CN109998934A - Cosmetic composition and its application method - Google Patents
Cosmetic composition and its application method Download PDFInfo
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- CN109998934A CN109998934A CN201910155368.8A CN201910155368A CN109998934A CN 109998934 A CN109998934 A CN 109998934A CN 201910155368 A CN201910155368 A CN 201910155368A CN 109998934 A CN109998934 A CN 109998934A
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- silica aerogel
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/61—Surface treated
- A61K2800/612—By organic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/61—Surface treated
- A61K2800/62—Coated
- A61K2800/622—Coated by organic compounds
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- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
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- Birds (AREA)
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Abstract
The present invention relates to cosmetic composition and its application methods.The present invention relates to a kind of keratin material (especially skin and lip, hair and nail), apply some make up composition.The invention further relates to the cosmetic methods for using the composition processing keratin material.More specifically, which includes the mixture of following component: at least one wax contains at least one fatty acid with 16 to 18 carbon atoms or its mixture；With hydrophobic silica aerogel particle, unit mass specific surface area (SM) it is 500 to 1500m2/ g, and be 1 to 1500 μm with the size that volume mean diameter (D [0.5]) indicates.
Description
The application be application No. is 201280074038.2(international filing date be on June 21st, 2012), it is entitled
The divisional application of the PCT application into thenational phase of " cosmetic composition and its application method ".
The present invention relates to a kind of keratin material (especially skin and lip, hair and nail), apply some make up combination
Object.The invention further relates to the cosmetic methods for using the composition processing keratin material.
In skin care cosmetic composition field, it is known that practice be to absorb sebum and sweat using organic wax,
To skin oil-control and/or optionally to smooth crude and to cover skin blemishes.
But using that generally adjoint can dry coarse feeling and sticky feeling when these waxes, consumer be difficult to receive.And
And wax will lead at high concentrations the composition it is unstable because its crystalline size grow over time.
Fatty acid is also widely used as oil-control agent because it can generate soft feeling on the skin, but fatty acid is necessary
With high level use to obtain the oil-control effect, this is especially the selection of quality, the stability of the composition
The cost of the formula causes to limit.
It is still necessary to a kind of cosmetic composition, has effects that oil-control and/or can cover skin blemishes, tool
There are a good cosmetic properties, especially the soft feel in application, through Shi Wending, and less is limited by cost.
Applicants have discovered that there is C16 to the fatty acid of C18 carbon atom or it is mixed by combining to be selected from the composition
Close the wax and hydrophobic silica aerogel particle of object, so that it may meet the requirement.
More specifically, it is an object of the invention to cosmetic compositions, and it includes the mixtures of following component:
At least one wax, contains at least one fatty acid with 16 to 18 carbon atoms or its mixture；With
Hydrophobic silica aerogel particle, unit mass specific surface area (SM) it is 500 to 1500m2/ g, and use volume
The size that average diameter (D [0.5]) indicates is 1 to 1500 μm.
The mixture can obtain this composition, feel comfortable and soft in application, and there is oil-control and soft focus to imitate
Fruit.The mixture also meets the requirement of ageing stability.
Another object of the present invention is cosmetic composition, and it includes the mixtures of following component:
At least one wax, contains at least one fatty acid with 16 to 18 carbon atoms or its mixture；
Hydrophobic silica aerogel particle, unit mass specific surface area (SM) it is 500 to 1500m2/ g, and use volume
The size that average diameter (D [0.5]) indicates is 1 to 1500 μm；With
At least one white pigment.
The mixture can obtain this composition, have effects that oil-control and soft focus, due to reducing flaw on skin
Obvious degree and have whitening effect, and at the same time showing naked adornment appearance.
Cosmetic composition of the invention can be any kind of cosmetic composition, such as foundation cream, face powder, eye
Shadow hides free time product, blush, lipstick, lipstick, lip gloss, liner, eyebrow pencil, eyeliner, mascara, body color make-up product, pigmenting of skin
Product, care product such as nurse frost, toning frost or sunscreen product, preferably care product and such as nurse frost.
Mixture of the invention advantageously gel or frost form.
Another object of the present invention is the cosmetic method for making up and/or nursing keratin material, including will be as preceding
The step of composition of the definition is applied to the material.
Hereinafter, term "at least one" is equivalent to " one or more ", and unless otherwise clear, numberical range
Endpoint value includes in the range.
