CN109965759A - Toilet paper - Google Patents
Toilet paper Download PDFInfo
- Publication number
- CN109965759A CN109965759A CN201810486821.9A CN201810486821A CN109965759A CN 109965759 A CN109965759 A CN 109965759A CN 201810486821 A CN201810486821 A CN 201810486821A CN 109965759 A CN109965759 A CN 109965759A
- Authority
- CN
- China
- Prior art keywords
- paper
- toilet paper
- tensile strength
- layers
- sense
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/002—Tissue paper; Absorbent paper
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K10/00—Body-drying implements; Toilet paper; Holders therefor
- A47K10/16—Paper towels; Toilet paper; Holders therefor
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/002—Tissue paper; Absorbent paper
- D21H27/004—Tissue paper; Absorbent paper characterised by specific parameters
- D21H27/005—Tissue paper; Absorbent paper characterised by specific parameters relating to physical or mechanical properties, e.g. tensile strength, stretch, softness
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
Landscapes
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Sanitary Thin Papers (AREA)
- Paper (AREA)
Abstract
The present invention relates to a kind of toilet paper, a kind of wiping other than human body is provided with the toilet paper for being not easy breakage on the way and skin sense of touch in the cleaning of people is excellent.The purpose of the present invention is resolved by toilet paper below, which is the toilet paper of 3 layers or 4 layers, and every 1 layer of the base weight of toilet paper is 14.9g/m2The above 16.2g/m2Hereinafter, thickness of paper as a whole is 297 μm or more 435 μm hereinafter, longitudinal dry tensile strength is 451cN/25mm or more 1001cN/25mm hereinafter, and laterally moistening tensile strength relative to laterally the ratio between dry tensile strength is 0.09 or more.
Description
Technical field
The present invention relates to toilet papers.In particular to the health for cleaning and the wiping other than human body of the human body after draining
Paper.
Background technique
Toilet paper is mainly used for the cleaning purpose after excretion, other purposes are according to area, region, country and difference.Also,
In sanitary tissue products, substantially other than the cleaning purpose finished proprietary item after excretion, also it is used as and is usually used in blow one's nose Deng faces
The substitute of the high tissue paper of the versatility of wiping other than the human bodies such as purposes or various articles, desk etc. uses.
For this toilet paper, the not damageability of the general tissue paper high as frequency of use is considered very heavy
It wants, and on the other hand, due to the cleaning purpose being also used to after draining, thus also require flexibility, fluffy sense.In addition, also vacation
If it can be discarded in water closet, to also require water-disintegrable.
It is not fragile in order to improve but for consumingly having for the toilet paper of the property of tissue paper alternative in this way
Damage property, it is thick and hard, it is inferior to special product in terms of skin sense of touch.
Existing technical literature
Patent document
Patent document 1: Japanese Unexamined Patent Publication 2017-169681
Summary of the invention
Problems to be solved by the invention
Therefore, major subjects of the invention are to provide a kind of toilet paper, have other than the cleaning purpose after excretion
The excellent intensity of versatilities such as the wiping purposes of article, while skin sense of touch is also excellent.
The means to solve the problem
The above-mentioned means to solve the problem are as follows.
Its first means is a kind of toilet paper, is the toilet paper of 3 layers or 4 layers, which is characterized in that
Every 1 layer of the base weight of toilet paper is 14.9g/m2The above 16.2g/m2Hereinafter, thickness of paper as a whole is 297 μm or more
435 μm hereinafter,
Longitudinal dry tensile strength be 451cN/25mm or more 1001cN/25mm hereinafter, and
Laterally wet tensile strength is 0.09 or more relative to laterally the ratio between dry tensile strength.
Second means is the toilet paper of above-mentioned first means, and absorption speed was less than 2.6 seconds.
Third means are the toilet paper of above-mentioned first means, and water-disintegrable is within 36 seconds.
The effect of invention
According to the present invention, it is possible to provide a kind of toilet paper has the wiping of the article other than the cleaning purpose after excretion
The excellent intensity of the versatilities such as purposes, while skin sense of touch is also excellent.
Detailed description of the invention
Fig. 1 is the perspective view of the roll toilet paper of present embodiment.
Fig. 2 is the figure for showing the measurement device of MMD.
Specific embodiment
The toilet paper of present embodiment for example formed as long ribbon shape, defend by the reel particularly suitable for the web-like on paper tube
The form of raw paper.In the case where the form of roll toilet paper is made, about its size etc., preferably wide L1 be 101~106mm,
Diameter L2 is 100~120mm, spooling length (overall length of toilet paper) is 18~70m, paper tube internal diameter L3 is 35~50mm.For
When the size, the paper frame of common roll toilet paper can be utilized, in the cleaning purpose after the excretion in closestool space easily
In use, also, the length of toilet paper is other than being sufficient length for the cleaning purpose after above-mentioned excretion, as thin page
Paper like that general use when be also sufficient length.
