CN109971557A - A kind of antibacterial degradable washing powder - Google Patents
A kind of antibacterial degradable washing powder Download PDFInfo
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- CN109971557A CN109971557A CN201910191493.4A CN201910191493A CN109971557A CN 109971557 A CN109971557 A CN 109971557A CN 201910191493 A CN201910191493 A CN 201910191493A CN 109971557 A CN109971557 A CN 109971557A
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- Prior art keywords
- parts
- washing powder
- plant extracts
- antibacterial degradable
- yttrium oxide
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of antibacterial degradable washing powder, which is characterized in that by weight includes following components: 30-50 parts of surfactant, 20-40 parts of natrium carbonicum calcinatum, 10-30 parts of plant extracts and 0.1-1 parts of nano yttrium oxide.A kind of antibacterial degradable washing powder of the invention, preparation method include the following steps: that 30-50 parts of surfactant, 20-40 parts of natrium carbonicum calcinatum are uniformly mixed by (1), obtain mixed liquor a；(2) 0.1-1 parts of 10-30 parts of plant extracts, nano yttrium oxide addition step (1) mixed liquor a are obtained into washing powder.Inventive formulation is mild, and the plant extracts ingredient in formula and nano yttrium oxide have synergistic function, strengthen bacteria resistance function, and effect is obvious.
Description
Technical field
The present invention relates to detergent applications, specifically provide a kind of antibacterial degradable washing powder.
Background technique
The detergent such as washing powder, liquid detergent are the necessitys of people's daily life, with the raising of living standard quality with
And the fast development of science and technology, people, which start to be transitioned by single emphasis laundry effect, focuses on other functions such as antibacterial, brilliant white.
Chinese Patent Application No. 201310242678.6 discloses a kind of bactericidal liquid detergent containing epsilon-polylysine.The sterilization
Liquid detergent raw material form weight percent % it is as follows: surfactant 10~50, anti redeposition agent 0~2, chelating agent 0.5~1,
Thickener 0~3, epsilon-polylysine 0.1~1, essence 0.1~0.5, deionized water surplus.The invention using epsilon-polylysine as
Fungicide can kill 99.99% or more microorganism, and have good restraining and sterilizing bacteria effect.Meanwhile Chinese Patent Application No.
201510175334.7 disclosing a kind of environment-friendly type liquid detergent and preparation method thereof that composite bactericidal is mould proof.Particularly one kind contains
Have natural component epsilon-polylysine hydrochloride, natamycin and alcohol ether glucoside can simultaneously fungus and mildew resistance decontamination antimicrobial laundry
Liquid.The invention is compounded with epsilon-polylysine hydrochloride and natamycin with antiseptic and mildew resistant ability, anionic surfactant,
Nonionic surfactant, amphoteric surfactant.The liquid detergent raw material percentage composition % content is as follows: anionic surface is living
Property agent 5~30%, nonionic surfactant 10~30%, amphoteric surfactant 2~5%, anti redeposition agent 0.5~2%,
Chelating 0.5~1.5%, epsilon-polylysine hydrochloride 0.1~0.4%, natamycin 0.1~0.6%, essence 0.1~
0.5%, deionized water surplus.The technology has good fungus and mildew resistance and dirt-removing functions, and formula is reasonable, gained laundry liquid product
Also there is good bactericidal effect.In short, detergent used is contained therein mainly based on synthetic detergent currently on the market
Some fungicide are usually that chemical industry synthesis obtains, degradable difference, and catalytic effect is slow, and removal is not thorough, and clothing lightening effect is not
Obviously.
In addition, the prior art is usually by addition brightener come so that clothes color blast.Chinese Patent Application No.
201410014634.2 disclose a kind of footgear personal cleansing liquid and preparation method thereof, belong to daily detergent technical field, should
Invention is compounded with humic acid/salt with sterilizing and deodorizing function and surfactant with dirt-removing power etc., thus will sterilize,
Deodorization and decontamination organically combine together, by antibacterial deodorant, surfactant, fluorescent whitening agent, other addition auxiliary agents and go
Ionized water etc. is formulated.Compared with prior art, which removes with mild faint scent, hard water resistance, antistatic, clean effect is aobvious
The traditional advantages such as work, and the new feature with good sterilizing and deodorizing function；Furthermore the waste water after washing flows into sewer or just
Pond etc. can make sewage deodorizing agent, can also be used as the natural plants fertilizer such as fruit tree；The present invention is simple, cost is relatively low, real
With value height, it is suitble to industrialized production.Although foregoing invention product has the function of antibacterial, brilliant white, since which are added fluorescence
Brightening agent, as cleaning process can move on clothing, especially personal clothing, then as the contacts such as sweat, friction are easy to
It is absorbed by the skin, allergic reaction will be generated once skin rejects into blood circulation.
