CN109966906A - A kind of recycle device and application method of constructing tunnel pernicious gas - Google Patents

A kind of recycle device and application method of constructing tunnel pernicious gas Download PDF

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Publication number
CN109966906A
CN109966906A CN201910340425.XA CN201910340425A CN109966906A CN 109966906 A CN109966906 A CN 109966906A CN 201910340425 A CN201910340425 A CN 201910340425A CN 109966906 A CN109966906 A CN 109966906A
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CN
China
Prior art keywords
reaction flask
exhaust fan
gas
pernicious gas
reaction
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Pending
Application number
CN201910340425.XA
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Chinese (zh)
Inventor
王军保
张永梦
张玉伟
宋战平
刘新荣
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Xian University of Architecture and Technology
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Xian University of Architecture and Technology
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Priority to CN201910340425.XA priority Critical patent/CN109966906A/en
Publication of CN109966906A publication Critical patent/CN109966906A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/02Separating dispersed particles from gases, air or vapours by liquid as separating agent by passing the gas or air or vapour over or through a liquid bath
    • B01D47/021Separating dispersed particles from gases, air or vapours by liquid as separating agent by passing the gas or air or vapour over or through a liquid bath by bubbling the gas through a liquid bath
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26Drying gases or vapours
    • B01D53/263Drying gases or vapours by absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/62Carbon oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/79Injecting reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
    • B01D53/82Solid phase processes with stationary reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/30Alkali metal compounds
    • B01D2251/304Alkali metal compounds of sodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/604Hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/10Inorganic absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/80Water

Abstract

The invention discloses the recycle devices and application method of a kind of constructing tunnel pernicious gas, by being provided with exhaust fan on cart, exhaust fan rear end is provided with several reaction flasks and gas collector, while making the present apparatus that tunnel environment action can be overcome to be limited, pernicious gas in tunnel can be absorbed again, and has also achieved the purpose of raw material of industry Gas recovery.The present apparatus has many advantages, such as that toxic gas transport distance is short, ventilation time is short, work efficiency is high, use cost is low, device is simple, action is convenient, resource recoverable.