Toilet paper of the invention is the uncoated toilet paper of moisturizer for not adding moisturizer come outside by coating etc. substantially.Make
For additive moisturizer can example go out the polyalcohols such as glycerol, diglycerol, propylene glycol, 1,3 butylene glycol, polyethylene glycol, sorbose
The polyalcohol of the carbohydrates such as alcohol, glucose, xylitol, maltose, maltitol, mannitol, trehalose etc.But it is if above-mentioned
Ingredient can only bring the influence for being unworthy the referred to as degree of moisture retention toilet paper containing degree, then do not refuse containing it is above-mentioned at
Point.Intensity is difficult to ensure if being coated with moisturizer.However, it is possible to add the flexibility of the interior decision body paper added in copy paper itself
Softening agent, soft moisturizer with paper power.As softening agent, fatty acid ester based compound, fatty acyl amine system chemical combination can be enumerated
Object.Wherein, fatty acid amide based compound has the effect of coated fiber surface.
The toilet paper of present embodiment is 3 layers or 4 layers.That is, being overlapped into one group for 3 or being overlapped into one group for 4.
By multilayered structure as forming 3 layers or 4 layers, although the thickness of each layer is thinned, whole thickness of paper can also be thickened, especially
It can be improved the skin sense of touch of " flexibility " and " fluffy sense " etc and not easily damaged.It should be noted that if being 2 layers, then
It is not easy to embody thickness sense, when being used for the cleaning of article as universal product, journey is easily experienced in terms of not damageability
It spends weaker.In addition, even if each layer is then thinned, being also not easy to experience as a whole when carrying out skin cleaning if 5 layers or more
Flexibility, it is difficult to embody skin sense of touch Optimality, and be easy breakage when each layer is excessively thin.In addition, especially at 5 layers or more
In the case where, rigidity sense can be experienced strongly when assigning embossing.The toilet paper of present embodiment in 3 layers or 4 layers appoint
There is characteristic below, so that damageability and skin sense of touch be not excellent when one.
The toilet paper of present embodiment for 3 layers or 4 layers and following base weights, thickness of paper, longitudinal dry tensile strength and
In the case that laterally wet tensile strength is relative to laterally the ratio between dry tensile strength all obtains satisfaction, not damageability and flesh
Skin sense of touch is excellent.
Every 1 layer of the base weight of the toilet paper of the present embodiment is 14.9g/m2The above 16.2g/m2Below.If 1 layer of base weight
For that within the scope of this, then at above-mentioned 3 or 4 layers, can have adequately the Optimality of not damageability and skin sense of touch, and hold
It easily embodies water-disintegrable.
The toilet paper of present embodiment is 297 μm or more 435 μm or less as 3 layers or 4 layers of whole thickness of paper.If thickness of paper
For within the scope of this, then when being 3 or 4 layers of above-mentioned base weight, it can be ensured that adequately not damageability, and then skin can be made to touch
Sense, particularly flexibility are good.
It should be noted that base weight of the invention is the value of the base weight measuring method based on JIS P 8124 (1998).Paper
Thickness is after test film is carried out abundant damping under conditions of 8111 (1998) P JIS, to be surveyed under the same conditions using dial type
The value that thick instrument (thickness tester) " PEACOCK G type " (the rugged production of tail is made) measurement obtains.Specifically, confirmation plunger with
There is no dirt, dust etc. between measurement platform, plunger dropped on measurement platform, keep the scale of above-mentioned dial type calibrator mobile and
Next zero lifts plunger and coupons is placed on measurement platform, slowly falls plunger, read table number (gauge) at this time.
Notice that the terminal (circular flat of diameter 10mm) for the plunger for manufacturing metal is vertically contacted with paper plane in measurement.It needs
It is noted that the load when thickness of paper measures is about 70gf.
The dry tensile strength in the longitudinal direction of the toilet paper of present embodiment is 451cN/25mm or more 1001cN/25mm or less.
Compared with the wiping special product after excretion, which is very high value.Firstly, the toilet paper of present embodiment is logical
Cross with drying tensile strength high in this way and in general use very not cracky.In addition, longitudinal dry tensile strength is high
When, it is particularly easy to embody the smoothness of skin sense of touch.
