CN109983108A - Liquid detergent composition - Google Patents

Liquid detergent composition Download PDF

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Publication number
CN109983108A
CN109983108A CN201780071005.5A CN201780071005A CN109983108A CN 109983108 A CN109983108 A CN 109983108A CN 201780071005 A CN201780071005 A CN 201780071005A CN 109983108 A CN109983108 A CN 109983108A
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CN
China
Prior art keywords
detergent composition
liquid detergent
alkyl
weight
anionic surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201780071005.5A
Other languages
Chinese (zh)
Inventor
P·班德佑帕德雅
A·萨
R·桑卡
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Unilever IP Holdings BV
Original Assignee
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever NV filed Critical Unilever NV
Publication of CN109983108A publication Critical patent/CN109983108A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers

Abstract

The present invention relates to a kind of liquid detergent composition, it includes: a) the first anionic surfactant is ethoxylated alkyl ether sulfate；B) the second anionic surfactant is selected from C8‑22Alkylbenzene sulfonate, C8‑22Alkyl sulfate and combinations thereof；C) total weight based on the liquid detergent composition, the aliphatic ester according to formula (II) of 0.1-2.5 weight %: R2‑C(O)‑O‑R3Wherein R2Indicate straight chain C8‑22Alkyl；R3Indicate linear chain or branched chain C1‑C4Alkyl；D) total weight based on the liquid detergent composition, at least water of 50 weight %；Total weight wherein based on the liquid detergent composition, first anionic surfactant and second anionic surfactant account for 12-30 weight % together.The liquid detergent composition effectively removes dirt from surface, and when being diluted with water, and is easy to produce the cleaning solution with creaminess foam abundant, which can be used only limited amount flushing water and easily remove from being clean surface.

