CN109957963A - A kind of preparation method of conductive fiber - Google Patents
A kind of preparation method of conductive fiber Download PDFInfo
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- CN109957963A CN109957963A CN201910271359.5A CN201910271359A CN109957963A CN 109957963 A CN109957963 A CN 109957963A CN 201910271359 A CN201910271359 A CN 201910271359A CN 109957963 A CN109957963 A CN 109957963A
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- fiber
- membrane tube
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/06—Inorganic compounds or elements
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Physical Vapour Deposition (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of preparation method of conductive fiber, including following content, fiber a, is immersed in dehydrated alcohol to the removal for carrying out surface grease, is rinsed 5 ~ 6min with deionized water;B, the step a fiber handled is penetrated in magnetron sputter, nickel layer, titanium layer and silver layer is successively plated in fiber surface using magnetron sputtering method;C, the fiber for being coated with metal layer is passed through to the spiral of microwave applicator into fiber tube, starting microwave applicator carries out microwave heating to fiber, and control heating temperature is 200 ~ 300 DEG C, and heating time is 10 ~ 15min;D, cooling treatment is carried out to the metallic fiber after heating, fiber temperature is down to room temperature, forms conductive fiber.
Description
Technical field
The invention patent relates to a kind of fibers, and in particular to a kind of preparation method of conductive fiber.
Background technique
With the continuous development of science and technology, the textile fiber for meeting people's difference needs emerges one after another, and is disappeared with meeting
The demand of the person of expense plays increasingly important role in people's daily life.
With the continuous development of industry, the market of fabric is also constantly expanding, but all effect is more single mostly for fabric,
Only have the function of blocking, such as cotton Products vulnerable to microbial action, is easy to be corroded by bacterium, mould, antibacterial and mouldproof
Effect is not significant;Cotton fiber anti-uv-ray itself is poor, so that it, which makes summer clothes, will lead to skin chromogenesis precipitating
Cutaneum carcinoma can even be caused.With the continuous improvement of living standards, demand of the people to the necessity in life is also constantly mentioning
Height, and the face liber being used alone often is unable to satisfy the use demand of people instantly after fabric is made, usually elasticity is fine
Dimension is unable to deposited metal layer, follows the string because will lead to elastomer after deposited metal layer, in order to meet elastomer simultaneously
Materials conductive and the requirement for maintaining elasticity, need to research and develop the structure and form of the metallic conduction metal layer of elastic material.
Summary of the invention
The purpose of invention: the purpose of the present invention is to provide a kind of preparation methods of conductive fiber, pass through a variety of plating metals
Technique plates metal layer in fiber surface, so that the fiber has electric conductivity, to meet higher demand.
A kind of the technical solution adopted by the present invention: preparation method of conductive fiber, it is characterised in that: specifically include following step
It is rapid:
A, fiber is immersed in dehydrated alcohol to the removal for carrying out surface grease, is then rinsed 5 ~ 6min with deionized water;
B, the step a fiber handled is mounted on the discharge roller in magnetron sputter, using magnetron sputtering method in fiber surface
Nickel layer, titanium layer and silver layer are successively plated, step includes:
B1, fiber penetrated to surface be spaced apart in the membrane tube equipped with arc notch, the shape of the arc notch by circular arc with it is ellipse
Circular arc is smoothly connected composition, and is wound up on the material receiving roller of the other end, controls fiber in membrane tube and is in tensional state;
B2, nickel strip target is successively laid in the cathode of magnetron sputter, magnetic is arranged at anode interval in titanium strip target and silver-colored strip target
Control head, and the position of magnetic control head is corresponding with the position of the arc notch in membrane tube;
B3, starting magnetron sputter, stablize 100s to build-up of luminance and move back the baffle above except membrane tube, so that target material surface atom sputtering
Out across arc notch, deposit to form metallic threadlike film in fiber surface;
B4, synchronous driving membrane tube and driving material receiving roller rotation, so that the arc notch rotation on membrane tube surface and fiber are in membrane tube
It moves forward internally, plates screw type nickel layer, titanium layer and silver layer to synchronize in fiber surface;
C, the fiber for being coated with metal layer is passed through to the spiral of microwave applicator into fiber tube, starting microwave applicator carries out fiber
Microwave heating, control heating temperature are 200 ~ 300 DEG C, and heating time is 10 ~ 15min, with the elasticity of reinforcing fiber;
D, cooling treatment is carried out to the metallic fiber after heating, fiber temperature is down to room temperature, forms conductive fiber.