In the toilet paper of present embodiment, laterally wet tensile strength is relative to laterally the ratio between dry tensile strength
0.09 or more.This is above the value of existing product.Herein, especially " laterally dry tensile strength " is considered not being to " soft
Property ", the other of " fluffy sense " etc aesthetic have an impact but have an impact to the entirety of " skin sense of touch " is aesthetic.It was found that
For measured not with the specific evaluation criteria of " flexibility ", " fluffy sense " etc and with after sample contact free
When " skin sense of touch " this overall merit benchmark evaluates tissue paper, it is somebody's turn to do the evaluation of " skin sense of touch " and " laterally drying is strong
Degree " has certain correlation.Laterally dry tensile strength is preferably 180cN/25mm or more 395cN/25mm or less.Another party
Face, laterally wet paper power has the tendency of the most weak value in the index for showing the intensity for indicating paper.Laterally wet paper power is high for this
In the case where, the strong sense that is wiped under moisture state and trusting when using cleaning after so-called warm water cleaning type pedestal toilet
Feel excellent.In the roll toilet paper of present embodiment, laterally wet tensile strength relative to laterally the ratio between dry tensile strength height,
It is 0.09 or more.That is, the balancing good of skin sense of touch and strong sense.Herein, from need its after the excretion in closestool space
In the actual use such as cleaning purpose will not it is damaged, have that from the aspect of trusting sense, laterally wet tensile strength is excellent in wiping
It is selected as 25cN/25mm or more 40cN/25mm or less.Above-mentioned wet tensile strength/transverse direction drying tensile strength in this range
Ratio be 0.09 or more when, for ensure using when flexibility be highly preferred.
It should be noted that the longitudinal direction of paper is also referred to as the direction MD, flow direction when being copy paper.The transverse direction of paper is also claimed
It is the direction orthogonal with flow direction (direction MD) when copy paper for the direction CD.In addition, drying tensile strength of the invention is base
Obtained value is measured in JIS P 8113 (2006), is measured as follows.Test film use is longitudinally, laterally being cut into width
The test film of 25mm (± 0.5mm) × long 150mm or so.Test film is directly measured using multilayer.Testing machine uses
The load cell cupping machine TG-200N of Minebea Co., Ltd. manufacture and comparable it is equal to instrument with its.It needs to illustrate
, between setting clamp distance be 100mm, tensile speed 100mm/min.Measurement is carried out using following processes: by test film
Both ends be fastened on the collet of testing machine, along the vertical direction to the scraps of paper apply tensile load, read paper fracture when indicated value
(digital value).Longitudinally, laterally preparing equal 5 groups of sample respectively, it is each respectively to carry out 5 measurements, by the average value of its measured value
Drying tensile strength as all directions.For product, multi-disc overlapping is measured according to the number of plies of product by dry tensile strength.
For body paper, multi-disc overlapping is also measured according to the number of plies of product by dry tensile strength.
In addition, wet tensile strength is to measure obtained value based on JIS P 8135 (1998), it is measured as follows.Test
Piece is used in the test film for being longitudinally, laterally cut into wide 25mm (± 0.5mm) × long 150mm or so.It is multilayer in tissue paper
In the case where, directly measure multilayer.The load cell cupping machine TG- that testing machine is manufactured using Minebea Co., Ltd.
200N and comparable it is equal to instrument with its.It should be noted that between setting clamp distance be 100mm, tensile speed 50mm/
min.Test film, which is used, carries out the test film after curing (curing) 10 minutes using 105 DEG C of drying machine.Utilize following processes
It is measured: the both ends of test film is fastened on the collet of testing machine, later using aqueous tack brush with the width of about 10mm
Degree horizontally assigns water to the central portion of test film, applies tensile load to the scraps of paper along the vertical direction immediately after, and it is disconnected to read paper
Indicated value (digital value) when splitting.Longitudinally, laterally preparing equal 5 groups of sample respectively, it is each respectively to carry out 5 measurements, it is surveyed
Wet tensile strength of the average value of definite value as all directions.In wet tensile strength, all in accordance with product the number of plies by multi-disc
Overlapping is to measure wet tensile strength.
In the toilet paper of present embodiment, indicate that the value of prima facie index MMD is preferably 6.6 or more 10.3 or less.MMD
If surface is excessively smooth less than 6.6, wiping is reduced；If skin sense of touch is poor more than 10.3, may be not suitable as defending
The purposes of raw paper.It should be noted that, using measurement device 100 shown in Fig. 2, making the contact of friction in the measurement of MMD
Face is contacted with the contact pressure of 25g with the surface of the measurement sample for the tension for having been assigned 20g/cm in the prescribed direction, simultaneously
With the speed of 0.1cm/s with have been assigned tension direction substantially common direction on mobile 2cm, use friction fremitus tester
KES-SE (manufacture of Katotech Co., Ltd.) or its equivalent instrument measure coefficient of friction at this time.The coefficient of friction is divided by rubbing
Wiping the obtained value of distance (moving distance=2cm) is MMD.Friction be it is adjacent by piano wire P that 20 diameters are 0.5mm and
At, there is in the way of growing and width is 10mm the contact surface formed.On the contact surface, front end is formed with by 20 steel
The unit bulge that qin line P (radius of curvature 0.25mm) is formed.