Description

Liquid detergent composition
Technical field
The present invention relates to a kind of liquid detergent compositions, provide desired foaming and detergency ability.More particularly, originally Invention is related to a kind of frothed aqueous detergent composition, contains:
Ethoxylated alkyl ether sulfate；
Alkylbenzene sulfonate and/or alkyl sulfate；With
Aliphatic ester.
The example of liquid detergent composition according to the present invention includes liquid hand dish washing detergent and liquid hard-surface Cleaning compositions.
When mixed with water, liquid detergent composition according to the present invention is easy to form has creaminess foam abundant Cleaning solution.After the cleaning, which can be by only rinsing surface with a small amount of flushing water, from being clean surface easily It removes.
Background technique
Water is becoming more and more rare commodity, and especially in developing country, people have to walk many kilometers It is not uncommon for reaching open water supply.As a result, having increasing need for saving water.
A kind of method saved water is to reuse water, and another method is to reduce water consumption.
Washing process, including laundry, wash up and other household cleaning processes need a large amount of water in the whole world.These Largely the water needed for rinsing clean article recently or surface determines water needed for washing process.Especially In the case where high-foaming detergent composition, need a large amount of water to rinse out foaming residue.
Liquid detergent composition is widely used in the various articles of cleaning and surface.These liquid detergent compositions should be able to Remove various dirts.In addition, soil redeposition should be prevented to clean article or table recently in order to obtain good cleaning effect On face.
It is also expected to liquid detergent composition provides lasting hair in the presence of by clean dirt in dilute cleaning solution Bubble.Once the foam is no longer just desired, and is likely difficult to remove, such as pass through punching however, article or surface are cleaned It washes.The increasingly rare of water can be consumed by being especially considering that, it is important to provide liquid detergent composition, one side is dilute clear Lasting foaming is provided in clean liquid, on the other hand by rinsing the foaming residue removal provided quickly and readily.
WO99/35237 describes a kind of clear microemulsion liquid cleaning compositions, and it includes by weight about:
The alkali metal salt of 20% to 34% sulfonate anionic surfactant；
5% to 10% C8-18The alkali metal salt of ethoxylated alkyl ether sulfate；
1% to 10% at least one solubilizer；
1% to 14% at least one cosurfactant, wherein the cosurfactant first is that dipropylene glycol Monomethyl ether；
0 to 10% supplement solubilizer；
1% to 8% water-insoluble organic compound；With
Surplus is water.
WO00/59454 describes a kind of liquid stratiform cleaning compositions, it includes:
The surfactant system of 5% to 50 weight %, it includes: (i) one or more anionic surfactants； One of anionic surfactant or at least one anionic surfactant are branch C10-C22Alkali alkyl ether sulphur Hydrochlorate；(ii) amphoteric surfactant of 0.1 to 25 weight % of total composition or zwitterionic surfactant or its mixing Object；With
The fatty acid or its ester of 1% to 15 weight %.
WO2006/081944 describes a kind of low ratio foamed aqueous based liquid detergent composition, and it includes carboxylates and/or low Spend alkoxy derivative, surfactant and water.
WO2016/030226 describes a kind of liquid detergent composition, has foaming and cleaning special in main washing Property, but during flushing there is significant foam to reduce.The composition includes anionic surfactant system, non-ionic surface Activating agent and saturated fatty acid.
US4017409 describes liquid household cleaners composition, and it includes anionic surfactant, organic or inorganics Builder salt, the foam inhibition suppressing system comprising aliphatic ester and water.
WO2011/075642 describes a kind of foaming liquid detergent composition, it includes:
At least one slightly water-soluble cleaning of total weight based on composition, about 0.5% to about 10% active weight is molten Agent reduces surfactant blistering；
Total weight based on composition, at least one anion surface active of about 6.0% to about 40% active weight Agent；
At least one foam surface of stability of total weight based on composition, about 6.0% to about 40% active weight is living Property agent；With
At least one carrier of the 0% of total weight to about 90%,
Wherein at least one slightly water-soluble cleaning solvent is selected from methyl laurate, ethyl laurate, myristic acid first Ester, ethyl myristate, C12-C14Methyl esters, C8-14Dimethylformamide, C8-14Diethylamide, derivative and combinations thereof.
Summary of the invention
Inventor developed a kind of liquid detergent composition, dirt is effectively removed from surface, and After being diluted with water, it is easy to produce the cleaning solution with creaminess foam abundant, which can be used only limited amount flushing Water is easily removed from being clean surface.
Liquid detergent composition of the invention includes:
A) the first anionic surfactant, for according to the ethoxylated alkyl ether sulfate of formula (I):
R1-(OCH2CH2)nOSO3 -M+
Wherein R1Indicate linear chain or branched chain C8-C22Alkyl；
N is the integer of 1-8；