Preferably, the rotation speed of membrane tube is 5r/min in the step b4, the speed of advancement of fiber is 5 ~ 10m/
min。
Preferably, the temperature of dehydrated alcohol is 40 ~ 50 DEG C in the step a.
Preferably, vacuumized in magnetron sputter in the step b, vacuum degree control (1~9) × 10-2Pa~
Between (1~9) × 10-5Pa.
Preferably, the shape of the arc notch is smoothly connected structure by the circular arc and 1/4-1/3 elliptic arc of 1/5-1/4
At to guarantee during fiber movement, in fiber surface formation helical metal cable architecture.
The utility model has the advantages that a kind of preparation method of disclosed conductive fiber, the fiber of preparation has following beneficial
Effect:
It is rotated using the membrane tube with arc notch, the synchronous Forward with condensating fiber can form spiral gold in fiber surface
Belong to layer, it is conductive that this spiral metal layer can not only make fiber, but also does not influence the elastic force of fiber;
High resiliency cooperates microwave heating using screwed pipe, so that homogeneous heating, so that it is guaranteed that metal layer is evenly affixed to fiber table
Layer, while the fibre weight that screwed pipe structure can be promoted while be heated, and thread forms can promote the elasticity of fiber.
Detailed description of the invention
Fig. 1 is the structure chart that the present invention uses magnetic force sputtering equipment;
Fig. 2 is the structure chart that the present invention uses microwave heating equipment;
Fig. 3 is the interior view of Fig. 2 microwave heating equipment;
1, cavity 11, discharge roller 12, material receiving roller 13, membrane tube 131, arc notch 14, baffle 15, cathode 16, anode
17, strip target 18, magnetic control head;2, cabinet 21, cooling tube 22, screwed pipe 23, microwave heating head.
Specific embodiment
The specific embodiment of the invention is described in detail combined with specific embodiments below:
Embodiment 1
A kind of preparation method of disclosed conductive fiber comprising following steps:
A, fiber is immersed in the dehydrated alcohol that temperature is 40 DEG C to the removal for carrying out surface grease, is then rushed with deionized water
Wash 5min;
B, the step a fiber handled is mounted on the discharge roller 11 in magnetron sputter, to being vacuumized in magnetron sputter, very
Reciprocal of duty cycle is (1~9) × 10-2Pa, successively plates nickel layer, titanium layer and silver layer, step packet in fiber surface using magnetron sputtering method
It includes:
B1, fiber is penetrated in the membrane tube 13 spaced apart equipped with arc notch 131 of surface, the shape of the arc notch is by circular arc
It is smoothly connected composition with elliptic arc, and is wound up on the material receiving roller 12 of the other end, fiber in membrane tube 13 is controlled and is in tensional state;
B2, nickel strip target 17 is successively laid in the cathode 15 of magnetron sputter, titanium strip target 17 and silver-colored strip target 17, in anode 16
Interval setting magnetic control head 18, and the position of magnetic control head 18 is corresponding with the position of arc notch 131 in membrane tube 13;
B3, starting magnetron sputter, stablize 100s to build-up of luminance and move back except the baffle 14 above membrane tube 13, so that target material surface atom
It sputters out across arc notch 131, deposits to form metallic threadlike film in fiber surface;
B4, synchronous driving membrane tube 13 and driving material receiving roller 12 rotate, so that the arc notch 131 on 13 surface of membrane tube rotates, and
Fiber is moved forward internally in membrane tube 13, plates screw type nickel layer, titanium layer and silver layer to synchronize in fiber surface, control membrane tube 13
Rotation speed is 5r/min, and the speed of advancement of fiber is 5m/min;
C, the fiber for being coated with metal layer is passed through to the spiral of microwave applicator into fiber tube, starting microwave applicator carries out fiber
Microwave heating, control heating temperature is 200 DEG C, heating time 10min, with the elasticity of reinforcing fiber;
D, cooling treatment is carried out to the metallic fiber after heating, fiber temperature is down to room temperature, forms conductive fiber.