The preferred pliability of the toilet paper of present embodiment is 1.8cN/100mm or more 3.5cN/100mm or less.Pliability is
One of index of flexibility, value is lower to be considered more soft.When for tissue paper, toilet paper, if pliability is 1.0cN/
100mm is hereinafter, then it is believed that sufficiently flexible.The measured value of pliability refers to according to based on JIS L 1096E method (1990)
The value that Handle-O-Meter method is measured.Wherein, make size, the gap 5mm of test film 100mm × 100mm
To implement.With single layer respectively in longitudinally, laterally each measurement 5 times, the whole 10 times average value is taken, it should be noted that soft
Degree considers the size of test film without unit, is also indicated as unit of cN/100mm sometimes.
The starting pulps of toilet paper, the fiber raw material for constituting toilet paper can enumerate photogrammetry pulp mill (GP), pressure mill
The mechanical pulps such as wood pulp (PGW), preheating chip groundwood (TMP)；Semichemical wood pulp (CP), coniferous tree high yield do not bleach sulfuric acid
Salt wood pulp (HNKP), coniferous tree masson pine (NBKP), the non-masson pine of broad leaf tree (LUKP), broad leaf tree drift
The chemical pulps such as white sulfate wood pulp (LBKP)；Old paper stocks such as de inked pulp (DIP), secondary stock (WP) etc..Also it may include
Fiber other than paper pulp.
Paper pulp can choose using one or more kinds of.It is suitable for the chemical pulp for being preferably free of filler or foreign matter.Especially
It is using the LBKP (also referred to as L material or broad leaf tree wood pulp) contained more than NBKP (also referred to as N material or conifer trees
Slurry) paper pulp.That is, the chemical pulp that the ratio (NBKP/LBKP) of NBKP and LBKP is 50/50~30/70 is suitable.NBKP
Fibre coarseness ratio LBKP it is thick, therefore when NBKP is more, product is fluffy.In addition, also may include in starting pulps straw pulp,
The woodies such as bamboo pulp, mestha paper pulp, draft class.In addition it can mixed old paper stock, but since old paper stock is difficult to show
" flexibility " out, thus extremely preferred be only made of the NBKP of primary paper pulp and LBKP.
In addition, polyethylene terephthalate, poly terephthalic acid fourth two can be contained as the fiber other than paper pulp
The polyolefin series fibers, polypropylene such as the polyester fibers such as alcohol ester and their copolymer, polyethylene, polypropylene, polystyrene
Acrylic fibres, nylon 6, nylon66 fiber, the nylon 12 such as the Dralons such as nitrile, modified acrylic fibre (モ ダ Network リ Le)
Etc. perlons, vinal, Saran, polyvinyl chloride fibre, carbamate fibre etc. close
At semisynthetic fibres, viscose rayon yarn, copper rayon, polynosics such as fiber, tricel, diacetate esters fibers
(Polynosic) regenerated celluloses such as artificial silk, lyocell series fiber, solution is made simultaneously in collagen, alginic acid, chitin etc.
Carry out the chemical fibres such as the regenerated fiber that spinning obtains.Constitute chemical fibre polymer can for homopolymer, it is polymer-modified,
The forms such as blend, copolymer.
In addition, the preferred absorption speed of the toilet paper of present embodiment was less than 2.4 seconds.When absorption speed was less than 2.4 seconds, wiping
When cleaning when wiping the moisture sprayed or after so-called warm water cleaning type pedestal toilet use, moisture can be promptly absorbed.Separately
Outside, the wiping purposes of the article other than the cleaning purpose after excretion, i.e. wiping vanity top or closestool edge or wipe
It is also easy to use whens the dust etc. on table or ground.In addition, in the case where rolled article is made in toilet paper, in manufacturing process
The middle operation fix the end section for being referred to as the paper roll of tail portion with tail portion paste, when absorption speed was less than 2.4 seconds
The infiltration of the tail portion paste can be made rapidly, steadily to carry out the fixation of tail portion.The measurement of absorption speed is according to old plant JIS
S 3104(1985).In the test of absorption of water, the shifting that is adjusted in the way of the use of 1 drop by dropwise addition being about 0.1mL
Test film (multi-disc is one group when being overlapped) is placed at the support table in the hole that central portion is 40mm or more with diameter by liquid pipe etc.
On, it is dripped from 20 ± 1 DEG C of height dropping temperature of the distilled water 1 of about 10mm.It is contacted from water droplet with test film with unit measurement in 0.1 second
When to be absorbed completely and reflected light disappear until time.Test carries out 5 times, is determined using its average value.