According to the prior art, it is necessary to develop antibacterial degradable washing powder to overcome the deficiencies of existing technologies.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of antibacterial degradable washing powder, overcome existing detergent antibacterial
Indifferent, fungicide non-degradable, the fluorescer in formula, which may lead to the problem of human body, to be endangered.Decontamination energy of the present invention
Power is strong, degradable, and bacteriostasis property is strong, simultaneously because addition nano yttrium oxide, reinforces bacteriostasis property, and make the color of clothes more
Highlight white, safety is good compared with conventional brilliant white fluorescer.
The present invention solve above-mentioned technical problem the technical solution adopted is as follows:
A kind of antibacterial degradable washing powder includes following components: 30-50 parts of surfactant, Carbon Dioxide by weight
20-40 parts of sodium, 10-30 parts of plant extracts, 0.1-1 parts of nano yttrium oxide.The plant extracts includes Ilex Latifolia Thunb, olive
Leaf.
The plant extracts and nano yttrium oxide have synergistic function.
Preferably, the surfactant is neopelex, appointing in sodium sulfate of polyethenoxy ether of fatty alcohol
It anticipates one kind.
A kind of antibacterial degradable washing powder, the preparation method of the washing powder include the following steps:
(1) 30-50 parts of surfactant, 20-40 parts of natrium carbonicum calcinatum homogeneous blender is poured into stir at a certain temperature
It mixes in certain time, obtains being uniformly mixed mixed liquor a；
(2) 0.1-1 parts of 10-30 parts of plant extracts, nano yttrium oxide addition step (1) mixed liquor a must be done washing
Powder.
Certain temperature is 30-60 DEG C in the step (1), certain time 10-60min.Nano oxygen in the step (2)
Change the partial size of yttrium in 10-50nm.
In above-mentioned technical proposal, the plant extracts the preparation method comprises the following steps: after Ilex Latifolia Thunb and olive leaf are cleaned by
Squeezer squeeze juice, then after water is filtered pure juice, pure juice heats to 0.5 at a temperature of 100~110 DEG C~
Cooling obtains plant extraction liquid after 1 hour.
The plant extracts includes Ilex Latifolia Thunb and olive leaf.The weight ratio of Ilex Latifolia Thunb and olive leaf in plant extracts
It is 1: 0.5-1.
Compared with prior art, the invention has the benefit that
(1) mild formulation of the present invention is suitable for machine washing and hand washing, and strong detergency is low-consuming, easily rinses, water-saving is time saving, is free of
The substance toxic to human body such as phosphorus, benzene, phenol, does not add fluorescent whitening agent, antibacterial additive plant extracts can natural degradation, because
This, product of the present invention has the characteristics that environmental protection；
(2) present invention does not need to add the auxiliary agents such as other defoaming agents again, to the removal ability of particulate fouling and dust dirt
Preferably, and it is good with other component compatibilities；
(3) plant extracts of the present invention has broad-spectrum antibacterial and bactericidal properties.Meanwhile the present invention adds nano yttrium oxide, leads to
The synergistic effect with plant extracts of the present invention is crossed, rises and strengthens bacteria resistance function, whole fungistatic effect is obvious.What the applicant carried out
The experimental results showed that the present invention has the bacteriostasis of wide spectrum to common strain, especially to Escherichia coli and Staphylococcus aureus
The bacteriostasis of bacterium is most strong；
(4) nano yttrium oxide of the present invention makes the color more brilliant white of clothes, and is not easy to adsorb dust debris, makes clothing
Object keeps cleaning.
Detailed description of the invention
Fig. 1 is fluorescent brightness calibrating instrument measuring principle schematic diagram.1- regulated power supply, 2- UV source, 3- sample stage, 4-
Clothes sample, 5- ultraviolet light, 6- correct optical filter, 7- photodetector, 8- display device.
Specific embodiment
Technical solution of the present invention is described in further detail below in conjunction with specific embodiment, so that this field
Technical staff can better understand the present invention and can be practiced, but illustrated embodiment is not as a limitation of the invention.
Embodiment 1
A kind of antibacterial degradable washing powder includes following components: 30 parts of neopelex, anhydrous carbon by weight
20 parts of sour sodium, 10 parts of plant extracts, 0.8 part of nano yttrium oxide；
The antibacterial degradable washing powder of one kind, the preparation method of the washing powder include the following steps:
(1) 30 parts of neopelex, 20 parts of natrium carbonicum calcinatum are uniformly mixed, obtain mixed liquor a；
(2) 0.8 part of 10 parts of plant extracts, nano yttrium oxide addition step (1) mixed liquor a are obtained into washing powder.
The weight ratio of Ilex Latifolia Thunb and olive leaf is 1: 1 in plant extracts in the step (2).