In this example, as shown in Figure 1, the magnetic force sputtering equipment is that the discharge roller at 1 both ends of cavity is arranged in by cavity 1
11 and material receiving roller 12, the membrane tube 13 at 1 center of cavity is set, and is adsorbed on 16 plate of 15 plate of cathode and anode of 1 inner wall of cavity
Composition, discharge roller 11 and material receiving roller 12 are equipped with through motor driven, the membrane tube 13 be mounted on discharge roller 11 and material receiving roller 12 it
Between, membrane tube 13 is fixed by bearing, and one end of the membrane tube 13 is additionally provided with driven gear, and the driven gear passes through sliding tooth
Wheel is connected to motor, and the membrane tube 13 was equipped with a arc notch 131, the shape of the arc notch 131 by circular arc with it is ellipse
Circular arc is smoothly connected composition, carries out autobiography movement by motor driven, 15 plate of cathode is distributed in the chamber of the top of membrane tube 13
On 1 inner wall of body, 16 plate of anode is arranged on 1 inner wall of cavity of the lower section of membrane tube 13, and 16 plate of anode is opposite with 15 plate of cathode
Distribution, 15 plate of cathode are equipped at least one strip target 17, and 16 plate of anode is equipped at least one magnetic control head 18.
In the present embodiment, the shape of the arc notch is smoothly connected structure by the circular arc and 1/4-1/3 elliptic arc of 1/5-1/4
At to guarantee during fiber movement, in fiber surface formation helical metal cable architecture.
In this example, 16 plate of anode in the magnetic force sputtering equipment is equipped with multiple magnetic control heads 18, the magnetic control head 18
It is at least identical as the absorption hole number in membrane tube 13, at least guarantee that each magnetic control head 18 and the adsorption hole one in membrane tube 13 are a pair of
It answers.
In this example, it is additionally provided with baffle 14 between 16 plate of 15 plate of cathode in the magnetic force sputtering equipment and anode, it is described
14 both ends of baffle and 1 both ends of cavity are hinged, and setting rotation knob is connect with baffle 14 outside cavity 1, and the baffle 14 is set
It sets between 16 plate of membrane tube 13 and 15 plate of cathode or anode.
In this example, as Figure 2-3, the microwave heating equipment is cabinet 2, and cooling tube 21 is equipped in cabinet 2, cooling
21 outer wall of pipe winds metal threaded pipe 22, and the upper and lower ends of cabinet 2 are equipped with the inlet and outlet of metal threaded pipe 22, microwave heating head 23
The upper surface of cabinet 2 is set, and is distributed on metal threaded pipe 22.
Embodiment 2
A kind of preparation method of disclosed conductive fiber comprising following steps:
A, fiber is immersed in the dehydrated alcohol that temperature is 45 DEG C to the removal for carrying out surface grease, is then rushed with deionized water
Wash 5 ~ 6min;
B, the step a fiber handled is mounted on the discharge roller 11 in magnetron sputter, to being vacuumized in magnetron sputter, very
Reciprocal of duty cycle control is (1~9) × 10-3Pa, successively plates nickel layer, titanium layer and silver layer in fiber surface using magnetron sputtering method, is walked
Suddenly include:
B1, fiber is penetrated in the membrane tube 13 spaced apart equipped with arc notch 131 of surface, the shape of the arc notch is by circular arc
It is smoothly connected composition with elliptic arc, and is wound up on the material receiving roller 12 of the other end, fiber in membrane tube 13 is controlled and is in tensional state;
B2, nickel strip target 17 is successively laid in the cathode 15 of magnetron sputter, titanium strip target 17 and silver-colored strip target 17, in anode 16
Interval setting magnetic control head 18, and the position of magnetic control head 18 is corresponding with the position of arc notch 131 in membrane tube 13;
B3, starting magnetron sputter, stablize 100s to build-up of luminance and move back except the baffle 14 above membrane tube 13, so that target material surface atom
It sputters out across arc notch 131, deposits to form metallic threadlike film in fiber surface;
B4, synchronous driving membrane tube 13 and driving material receiving roller 12 rotate, so that the arc notch 131 on 13 surface of membrane tube rotates, and
Fiber is moved forward internally in membrane tube 13, plates screw type nickel layer, titanium layer and silver layer to synchronize in fiber surface, control membrane tube 13
Rotation speed is 5r/min, and the speed of advancement of fiber is 8m/min;
C, the fiber for being coated with metal layer is passed through to the spiral of microwave applicator into fiber tube, starting microwave applicator carries out fiber
Microwave heating, control heating temperature is 25 DEG C, heating time 12min, with the elasticity of reinforcing fiber;
D, cooling treatment is carried out to the metallic fiber after heating, fiber temperature is down to room temperature, forms conductive fiber.