In addition, the toilet paper selective hydrolysis of present embodiment is within 36 seconds.It is water-disintegrable if within 36 seconds, then flowing
When water is discarded in water closet etc., being piped a possibility that being blocked is significantly reduced.The measurement of water-disintegrable (the easy shatter value) according to
According to JIS P 4501 (1993).In the test of easy shatter value, it is loaded into the burning of the 300mL of 300mL water (20 ± 5 DEG C of water temperature)
Cup is placed in magnetic stirring apparatus, and the revolving speed for adjusting rotor is 600 ± 10 revs/min.It puts into thereto on one side as 114 ± 2mm square
Test film, press stopwatch.The revolving speed of rotor due to test film resistance and drop to about 500 turns for the time being, with test film pine
It dissipates, revolving speed rises.Stop stopwatch at the time of the revolving speed is restored to 540 turns, which was measured with 1 second unit.Carry out 5 examinations
It tests, the result of easy shatter value is indicated with its average value.Rotor is the disc-like rotor of diameter 35mm, thickness 12mm.
In the toilet paper of present embodiment, the adjustment of dry tensile strength and wet tensile strength can preferably pass through to
In paper stock or l Water Paper in add drying strengthening agent, wet strength agent and be easy to carry out, but can also pass through the number of plies, pulp varieties and paper pulp mixture
Ratio etc. is adjusted without using the method for paper strengthening agent.Wet strength agent is easy to obtain wet paper power and water-disintegrable balance.
As drying strengthening agent, starch, polyacrylamide, CMC (carboxymethyl cellulose) or the carboxylic first as its salt can be enumerated
Base sodium cellulosate, calcium carboxymethylcellulose, carboxymethyl cellulose zinc etc..In the case where adding drying strengthening agent inside, starched relative to paper pulp
Material is with 1.0kg/ paper pulp t degree addition below.
As wet strength agent, polyamide polyamine epichlorhydrin resin, carbamide resin, acid colloids-melamine tree can be enumerated
Rouge, heat cross-linking coating PAM etc..Using wet strength agent, more preferable temporary wet strength agent (transient wet strength agent).It is special
The temporary wet strength agent of other preferred cationic.Temporary wet strength agent can substantially maintain the intensity of the paper after just contacting with water,
And thereafter reduce rapidly the wet intensity of paper.It carries out having when the wiping of moisture in versatility, particularly universally as a result,
Excellent intensity, without due to wiping moisture when water content degree and keep surface roughening or damaged, and skin sense of touch
Also excellent, at the same can a large amount of water when discarded, the water flow in such as water closet under the action of and be crushed.As temporary
Property wet strength agent, for example, Nippon PMC K. K. manufacture TS-20, glyoxalated polyacrylamide, cationic second
The polymeric aldehydes such as aldehydic acid polyacrylamide-functionality compounds, the acryloyl being modified using dialdehydes such as glyoxals
The copolymer or dialdehyde starch etc. of amine monomers and other copolymerizable unsaturated monomers.They also can be used two or more.?
In the case where adding wet strength agent, the content in paper is 0.5~20.0kg/ paper pulp t or so.Preferred content is 1.0~
12.0kg/ paper pulp t.Preferred content is 4.0~8.0kg/ paper pulp t.If being less than 0.5kg/ paper pulp t, moistening paper power may
It is not high enough；If water-disintegrable to become too slow more than 20.0kg/ paper pulp t.
On the other hand, the tissue paper of present embodiment is 3 layers or 4 layers of tissue paper, but Embossing processing also can be implemented.More
It is preferred that because the protrusion caused by Embossing processing is towards double embossings on the inside of the lamination of layer.It is preferably being 3 layers in the case where double embossings
When to 1~2 layer of implementation Embossing processing, to 1~3 layer of implementation Embossing processing when for 4 layers.That is, there may be do not pressed in layer
The layer of line processing.Additionally, it is preferred that implementing the lamination Embossing processing with following structures, which is to assign forming sediment to the top of protrusion
Made of lamination well known to powder, carboxymethyl cellulose, water-based ink etc. pastes and layer is bonded to each other by protrusion top.Embossing adds
The area that respectively embosses in work, depth, range are not necessarily defined, but preferably according to embossing pressure assign area be whole 5~
It is 0.50 that 20% mode forms 5~30 in the unilateral area substantially with flat top, top surface in every 10mm square
~2.50mm2, embossing recess depths be 0.05~0.50mm embossing.Embossing recess depths are to utilize Co., Ltd. KEYENCE
The single of company's manufacture claps auto-focusing 3D measuring microscope VR-3200 or its equivalent instrument and image analysis software " VR-
The value that H1A " or its equivalent software measure.Measurement carries out under conditions of 12 times of multiplying power, field area 24mm × 18mm.Its
In, multiplying power and field area can suitably be changed according to the size of embossing.About specific continuous mode, using above-mentioned software,
Obtain crossing the embossing recess depths (measurement cross section curve) point in the line segment in the longest portion on the periphery of an embossing in image
Cloth.Wavelength is removed by low-pass filter in the cross section curve being distributed by the embossing recess depths and is shorter than λ c:800 μm (wherein,
λ c is " filter for defining the boundary of roughness ingredient and ripple elements " recorded in JIS-B0601 " 3.1.1.2 ") shortwave
The ingredient of long surface roughness obtains " contour curve ", in obtained " contour curve ", finds out 2 to raise upward and turns
Point P1, P2 and it is clipped in inflection point P1, the minimum value between P2, the minimum M in as depth.Further by inflection point P1, P2's
Maximum value Max of the average value of depth value as depth.In this way, embossing recess depths=maximum value Max- minimum M in.Separately
Outside, by inflection point P1, the distance (length) of P2 on an x-y plane is defined as the length in longest portion.It hangs down similarly, for longest portion
Most short portion on straight direction, also measurement embossing recess depths, are used as embossing recess depths using big value.For toilet paper surface
Any 10 embossing carry out more than measurement, using its average value as final embossing recess depths.