Embodiment 2
A kind of antibacterial degradable washing powder includes following components by weight: 40 parts of sodium sulfate of polyethenoxy ether of fatty alcohol,
30 parts of natrium carbonicum calcinatum, 15 parts of plant extracts, 0.1 part of nano yttrium oxide；
The antibacterial degradable washing powder of one kind, the preparation method of the washing powder include the following steps:
(1) 40 parts of neopelex, 30 parts of natrium carbonicum calcinatum are uniformly mixed, obtain mixed liquor a；
(2) 0.1 part of 15 parts of plant extracts, nano yttrium oxide addition step (1) mixed liquor a are obtained into washing powder.
The weight ratio of Ilex Latifolia Thunb and olive leaf is 1: 0.8 in plant extracts in the step (2).
Embodiment 3
A kind of antibacterial degradable washing powder includes following components: 50 parts of neopelex, anhydrous carbon by weight
40 parts of sour sodium, 30 parts of plant extracts, 0.5 part of nano yttrium oxide；
The antibacterial degradable washing powder of one kind, the preparation method of the washing powder include the following steps:
(1) 50 parts of neopelex, 40 parts of natrium carbonicum calcinatum are uniformly mixed, obtain mixed liquor a；
(2) 1 part of 20 parts of plant extracts, nano yttrium oxide addition step (1) mixed liquor a are obtained into washing powder.
The weight ratio of Ilex Latifolia Thunb and olive leaf is 1: 0.5 in plant extracts in the step (2).
In embodiment 1-3, the plant extracts the preparation method comprises the following steps: by squeezing after Ilex Latifolia Thunb and olive leaf are cleaned
Machine squeeze juice, then pure juice is obtained after water is filtered, it is small that pure juice is heated to 0.5~1 at a temperature of 100~110 DEG C
When after cooling obtain plant extraction liquid.
Comparative experiments 1
The present invention is identical as 1 other conditions of embodiment, is uniquely a difference in that and does not add nano yttrium oxide.The result shows that going
Dirty ability is obvious not as good as the laundry effect of 1 invention of embodiment, and the inadequate brilliant white of clothes color.
Comparative experiments 2
The present invention is identical as 1 other conditions of embodiment, is uniquely a difference in that and does not add plant extracts.The result shows that going
Dirty ability is obvious not as good as the laundry effect of 1 invention of embodiment.
Comparative experiments 1-2 the result shows that, gained liquid detergent is after lacking one of plant extracts or nano yttrium oxide, institute
Laundry effect decline, it is unobvious.And the sum of comparative experiments 1-2 income effect is good without present invention gained liquid detergent effect.
1, bacteriostatic experiment
The present invention has carried out bacteriostasis property test to gained washing powder, respectively to Escherichia coli, Staphylococcus aureus, withered grass
Bacillus, Candida albicans are tested, and experiment carries out at room temperature at 20 DEG C, first hang the bacterial strain of above-mentioned three kinds of strains
Liquid and detergent heated at constant temperature in test tube, are then added 1ml using bovine serum albumin as culture medium in sterile test tube
Bacteria suspension and 4ml detergent fully shake 5 minutes after mixing, then calculate sterilizing rate (before and after measurement experiment in bacteria suspension
Average colony number), experimental result is shown, the detergent of above-mentioned 3 embodiments of the invention is above Escherichia coli killing rate
98%, it is shown that extremely strong killing effect is above 95% to the killing rate of Staphylococcus aureus, and there is significant sterilization to make
With for bacillus subtilis, Candida albicans, embodiment 1-3 killing rate is higher than 95%.
2, brilliant white is tested
4 identical outmoded clothings are chosen, control group: daily washing powder is added and is cleaned；Embodiment 1-3 group adds this hair
Bright washing powder is cleaned.Using fluorescent brightness calibrating instrument according to " JJG 941-2009 fluorescent brightness calibrating instrument is examined and determine after drying
Regulation " data test is carried out, record data such as following table.
It is successively operated repeatedly 8 times according to this operating procedure, records data, it was therefore concluded that, as shown in the table:
The effect of gained liquid detergent of the invention is as follows:
(1) of the invention, formula is mild, is suitable for machine washing and hand washing, and strong detergency is low-consuming, easily rinses, water-saving is time saving, no
The substance toxic to human body such as phosphorous, benzene, phenol does not add fluorescent whitening agent, and antibacterial additive plant extracts can natural degradation；
(2) of the invention, formula does not need to add the auxiliary agents such as other defoaming agents again, the removal to particulate fouling and dust dirt
Ability is preferable, and good with other component compatibilities；
(3) of the invention, plant extracts has broad-spectrum antibacterial and bactericidal properties in formula.Meanwhile the present invention adds nano oxygen
Change yttrium, by the synergistic function with plant extracts of the present invention, strengthens bacteria resistance function, whole fungistatic effect is obvious；
(4) of the invention, nano yttrium oxide makes the color more brilliant white of clothes in formula, and is not easy to adsorb grey trifle in the world
Object makes clothing keep cleaning.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to restrict the invention, it is all in spirit of the invention and
Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of antibacterial degradable washing powder, which is characterized in that by weight include following components: 30-50 parts of surfactant,
20-40 parts of natrium carbonicum calcinatum, 10-30 parts of plant extracts, 0.1-1 parts of nano yttrium oxide.The plant extracts includes bitter leaves
Tea, olive leaf.
2. the antibacterial degradable washing powder of one kind described in accordance with the claim 1, it is characterised in that: the surfactant is 12
Any one in sodium alkyl benzene sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol.
3. the antibacterial degradable washing powder of one kind described in accordance with the claim 1, it is characterised in that: the plant extracts is using such as
The preparation of lower section method: pure juice is obtained by squeezer squeeze juice after Ilex Latifolia Thunb, olive leaf are cleaned, then after water is filtered
Liquid, cooling obtains plant extraction liquid after pure juice is heated 0.5~1 hour at a temperature of 100~110 DEG C.
4. the antibacterial degradable washing powder of one kind described in accordance with the claim 1, it is characterised in that: bitter leaves in the plant extracts
The ratio of tea and olive leaf is 1: 0.5-1.
5. the antibacterial degradable washing powder of one kind described in accordance with the claim 1, it is characterised in that: the nano yttrium oxide have make
The effect of clothes brilliant white.
6. the antibacterial degradable washing powder of one kind described in accordance with the claim 1, it is characterised in that: the plant extracts and nanometer
Yttrium oxide has synergistic function.
7. a kind of antibacterial degradable washing powder, it is characterised in that preparation method includes the following steps:
(1) 30-50 parts of surfactant, 20-40 parts of natrium carbonicum calcinatum are poured into homogeneous blender and stirs one at a certain temperature
In fixing time, obtain being uniformly mixed mixed liquor a；
(2) 0.1-1 parts of 10-30 parts of plant extracts, nano yttrium oxide addition step (1) mixed liquor a are obtained into washing powder.
8. the antibacterial degradable washing powder of one kind according to claim 7, which is characterized in that the preparation method step
(1) certain temperature is 30-60 DEG C in, certain time 10-60min.
9. the antibacterial degradable washing powder of one kind according to claim 7, which is characterized in that the preparation method step
(2) partial size of nano yttrium oxide is in 10-50nm in.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910191493.4A CN109971557A (en) | 2019-02-28 | 2019-02-28 | A kind of antibacterial degradable washing powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910191493.4A CN109971557A (en) | 2019-02-28 | 2019-02-28 | A kind of antibacterial degradable washing powder |
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| Publication Number | Publication Date |
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| CN109971557A true CN109971557A (en) | 2019-07-05 |
Family
ID=67078776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201910191493.4A Pending CN109971557A (en) | 2019-02-28 | 2019-02-28 | A kind of antibacterial degradable washing powder |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023025748A1 (en) | 2021-08-27 | 2023-03-02 | Unilever Ip Holdings B.V. | Use of a detergent composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1566302A (en) * | 2003-06-13 | 2005-01-19 | 贾胜富 | Bacteriostatic decontaminating disinfecting washing powder |
| CN104059782A (en) * | 2014-06-30 | 2014-09-24 | 张松波 | Efficient stain-removing washing powder |
| CN107287048A (en) * | 2017-06-14 | 2017-10-24 | 广东红日星实业有限公司 | A kind of new and effective acidic cleaning and preparation method thereof |
-
2019
- 2019-02-28 CN CN201910191493.4A patent/CN109971557A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1566302A (en) * | 2003-06-13 | 2005-01-19 | 贾胜富 | Bacteriostatic decontaminating disinfecting washing powder |
| CN104059782A (en) * | 2014-06-30 | 2014-09-24 | 张松波 | Efficient stain-removing washing powder |
| CN107287048A (en) * | 2017-06-14 | 2017-10-24 | 广东红日星实业有限公司 | A kind of new and effective acidic cleaning and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 南京中医药大学: "《中药大辞典 上 第2版》", 31 March 2006, 上海科学技术出版社 * |
| 王昌涛等: "《化妆品植物添加剂的开发与应用》", 30 April 2013, 中国轻工业出版社 * |
| 黄锐等: "《稀土在高分子工业中的应用》", 31 July 2009, 中国轻工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023025748A1 (en) | 2021-08-27 | 2023-03-02 | Unilever Ip Holdings B.V. | Use of a detergent composition |
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Application publication date: 20190705 |