Description

A kind of recycle device and application method of constructing tunnel pernicious gas
Technical field
The invention belongs to constructing tunnel fields, and in particular to a kind of recycle device of constructing tunnel pernicious gas and make Use method.
Background technique
The toxic gas generated in the flue dust that explosive generates when tunnel, mine working Blasting Excavation is to evaluate its security level Important indicator, explosive charge product mainly has CO, NO2, NO, sulfide, dust.CO is formed easily in conjunction with hemoglobin Carbonyl haemoglobin makes hemoglobin lose the ability and effect of oxygen carrying, tissue is caused to suffocate, dead when serious.CO is to complete The toxic effect of the histocyte of body, it is especially the most serious on corticocerebral influence.CO has combustibility simultaneously, is a kind of Industrial reduction agent can be recycled and be used for industrial metal smelting and industrial fuel.
S0 in atmosphere2Concentration has potential impact to human body in 0.5ppm or more;In 1~3ppm, majority start to feel Stimulation;People will appear ulcer and pulmonary edema until death by suffocation when 400~500ppm.Sulfur dioxide has with the flue dust in atmosphere Synergistic effect.As S0 in atmosphere2Concentration is 0.21ppm, and dust concentration is greater than 0.3mg/L, and respiratory disease disease incidence can be made to increase The state of an illness of height, chronic deteriorates rapidly.Hydrogen sulfide (H2It S) is a kind of colourless gas for having rotten-egg odour, it is soluble easily in water, There is intense stimulus effect to ocular delivery and respiratory tract, can seriously make conjunctival congestion, lung's dry rale.
Toxic gas, the dust of tunnel blasting excavation generation, excavator are toxic with the engine exhaust of large-scale slag waggon Gas seriously endangers the life and health of construction personnel.Fresh air is sent by ventilation duct and is tunneled by existing major long tunnel Working face, the wind pressure that the toxic gas after dilution is provided by blower take pernicious gas out of tunnel, and ventilation time is too long, imitates Rate is low.Since the long range tunnel less than 300m short distance and big 3000m can not be discharged in the increase of major long tunnel ventilation resistance in time Road pernicious gas and the requirement for meeting construction.As urban transportation builds ground tremendous development, major long tunnel needs more and more Construction proposes increasingly higher demands for construction environment, air quality, and existing method of ventilation has been unable to meet in construction Requirement.
Summary of the invention
The purpose of the present invention is to overcome the above shortcomings and to provide a kind of recycle device of constructing tunnel pernicious gas and Application method, to overcome the shortcomings that existing major long tunnel drafting efficiency is low, the time is long, the at high cost, wasting of resources.
In order to achieve the above object, a kind of recycle device of constructing tunnel pernicious gas, including the first exhaust fan and Second exhaust fan, the first exhaust fan and the second exhaust fan and rear end are disposed with several reaction flasks, the air inlet of the first exhaust fan It is provided with the first hurricane globe on mouthful, the second hurricane globe is provided on the air inlet of the second exhaust fan, the first exhaust fan and second are taken out The gas of the discharge of working off one's feeling vent one's spleen of blower is successively passed through in the reaction flask at rear, and the gas outlet of end reaction bottle is provided with gas Body collection device, if being liquid in reaction flask, air inlet end is placed in liquid, and outlet side is placed in outside liquid, if being in reaction flask Solid, then air inlet end is lower than outlet side.
First exhaust fan and the second exhaust fan and rear end are disposed with the first reaction flask, the second reaction flask and third reaction Bottle is connected between the first reaction flask and the second reaction flask by the first connecting tube, by the between the second reaction flask and third reaction flask Two connecting tubes connect, and the gas after cleaning in the first reaction flask is passed through in the liquid of the second reaction flask, clean in the second reaction flask Gas afterwards is passed through in the powder of third reaction flask, and the gas outlet of third reaction flask is provided with gas collector.
It is alkaline reagent in first reaction flask and the second reaction flask, third reaction flask is provided with sodium powder, the first connecting tube It is inside filled with active carbon powder, soda lime powder is filled in the second connecting tube.
First windproof cover opening 45 degree of settings obliquely, the opening up setting of the second hurricane globe.
Gas collector uses air bag.
First exhaust fan and the second exhaust fan are placed on cart.
Cart uses crawler type cart.
A kind of application method of the recycle device of constructing tunnel pernicious gas, comprising the following steps:
First exhaust fan and the second exhaust fan are placed in operating position by step 1;
Step 2 opens the first exhaust fan and the second exhaust fan, the first exhaust fan and the second exhaust fan for constructing tunnel mistake The pernicious gas that journey generates is sent into reaction flask;
After cleaning and absorption that pernicious gas passes through several reaction flasks, final residual gas is received by gas for step 3 Acquisition means are collected.
First exhaust fan and the second exhaust fan and rear end are disposed with the first reaction flask, the second reaction flask and third reaction Bottle is connected between the first reaction flask and the second reaction flask by the first connecting tube, by the between the second reaction flask and third reaction flask The connection of two connecting tubes, is alkaline reagent in the first reaction flask and the second reaction flask, and third reaction flask is provided with sodium powder, and first It is filled with active carbon powder in connecting tube, soda lime powder is filled in the second connecting tube;