In addition, the toilet paper of present embodiment is particularly suitable for that the form of roll toilet paper is made.Utilizing present embodiment
The obtained preferred embodiment of roll toilet paper of toilet paper in, preferably winding hardness be 0.45~0.60kgf, spooling length 20
~30m, winding diameter are 100~117mm.Hardness is wound using the π meter of Muratec KDS Co., Ltd. manufacture or it is equivalent
Instrument is measured.Specifically, stretched by π meter on the circumference of reel along reel tangential direction or so, thus
The central portion for squeezing reel, tension when reducing 3mm from reset condition using the diameter of pull and push dynamometer measurement reel central portion.Volume
Diameter is similarly measured using π meter.π meter described herein is the tape measure using stainless steel making wound on reel
Circumference on and take by its length read the instrument of diameter.
Further the effect of the toilet paper in the present invention is illustrated referring to embodiment.
Embodiment
Manufacture the volume of the embodiment of the present invention (Examples 1 to 9), comparative example 1~4 and the toilet paper in conventional example 1~6
Cylinder toilet paper, carries out the toilet paper on the roll toilet paper measurement of physics value and composition value, simultaneously for " profit
Damageability (to the object) of strong sense after wet/not ", " flexibility of skin sense of touch ", " fluffy sense ", " smoothness " carry out sense organ examination
It tests.Base weight, thickness of paper, drying and wet tensile strength, MMD, pliability, winding hardness, absorption speed and water-disintegrable measurement side
Method is as described above.
The test method of sensory evaluation is as described below.Test is carried out using 15 estimators, and every 1 estimator is for each examination
Sample carries out 5 evaluations, using its average value for excluding to obtain after exceptional value score as the score of the estimator of a certain sample.Separately
Outside, it if the score of conventional example 1 is 4 points, is scored to each sample with 1~7 point, the average value for calculating each estimator carries out score
Change.It should be noted that the estimator of this evaluation is 9, it, can be abundant when every 1 estimator carries out 5 evaluations to each sample
It is evaluated with being without prejudice on ground.
Toilet paper as sample is 4 kinds of comparative example, 9 kinds of embodiment, 6 kinds of the conventional example of commercially available product, adds up to 19 kinds.It needs
It is noted that the conventional example 1 of the commercially available product as standard sample is the highest toilet paper of occupation rate of market, it is most consumers
The sample contacted.
The project of sensory evaluation is " strong sense when wetting/not damageability (to object) ", " flexibility of skin sense of touch ",
This 4 projects of " fluffy sense ", " smoothness ".
About " strong sense when wetting/not damageability (to object) ", vanity top (TOTO compact hand washer (hand is wiped
Shank type tap) LSL870AP) inboard portion ceramic surface moisture, if the score of standard sample be 4 points, with 7 grades to this
When whether without damaged and be rubbed off and score really.
About " flexibility of skin sense of touch ", estimator pulls out toilet paper, right with 7 grades if the score of standard sample is 4 points
The flexibility of skin sense of touch when being touched with hand is scored.
About " fluffy sense ", estimator pulls out toilet paper and kneads, if the score of standard sample is 4 points, is docked with 7 grades
Fluffy sense when touching is scored.
About " smoothness ", estimator pulls out toilet paper, if the score of standard sample is 4 points, when with 7 grades to being touched with hand
Smoothness score.
If confirming to the result of the sensory evaluation of table 1, in an embodiment of the present invention, " strong sense when wetting/
Not damageability (to object) ", " flexibility of skin sense of touch ", " fluffy sense ", each sensory evaluation of " smoothness " are much excellent
In each conventional example.On the other hand, compared with comparative example, " strong sense when wetting/not damageability (to object) ", " fluffy sense ",
" smoothness " is also especially excellent result.About " flexibility of skin sense of touch ", the evaluation of comparative example 3 is high, but in view of real
Applying example is 3 layers or 4 layers, and in contrast, comparative example 3 is 2 layers, although embodiment is multilayer, be can be evaluated as compared with 2 layers
Example 3 is same above " flexibility of skin sense of touch ".In addition, the sensory evaluation of the embodiment of the present invention is excellent, and the speed that absorbs water
Degree is also especially higher than conventional example and comparative example, also has strong sense.That is, toilet paper of the invention is the wiping use other than human body
Not cracky and skin sense of touch in the cleaning of people also excellent toilet paper on the way.