Wax
It is solid lipophilic cpd that wax of interest, which is usually under room temperature (25 DEG C), in the context of the present invention, Gu/
The conversion of liquid states of matter is reversible, and has the fusing point more than or equal to 30 DEG C, which can reach 200 DEG C and especially reach 120 DEG C of (ginsengs
See such asUllmann's Encyclopedia of Industrial Chemistry “Waxes” Uwe Wolfmeier et
al.; http://onlinelibrary.wiley.com/doi/10.1002/14356007.a28_103/pdf;It is online public
It opens: on June 15th, 2000, DOI:10.1002/14356007.a28_103; 2012 Wiley-VCH Verlag GmbH &
Co. KGaA, Weinheim;DOI:10.1002/14356007.a28_103).
Particularly, there can be the fusing point greater than 40 DEG C without decomposing suitable for wax of the invention, particularly greater than or wait
In 45 DEG C, the fusing point especially greater than or equal to 55 DEG C.
According to embodiment of the present invention, melt viscosity of the wax when being higher than 10 DEG C of dropping point must not exceed
10000mPa.s。
Can be selected from wax in the compositions of the present invention animal origin, plant origin, mineral origin or synthesis source
It is at room temperature solid wax and its mixture.The latter can be native paraffin, partially synthetic wax or fully synthetic wax (referring toUllmann's Encyclopedia of Industrial Chemistry" Waxes ", ibidem).
Therefore, by the fluid properties of wax under high temperature, it is easier to mixing, operation at such temperatures and adjusts the present invention
Composition.
As the example for being suitable for wax of the invention, alkyl wax can be especially mentioned, for example, beeswax, lanolin wax, Chinese worm
Wax, rice bran wax, Brazil wax, candelila wax, ouricury wax, esparto wax, berry wax, shellac wax, Japan tallow and lacquer tree
Wax；Lignite wax, orange wax, lemon wax, microwax, paraffin and ceresine；Polyethylene wax is obtained by Fisher-Tropsch synthesis
Wax and wax copolymer, there are also its esters.
It can also refer to through containing straight chain or branch C8-C32Aliphatic chain (preferably C16To C18Chain) animal oil
Or the fatty acid that the catalytic hydrogenation of vegetable oil obtains.Wherein, or mixtures thereof stearic acid, palmitinic acid can especially be mentioned.The present invention
Used fatty acid can be by commercially available acquisition, such as by title AEC Stearic Acid purchased from A & E Connock
(Perfumery & Cosmetics) Co., Ltd, by title Emersol purchased from Emery Oleochemical company, with name
Palmitic Acid PC is claimed to be purchased from Protameen Chemicals company.
Silicone wax (C can also be mentioned30-45Alkyl dimethicone) and fluoro wax.
It can also use and be sold by Sophim company with the title of Phytowax ricin 16L64 and 22L73
Wax, the wax obtain and to being hydrogenated with the castor oil of spermaceti alcohol esterification.This kind of wax can be found in patent application FR-A-2
792 190。
Workable wax is the olefin wax C used alone or as mixture20-C40Alkyl (hydroxy stearate acyl-oxygen
Base) stearate (alkyl includes 20-40 carbon atom).
Such wax in particular sells entitled Kester Wax K82 P by Koster Keunen company,
The product of Hydroxypolyester K 82P and Kester Wax K 80P.
Preferably, composition of the invention includes at least one wax, selected from the fat with 16 to 18 carbon atoms
Or mixtures thereof acid.
Appropriately, composition of the invention include relative to the composition total weight be 6% to 18% weight, preferably 7% to
The wax of 10% weight.
Hydrophobic silica aerogel
Aerosil is porous material, and the liquid component by substituting with air and (passing through drying) silica gel obtains.
It is usually synthesized via sol-gel process in liquid medium, is then dried, is generally passed through supercritical fluid
Extraction；It is most common a kind of for supercritical CO2.This kind of drying makes it possible the contraction for avoiding hole and material.Colloidal sol-is solidifying
Gluing method and various drying means are described in detail in Brinker CJ. and Scherer G.W., Sol-Gel Science:
New York:Academic Press, in 1990.
Unit mass specific surface area (the S for the hydrophobic silica aerogel particle being used in the present inventionM) be 500 to
1500m2/ g, preferably 600 to 1200 m2/ g and further preferred 600 to 800 m2/ g, and with volume mean diameter (D [0.5])
The size of expression is 1 to 30 μm, preferably 5 to 25 μm, further preferred 5 to 20 μm, and still more preferably 5 to 15 μm.
The unit mass specific surface area can be via BET(Brunauer-Emmett-Teller) N2 adsorption method measures,
It is described in Journal of the Amercian Chemical Society, volume 60, page 309,2 months 1938, and phase
It should be in international standard ISO 5794/1(Appendix D).The BET specific surface area corresponds to total specific surface area of particle of interest.
The size of silica aerogel particles can be measured by static light scattering using commercial particle size analyzer, such as from
2000 type of MasterSizer of Malvern.Data are handled on the basis of Mie scattering theory.The theory for it is each to
The particle of the same sex be it is accurate, for aspherical particle, make it possible the measurement of " effective " partial size.The theory especially describes
In the open source literature " Light Scattering by Small Particles " of Van de Hulst, H.C., the 9th and 10 chapters,
Wiley, New York, in 1957.
According to an advantageous embodiment, the unit matter for the hydrophobic silica aerogel particle being used in the present invention
Measure specific surface area (SM) it is 600 to 800m2/ g and be 5 to 20 μm with the size that volume mean diameter (D [0.5]) indicates, and into one
Preferably 5 to 15 μm of step.
The silica aerogel particles being used in the present invention can advantageously have 0.04g/cm3To 0.10g/cm3And it is excellent
Select 0.05g/cm3To 0.08g/cm3Tap density (r).
In the context of the present invention, which can assess according to following scheme:
The powder of 40g pours into graduated cylinder；Then graduated cylinder is placed on to 2003 machine of Stav from Stampf Volumeter
On；Then so that graduated cylinder is subjected to a series of 2500 compaction actions and (repeat volume of the operation between test twice in succession
Difference is less than 2%)；Then the final volume Vf of compacted powder is measured directly on graduated cylinder.Tap density is measured by ratio m/Vf,
It here is 40/Vf(Vf with cm3It indicates and m is indicated with g).
According to one embodiment, the unit volume specific surface of hydrophobic silica aerogel particle used in the present invention
Product SVIt is 5 to 60m2/cm3, preferably 10 to 50m2/cm3And further preferred 15 to 40m2/cm3。
Relational expression: SV=SM× r provides unit volume specific surface area, and wherein r is with g/cm3The tap density of expression, and
SMFor unit mass specific surface area defined above, with m2/ g is indicated.
Preferably, the absorbency capacity that hydrophobic silica aerogel particle according to the present invention measures at wetting point is 5
To 18ml/g, preferably 6 to 15ml/g and further preferred 8 to 12ml/g.
(W is expressed as in wetting pointP) at the absorbency capacity that measures corresponding to being added in 100g particle to obtain uniformly paste
Water needed for shape object.
It is surveyed according to the method for the oil absorption of measurement powder described in wetting point methods or standard NF T 30-022
Amount.It corresponds to the oil mass absorbed in the oil mass and/or measurement wetting point adsorbed on the active surface of powder by powder, retouches
It states as follows:
The powder of 2g amount is placed on a glass, is then added dropwise oily (isononanoic acid isononyl ester).4 to 5 drops are being added to powder
It after oil, is mixed using toolsetting, and continuously adds agglomerate of the oil until forming oil and powder.At this point, an oil dripping is once added
Then the mixture is ground with toolsetting.When obtaining solid smooth paste, stop the addition of oil.The paste must be able to spread
Exhibition on a glass without crack or it is blocking.Then the oil volume V used is recordedS(being indicated with ml).Oil absorption correspond to than
Rate VS/m。
The aeroge that the present invention uses is hydrophobic silica aerogel, the preferably (INCI of silica silylate
Title: silylated silica).
Term " hydrophobic silica " refers to that surface handles to make OH group by silyl-group through silylating agent
Si-Rn(such as trimethyl silyl group) functionalized any silica, the silylating agent such as halogenated silanes
Such as alkylchlorosilane, siloxanes especially dimethyl siloxane such as hexamethyldisiloxane or silazane.
About the preparation for the hydrophobic silica aerogel particle being modified by silylated surface, document can refer to
US 7 470 725。
The modified hydrophobic silica aerogel particle in trimethyl silyl group surface especially can be used.
As the example for the hydrophobic silica aerogel that can be used in the present invention, what be can be mentioned that includes by Dow
The aeroge that Corning company is sold with title VM-2260 (INCI: silylated silica), particle have about 1000
The average-size and 600 to 800m of micron2The unit mass specific surface area of/g.
The aeroge that also can be mentioned that be by Cabot company with number AEROGEL TLD 201, AEROGEL OGD 201,
What AEROGEL TLD 203, ENOVA AEROGEL MT 1100 and ENOVA AEROGEL MT 1200 were sold.