NO, NO in alkaline solution absorption pernicious gas in first reaction flask2And CO2, sulfide and dust, first connects Active carbon powder in adapter tube adsorbs the formaldehyde in pernicious gas, in the alkaline solution absorption pernicious gas in the second reaction flask Remaining NO, NO2And CO2, the soda lime powder in the second connecting tube absorbs the moisture in pernicious gas, in third reaction flask Sodium powder absorb pernicious gas in O2, and remaining CO gas is sent into air bag and is collected.
In step 1, the first exhaust fan, the second exhaust fan, the first reaction flask, the second reaction flask and third reaction flask are set In on cart;
Cart is pushed into operating position.
Compared with prior art, recycle device of the invention is provided with exhaust fan, and exhaust fan rear end is provided with several Reaction flask and gas collector are filled with the present apparatus by acquisition and separate with recyclable device, can overcome tunnel environment action by While limit, and pernicious gas in tunnel can be absorbed, and have also achieved the purpose of raw material of industry Gas recovery.This Device is with toxic gas transport distance is short, ventilation time is short, work efficiency is high, use cost is low, device is simple, action side Just, the advantages that resource recoverable.
Working method of the invention is that cart is placed in operating position, and the first exhaust fan and the second exhaust fan are by constructing tunnel The pernicious gas that process generates is sent into reaction flask, will be final remaining after cleaning and absorption that pernicious gas passes through several reaction flasks Gas is collected by gas collector, is able to solve the ineffective problem of major long tunnel construction ventilation, is reached simultaneously The purpose of pernicious gas resource recycling, this method is with toxic gas transport distance is short, ventilation time is short, working efficiency High, the advantages that use cost is low, device is simple, resource recoverable, it is possible to prevente effectively from pernicious gas pair in constructing tunnel The harm of human life safety.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention;
Fig. 2 is work flow diagram of the invention;
Wherein, the 1, first hurricane globe;2, the first exhaust fan;3, the second hurricane globe;4, the second exhaust fan;11, the first reaction Bottle;14, the first connecting tube;17, the second reaction flask;20, the second connecting tube;23, third reaction flask;25, gas collector; 26, cart.
Specific embodiment
The present invention will be further described with reference to the accompanying drawing.
Referring to Fig. 1, a kind of recycle device of constructing tunnel pernicious gas, including cart 26,26 upper surface of cart Front end is provided with the first exhaust fan 2 and the second exhaust fan 4, and the first exhaust fan 2 and the second exhaust fan 4 and rear end are disposed with Several reaction flasks are provided with the first hurricane globe 1 on the air inlet of the first exhaust fan 2, are arranged on the air inlet of the second exhaust fan 4 There are the second hurricane globe 3, the 45 degree of settings obliquely of the first hurricane globe 1 opening, the opening up setting of the second hurricane globe 3, the first exhausting The gas of the discharge of working off one's feeling vent one's spleen of machine 2 and the second exhaust fan 4 is successively passed through in the reaction flask at rear, and the gas of end reaction bottle goes out It is provided with gas collector 25 at mouthful, if being liquid in reaction flask, air inlet end is placed in liquid, and outlet side is placed in liquid Outside, if in reaction flask being solid, air inlet end is lower than outlet side.
Preferably, the first exhaust fan 2 and the second exhaust fan 4 and rear end are disposed with the reaction of the first reaction flask 11, second Bottle 17 and third reaction flask 23 are connected between first reaction flask 11 and the second reaction flask 17 by the first connecting tube 14, the second reaction It is connected between bottle 17 and third reaction flask 23 by the second connecting tube 20, the gas after cleaning in the first reaction flask 11 is passed through second In the liquid of reaction flask 17, the gas after cleaning in the second reaction flask 17 is passed through in the powder of third reaction flask 23, third reaction The gas outlet of bottle 23 is provided with gas collector 25, is alkaline examination in the first reaction flask 11 and the second reaction flask 17 Agent, third reaction flask 23 are provided with sodium powder, and active carbon powder, filling in the second connecting tube 20 are filled in the first connecting tube 14 There is soda lime powder.
Preferably, gas collector 25 uses air bag, and cart 26 uses crawler type cart.
Referring to fig. 2, a kind of application method of the recycle device of constructing tunnel pernicious gas, comprising the following steps:
Step 1 pushes cart 26 to be placed in operating position;
Step 2, opens the first exhaust fan 2 and the second exhaust fan 4, the first exhaust fan 2 and the second exhaust fan 4 apply tunnel The pernicious gas that work process generates is sent into reaction flask, the NO in alkaline solution absorption pernicious gas in the first reaction flask 11, NO2And CO2, sulfide and dust, the formaldehyde in active carbon powder absorption pernicious gas in the first connecting tube 14, the second reaction Remaining NO, NO in alkaline solution absorption pernicious gas in bottle 172And CO2, soda lime powder in the second connecting tube 20 The moisture in pernicious gas is absorbed, the sodium powder in third reaction flask 23 absorbs the O in pernicious gas2
After cleaning and absorption that pernicious gas passes through several reaction flasks, final residual gas is received by gas for step 3 Acquisition means 25 are collected.
First exhaust fan 1 and the second exhaust fan 2 are centrifugal exhauster.
Alkaline solution is sodium hydroxide solution, solution concentration 20%-30%, preferably 25%.
Gas in gas collector 25 is CO and N actually2Mixed gas, it is contemplated that when CO excessive concentration, prevent Worker is exploded because mixing with air when careless manipulation stores gas, so nitrogen does not remove, but using nitrogen as guarantor Protect gas.