Symbol description
1 ... roll toilet paper, 10 ... toilet papers, 20 ... paper tubes, the width of L1 ... roll toilet paper, L2 ... roll toilet paper
Diameter, L3 ... paper tube diameter, 100 ... MMD measurement devices.
Claims (3)
1. a kind of toilet paper is the toilet paper of 3 layers or 4 layers, which is characterized in that
Every 1 layer of the base weight of toilet paper is 14.9g/m2The above 16.2g/m2Hereinafter, thickness of paper as a whole is 297 μm or more 435 μm
Hereinafter,
Longitudinal dry tensile strength be 451cN/25mm or more 1001cN/25mm hereinafter, and
Laterally wet tensile strength is 0.09 or more relative to laterally the ratio between dry tensile strength.
2. toilet paper as described in claim 1, wherein the absorption speed of the toilet paper was less than 2.6 seconds.
3. toilet paper as described in claim 1, wherein the water-disintegrable of the toilet paper is within 36 seconds.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017252551A JP7084717B2 (en) | 2017-12-27 | 2017-12-27 | Toilet Paper |
| JP2017-252551 | 2017-12-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109965759A true CN109965759A (en) | 2019-07-05 |
| CN109965759B CN109965759B (en) | 2023-03-28 |
Family
ID=67067135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810486821.9A Active CN109965759B (en) | 2017-12-27 | 2018-05-21 | Toilet paper |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20210059484A1 (en) |
| EP (1) | EP3733034B1 (en) |
| JP (1) | JP7084717B2 (en) |
| KR (1) | KR20200101910A (en) |
| CN (1) | CN109965759B (en) |
| WO (1) | WO2019131103A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7133943B2 (en) * | 2018-02-28 | 2022-09-09 | 大王製紙株式会社 | tissue paper |
| JP6689944B1 (en) * | 2018-11-30 | 2020-04-28 | 大王製紙株式会社 | Toilet Paper |
| JP7175801B2 (en) * | 2019-03-06 | 2022-11-21 | 大王製紙株式会社 | Toilet Paper |
| WO2024203733A1 (en) * | 2023-03-31 | 2024-10-03 | 日本製紙クレシア株式会社 | Toilet paper roll |
Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1339951A (en) * | 1999-02-09 | 2002-03-13 | 宝洁公司 | Tissue paper |
| CN1370252A (en) * | 1999-08-19 | 2002-09-18 | 宝洁公司 | Multi-ply tissue having caliper, low density, absorbent layer |
| JP2004209150A (en) * | 2003-01-08 | 2004-07-29 | Daio Paper Corp | Single-ply toilet paper, and method for manufacturing the same |
| US20090162597A1 (en) * | 2006-04-14 | 2009-06-25 | Georgia-Pacific France | Multi-Ply Disintegratable Absorbent Sheet, Associated Roll and Associated Manufacturing Process |
| JP2009161900A (en) * | 2009-01-20 | 2009-07-23 | Daio Paper Corp | Hydrolyzabable sanitary paper |
| CN101529019A (en) * | 2006-10-27 | 2009-09-09 | 金伯利-克拉克环球有限公司 | Molded wet-pressed tissue |
| CN101637366A (en) * | 2008-07-31 | 2010-02-03 | 大王制纸株式会社 | Hygienic tissue paper product and manufacturing method thereof |
| CN101637365A (en) * | 2008-07-31 | 2010-02-03 | 大王制纸株式会社 | Hygienic tissue paper and manufacturing method of the same |
| US20110024947A1 (en) * | 1999-11-01 | 2011-02-03 | Georgia Pacific Consumer Products Lp | Multi-ply absorbent paper product having impressed pattern |
| CN102578944A (en) * | 2005-04-21 | 2012-07-18 | 佐治亚-太平洋消费产品有限合伙公司 | Multi-ply paper towel with absorbent core |
| CN103384489A (en) * | 2011-02-22 | 2013-11-06 | 大王制纸株式会社 | Method for manufacturing toilet roll product, and toilet roll product |
| CN104271837A (en) * | 2012-05-08 | 2015-01-07 | 宝洁公司 | Fibrous structures and methods for making same |
| CN104510397A (en) * | 2013-08-30 | 2015-04-15 | 大王制纸株式会社 | Roll toilet paper |
| JP2015126771A (en) * | 2013-12-27 | 2015-07-09 | 日本製紙クレシア株式会社 | Toilet paper and method of manufacturing the same |
| JP2017176680A (en) * | 2016-03-31 | 2017-10-05 | 大王製紙株式会社 | Tissue paper |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3619808B2 (en) * | 2002-01-08 | 2005-02-16 | 大王製紙株式会社 | Sanitary roll paper for toilet |
