CN109989071A - One kind is with water and CO2For the energy source router of raw material - Google Patents

One kind is with water and CO2For the energy source router of raw material Download PDF

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Publication number
CN109989071A
CN109989071A CN201910375906.4A CN201910375906A CN109989071A CN 109989071 A CN109989071 A CN 109989071A CN 201910375906 A CN201910375906 A CN 201910375906A CN 109989071 A CN109989071 A CN 109989071A
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CN
China
Prior art keywords
hydrogen
water
raw material
energy source
source router
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910375906.4A
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Chinese (zh)
Inventor
罗丽珍
王鹏杰
徐越
任永强
刘沅
樊强
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Huaneng Clean Energy Research Institute
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Huaneng Clean Energy Research Institute
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Filing date
Publication date
Application filed by Huaneng Clean Energy Research Institute filed Critical Huaneng Clean Energy Research Institute
Priority to CN201910375906.4A priority Critical patent/CN109989071A/en
Publication of CN109989071A publication Critical patent/CN109989071A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/152Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

One kind provided by the invention is with water and CO2For the energy source router of raw material, including energy router body, energy router body includes electrolytic water device and CO2Hydrogenation reaction kettle, wherein the hydrogen outlet of electrolytic water device connects CO2The entrance of hydrogenation reaction kettle;Hydrogen is generated by electrolytic water device, by the hydrogen of generation and carbon dioxide gas in CO2Reaction is carried out in hydrogenation reaction kettle and generates methanol, and the present apparatus generates a variety of useful products, turns waste into wealth, bring economic benefit.

Description

One kind is with water and CO2For the energy source router of raw material
Technical field
The invention belongs to clean energy technology fields, in particular to one kind is with water and CO2For the energy source router of raw material.
Background technique
With increasingly sharpening for fossil energy environmental pollution, the reproducible new energy such as water energy, solar energy, wind energy by It attractes attention, water power, solar power generation, wind-powered electricity generation are the important Land use systems of new energy.But due to water power, solar power generation, wind-powered electricity generation Have the shortcomings that unstable, large-scale abandonings water, abandoning solar energy and abandonment occurs every year in the whole nation, causes a large amount of energy Waste.At the same time, CO2Global warming problem caused by isothermal chamber gas has become the weight of current international community discussion Subject under discussion is wanted, CO is being reduced2While discharge, CO2Recycling be also national governments and science researcher's focus of attention. By CO2Being converted into useful chemicals is CO2The effective way of recycling, CO2Add hydrogen under catalysts conditions, can be generated Methanol.Methanol is a large industrial chemicals, while being also the potential substitute of fossil fuel.Therefore, CO2Hydrogenation synthesis first Alcohol all has significance in multiple fields such as environmental protection, the energy and chemical industry.However, due to the sky high cost for manufacturing hydrogen, so that CO2Hydrogen is added to lack economy.
Currently, new forms of energy resource can be integrated, efficent use of resources brings the energy of economic results in society, environmental benefit Router is still blank out.
Summary of the invention
The purpose of the present invention is to provide one kind with water and CO2For the energy source router of raw material, solve existing two During the recycling of carbonoxide, the high defect of existing economic cost.
In order to achieve the above object, the technical solution adopted by the present invention is that:
One kind provided by the invention is with water and CO2For the energy source router of raw material, including energy router body, energy road It include electrolytic water device and CO by device ontology2Hydrogenation reaction kettle, wherein the hydrogen outlet of electrolytic water device connects CO2Hydrogenation reaction The entrance of kettle.
Preferably, electrolytic water device includes electrolytic water device ontology, new energy abandoning electricity and water storage tank, wherein new energy is useless Electricity and water storage tank are connect with electrolytic water device ontology.
Preferably, the oxygen outlet of electrolytic water device ontology is connected with oxygen storage tank;The hydrogen outlet of electrolytic water device connects Meet CO2Hydrogenation reaction kettle.
Preferably, the hydrogen outlet of electrolytic water device is also connected with hydrogen-holder.
Preferably, hydrogen-holder is connected with hydrogen fuel cell.
Preferably, CO2Hydrogenation reaction kettle includes CO2Hydrogenation reaction kettle ontology and carbon dioxide storage tank, wherein CO2Add hydrogen anti- The entrance of kettle is answered to connect the hydrogen outlet of carbon dioxide storage tank and electrolytic water device.
Preferably, CO2The outlet of hydrogenation reaction kettle connects methanol tank.
Compared with prior art, the present invention, which obtains beneficial effect, is:
One kind provided by the invention is with water and CO2For the energy source router of raw material, hydrogen is generated by electrolytic water device, it will The hydrogen and carbon dioxide gas of generation are in CO2Reaction is carried out in hydrogenation reaction kettle and generates methanol, and the present apparatus generates a variety of useful Product, turn waste into wealth, bring economic benefit.
Further, effective use new energy abandons the energy of the electricity as electrolytic water device, generates oxygen, hydrogen, methanol and produces Product;The structure can integrate new forms of energy resource, and efficent use of resources brings preferable economic results in society.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of energy source router of the present invention.
Specific embodiment
With reference to the accompanying drawing, the present invention is described in more detail.
As shown in Figure 1, one kind provided by the invention is with water and CO2For the energy source router of raw material, including energy source router 1, new energy abandons electricity 2, carbon dioxide storage tank 3, water storage tank 4, oxygen storage tank 5, methanol tank 6, hydrogen-holder 7 and hydrogen fuel cell 8, wherein new energy abandon the outlet of the outlet of electricity 2, the outlet of carbon dioxide storage tank 3 and water storage tank 4 with can source router 1 Entrance connects;Can source router 1 outlet respectively with the entrance of oxygen storage tank 5, the entrance of methanol tank 6 and hydrogen-holder 7 Entrance connects;The outlet of hydrogen-holder 7 connects with the entrance of hydrogen fuel cell 8.
The energy source router 1 is by electrolytic water device and CO2Hydrogenation reaction kettle;Wherein, the new energy abandons electricity 2 and water Storage tank 4 connects electrolytic water device end, generates hydrogen and oxygen, and oxygen outlet connects external device through compression, and hydrogen outlet is divided into Two-way, all the way with CO2Hydrogenation reaction kettle connection;Another way connects hydrogen-holder 7.
The CO2Storage tank and CO2The connection of hydrogenation reaction kettle end, the hydrogen generated with electrolytic water device react, and generate first Alcohol.
Embodiment:
The existing power station wet season, when water is richer, generated energy has been more than the electricity consumption level of this area, because of the electricity of power grid It cannot save, the few power generation of hair have to be subtracted, wet season duration 3000 hours, abandon water power up to 100,000,000 degree.However, dry season generated energy is again It is not able to satisfy the power consumption of this area.On the other hand, the coal plant by power station can discharge a large amount of CO daily2, it is computed about Up to 1000m3/h。
Present this area uses the energy source router of 30MW, has abandoning electricity, dry season electric insufficient to solve the wet season on the ground The problem of and CO2Problem of outlet.
Following reaction can mainly occur in source router:
2H2O=2H2+O2
CO2+3H2=CH3OH+H2O
By water and the 1000m trapped from coal plant3The CO of/h2It inputs in the energy source router of 30MW, it every year can benefit With 0.9 hundred million degree of abandoning electricity, 3000m is generated3The oxygen of/h, 1000m3The methanol of/h, 3000m3The hydrogen of/h solves 1000m3/ h bis- The outlet of carbonoxide.By 3000m31000m in the hydrogen product of/h3The hydrogen of/h is sold to hydrogen users as product, 2000m3The hydrogen storage of/h is got up, and is generated electricity in dry season using hydrogen fuel cell supplement water power.

Claims (7)

1. one kind is with water and CO2For the energy source router of raw material, which is characterized in that including energy router body (1), energy road It include electrolytic water device and CO by device ontology (1)2Hydrogenation reaction kettle, wherein the hydrogen outlet of electrolytic water device connects CO2Add hydrogen The entrance of reaction kettle.
2. one kind according to claim 1 is with water and CO2For the energy source router of raw material, which is characterized in that electrolytic water device Abandon electric (2) and water storage tank (4) including electrolytic water device ontology, new energy, wherein the useless electricity (2) of new energy and water storage tank (4) with The connection of electrolytic water device ontology.
3. one kind according to claim 1 is with water and CO2For the energy source router of raw material, which is characterized in that electrolytic water device The oxygen outlet of ontology is connected with oxygen storage tank (5);The hydrogen outlet of electrolytic water device connects CO2Hydrogenation reaction kettle.
4. one kind according to claim 3 is with water and CO2For the energy source router of raw material, which is characterized in that electrolytic water device Hydrogen outlet be also connected with hydrogen-holder (7).
5. one kind according to claim 4 is with water and CO2For the energy source router of raw material, which is characterized in that hydrogen-holder (7) hydrogen fuel cell (8) are connected with.
6. one kind according to claim 1 is with water and CO2For the energy source router of raw material, which is characterized in that CO2Add hydrogen anti- Answering kettle includes CO2Hydrogenation reaction kettle ontology and carbon dioxide storage tank (3), wherein CO2The entrance of hydrogenation reaction kettle connects titanium dioxide The hydrogen outlet of carbon storage tank (3) and electrolytic water device.
7. one kind according to claim 6 is with water and CO2For the energy source router of raw material, which is characterized in that CO2Add hydrogen anti- The outlet of kettle is answered to connect methanol tank (6).
CN201910375906.4A 2019-05-07 2019-05-07 One kind is with water and CO2For the energy source router of raw material Pending CN109989071A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910375906.4A CN109989071A (en) 2019-05-07 2019-05-07 One kind is with water and CO2For the energy source router of raw material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910375906.4A CN109989071A (en) 2019-05-07 2019-05-07 One kind is with water and CO2For the energy source router of raw material

Publications (1)

Publication Number Publication Date
CN109989071A true CN109989071A (en) 2019-07-09

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Country Status (1)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120226080A1 (en) * 2009-08-13 2012-09-06 Silicon Fire Ag Method and system for providing a hydrocarbon-based energy carrier using a portion of renewably produced methanol and a portion of methanol that is produced by means of direct oxidation, partial oxidation, or reforming
CN106285802A (en) * 2016-09-29 2017-01-04 中国化学工程第七建设有限公司 A kind of electricity-generating method and TRT
CN106748646A (en) * 2016-12-14 2017-05-31 李卫教 A kind of power storage processing method and system
CN106977369A (en) * 2016-12-15 2017-07-25 华青松 It is a kind of to comprehensively utilize the device and method that electric energy combines methanol processed and ammonia
CN210237792U (en) * 2019-05-07 2020-04-03 中国华能集团清洁能源技术研究院有限公司 Energy router using water and carbon dioxide as raw materials

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120226080A1 (en) * 2009-08-13 2012-09-06 Silicon Fire Ag Method and system for providing a hydrocarbon-based energy carrier using a portion of renewably produced methanol and a portion of methanol that is produced by means of direct oxidation, partial oxidation, or reforming
CN106285802A (en) * 2016-09-29 2017-01-04 中国化学工程第七建设有限公司 A kind of electricity-generating method and TRT
CN106748646A (en) * 2016-12-14 2017-05-31 李卫教 A kind of power storage processing method and system
CN106977369A (en) * 2016-12-15 2017-07-25 华青松 It is a kind of to comprehensively utilize the device and method that electric energy combines methanol processed and ammonia
CN210237792U (en) * 2019-05-07 2020-04-03 中国华能集团清洁能源技术研究院有限公司 Energy router using water and carbon dioxide as raw materials

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