Claims (10)

1. a kind of recycle device of constructing tunnel pernicious gas, which is characterized in that taken out including the first exhaust fan (2) and second Blower (4), the first exhaust fan (2) and the second exhaust fan (4) and rear end are disposed with several reaction flasks, the first exhaust fan (2) Air inlet on be provided with the first hurricane globe (1), be provided on the air inlet of the second exhaust fan (4) the second hurricane globe (3), first The gas of the discharge of working off one's feeling vent one's spleen of exhaust fan (2) and the second exhaust fan (4) is successively passed through in the reaction flask at rear, end reaction bottle Gas outlet is provided with gas collector (25), if being liquid in reaction flask, air inlet end is placed in liquid, and outlet side is set In outside liquid, if in reaction flask being solid, air inlet end is lower than outlet side.
2. a kind of recycle device of constructing tunnel pernicious gas according to claim 1, which is characterized in that first takes out Blower (2) and the second exhaust fan (4) and rear end are disposed with the first reaction flask (11), the second reaction flask (17) and third reaction Bottle (23) is connected between the first reaction flask (11) and the second reaction flask (17) by the first connecting tube (14), the second reaction flask (17) It is connected between third reaction flask (23) by the second connecting tube (20), the gas in the first reaction flask (11) after cleaning is passed through second In the liquid of reaction flask (17), the gas in the second reaction flask (17) after cleaning is passed through in the powder of third reaction flask (23), the The gas outlet of three reaction flasks (23) is provided with gas collector (25).
3. a kind of recycle device of constructing tunnel pernicious gas according to claim 2, which is characterized in that first is anti- Answering in bottle (11) and the second reaction flask (17) is alkaline reagent, and third reaction flask (23) is provided with sodium powder, the first connecting tube (14) it is filled with active carbon powder in, is filled with soda lime powder in the second connecting tube (20).
4. a kind of recycle device of constructing tunnel pernicious gas according to claim 1, which is characterized in that first is anti- The 45 degree of settings obliquely of fan housing (1) opening, the second hurricane globe (3) opening up setting.
5. a kind of recycle device of constructing tunnel pernicious gas according to claim 1, which is characterized in that gas is received Acquisition means (25) use air bag.
6. a kind of recycle device of constructing tunnel pernicious gas according to claim 1, which is characterized in that first takes out Blower (2) and the second exhaust fan (4) are placed on cart (26).
7. a kind of recycle device of constructing tunnel pernicious gas according to claim 6, which is characterized in that cart (26) crawler type cart is used.
8. a kind of application method of the recycle device of constructing tunnel pernicious gas described in claim 1, which is characterized in that The following steps are included:
First exhaust fan (2) and the second exhaust fan (4) are placed in operating position by step 1;
Step 2 opens the first exhaust fan (2) and the second exhaust fan (4), the first exhaust fan (2) and the second exhaust fan (4) for tunnel The pernicious gas that road work progress generates is sent into reaction flask;
After cleaning and absorption that pernicious gas passes through several reaction flasks, final residual gas is filled by gas collection for step 3 (25) are set to be collected.
9. a kind of application method of the recycle device of constructing tunnel pernicious gas according to claim 8, feature It is, the first exhaust fan (2) and the second exhaust fan (4) and rear end are disposed with the first reaction flask (11), the second reaction flask (17) and third reaction flask (23) it, is connected between the first reaction flask (11) and the second reaction flask (17) by the first connecting tube (14), It is connected between second reaction flask (17) and third reaction flask (23) by the second connecting tube (20), the first reaction flask (11) and second is instead Answering is alkaline reagent in bottle (17), and third reaction flask (23) is provided with sodium powder, is filled with active carbon in the first connecting tube (14) Powder, the second connecting tube (20) is interior to be filled with soda lime powder;
NO, NO in alkaline solution absorption pernicious gas in first reaction flask (11)2And CO2, sulfide and dust, first connects The formaldehyde in the active carbon powder absorption pernicious gas in (14) is taken over, the alkaline solution in the second reaction flask (17) adsorbs harmful Remaining NO, NO in gas2And CO2, the soda lime powder in the second connecting tube (20) absorbs the moisture in pernicious gas, the Sodium powder in three reaction flasks (23) absorbs the O in pernicious gas2, and remaining CO gas is sent into air bag and is collected.
10. a kind of application method of the recycle device of constructing tunnel pernicious gas according to claim 8, feature It is, in step 1, the first exhaust fan (2), the second exhaust fan (4), the first reaction flask (11), the second reaction flask (17) and third Reaction flask (23) is placed on cart (26);
Cart (26) are pushed into operating position.
CN201910340425.XA 2019-04-25 2019-04-25 A kind of recycle device and application method of constructing tunnel pernicious gas Pending CN109966906A (en)