| JP4317434B2 (en) * | 2003-12-08 | 2009-08-19 | 大王製紙株式会社 | Water-degradable sanitary paper |
| JP4570669B2 (en) * | 2008-03-31 | 2010-10-27 | 大王製紙株式会社 | Sanitary tissue paper |
| JP5602998B2 (en) * | 2008-09-19 | 2014-10-08 | 大王製紙株式会社 | Sanitary thin paper roll |
| JP5497310B2 (en) * | 2009-02-27 | 2014-05-21 | 大王製紙株式会社 | Water-degradable sanitary thin paper and toilet paper roll |
| JP5912196B1 (en) * | 2015-03-31 | 2016-04-27 | 大王製紙株式会社 | Tissue paper |
| TN2017000446A1 (en) * | 2015-04-29 | 2019-04-12 | Sca Hygiene Prod Ab | Tissue paper comprising pulp fibers originating from miscanthus and method for manufacturing the same |
| JP6794640B2 (en) | 2016-03-22 | 2020-12-02 | 王子ホールディングス株式会社 | Toilet Paper |
-
2017
- 2017-12-27 JP JP2017252551A patent/JP7084717B2/en active Active
-
2018
- 2018-05-21 CN CN201810486821.9A patent/CN109965759B/en active Active
- 2018-12-11 WO PCT/JP2018/045438 patent/WO2019131103A1/en unknown
- 2018-12-11 US US16/958,335 patent/US20210059484A1/en not_active Abandoned
- 2018-12-11 KR KR1020207015219A patent/KR20200101910A/en not_active Application Discontinuation
- 2018-12-11 EP EP18894199.1A patent/EP3733034B1/en active Active
Patent Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1339951A (en) * | 1999-02-09 | 2002-03-13 | 宝洁公司 | Tissue paper |
| CN1370252A (en) * | 1999-08-19 | 2002-09-18 | 宝洁公司 | Multi-ply tissue having caliper, low density, absorbent layer |
| US20110024947A1 (en) * | 1999-11-01 | 2011-02-03 | Georgia Pacific Consumer Products Lp | Multi-ply absorbent paper product having impressed pattern |
| JP2004209150A (en) * | 2003-01-08 | 2004-07-29 | Daio Paper Corp | Single-ply toilet paper, and method for manufacturing the same |
| CN102578944A (en) * | 2005-04-21 | 2012-07-18 | 佐治亚-太平洋消费产品有限合伙公司 | Multi-ply paper towel with absorbent core |
| US20090162597A1 (en) * | 2006-04-14 | 2009-06-25 | Georgia-Pacific France | Multi-Ply Disintegratable Absorbent Sheet, Associated Roll and Associated Manufacturing Process |
| CN101529019A (en) * | 2006-10-27 | 2009-09-09 | 金伯利-克拉克环球有限公司 | Molded wet-pressed tissue |
| CN101637366A (en) * | 2008-07-31 | 2010-02-03 | 大王制纸株式会社 | Hygienic tissue paper product and manufacturing method thereof |
| CN101637365A (en) * | 2008-07-31 | 2010-02-03 | 大王制纸株式会社 | Hygienic tissue paper and manufacturing method of the same |
| JP2009161900A (en) * | 2009-01-20 | 2009-07-23 | Daio Paper Corp | Hydrolyzabable sanitary paper |
| CN103384489A (en) * | 2011-02-22 | 2013-11-06 | 大王制纸株式会社 | Method for manufacturing toilet roll product, and toilet roll product |
| CN104271837A (en) * | 2012-05-08 | 2015-01-07 | 宝洁公司 | Fibrous structures and methods for making same |
| CN104510397A (en) * | 2013-08-30 | 2015-04-15 | 大王制纸株式会社 | Roll toilet paper |
| JP2015126771A (en) * | 2013-12-27 | 2015-07-09 | 日本製紙クレシア株式会社 | Toilet paper and method of manufacturing the same |
| JP2017176680A (en) * | 2016-03-31 | 2017-10-05 | 大王製紙株式会社 | Tissue paper |
Non-Patent Citations (1)
| Title |
|---|
| 陈明华: "《印刷纸 - 适印性及印刷故障》", 31 December 1986, 轻工业出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109965759B (en) | 2023-03-28 |
| EP3733034A4 (en) | 2021-08-25 |
| JP2019115593A (en) | 2019-07-18 |
| WO2019131103A1 (en) | 2019-07-04 |
| EP3733034B1 (en) | 2022-06-29 |
| KR20200101910A (en) | 2020-08-28 |
| EP3733034A1 (en) | 2020-11-04 |
| US20210059484A1 (en) | 2021-03-04 |
| JP7084717B2 (en) | 2022-06-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109965759A (en) | Toilet paper | |
| US12122137B2 (en) | Fibrous structure-containing articles that exhibit consumer relevant properties |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |