CN109989291A - A kind of anion facing paper and preparation method thereof - Google Patents
A kind of anion facing paper and preparation method thereof Download PDFInfo
- Publication number
- CN109989291A CN109989291A CN201910296315.8A CN201910296315A CN109989291A CN 109989291 A CN109989291 A CN 109989291A CN 201910296315 A CN201910296315 A CN 201910296315A CN 109989291 A CN109989291 A CN 109989291A
- Authority
- CN
- China
- Prior art keywords
- anion
- parts
- facing paper
- powder
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/42—Coatings with pigments characterised by the pigments at least partly organic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
- Paper (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a kind of anion facing papers, belong to technical field of finishing materials comprising facing paper, and it is spread evenly across the anion coating of facing paper outer surface, according to parts by weight, the raw material of the anion coating includes following components, and 30-35 parts of tourmaline powder；90-110 parts of fluorocarbon resin；20-25 parts of titanium dioxide；1-2 parts of surfactant；25-30 parts of distilled water.The present invention has system dispersed homogeneous degree height, the high advantage of Negative ion disengagement.
Description
Technical field
The present invention relates to decorating and renovating material technical field, more specifically, it relates to a kind of anion facing paper and its
Preparation method.
Background technique
It stays in the closed room of city for a long time, people can feel brain dizziness, when the place for coming forest seashore, waterfall etc.
When, people can feel spirit and QI cleaning again, and here it is the effects of negative aeroion pair.Negative aeroion is also negative oxygen ion,
Refer to and obtains excess electron and negatively charged oxygen ion.It is that oxygen molecule in air combines free electron and formed
's.Negative oxygen ion enjoys the laudatory titles such as " tie up his oxygen ", " air vitamin " in medical field.
The patent of Publication No. CN109235133A discloses a kind of anion facing paper comprising impregnated paper and uniformly painting
It is distributed in the anion concentrate on impregnated paper surface, anion concentrate includes the following component with volume percentage: distilled water
30-70%, transparent water-soluble negative ion powder 20-50%, water solubility transparent resin adhesive 5-15% and the auxiliary agent 2-8% that volatilizees, bear from
Percent by volume summation shared by component contained by sub- facing paper is 100%.
But the surface property of negative ion powder and water-soluble transparent resin adhesive differs greatly, and makes it in nonpolar polymer
Bad dispersibility in resin, is affected so as to cause Negative ion disengagement, has much room for improvement.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of anion facing paper, can be improved
The release performance of anion.
To achieve the above object, the present invention provides the following technical scheme that
A kind of anion facing paper, including facing paper, and it is spread evenly across the anion coating of facing paper outer surface, it presses
Parts by weight meter, the raw material of the anion coating include following components,
By using above-mentioned technical proposal, there is tourmaline powder characteristics, the piezoelectricity such as piezoelectricity and pyroelectricity to show as
When temperature, pressure change, the potential difference of the crystal of tourmaline can be made to generate change, the air around tourmaline will
Ionization is generated, to generate negative aeroion, plays the role of purifying air.Its pyroelectricity shows as changing in temperature
When, voltage can generate at crystallizable mineral both ends, and due to vibrating in equilbrium position, therefore dipole moment changes polar ion,
The electromagnetic radiation of far infrared band will generate, since this infra-red radiation can make human body generate fuel factor and RESONANCE ABSORPTION effect
It answers, there is health-care effect to human body.
Titanium dioxide is a kind of stable nontoxic UV absorbers, has good electricity, hot property.Titanium dioxide adds
Add, can reduce the roughness of coating surface, and the tensile strength of coating is reduced, elongation percentage increases.In addition, titanium dioxide energy
Each type organic being attached on facing paper is enough catalytically decomposed and plays bacteria-eliminating efficacy.
Contain a large amount of C-F chemical bond in fluorocarbon resin, C-F bond distance is very short, and bond energy is very big, makes it in chemistry highlightedly
Show as high heat stability and chemical inertness.