M+Indicate alkali metal or ammonium cation；
B) the second anionic surfactant is selected from C8-22Alkylbenzene sulfonate, C8-22Alkyl sulfate and combinations thereof；
C) total weight based on the liquid detergent composition, the fatty acid according to formula (II) of 0.1-2.5 weight % Ester:
R2-C(O)-O-R3
Wherein R2Indicate straight chain C8-22Alkyl；
R3Indicate linear chain or branched chain C1-C4Alkyl；
D) total weight based on the liquid detergent composition, at least water of 50 weight %；
Total weight wherein based on the liquid detergent composition, first anionic surfactant and described Two anionic surfactants account for 12-30 weight % together.
Although the present inventor is not wishing to be bound by theory, it is believed that when detergent composition is mixed with water to prepare cleaning solution When, the combination of the first and second anionic surfactants largely results in abundant in liquid detergent composition Creaminess foam.It was found that the aliphatic ester substance of liquid detergent composition improves the flush with foam after cleaning.In addition, It is believed that the combination of anionic surfactant and aliphatic ester causes liquid detergent composition to remove the efficient of degreasing from surface Property.
Specific embodiment
The first aspect of the present invention is related to a kind of liquid detergent composition, it includes:
A) the first anionic surfactant, for according to the ethoxylated alkyl ether sulfate of formula (I):
R1-(OCH2CH2)nOSO3 -M+
Wherein R1Indicate linear chain or branched chain C8-C22Alkyl；
N is the integer of 1-8；
M+Indicate alkali metal or ammonium cation；
B) the second anionic surfactant is selected from C8-22Alkylbenzene sulfonate, C8-22Alkyl sulfate and combinations thereof；
C) total weight based on the liquid detergent composition, the fatty acid according to formula (II) of 0.1-2.5 weight % Ester:
R2-C(O)-O-R3
Wherein R2Indicate straight chain C8-22Alkyl；
R3Indicate linear chain or branched chain C1-C4Alkyl；
D) total weight based on the liquid detergent composition, at least water of 50 weight %；
Total weight wherein based on the liquid detergent composition, first anionic surfactant and described Two anionic surfactants account for 12-30 weight % together.
Unless otherwise stated, the term as used herein " sulfonate " refers to the salt of sulfonic acid moieties and sulfonic acid moieties.
Equally, unless otherwise stated, the term as used herein " sulfate " refers to sulfuric acid residue and sulfuric acid residue Salt.
Unless otherwise stated, all percentages being mentioned above are w/w percentage.
The example of liquid detergent composition by the invention includes liquid hand dish washing detergent and liquid hard-surface Cleaning compositions.Most preferably, liquid detergent composition of the invention is liquid hand dish washing detergent.
First anionic surfactant is preferably the ethoxylated alkyl ether sulfate according to formula (I), wherein R1It is straight Chain C8-C20Alkyl, more preferably straight chain C10-C18Alkyl, even more preferably straight chain C12-C16Alkyl, even more preferably from straight chain C12- C14Alkyl, most preferably C12Alkyl.
Liquid detergent composition preferably comprises 3-25 weight %, more preferable 5-20 weight %, most preferably 6-18 weight % The first anionic surfactant.
According to another preferred embodiment, the Integer n in formula (I) is 1 to 6, more preferably 1 to 4, most preferably 1 To 3.
Cationic M in formula (I)+Preferably alkali metal cation, most preferably sodium cation.
The second anionic surfactant in liquid detergent composition of the invention preferably comprises one or more straight Chain C8-22Alkylbenzene sulfonate, more preferable one or more straight chain Cs8-18Alkylbenzene sulfonate is even more preferably one or more straight Chain C10-16Alkylbenzene sulfonate.Most preferably, alkylbenzene sulfonate is linear dodecylbenzene sulfonate.
Preferably, liquid detergent composition contains at least 3 weight %, more preferably at least 4 weight %, even more preferably extremely Few 5 weight %, most preferably at least one or more straight chain Cs of 6 weight %8-22Alkylbenzene sulfonate.
Alkylbenzene sulfonate is preferably selected from alkyl benzene sulphonate, sodium alkyl benzene sulfonate, alkyl benzene sulphonate potassium, alkyl benzene sulphonate ammonium And combinations thereof.Most preferably, alkylbenzene sulfonate is sodium alkyl benzene sulfonate.
It include the alkyl benzene sulphonate in liquid detergent composition other than alkyl substituent and sulfonate substituent The phenyl ring of salt can have other substituent group.Therefore, the invention also includes use such as alkyl toluene sulfonate, alkyl xylene Sulfonate and alkyl phenol sulfonate.Most preferably, in addition to C8-22Other than alkyl substituent and sulfonate substituent, alkyl benzene sulphonate The phenyl ring of salt is without any other substituent group.
Alkyl sulfate is preferably straight chain C10-16Alkyl sulfate, most preferably straight chain lauryl sulfate.Alkyl sulfide Hydrochlorate is preferably selected from alkylsurfuric acid, sodium alkyl sulfate, alkylsurfuric acid potassium, alkylsurfuric acid ammonium, diethanol amine alkyl sulfate and its Combination.Most preferably, alkyl sulfate is sodium alkyl sulfate.
Liquid detergent composition preferably comprises 3-25 weight %, more preferable 4-18 weight %, most preferably 5-15 weight % The second anionic surfactant.
The combination of first and second anionic surfactants is preferably at least 15 weight %, more preferably at least 18 weights % is measured, the concentration of most preferably at least 20 weight % is present in liquid detergent composition.
The weight ratio of first anionic surfactant and the second anionic surfactant in liquid detergent composition Usually less than 3:1, more preferably less than 2.5:1, more preferably less than 2:1.
First anionic surfactant and the second anionic surfactant usually with more than 1:3, preferably greater than 1:2, The first anionic surfactant of more preferably above 1:1.5 and the weight ratio of the second anionic surfactant are present in liquid In detergent composition.
According to the aliphatic ester of formula (II) preferably with 0.2-2 weight %, more preferable 0.25-1.7 weight %, most preferably 0.3- The concentration of 1.5 weight % is included in liquid detergent composition.
R in formula (II)3It is preferred that indicating straight chain C1-C4Alkyl, more preferable R3Selected from methyl or ethyl.Most preferably, R3It is Methyl.
Advantageous embodiments according to the present invention, the R in formula (II)2Indicate straight chain C8-16Alkyl, more preferable straight chain C10-16 Alkyl.Even further preferably, aliphatic ester is selected from methyl caprate, methyl laurate, methyl myristate, methyl palmitate And combinations thereof.Most preferably, aliphatic ester is methyl caprate.
According to a particularly preferred embodiment, liquid detergent composition according to the present invention includes at least 0.2 weight Measure the methyl laurate of %, the more preferably at least methyl laurate of 0.25 weight %, most preferably at least the ten of 0.3 weight % Two alkanoic acid methyl esters.
The water content of liquid detergent composition is preferably at least 60 weight %, more preferably at least 62 weight %, most preferably At least 68 weight %.
The pH of liquid detergent composition is usually 4.5 to 6.5, and more preferably 5 to 6.5, most preferably 5.5 to 6.
Liquid detergent composition can be suitably containing selected from flavouring agent, antimicrobial, pH adjusting agent, viscosity-adjusting agent Agent, dyestuff, enzyme, one or more ingredients of hydrotrote and combinations thereof.
Liquid detergent composition can be packed in the form of any commercially available bottle, for storing liquid.Contain liquid Bottle can have different size and shape, to adapt to the liquid composition of different volumes；Preferably, the volume exists Between 0.25 and 2L, more preferably between 0.25 and 1.5L, or even between 0.25 and 1L.Preferably, bottle is provided with point Orchestration enables consumers to distribute liquid detergent composition with easier way.Also spraying or pump point can be used Orchestration.
Another aspect of the present invention relates to a kind of methods for cleaning and rinsing surface comprising following steps:
A. on the surface by liquid detergent composition according to the present invention application；
B. the surface is cleaned with burnisher；With
C. it is rinsed with water the surface.
For hard-surface cleaning or it is used for dishwashing detergent purpose, liquid detergent composition can be straight with itself (as such) It connects and is applied to surface.When being applied with dilute form, composition preferably uses water to dilute with the ratio of 1:1 to 1:10.
Composition can be applied by any of mode, such as by using scouring object, sponge, paper, cloth, cleaning piece Or any other is directly applied.The composition of application can be used burnisher and such as clean object, and sponge, paper, cloth or cleaning piece are clear It is clean.
Another aspect of the present invention is related to the aliphatic ester defined above in the first and second yin comprising defining above For with the processed table of the liquid detergent composition in the liquid detergent composition of ionic surface active agent Accelerate the purposes of foam removal in the flushing process in face.
It is further illustrated by the following non-limitative examples the present invention.
Embodiment
Embodiment 1
Liquid detergent composition is prepared based on preparation shown in table 1.
Table 1
The foaming behavior of these liquid detergent compositions, including foam flushability are evaluated using following procedure:
1. 6.25 grams of liquid detergent compositions are diluted with water to prepare 1 liter of cleaning solution.
2. 50ml cleaning solution is introduced into 250ml graduated cylinder, the graduated cylinder is shaken ten times.
3. liquid is carefully decanted and measures foam volume.
4. 50ml fresh water is introduced into graduated cylinder to simulate and rinse, and graduated cylinder is shaken again.
5. repeating step 4 until foam volume is less than or equal to 2ml.
Assessment result is summarised in table 2.
Table 2
Embodiment 2
Liquid detergent composition is prepared based on preparation shown in table 3.
Table 3
The foaming behavior of these liquid detergent compositions is evaluated using method described in embodiment 1, including foam can Washability.
Assessment result is summarized in table 4.
Table 4
Embodiment 3
Liquid detergent preparation is prepared based on preparation shown in table 5.Preparation B is in the table 1 based on WO2006/081944 Embodiment 2.
Table 5
The foaming behavior of these liquid detergent compositions is evaluated using method described in embodiment 1, including foam can Washability.
Assessment result is summarised in table 6.
Table 6

Claims (15)

1. a kind of liquid detergent composition, it includes:
A) the first anionic surfactant, for according to the ethoxylated alkyl ether sulfate of formula (I):
R1-(OCH2CH2)nOSO3 -M+
Wherein R1Indicate linear chain or branched chain C8-C22Alkyl；
N is the integer of 1-8；
M+Indicate alkali metal or ammonium cation；
B) the second anionic surfactant is selected from C8-22Alkylbenzene sulfonate, C8-22Alkyl sulfate and combinations thereof；
C) total weight based on the liquid detergent composition, the aliphatic ester according to formula (II) of 0.1-2.5 weight %:
R2-C(O)-O-R3
Wherein R2Indicate straight chain C8-22Alkyl；
R3Indicate linear chain or branched chain C1-C4Alkyl；
D) total weight based on the liquid detergent composition, at least water of 50 weight %；
Total weight wherein based on the liquid detergent composition, first anionic surfactant and second yin Ionic surface active agent accounts for 12-30 weight % together.
2. liquid detergent composition according to claim 1, wherein R1Indicate straight chain C10-C18Alkyl.
3. liquid detergent composition according to claim 1 or 2, wherein n is 1 to 4, preferably 1 to 3.
4. liquid detergent composition according to any one of the preceding claims, wherein the composition contains 3-25 weight Measure first anionic surfactant of %.
5. liquid detergent composition according to any one of the preceding claims, wherein the composition contains 3-25 weight Measure second anionic surfactant of %.
6. liquid detergent composition according to any one of the preceding claims, wherein second anionic surface is living Property agent be selected from straight chain C8-22Alkylbenzene sulfonate.
7. liquid detergent composition according to claim 6, wherein the composition contains one kind of at least 3 weight % Or a variety of straight chain Cs8-22Alkylbenzene sulfonate.
8. liquid detergent composition according to any one of the preceding claims, wherein first anionic surface is living Property agent and second anionic surfactant weight ratio be less than 3:1 and be greater than 1:3.
9. liquid detergent composition according to any one of the preceding claims, wherein the aliphatic ester is with 0.2-2 The concentration of weight % exists.
10. liquid detergent composition according to any one of the preceding claims, the wherein R in formula (II)3Indicate straight chain C1-C4Alkyl.
11. liquid detergent composition according to claim 10, wherein R3Indicate methyl.
12. liquid detergent composition according to any one of the preceding claims, wherein the aliphatic ester is fat Acid esters, and the R in formula (II)2Indicate straight chain C8-16Alkyl.
13. liquid detergent composition according to claim 10, wherein the aliphatic ester is to be selected from methyl caprate, ten Two alkanoic acid methyl esters, methyl myristate, the aliphatic ester of methyl palmitate and combinations thereof.
14. a kind of method for cleaning and rinsing surface comprising following steps:
A) on the surface by liquid detergent composition according to claim 1 to 13 application；
B) surface is cleaned with burnisher；With
C) it is rinsed with water the surface.
15. aliphatic ester defined in claim 1 comprising the first anionic surfactant defined in claim 1 and For with the liquid in the liquid detergent composition of second anionic surfactant defined in claim 1 Accelerate the purposes of foam removal in the flushing process on the processed surface of detergent composition.
CN201780071005.5A 2016-11-24 2017-10-27 Liquid detergent composition Pending CN109983108A (en)

Applications Claiming Priority (3)

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EP16200420 2016-11-24
EP16200420.4 2016-11-24
PCT/EP2017/077583 WO2018095695A1 (en) 2016-11-24 2017-10-27 Liquid detergent composition

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AR (1) AR110217A1 (en)
CL (1) CL2019001327A1 (en)
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ZA (1) ZA201902304B (en)

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Publication number Priority date Publication date Assignee Title
WO2023025739A1 (en) 2021-08-25 2023-03-02 Unilever Ip Holdings B.V. Detergent composition

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US4017409A (en) * 1975-01-02 1977-04-12 The Procter & Gamble Company Liquid household cleaner
CN1225677A (en) * 1996-05-17 1999-08-11 普罗格特-甘布尔公司 Detergent composition
CN1228111A (en) * 1996-06-26 1999-09-08 普罗格特-甘布尔公司 Low sudsing liquid detergent compositions comprising silicone suds suppressor and fatty acid ester
WO2006081944A1 (en) * 2005-02-04 2006-08-10 Unilever N.V. Low-foaming liquid laundry detergent
CN102762709A (en) * 2009-12-17 2012-10-31 斯特潘公司 Foaming light duty liquid detergent compositions, methods of making and uses thereof
WO2016030226A1 (en) * 2014-08-29 2016-03-03 Unilever N.V. Liquid detergent composition

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Publication number Priority date Publication date Assignee Title
US5905064A (en) 1998-01-08 1999-05-18 Colgate-Palmolive Co. Microemulsion cleaning compositions
US6150312A (en) 1999-04-05 2000-11-21 Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. Liquid composition with enhanced low temperature stability comprising sodium tricedeth sulfate

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4017409A (en) * 1975-01-02 1977-04-12 The Procter & Gamble Company Liquid household cleaner
CN1225677A (en) * 1996-05-17 1999-08-11 普罗格特-甘布尔公司 Detergent composition
CN1228111A (en) * 1996-06-26 1999-09-08 普罗格特-甘布尔公司 Low sudsing liquid detergent compositions comprising silicone suds suppressor and fatty acid ester
WO2006081944A1 (en) * 2005-02-04 2006-08-10 Unilever N.V. Low-foaming liquid laundry detergent
CN102762709A (en) * 2009-12-17 2012-10-31 斯特潘公司 Foaming light duty liquid detergent compositions, methods of making and uses thereof
WO2016030226A1 (en) * 2014-08-29 2016-03-03 Unilever N.V. Liquid detergent composition

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WO2018095695A1 (en) 2018-05-31
CL2019001327A1 (en) 2019-08-09
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ZA201902304B (en) 2020-08-26
AR110217A1 (en) 2019-03-06

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