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CN201910340425.XA CN109966906A (en) 2019-04-25 2019-04-25 A kind of recycle device and application method of constructing tunnel pernicious gas

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Application Number Priority Date Filing Date Title
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10323540A (en) * 1997-05-26 1998-12-08 Kurimoto Ltd Waste gas treating device
CN2928875Y (en) * 2006-06-02 2007-08-01 包荣初 Hydrogen generator device
CN102434183A (en) * 2011-11-03 2012-05-02 谢飞鸿 Air purifier for clearing away harmful gases and dust for long tunneling working surface
CN102505952A (en) * 2011-11-03 2012-06-20 谢飞鸿 Method for clearing harmful gas and dust in long tunnel
CN106431339A (en) * 2016-09-29 2017-02-22 蒋文兰 Cylindrical activated carbon light porous ceramsite with function of purifying air
CN206701004U (en) * 2017-03-16 2017-12-05 广州昕曦冶金设备科技有限公司 A kind of tunnel cave dust pelletizing system
CN109000998A (en) * 2018-09-04 2018-12-14 株洲时代新材料科技股份有限公司 A kind of material at high temperature decomposes poison gas collection device and method
CN209865757U (en) * 2019-04-25 2019-12-31 西安建筑科技大学 Recycling device for harmful gas in tunnel construction

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10323540A (en) * 1997-05-26 1998-12-08 Kurimoto Ltd Waste gas treating device
CN2928875Y (en) * 2006-06-02 2007-08-01 包荣初 Hydrogen generator device
CN102434183A (en) * 2011-11-03 2012-05-02 谢飞鸿 Air purifier for clearing away harmful gases and dust for long tunneling working surface
CN102505952A (en) * 2011-11-03 2012-06-20 谢飞鸿 Method for clearing harmful gas and dust in long tunnel
CN106431339A (en) * 2016-09-29 2017-02-22 蒋文兰 Cylindrical activated carbon light porous ceramsite with function of purifying air
CN206701004U (en) * 2017-03-16 2017-12-05 广州昕曦冶金设备科技有限公司 A kind of tunnel cave dust pelletizing system
CN109000998A (en) * 2018-09-04 2018-12-14 株洲时代新材料科技股份有限公司 A kind of material at high temperature decomposes poison gas collection device and method
CN209865757U (en) * 2019-04-25 2019-12-31 西安建筑科技大学 Recycling device for harmful gas in tunnel construction

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