The addition of surfactant, so that each component is evenly dispersed in entire deduction system, to improve releasing for anion
Put efficiency.
Further, according to parts by weight, the raw material of the anion coating includes two (triethanolamine) metatitanic acid diisopropyls
1-3 parts of ester.
By using above-mentioned technical proposal, two (triethanolamine) metatitanic acid diisopropyl esters can occur even with tourmaline powder surface
Connection reaction, reduces the polarity on tourmaline powder surface, tourmaline powder is further uniformly distributed among system, is reduced
The intergranular reunion of tourmaline powder, the surface area relative increase of powder, to be conducive to the release of anion.Meanwhile two (three second
Hydramine) metatitanic acid diisopropyl ester and tourmaline powder react the hydrophobicity for improving tourmaline surface, and tourmaline powder is not destroyed
Crystal structure improves the compatibility of tourmaline powder and system.
Titanium dioxide surface polarity and relative density are larger, the easily natural subsidence in system.Using two (triethanolamine) titaniums
Sour diisopropyl ester is surface-treated titanium dioxide, its surface can be made by polarity transformation nonpolarity, had very strong hydrophobic
Property and biggish surface tension reduce its sedimentation rate, to improve the compatibility and dispersing uniformity of titanium dioxide and system.
Further, according to parts by weight, the raw material of the anion coating includes 15-20 parts of CuPc.
By using above-mentioned technical proposal, CuPc has structure similar with metalloporphyrin, and CuPc can be catalyzed many
Organic reaction, especially can effective activation oxygen molecule, and the autoxidation of catalyzing organic at room temperature can be to electrical
Stone release anion plays synergistic function.
In addition, CuPc can be excited, and electrons transit on the conduction band of titanium dioxide under the conditions of radiation of visible light, it is raw
At positive carbon radicals, can not and visible light absorption capacity be just provided with by the titanium dioxide of excited by visible light originally in this way, thus will
The optical response range of titanium dioxide is extended to visible light region from ultraviolet light, improves the photocatalysis efficiency of titanium dioxide.
Further, according to parts by weight, the raw material of the anion coating includes 5-10 parts of carbon nanotube.
By using above-mentioned technical proposal, the special construction of carbon nanotube can be improved the flexibility of coating, and be received by carbon
Under the anchorage effect of mitron, the cracking and obscission of coating can be effectively avoided.
Further, according to parts by weight, the raw material of the anion coating includes 15-20 parts of expanded vermiculite powder.
By using above-mentioned technical proposal, the surface of expanded vermiculite has large number of pore, has good suction
Attached ability, can adsorb the polluted gas such as indoor formaldehyde, cooperate the effect of tourmaline powder and titanium dioxide, to polluted gas into
Row is eliminated, and the purification efficiency of room air is improved.In addition, expanded vermiculite powder also has good sound-insulating and heat-insulating effect, improve
Indoor environment comfort level.
Further, the surfactant uses ammonium lauryl sulfate.
By using above-mentioned technical proposal, expanded vermiculite is the silicate of layer structure, and there is biggish surface can and dredge
Oiliness, so that fluorocarbon resin molecule is difficult to enter between its layer of structure.And the organoammonium cations energy in ammonium lauryl sulfate
It is enough that original hydrated cation between expanded vermiculite is replaced by ion-exchange reactions, thus make hydrophilic expanded vermiculite hydrophobization,
The organic cation can reduce the surface energy of expanded vermiculite simultaneously, improves the wetting action between expanded vermiculite and pitch, makes
Expanded vermiculite and pitch have good compatibility and caking property.
Another object of the present invention is to provide a kind of preparation methods of anion facing paper comprising following steps:
Step 1, the preparation of powder: tourmaline powder, titanium dioxide and carbon nanotube and expanded vermiculite powder are mutually mixed, and are used
Ball mill carries out wet ultra-fine grinding to mixed-powder, and is screened with 4000 mesh screens to mixed-powder, obtains less than 3.5 μm
Superfines；
Step 2, modification: distilled water being added into superfines, and ultrasonication 20-30min is stirred and heated to
It 40 DEG C, is filtered after two (triethanolamine) metatitanic acid diisopropyl esters and constant temperature stirring 1h is added, once uses ethyl alcohol and acetone washing
Three times, it dries, obtains modified powder；
Step 3, the preparation of coating: ammonium lauryl sulfate is added into fluorocarbon resin and stirs evenly, continuously adds steaming
Distilled water, modified powder and CuPc continuously add distilled water after ultrasonication 1-1.5h and are diluted, and obtain coating；
Step 4, coating: being spread evenly across the outer surface of facing paper by the preparation of anion facing paper, and drying obtains finished product.
In conclusion the invention has the following advantages:
1. tourmaline powder has the characteristics such as piezoelectricity and pyroelectricity, piezoelectricity shows as changing when temperature, pressure
When, the potential difference of the crystal of tourmaline can be made to generate change, the air around tourmaline will generate ionization, to generate
Negative aeroion plays the role of purifying air；
2. titanium dioxide is a kind of stable nontoxic UV absorbers, there is good electricity, hot property.Titanium dioxide adds
Add, can reduce the roughness of coating surface, and the tensile strength of coating is reduced, elongation percentage increases.In addition, titanium dioxide energy
Each type organic being attached on facing paper is enough catalytically decomposed and plays bacteria-eliminating efficacy；
3. with tourmaline powder surface coupling reaction can occur for two (triethanolamine) metatitanic acid diisopropyl esters, tourmaline powder is reduced
The polarity on surface, enables tourmaline powder to be further uniformly distributed among system, reduces the intergranular group of tourmaline powder
It is poly-, the surface area relative increase of powder, to be conducive to the release of anion.Meanwhile two (triethanolamine) metatitanic acid diisopropyl ester
The hydrophobicity on tourmaline surface is improved with reacting for tourmaline powder, and does not destroy the crystal structure of tourmaline powder, improves electricity
The compatibility of gas mountain flour and system；
4. titanium dioxide surface polarity and relative density are larger, the easily natural subsidence in system.Using two (triethanolamines)
Metatitanic acid diisopropyl ester is surface-treated titanium dioxide, its surface can be made by polarity transformation nonpolarity, have very strong dredge
Aqueous and biggish surface tension reduces its sedimentation rate, to improve the compatibility and dispersing uniformity of titanium dioxide and system；
5. CuPc has structure similar with metalloporphyrin, CuPc can be catalyzed many organic reactions, can especially have
Activating oxygen molecule, and the autoxidation of catalyzing organic at room temperature are imitated, anion can be discharged to tourmaline and play association
Same synergistic effect.In addition, CuPc can be excited, and electrons transit on the conduction band of titanium dioxide under the conditions of radiation of visible light,
Positive carbon radicals are generated, can not and visible light absorption capacity be just provided with by the titanium dioxide of excited by visible light originally in this way, thus
The optical response range of titanium dioxide is extended to visible light region from ultraviolet light, improves the photocatalysis efficiency of titanium dioxide；
6. the surface of expanded vermiculite has large number of pore, there is good adsorption capacity, it can be in adsorption chamber
The polluted gas such as formaldehyde, cooperate the effect of tourmaline powder and titanium dioxide, polluted gas eliminated, Interior Space is improved
The purification efficiency of gas.In addition, expanded vermiculite powder also has good sound-insulating and heat-insulating effect, indoor environment comfort level is improved；
7. expanded vermiculite is the silicate of layer structure, there is biggish surface energy and oleophobic property, so that fluorocarbon resin point
Son is difficult to enter between its layer of structure.And the organoammonium cations in ammonium lauryl sulfate can by ion-exchange reactions come
Original hydrated cation between displacement expanded vermiculite, to make hydrophilic expanded vermiculite hydrophobization, while the organic cation can
The surface energy for reducing expanded vermiculite, improves the wetting action between expanded vermiculite and pitch, has expanded vermiculite and pitch good
Good compatibility and caking property.
Detailed description of the invention
Fig. 1 is the flow chart of method provided by the invention.
Specific embodiment
Below in conjunction with attached drawing 1 and embodiment, invention is further described in detail.
Embodiment
Embodiment 1
A kind of anion facing paper, including facing paper, and it is spread evenly across the anion coating of facing paper outer surface, it presses
The raw material components of parts by weight meter, the anion coating are as shown in table 1.Wherein, the preparation method of the anion facing paper includes
Following steps:
Step 1, the preparation of powder: tourmaline powder, titanium dioxide and carbon nanotube and expanded vermiculite powder are mutually mixed, and are used
Ball mill carries out wet ultra-fine grinding to mixed-powder, and is screened with 4000 mesh screens to mixed-powder, obtains less than 3.5 μm
Superfines；
Step 2, modification: distilled water being added into superfines, and ultrasonication 20-30min is stirred and heated to
It 40 DEG C, is filtered after two (triethanolamine) metatitanic acid diisopropyl esters and constant temperature stirring 1h is added, once uses ethyl alcohol and acetone washing
Three times, it dries, obtains modified powder；
Step 3, the preparation of coating: being added into fluorocarbon resin and surfactant and stir evenly, continuously add distilled water,
Modified powder and CuPc continuously add distilled water after ultrasonication 1-1.5h and are diluted, and obtain coating；
Step 4, coating: being spread evenly across the outer surface of facing paper by the preparation of anion facing paper, drying obtain at
Product..
Wherein, surfactant uses ammonium lauryl sulfate
Embodiment 2
The difference from embodiment 1 is that according to parts by weight, the raw material components of anion coating are as shown in table 1.
Comparative example
Comparative example 1
The difference from embodiment 1 is that according to parts by weight, the raw material components of anion coating are as shown in table 1.
Comparative example 2
Difference with comparative example 1 is that according to parts by weight, the raw material components of anion coating are as shown in table 1.
Comparative example 3
The difference from embodiment 1 is that according to parts by weight, the raw material components of anion coating are as shown in table 1.
Comparative example 4
Difference with comparative example 3 is that according to parts by weight, the raw material components of anion coating are as shown in table 1.
Comparative example 5
The difference from embodiment 1 is that according to parts by weight, the raw material components of anion coating are as shown in table 1.
Comparative example 6
Difference with comparative example 5 is that according to parts by weight, the raw material components of anion coating are as shown in table 1.
Comparative example 7
The difference from embodiment 1 is that according to parts by weight, the raw material components of anion coating are as shown in table 1.
Comparative example 8
Difference with comparative example 7 is that according to parts by weight, the raw material components of anion coating are as shown in table 1.
Comparative example 9
The difference from embodiment 1 is that according to parts by weight, the raw material components of anion coating are as shown in table 1.
Wherein, surfactant uses lauryl sodium sulfate.
Comparative example 10
Difference with comparative example 9 is that according to parts by weight, the raw material components of anion coating are as shown in table 1.
Performance detection test
Anion burst size detection: with the burst size and reserved of negative aeroion measuring instrument analytical unit space anion
(minute is the 4th day after facing paper is pasted).Anion burst size is by negative aeroion tester apart from anion wall
The content of paper 1cm measurement anion；Anion reserved is to test negative aeroion measuring instrument apart from anion wallpaper 100cm
Anion concentration in air.
Table 1
Table 1- is continuous
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art
Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this
All by the protection of Patent Law in the scope of the claims of invention.
Claims (7)
1. a kind of anion facing paper, including facing paper, and it is spread evenly across the anion coating of facing paper outer surface, it is special
Sign is: according to parts by weight, the raw material of the anion coating includes following components,
30-35 parts of tourmaline powder；
90-110 parts of fluorocarbon resin；
20-25 parts of titanium dioxide；
1-2 parts of surfactant；
25-30 parts of distilled water.
2. a kind of anion facing paper according to claim 1, it is characterised in that: according to parts by weight, the anion
The raw material of coating includes two 1-3 parts of (triethanolamine) metatitanic acid diisopropyl esters.
3. a kind of anion facing paper according to claim 1, it is characterised in that: according to parts by weight, the anion
The raw material of coating includes 15-20 parts of CuPc.
4. a kind of anion facing paper according to claim 1, it is characterised in that: according to parts by weight, the anion
The raw material of coating includes 5-10 parts of carbon nanotube.
5. a kind of anion facing paper according to claim 1, it is characterised in that: according to parts by weight, the anion
The raw material of coating includes 15-20 parts of expanded vermiculite powder.
6. a kind of anion facing paper according to claim 5, it is characterised in that: the surfactant uses dodecane
Base ammonium sulfate.
7. the preparation method of -6 any a kind of anion facing papers according to claim 1, which is characterized in that including following
Step:
Step 1, the preparation of powder: tourmaline powder, titanium dioxide and carbon nanotube and expanded vermiculite powder are mutually mixed, ball milling is used
Machine carries out wet ultra-fine grinding to mixed-powder, and is screened with 4000 mesh screens to mixed-powder, obtains ultra-fine less than 3.5 μm
Powder；
Step 2, modification: distilled water being added into superfines, and ultrasonication 20-30min is stirred and heated to 40
DEG C, it is filtered after two (triethanolamine) metatitanic acid diisopropyl esters and constant temperature stirring 1h is added, once uses ethyl alcohol and acetone washing three
Secondary, drying obtains modified powder；
Step 3, the preparation of coating: being added into fluorocarbon resin and ammonium lauryl sulfate and stir evenly, continuously add distilled water,
Modified powder and CuPc continuously add distilled water after ultrasonication 1-1.5h and are diluted, and obtain coating；
Step 4, coating: being spread evenly across the outer surface of facing paper by the preparation of anion facing paper, and drying obtains finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910296315.8A CN109989291A (en) | 2019-04-13 | 2019-04-13 | A kind of anion facing paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910296315.8A CN109989291A (en) | 2019-04-13 | 2019-04-13 | A kind of anion facing paper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109989291A true CN109989291A (en) | 2019-07-09 |
Family
ID=67133582
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910296315.8A Pending CN109989291A (en) | 2019-04-13 | 2019-04-13 | A kind of anion facing paper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109989291A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112431063A (en) * | 2020-11-19 | 2021-03-02 | 山东米老鼠木业有限公司 | Preparation method of graphene negative oxygen ion decorative paper |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101177582A (en) * | 2006-11-09 | 2008-05-14 | 深圳市海川实业股份有限公司 | Road surface coating capable of absorbing decomposing automobile exhaust and preparation method thereof |
| CN104059418A (en) * | 2014-06-30 | 2014-09-24 | 南通蛇类治疗研究所 | Nanometer fluorocarbon air-purifying luminescent coating |
| CN108587342A (en) * | 2018-05-15 | 2018-09-28 | 张子晗 | A kind of nano titanium oxide photocatalysis disinfectant purification coating |
| CN108822638A (en) * | 2018-06-13 | 2018-11-16 | 安庆越球建筑防水材料有限公司 | A kind of environment-friendly waterproof paint discharging anion |
| CN109056448A (en) * | 2018-08-16 | 2018-12-21 | 正坚建设有限公司 | It is a kind of for absorbing the town road and its construction method of vehicle exhaust |
-
2019
- 2019-04-13 CN CN201910296315.8A patent/CN109989291A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101177582A (en) * | 2006-11-09 | 2008-05-14 | 深圳市海川实业股份有限公司 | Road surface coating capable of absorbing decomposing automobile exhaust and preparation method thereof |
| CN104059418A (en) * | 2014-06-30 | 2014-09-24 | 南通蛇类治疗研究所 | Nanometer fluorocarbon air-purifying luminescent coating |
| CN108587342A (en) * | 2018-05-15 | 2018-09-28 | 张子晗 | A kind of nano titanium oxide photocatalysis disinfectant purification coating |
| CN108822638A (en) * | 2018-06-13 | 2018-11-16 | 安庆越球建筑防水材料有限公司 | A kind of environment-friendly waterproof paint discharging anion |
| CN109056448A (en) * | 2018-08-16 | 2018-12-21 | 正坚建设有限公司 | It is a kind of for absorbing the town road and its construction method of vehicle exhaust |
Non-Patent Citations (1)
| Title |
|---|
| 中国纺织科学研究院: "《第八届功能性纺织品及纳米技术研讨会论文集》", 30 April 2008 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112431063A (en) * | 2020-11-19 | 2021-03-02 | 山东米老鼠木业有限公司 | Preparation method of graphene negative oxygen ion decorative paper |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Bayramoglu et al. | Preparation and characterization of strong cation exchange terpolymer resin as effective adsorbent for removal of disperse dyes | |
| Hu et al. | Ceria hollow spheres as an adsorbent for efficient removal of acid dye | |
| CN102876147B (en) | A kind of composite air purifying paint and preparation method thereof | |
| CN105749894A (en) | Preparation method of three-dimensional graphene-titanium dioxide compound photocatalyst | |
| CN109351165A (en) | It is a kind of indoor except formaldehyde spray | |
| CN109370344B (en) | Zeolite negative ion coating | |
| CN107335320A (en) | The net taste of environment-friendly type is except formaldehyde composition and preparation method thereof | |
| Šťastný et al. | Graphene oxide/MnO2 nanocomposite as destructive adsorbent of nerve-agent simulants in aqueous media | |
| CN109989291A (en) | A kind of anion facing paper and preparation method thereof | |
| KR20180110740A (en) | Nature friendly mud paint and the manufacturing method thereof | |
| JP2006124267A (en) | Composite particle containing titanium dioxide and its application | |
| CN112442304B (en) | Multifunctional ecological negative ion coating and preparation method thereof | |
| CN109181434A (en) | A kind of environment-friendly type coating and preparation method thereof | |
| CN109336512A (en) | A kind of nano metal organic frame wall material and preparation method thereof | |
| CN108822605A (en) | A kind of coating composition, nano coating and structural body | |
| CN109250998A (en) | A kind of environment-friendly type plasterboard and preparation method thereof | |
| JP2000279500A (en) | Deodorant composition and deodorant product | |
| CN109433174A (en) | Silicate cladding titanium dioxide photocatalyst powder and preparation method thereof | |
| Kamegawa et al. | Spherical TiO2/Mesoporous SiO2 core/shell type photocatalyst for water purification | |
| CN109593393A (en) | The preparation method of interior wall coating antibacterial agent | |
| Chen et al. | A facile synthesis of titanium dioxide/reduced graphene oxide composite with high photocatalytic activity for removal of gaseous formaldehyde | |
| CN104768642A (en) | Photocatalyst, and method for producing photocatalyst | |
| CN109054551A (en) | A kind of tourmaline wall finiss capable of releasing far infrared ray and preparation method thereof | |
| JP2005144431A (en) | Functional ceramic particle colloid, producing method of functional ceramic particle colloid, and product produced by using functional ceramic particle colloid | |
| CN105542523B (en) | A kind of indoor highly effective removes formaldehyde photocatalyst varnish |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190709 |
|
| RJ01 | Rejection of invention patent application after publication |