The aeroge that particularly can be used is by Dow Corning company with title VM-2270 (INCI: monosilane
Base SiClx stone) sale, particle has 5-15 microns of average-size and 600 to 800m2The unit mass specific surface of/g
Product.
With the meter of active material, the silica aerogel particles of the invention preferred phase in the cosmetic composition
For the composition total weight with 0.1% to 1% weight, the amount of more preferable 0.4% to 0.6% weight exists.
" white " pigment
Specific pigment used in composition of the invention refers to that the inorganic or organic granular of solution not soluble in water, the particle are
It is white, spherical or aspherical and porous or non-porous, and have and be greater than or equal to 1.6, be particularly greater than or be equal to 1.8, be preferably
1.6 to 2.5 refractive index.
" pigment " of the invention has preferably smaller than 15 microns, especially less than 10 microns of volume size.Particularly, this hair
Bright " pigment " has more than 200 nanometers, preferably greater than 500 nanometers and preferably smaller than 15 microns and especially less than 10 microns
Volume size.
Particularly, the pigment is white powder.
Term " white " is intended to particularly relate to white and its induced color (canescence, snowy white, silvery white etc.) or has
Silver color, white color, rather than primary colours and induced color.
Particularly, should " white " pigment in TSL(hue, saturation, intensity) in system close to 100 brightness value L.
MINOLTA CR400 can be used in the colour measurement of L* and C* in 1976 chrominance space of CIE Lab®Coloration color difference
Instrument carries out.
For this purpose, by the pigment percentage (such as pigment of the 5-6%) dispersion in advance of opacity can be assigned (with three
Roller machine (tricylinder) grinding) in transparence cosmetic medium, and it is subsequently added to 15 milliliters of tanks (opening diameter: 1.9 lis
Rice；Depth: 1.8 centimetres) in.By being flattened with glass slide by the surface decurl of the cosmetic vehicles of introducing.It is subsequently placed with ratio
Color ware contacts with the surface and measures colorimetric parameter.
The MINOLTA CR400®Reference white of the coloration color difference meter with 100 lightness L* value and 0 saturation degree C* value
(for the whiteware of correction, such as Spectralon) and trap light correction.
According to a particular implementation, " white " pigment of the invention, which will especially have according to aforementioned schemes, to be more than or waits
Lightness L* value in 95 and saturation degree C* value less than or equal to 3.
Composition of the invention includes and has to be greater than or equal to 1.6 refractive index and preferably smaller than 15 microns of body as a result,
Product size, especially more than 200 nanometers, preferably greater than 500 nanometers and the porous or non-porous of volume size less than 15 microns, ball
At least one pigment of shape or aspherical, inorganic or organic white particle form.
The pigment is (i) special in particular selected from titanium oxide, zinc oxide, the optionally bismuth oxychloride, the insoluble barium salt that disperse
Be not barium sulfate, calcium carbonate, calcium sulfate, the plaster of paris, mineral, animal or plant source natural powder, whiting, land plaster,
Alabaster powder or selenite powder, eggshell or shellfish powder, vegetable ivory and its mixture.
Bismuth oxychloride can as former state (in powder form) use, or advantageously in ester oil dispersion use,
The ester oil is in particular selected from Dermol 105；The different cetyl of octanoic acid；Isononyl isononanoate, isopropyl isostearate, hydroxyl are hard
Resin acid 2- ethylhexyl, stearic acid 2- octyldodecyl, the different stearyl ester of isostearic acid；And its mixture.Preferably, the chlorine
Bismuth oxide dispersion includes hydroxy stearic acid 2- ethylhexyl, such as by MERCK company with Biron®Liquid Silver runs after fame
The product of sale.
According to one kind an alternative it would also be possible to use white tone coated interference pigment as white pigment (i), the white cadre enrolled among workers
The fluorophologopite base composite particles that pigment is such as coated with titanium dioxide and tin oxide are related to, such as by ECKART company with SYNCRYSTAL
SILVER run after fame sale those of, be different from the coated interference pigment of non-white tone, such as especially Timiron Silk
Blue mica/titanium dioxide/tin oxide blue cast pearling agent.
According to a kind of particular implementation, the pigment is (i) white tone coated interference pigment.
According to another particular implementation, the pigment is (i) selected from titanium oxide, zinc oxide, the chlorine oxygen optionally dispersed
Change bismuth, insoluble barium salt especially barium sulfate, calcium carbonate, calcium sulfate, the plaster of paris, mineral, animal or plant source natural powder
End, whiting, land plaster, alabaster powder or selenite powder, eggshell or shellfish powder, vegetable ivory and its mixture, preferably titanium
Oxide, zinc oxide and its mixture, and not coated interference pigment.
According to a particular implementation, the composition includes at least titanium oxide as pigment (i), and optionally in combination with white
Tone coated interference pigment.
Not including in the definition of pigment (i) of the invention is the titanium oxide being encapsulated in silica dioxide granule, such as
The particle of porous silica comprising titanium dioxide, especially by Suzuki Oil and Fat company with God Ball PC-
LS run after fame sale particle or the PC-LS-14 that is sold by MIYOSHI KASEI.
Preferably, which is (i) selected from the titanium oxide of coating or uncoated rutile or Detitanium-ore-type.
As a result, according to a kind of particular implementation, composition of the invention includes at least coating or uncoated rutile
Or the titanium oxide of Detitanium-ore-type.
Pigment used according to the invention may or may not be at least one hydrophily or hydrophobicity inorganic agent completely or
Part of the surface processing.
For the purposes of the present invention, the surface treatment of pigment of the present invention is typically referred to using the complete of surface treating agent
Or part of the surface processing, it absorption and sorption or is grafted on the pigment.
Can according to it is well known in the art for chemistry, electronics, mechanochemistry or engineering properties surface treatment technology
Prepare the pigment of the surface treatment.Also commercial product can be used.
The surface treating agent can be evaporated by solvent, chemical reaction or covalent bond generate absorption and sorption or be grafted to
On the pigment.
The surface treatment can account for 0.1 to 50 weight % of the coating pigment total weight and specifically for 0.5 to 5 weight %.
The surface treatment for example can the pigment is mixed it is described makeup or care composition other ingredients in it
Before pass through, optionally under heat condition, make pigment under stiring and liquid surface inorganic agent be simply mixed and make the surface treating agent
The mode of solid particles surface is adsorbed on to carry out.
The surface treatment for example can be by making the chemical reaction of surface treating agent and the surface of pigments and being surface-treated
The mode of covalent bond is generated between agent and particle to carry out.This method is particularly described in patent US 4 578 266.
The chemical surface treatment may include that the surface treating agent is diluted in volatile solvent, and pigment is dispersed in this
In mixture, and then slow evaporation volatile solvent, so that surface treating agent is deposited on the surface of pigment.This volatility
Solvent can be water.
Lipophilicity or hydrophobicity inorganic agent
A kind of particular implementation according to the present invention, pigment of the invention can use at least one hydrophobicity or lipophilicity processing
Agent surface treatment, the inorganic agent are selected from siloxane surface inorganic agent；Fluorochemical surface treatment；Fluorosilicone surface treatment
Agent；Metal soap, N- acylated amino or its salt；Lecithin and its derivative；Three iso stearyl titanate esters of isopropyl；Decanedioic acid
Different stearyl ester；Plant or natural animal wax, polarity synthetic wax；Fatty ester；Fatty alcohol；Phosphatide and its mixture.
According to a kind of particular implementation, which is surface-treated with fluorochemical surface treatment, especially fluorinated alcohols surface
Inorganic agent or fluoro-alkyl surface treating agent.
According to a preferred embodiment, the pigment that the present invention can be used is surface-treated by fluorinated alcohols phosphate
Titanium dioxide.This pigment is such as with title Tudor Aspen by Kingfisher Colours companies market or with title
AC series is by Active Concepts companies market.
Hydrophily inorganic agent
According to a kind of particular implementation, which can use at least one hydrophily inorganic agent surface treatment, the inorganic agent
Selected from biopolymer, carbohydrate, polysaccharide, polyacrylate or polyethyleneglycol derivative.It can also refer to mineral agent, such as
Silica, silicate, aluminium oxide and its mixture (such as: silica/alumina).
Example as the present invention for being coated with the biopolymer to solubilized material, it can be mentioned that being based on carbohydrate
The polymer of the monomer of type, it is especially dynamic derived from algae, terrestrial plant, fungi or biotechnology, planktonic organism or segmental appendage
Those of beyond the region of objective existence shell.Particularly it can be mentioned that guar gum, locust bean gum, xanthan gum, gum arabic, sclerotium gum；Konjaku, angle
Pitch dish glue, alginate and its derivative, pectin, agar；Glycogen；Glucan；Starch and its derivative；Cellulose and its derivative
Object；Hyaluronate, such as Sodium Hyaluronate and its derivative；Soluble protein polysaccharide；Glycosaminoglycan, chitin, chitosan and
Its derivative and its mixture.
C1-C20Diol alkylene or C1-C20Diol alkylene ether, individually or with three C1-C20Alkyl silane is used in combination,
It can be used as surface treating agent.As example it can be mentioned that with PEG alkyl ether alkoxysilane surface handle pigment, such as by
KOBO company with " SW " pigment run after fame sale with PEG-8- methyl ether triethoxysilane handle pigment.
According to a kind of preferred embodiment, composition of the invention include at least titanium oxide, especially with aluminium oxide/
Silica/trimethylolpropane surface treatment TiO2, run after fame by Ishihara Sangyo with Tipaque PF671 and
It is run after fame sale by Myoshi Kasei with SA-TAO.
According to another preferred embodiment, composition of the invention includes that at least one is optionally dispersed in hydroxy stearic acid 2-
Bismuth oxychloride in ethylhexyl, such as by MERCK company with Biron®Liquid Silver runs after fame the product of sale.
According to another embodiment, composition of the invention includes at least the fluorophologopite for being coated with titanium dioxide and tin oxide
Base composite particles, such as by ECKART company with SYNCRYSTAL SILVER run after fame sale those of.
The pigment (i) usually with relative to the composition total weight for 0.1% to 4 weight %, preferably 0.5 to 3 weight %
The content of (in the carrier or in the case where being applied, referring to active material for pigment dispersion) is present in composition of the invention
In.
In the case where white tone coated interference pigment (i), as the above-mentioned fluorophologopite base for being coated with titanium dioxide and tin oxide is multiple
The case where closing particle, they will be preferably to be less than or equal to 2 weight %, especially less than relative to the composition total weight
Or the amount equal to 1 weight %, particularly less than or equal to 0.5 weight % is present in the composition.
Auxiliary agent
Composition of the invention can include common auxiliary agent in cosmetics and/or dermatology, such as activity with known way
Agent, preservative, antioxidant, complexing agent, pH adjusting agent (acid or alkalinity), fragrance, filler, fungicide, odour absorbents,
Toner (pigment and dyestuff), film forming polymer, the aliphatic ester of emulsifier such as polyethylene glycol, the aliphatic ester of glycerol and dehydration
The aliphatic ester of D-sorbite, for optionally polyoxyethylated, polyoxyethylated fatty alcohol and aliphatic ester or sugar (such as sugarcane
Sugar or glucose) ether；Thickener and/or gelling agent, especially polyacrylamide, acrylic acid series homopolymer and copolymer, and
The homopolymer and copolymer and lipid vesicle of acrylamido methyl propane sulfonic acid.The amount of these various auxiliary agents is in this field
Consideration those of uses conventional amount used, for example, the 0.5% to 3% of composition total weight.Depending on its property, these auxiliary agents can draw
Enter in fatty phase, water phase and/or lipid vesicle.
Much less, those skilled in the art can select this or these optional added compound and/or its dosage with caution,
So that the adverse effect that the oil-control of the present composition/soft focus property will not or will not substantially be added by the expection.
In the present patent application, unless in addition it is specifically mentioned, content relative to composition total weight with weight basis table
Show.
The composition and method that the following examples are used to illustrate the present invention, but the present invention is not limited in any way
Range.Unless otherwise stated, all parts and percentages in embodiment are on the basis of weight, and all measurements
Value is obtained at about 25 DEG C.
Embodiment
Embodiment 1: inventive formulation 1
Program:
Phase A to 80-85 DEG C of heating,
Phase B to phase A is added, keeps the temperature 15 minutes,
It is cooled to 70-75 DEG C, adds phase C,
It is cooled to 30-35 DEG C, adds phase D and E.
Embodiment 2: inventive formulation 2
Program:
Phase A to 80-85 DEG C of heating,
Phase B to phase A is added, keeps the temperature 15 minutes,
It is cooled to 70-75 DEG C, adds phase C,
It is cooled to 30-35 DEG C, adds phase D and E.
Embodiment 3: comparative formula 1
Program:
Phase A to 80-85 DEG C of heating,
Phase B to phase A is added, keeps the temperature 15 minutes,
It is cooled to 70-75 DEG C, adds phase C,
It is cooled to 30-35 DEG C, adds phase D.
Embodiment 4: comparative formula 2
Program:
Phase A to 80-85 DEG C of heating,
Phase B to phase A is added, keeps the temperature 15 minutes,
It is cooled to 70-75 DEG C, adds phase C,
It is cooled to 30-35 DEG C, adds phase D.
Embodiment 5: comparative formula 3
Program:
Phase B is added in phase A to 70-75 DEG C of heating,
It is cooled to 30-35 DEG C, adds phase C and D.
Embodiment 6: comparative formula 4
Program:
Phase B is added in phase A to 70-75 DEG C of heating,
It is cooled to 30-35 DEG C.
Embodiment 7: comparative test
By by 1 to 6 application to skin of embodiment, using 6 people groups come the oil resistant light effect of testing example 1 to 6.
Oil resistant light effect scores according to 0 to 5.It scores higher, the oil resistant light effect of the embodiment is better.
By being imitated on 1 to 6 application to skin of embodiment using 6 people groups come the moment whitening of testing example 1 to 6
Fruit.
Moment whitening effect scores according to 0 to 5.It scores higher, the moment whitening effect of the embodiment is better.
As shown in the table, compared with the comparative example formula of embodiment 3 to 6, composition of the invention shows obvious more preferable
Oil resistant light effect, and preferably moment whitening effect.
Embodiment 8: Oily whitening gel frost
Program:
Phase A to 80-85 DEG C of heating,
Phase B to phase A is added, keeps the temperature 15 minutes,
It is cooled to 70-75 DEG C, adds phase C1,
It is cooled to 30-35 DEG C, adds phase D, C2, E, F.
Embodiment 9: Oily skin whitener
Program:
Phase A to 80-85 DEG C of heating,
Phase B to phase A is added, keeps the temperature 15 minutes,
It is cooled to 30-35 DEG C, adds phase C and D.
Claims (15)
1. a kind of cosmetic composition, it includes:
At least one wax, is at least one fatty acid with 16 to 18 carbon atoms or its mixture；With
At least one hydrophobic silica aerogel particle, unit mass specific surface area (SM) it is 500 to 1500m2/ g, and
And with volume mean diameter (D [0.5]) indicate size be 1 to 1500 μm, and
At least one white pigment, the white pigment is selected from spherical or aspherical, porous or non-porous pigment, by least
A kind of hydrophily or hydrophobicity inorganic agent are surface-treated completely or partially,
Wherein the composition includes the wax of 6-18% weight, the total weight relative to the composition.
2. cosmetic composition according to claim 1, wherein the wax contains at least one palmitinic acid, at least one stearic acid
Or mixtures thereof.
3. according to the cosmetic composition of any one of aforementioned claim, wherein the composition includes the described of 7-10% weight
Wax, the total weight relative to the composition.
4. according to the cosmetic composition of any one of aforementioned claim, wherein the list of the hydrophobic silica aerogel particle
Position mass specific area is 600 to 1200m2/ g, and more preferable 600 to 800m2/g。
5. according to the cosmetic composition of any one of aforementioned claim, wherein the use of the hydrophobic silica aerogel particle
The size that volume mean diameter indicates is 1 to 1000 μm, preferably 1 to 100 μm, especially 1 to 30 μm, more preferable 5 to 25 μm, into
Preferably 5 to 20 μm of one step and still more preferably 5 to 15 μm.
6. according to the cosmetic composition of any one of aforementioned claim, wherein the list of the hydrophobic silica aerogel particle
Position mass specific area (SM) it is 600 to 800m2/ g, and with volume mean diameter (D [0.5]) indicate size be 5 to 20 μm and
More preferable 5 to 15 μm.
7. according to the cosmetic composition of any one of aforementioned claim, wherein the vibration of the hydrophobic silica aerogel particle
Real density is 0.04g/cm3To 0.10g/cm3And preferably 0.05g/cm3To 0.08g/cm3。
8. according to the cosmetic composition of any one of aforementioned claim, wherein the list of the hydrophobic silica aerogel particle
Position volumetric surface area SVIt is 5 to 60m2/cm3, preferably 10 to 50m2/cm3And further preferred 15 to 40m2/cm3。
9. according to the cosmetic composition of any one of aforementioned claim, wherein the hydrophobic silica aerogel particle is moistening
The absorbency capacity measured at wet point is 5 to 18ml/g, preferably 6 to 15ml/g and further preferred 8 to 12ml/g particle.
10. according to the cosmetic composition of any one of aforementioned claim, wherein the hydrophobic silica aerogel particle quilt
Trimethyl silyl group surface is modified.
11. according to the cosmetic composition of any one of aforementioned claim, wherein the composition includes 0.1% to 1% weight, it is excellent
Select the hydrophobic silica aerogel particle of 0.4% to 0.6% weight, the total weight relative to the composition.
12. according to the cosmetic composition of any one of aforementioned claim, comprising modified with trimethyl silyl group surface
Hydrophobic silica aerogel particle；With or mixtures thereof palmitinic acid, stearic acid.
13. according to the cosmetic composition of any one of aforementioned claim, wherein the white pigment is to be fluorinated surface treatment
The TiO that agent is completely or partially surface-treated2。
14. wherein the composition further includes at least one and helps according to the cosmetic composition of any one of aforementioned claim
Agent, selected from activating agent, preservative, antioxidant, complexing agent, pH adjusting agent (acid or alkalinity), fragrance, filler, fungicide,
Odour absorbents, colorant (pigment and dyestuff), film forming polymer, emulsifier, glycerol aliphatic ester and sorbitan
Aliphatic ester；Thickener, gelling agent and lipid vesicle.
15. for making up and/or nursing the cosmetic method of keratin material, including will be according to the change of any one of aforementioned claim
Cosmetic compositions are applied to the step of material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910155368.8A CN109998934A (en) | 2012-06-21 | 2012-06-21 | Cosmetic composition and its application method |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201280074038.2A CN104363882A (en) | 2012-06-21 | 2012-06-21 | In vitro method for the diagnosis and surveillance of cancer |
| CN201910155368.8A CN109998934A (en) | 2012-06-21 | 2012-06-21 | Cosmetic composition and its application method |
| PCT/CN2012/077307 WO2013189060A1 (en) | 2012-06-21 | 2012-06-21 | Cosmetic composition and method for using thereof |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280074038.2A Division CN104363882A (en) | 2012-06-21 | 2012-06-21 | In vitro method for the diagnosis and surveillance of cancer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109998934A true CN109998934A (en) | 2019-07-12 |
Family
ID=49768041
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910155368.8A Pending CN109998934A (en) | 2012-06-21 | 2012-06-21 | Cosmetic composition and its application method |
| CN201280074038.2A Pending CN104363882A (en) | 2012-06-21 | 2012-06-21 | In vitro method for the diagnosis and surveillance of cancer |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280074038.2A Pending CN104363882A (en) | 2012-06-21 | 2012-06-21 | In vitro method for the diagnosis and surveillance of cancer |
Country Status (4)
| Country | Link |
|---|---|
| CN (2) | CN109998934A (en) |
| BR (1) | BR112014031423A2 (en) |
| WO (1) | WO2013189060A1 (en) |
| ZA (1) | ZA201409029B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20180140536A1 (en) * | 2016-11-22 | 2018-05-24 | Epc Natural Products Co., Ltd. | Ivory nut powder and mannan from ivory nut |
| EP4236905A1 (en) * | 2020-10-30 | 2023-09-06 | L'oreal | Composition for conditioning keratin materials |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101530375A (en) * | 2008-03-11 | 2009-09-16 | 莱雅公司 | Cosmetic composition comprising an ascorbic acid or salicylic acid compound |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0910045A2 (en) * | 2008-03-25 | 2015-12-29 | Mary Kay Inc | tallow absorption compositions |
| FR2968984B1 (en) * | 2010-12-21 | 2012-12-14 | Oreal | COSMETIC COMPOSITION COMPRISING SILICA AEROGEL PARTICLES |
-
2012
- 2012-06-21 CN CN201910155368.8A patent/CN109998934A/en active Pending
- 2012-06-21 WO PCT/CN2012/077307 patent/WO2013189060A1/en active Application Filing
- 2012-06-21 CN CN201280074038.2A patent/CN104363882A/en active Pending
- 2012-06-21 BR BR112014031423A patent/BR112014031423A2/en not_active Application Discontinuation
-
2014
- 2014-12-09 ZA ZA2014/09029A patent/ZA201409029B/en unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101530375A (en) * | 2008-03-11 | 2009-09-16 | 莱雅公司 | Cosmetic composition comprising an ascorbic acid or salicylic acid compound |
Non-Patent Citations (1)
| Title |
|---|
| TODD OSTERGAARD ET AL: "Silica silylate aerogel for cosmetic applications", 《IP.COM JOURNAL》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013189060A8 (en) | 2015-01-29 |
| BR112014031423A2 (en) | 2017-06-27 |
| CN104363882A (en) | 2015-02-18 |
| WO2013189060A1 (en) | 2013-12-27 |
| ZA201409029B (en) | 2015-10-28 |
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