integrated circuit Between face and the heat-absorbent surface of cooling fin.The present invention can effectively allow silicone oil and Nano diamond, nitridation using lauryl sodium sulfate Aluminium powder is perfectly combined, and the reunion and fusion of a variety of materials can be effectively ensured, moreover it is possible to be prevented subsequent in use, aluminum nitride powder, Buddha's warrior attendant Mountain flour etc. is precipitated out of silicone oil, and performance is more stable;The viscosity of finished product is increased using amino alcohol solvay-type titanate esters, not only Conducive to the smearing in use, character will not cause product from integrated circuit because mobility enhances after also ensuring finished product heat absorption It is flowed out between shell upper end radiating surface and the heat-absorbent surface of cooling fin and then heat dissipation performance is caused to be deteriorated.Present invention combination aluminium nitride Powder specific heat capacity is low, thermal coefficient is big, and the big feature of bortz powder thermal coefficient (thermal coefficient is in 2000W/mK) (lead by bortz powder Hot coefficient is big but specific heat capacity is high, temperature rise is slow), after smearing, partial size is that the diamond dust of W5 or so can effectively be bonded integrated electricity (in the prior art, the radiator mirror that object finely polishes at present between the shell upper end radiating surface on road and the lower end of radiating copper sheet In W5 or so, partial size is that the diamond dust of W5 or so can effectively be bonded the shell upper end radiating surface and radiating copper of integrated circuit in face Between the lower end of piece), the heat efficiency that integrated circuit generates acts on aluminum nitride powder, and aluminum nitride powder temperature rise fastly in time passes heat Bortz powder is passed, and then the bortz powder with big thermal conductivity can effectively transfer heat to radiating copper sheet, bortz powder is used Amount 20 or so percent, due to bortz powder partial size and cooling fin, integrated circuit shell radiating surface gap close to consistent, Energy effective, thermal conductivity is at least in 300W/(mK), the thermal coefficient of finished product is thus effectively increased, ensure that in use and collect It effectively radiates at circuit, improve integrated circuit operation performance and reduces the probability of damage.Based on above-mentioned, so the present invention has The application prospect having had.
Detailed description of the invention
The present invention is described further below in conjunction with drawings and examples.
Fig. 1 is that invention constitutes block diagram signal.
Specific embodiment
Shown in Fig. 1, a kind of heat-conducting silicone grease, including silicone oil, aluminum nitride powder, also there is diamond dust, dodecyl sulphur Sour sodium, amino alcohol solvay-type titanate esters, diamond dust grain size specification be W5 and two kinds of W0.25, wherein partial size W5 and W0.25 Ratio is 3:1, and silicon oil dosage is 24 percent, aluminum nitride powder dosage is 50 percent, diamond dust dosage is hundred / mono- ten five, lauryl sodium sulfate dosage is 10, the dosage of amino alcohol solvay-type titanate esters is 1 percent, silicon The diamond dust of oil, aluminum nitride powder and partial size W5 is as base-material, lauryl sodium sulfate, amino alcohol solvay-type titanate esters and grain The diamond dust of diameter W0.25 reconciles as auxiliary material, above-mentioned each raw material through high temperature.
Shown in Fig. 1, in heat-conducting silicone grease preparation, first silicone oil is poured into the thermostatic container of process equipment, in thermostatic container After temperature rises to 80 DEG C or so, keep thermostatic container in constant temperature, then respectively successively in thermostatic container be added partial size W5 and The bortz powder and aluminum nitride powder of W0.25, starts the rabbling mechanism of process equipment, and rabbling mechanism is stirred continuously object in thermostatic container Material, after ten minutes, after above-mentioned material stirs, stopping is stirred into next process at interval.Bortz powder and nitrogen After change aluminium powder, silicone oil material stir, lauryl sodium sulfate, amino alcohol solvay-type titanate esters are added in material, And continue to guarantee the temperature of thermostatic container, the rabbling mechanism of process equipment is opened, rabbling mechanism is stirred continuously silicon in thermostatic container Oil, aluminum nitride powder, diamond dust, lauryl sodium sulfate, amino alcohol solvay-type titanate esters material, interval after twenty minutes, to After above-mentioned material stirs, material just obtains finished product after stopping stirring cooling, and the laggard marketing of finished product packing is sold.Processing is set In standby rabbling mechanism whipping process, agitating shaft stirs the stirring of a period of time according to stirring a period of time clockwise, counterclockwise Sequence be stirred, fully ensure that stirring after material it is uniform.
Shown in Fig. 1, the present invention is in use, be uniformly applied to finished product shell upper end radiating surface and the heat dissipation of integrated circuit Between the heat-absorbent surface of piece.The present invention can effectively allow silicone oil and Nano diamond, aluminum nitride powder perfect using lauryl sodium sulfate The reunion and fusion of a variety of materials can be effectively ensured in fusion, moreover it is possible to prevent it is subsequent in use, aluminum nitride powder, bortz powder etc. from It is precipitated in silicone oil, performance is more stable.The viscosity of finished product is increased using amino alcohol solvay-type titanate esters, is not only conducive to use In smearing, also ensure finished product heat absorption after character will not because mobility enhance due to lead to shell upper end of the product from integrated circuit It is flowed out between radiating surface and the heat-absorbent surface of cooling fin and then heat dissipation performance is caused to be deteriorated.Present invention combination aluminum nitride powder specific heat capacity It is low, thermal coefficient is big, big feature (the bortz powder thermal coefficient of bortz powder thermal coefficient (thermal coefficient is in 2000W/mK) Greatly, but specific heat capacity is high, temperature rise is slow, and specific heat capacity is on a 399.84J/(kg DEG C of left side), after smearing, partial size is the diamond of W5 or so Powder can effectively be bonded between the shell upper end radiating surface of integrated circuit and the lower end of radiating copper sheet (in the prior art, object at present For the radiator mirror surface that part finely polishes in W5 or so, partial size is that the diamond dust of W5 or so can effectively be bonded the shell of integrated circuit Between body upper end radiating surface and the lower end of radiating copper sheet), the heat efficiency that integrated circuit generates acts on aluminum nitride powder, aluminium nitride Powder temperature rise transfers heat to bortz powder in time fastly, and then the bortz powder with big thermal conductivity can be transferred heat to effectively Radiating copper sheet, bortz powder dosage is 20 or so percent, due to the shell of bortz powder partial size and cooling fin, integrated circuit Radiating surface gap is close to unanimously, and energy effective, thermal conductivity is at least in 300W/(mK), thus effectively increase the thermally conductive of finished product Coefficient ensure that integrated circuit effectively radiates in use, improves integrated circuit operation performance and reduces the probability of damage.This Invention partial size is existing for the diamond dust of W0.25 or so can effectively make between cooling integrated face and heat sink face Microscopic gaps are filled, and cooling integrated face and heat sink face can more be effectively ensured in conjunction with the bortz powder of partial size W5 Between be sufficiently bonded thermally conductive, reach better heat transfer efficiency, thus effectively increase the thermal coefficient of finished product, ensure that in use Integrated circuit effectively radiates, and improves integrated circuit operation performance and reduces the probability of damage.
Basic principles and main features and advantages of the present invention of the invention have been shown and described above, for this field skill For art personnel, it is clear that the present invention is limited to the details of above-mentioned exemplary embodiment, and without departing substantially from spirit or base of the invention In the case where eigen, the present invention can be realized in other specific forms.It therefore, in all respects, should all be by reality Apply example and regard exemplary as, and be non-limiting, the scope of the present invention by appended claims rather than above description It limits, it is intended that including all changes that fall within the meaning and scope of the equivalent elements of the claims in the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (4)

1. a kind of heat-conducting silicone grease, including silicone oil, aluminum nitride powder, it is characterised in that also have diamond dust, dodecyl sulphate Sodium, amino alcohol solvay-type titanate esters, diamond dust grain size specification are W5 and two kinds of W0.25, wherein the ratio of partial size W5 and W0.25 Example is 3:1, and silicon oil dosage is 24 percent, aluminum nitride powder dosage is 50 percent, diamond dust dosage is percentage One of 15, lauryl sodium sulfate dosage be 10, the dosage of amino alcohol solvay-type titanate esters is 1 percent, silicon The diamond dust of oil, aluminum nitride powder and partial size W5 is as base-material, lauryl sodium sulfate, amino alcohol solvay-type titanate esters and grain The diamond dust of diameter W0.25 reconciles as auxiliary material, above-mentioned each raw material through high temperature.
2. a kind of heat-conducting silicone grease according to claim 1, it is characterised in that in heat-conducting silicone grease preparation, first pour into silicone oil and add In the thermostatic container of construction equipment, after temperature rises to 80 DEG C or so in thermostatic container, constant temperature in thermostatic container is kept, is then distinguished The bortz powder and aluminum nitride powder of partial size W5 and W0.25 are successively added in thermostatic container, starts the rabbling mechanism of process equipment, Rabbling mechanism is stirred continuously material in thermostatic container, and interval after ten minutes, after above-mentioned material stirs, stops stirring Into next process.
3. a kind of heat-conducting silicone grease according to claim 2, it is characterised in that bortz powder and aluminum nitride powder, silicone oil material fill Divide after mixing evenly, lauryl sodium sulfate, amino alcohol solvay-type titanate esters are added in material, and continues to guarantee thermostatic container Temperature, open the rabbling mechanism of process equipment, rabbling mechanism is stirred continuously silicone oil in thermostatic container, aluminum nitride powder, diamond Powder, lauryl sodium sulfate, amino alcohol solvay-type titanate esters material, interval after twenty minutes, are sufficiently stirred to above-mentioned material After even, material just obtains finished product after stopping stirring cooling, and the laggard marketing of finished product packing is sold.
4. a kind of heat-conducting silicone grease according to claim 2, it is characterised in that in the rabbling mechanism whipping process of process equipment, Agitating shaft stirs the stirring sequence of a period of time according to stirring a period of time clockwise, counterclockwise and is stirred, and fully ensures that and stirs Mix the uniform of rear material.
CN201910344545.7A 2019-04-26 2019-04-26 A kind of heat-conducting silicone grease Pending CN110003659A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101104738A (en) * 2006-07-12 2008-01-16 信越化学工业株式会社 Heat conductive silicone grease composition and cured product thereof
US20080234421A1 (en) * 2007-03-23 2008-09-25 Zep Ip Holding Llc Optically-Enhanced Tire Preparation
CN102134474A (en) * 2010-12-29 2011-07-27 深圳市优宝惠新材料科技有限公司 Thermal grease composition
CN109206912A (en) * 2017-07-06 2019-01-15 河北高富氮化硅材料有限公司 A kind of insulating heat conductive silicon grease composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101104738A (en) * 2006-07-12 2008-01-16 信越化学工业株式会社 Heat conductive silicone grease composition and cured product thereof
US20080234421A1 (en) * 2007-03-23 2008-09-25 Zep Ip Holding Llc Optically-Enhanced Tire Preparation
CN102134474A (en) * 2010-12-29 2011-07-27 深圳市优宝惠新材料科技有限公司 Thermal grease composition
CN109206912A (en) * 2017-07-06 2019-01-15 河北高富氮化硅材料有限公司 A kind of insulating heat conductive silicon grease composition

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
钱逢麟等主编: "《涂料助剂 品种和性能手册》", 30 November 1990, 北京:化学工业出版社 *
顾伟程等主编: "《新编皮肤科用药手册》", 1 March 1997, 北京医科大学 中国协和医科大学联合出版社 *

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