In this example, as shown in Figure 1, the magnetic force sputtering equipment is that the discharge roller at 1 both ends of cavity is arranged in by cavity 1
11 and material receiving roller 12, the membrane tube 13 at 1 center of cavity is set, and is adsorbed on 16 plate of 15 plate of cathode and anode of 1 inner wall of cavity
Composition, discharge roller 11 and material receiving roller 12 are equipped with through motor driven, the membrane tube 13 be mounted on discharge roller 11 and material receiving roller 12 it
Between, membrane tube 13 is fixed by bearing, and one end of the membrane tube 13 is additionally provided with driven gear, and the driven gear passes through sliding tooth
Wheel is connected to motor, and the membrane tube 13 was equipped with a arc notch 131, the shape of the arc notch 131 by circular arc with it is ellipse
Circular arc is smoothly connected composition, carries out autobiography movement by motor driven, 15 plate of cathode is distributed in the chamber of the top of membrane tube 13
On 1 inner wall of body, 16 plate of anode is arranged on 1 inner wall of cavity of the lower section of membrane tube 13, and 16 plate of anode is opposite with 15 plate of cathode
Distribution, 15 plate of cathode are equipped at least one strip target 17, and 16 plate of anode is equipped at least one magnetic control head 18.
In the present embodiment, the shape of the arc notch is smoothly connected structure by the circular arc and 1/4-1/3 elliptic arc of 1/5-1/4
At to guarantee during fiber movement, in fiber surface formation helical metal cable architecture.
In this example, 16 plate of anode in the magnetic force sputtering equipment is equipped with multiple magnetic control heads 18, the magnetic control head 18
It is at least identical as the absorption hole number in membrane tube 13, at least guarantee that each magnetic control head 18 and the adsorption hole one in membrane tube 13 are a pair of
It answers.
In this example, it is additionally provided with baffle 14 between 16 plate of 15 plate of cathode in the magnetic force sputtering equipment and anode, it is described
14 both ends of baffle and 1 both ends of cavity are hinged, and setting rotation knob is connect with baffle 14 outside cavity 1, and the baffle 14 is set
It sets between 16 plate of membrane tube 13 and 15 plate of cathode or anode.
In this example, as Figure 2-3, the microwave heating equipment is cabinet 2, and cooling tube 21 is equipped in cabinet 2, cooling
21 outer wall of pipe winds metal threaded pipe 22, and the upper and lower ends of cabinet 2 are equipped with the inlet and outlet of metal threaded pipe 22, microwave heating head 23
The upper surface of cabinet 2 is set, and is distributed on metal threaded pipe 22.
Embodiment 3
A kind of preparation method of disclosed conductive fiber comprising following steps:
A, fiber is immersed in the dehydrated alcohol that temperature is 50 DEG C to the removal for carrying out surface grease, is then rushed with deionized water
Wash 6min;
B, the step a fiber handled is mounted on the discharge roller 11 in magnetron sputter, to being vacuumized in magnetron sputter, very
Reciprocal of duty cycle control is (1~9) × 10-5Pa, successively plates nickel layer, titanium layer and silver layer in fiber surface using magnetron sputtering method, is walked
Suddenly include:
B1, fiber is penetrated in the membrane tube 13 spaced apart equipped with arc notch 131 of surface, the shape of the arc notch is by circular arc
It is smoothly connected composition with elliptic arc, and is wound up on the material receiving roller 12 of the other end, fiber in membrane tube 13 is controlled and is in tensional state;
B2, nickel strip target 17 is successively laid in the cathode 15 of magnetron sputter, titanium strip target 17 and silver-colored strip target 17, in anode 16
Interval setting magnetic control head 18, and the position of magnetic control head 18 is corresponding with the position of arc notch 131 in membrane tube 13;
B3, starting magnetron sputter, stablize 100s to build-up of luminance and move back except the baffle 14 above membrane tube 13, so that target material surface atom
It sputters out across arc notch 131, deposits to form metallic threadlike film in fiber surface;
B4, synchronous driving membrane tube 13 and driving material receiving roller 12 rotate, so that the arc notch 131 on 13 surface of membrane tube rotates, and
Fiber is moved forward internally in membrane tube 13, plates screw type nickel layer, titanium layer and silver layer to synchronize in fiber surface, control membrane tube 13
Rotation speed is 5r/min, and the speed of advancement of fiber is 10m/min;
C, the fiber for being coated with metal layer is passed through to the spiral of microwave applicator into fiber tube, starting microwave applicator carries out fiber
Microwave heating, control heating temperature is 300 DEG C, heating time 15min, with the elasticity of reinforcing fiber;
D, cooling treatment is carried out to the metallic fiber after heating, fiber temperature is down to room temperature, forms conductive fiber.
In this example, as shown in Figure 1, the magnetic force sputtering equipment is that the discharge roller at 1 both ends of cavity is arranged in by cavity 1
11 and material receiving roller 12, the membrane tube 13 at 1 center of cavity is set, and is adsorbed on 16 plate of 15 plate of cathode and anode of 1 inner wall of cavity
Composition, discharge roller 11 and material receiving roller 12 are equipped with through motor driven, the membrane tube 13 be mounted on discharge roller 11 and material receiving roller 12 it
Between, membrane tube 13 is fixed by bearing, and one end of the membrane tube 13 is additionally provided with driven gear, and the driven gear passes through sliding tooth
Wheel is connected to motor, and the membrane tube 13 was equipped with a arc notch 131, the shape of the arc notch 131 by circular arc with it is ellipse
Circular arc is smoothly connected composition, carries out autobiography movement by motor driven, 15 plate of cathode is distributed in the chamber of the top of membrane tube 13
On 1 inner wall of body, 16 plate of anode is arranged on 1 inner wall of cavity of the lower section of membrane tube 13, and 16 plate of anode is opposite with 15 plate of cathode
Distribution, 15 plate of cathode are equipped at least one strip target 17, and 16 plate of anode is equipped at least one magnetic control head 18.
In the present embodiment, the shape of the arc notch is smoothly connected structure by the circular arc and 1/4-1/3 elliptic arc of 1/5-1/4
At to guarantee during fiber movement, in fiber surface formation helical metal cable architecture.
In this example, 16 plate of anode in the magnetic force sputtering equipment is equipped with multiple magnetic control heads 18, the magnetic control head 18
It is at least identical as the absorption hole number in membrane tube 13, at least guarantee that each magnetic control head 18 and the adsorption hole one in membrane tube 13 are a pair of
It answers.
In this example, it is additionally provided with baffle 14 between 16 plate of 15 plate of cathode in the magnetic force sputtering equipment and anode, it is described
14 both ends of baffle and 1 both ends of cavity are hinged, and setting rotation knob is connect with baffle 14 outside cavity 1, and the baffle 14 is set
It sets between 16 plate of membrane tube 13 and 15 plate of cathode or anode.
In this example, as Figure 2-3, the microwave heating equipment is cabinet 2, and cooling tube 21 is equipped in cabinet 2, cooling
21 outer wall of pipe winds metal threaded pipe 22, and the upper and lower ends of cabinet 2 are equipped with the inlet and outlet of metal threaded pipe 22, microwave heating head 23
The upper surface of cabinet 2 is set, and is distributed on metal threaded pipe 22.
The above is only a preferred embodiment of the present invention, it should be pointed out that: for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (5)
1. a kind of preparation method of conductive fiber, it is characterised in that: specifically comprise the following steps:
A, fiber is immersed in dehydrated alcohol to the removal for carrying out surface grease, is then rinsed 5 ~ 6min with deionized water;
B, the step a fiber handled is mounted on the discharge roller in magnetron sputter, using magnetron sputtering method in fiber surface
Nickel layer, titanium layer and silver layer are successively plated, step includes:
B1, fiber penetrated to surface be spaced apart in the membrane tube equipped with arc notch, the shape of the arc notch by circular arc with it is ellipse
Circular arc is smoothly connected composition, and is wound up on the material receiving roller of the other end, controls fiber in membrane tube and is in tensional state;
B2, nickel strip target is successively laid in the cathode of magnetron sputter, magnetic is arranged at anode interval in titanium strip target and silver-colored strip target
Control head, and the position of magnetic control head is corresponding with the position of the arc notch in membrane tube;
B3, starting magnetron sputter, stablize 100s to build-up of luminance and move back the baffle above except membrane tube, so that target material surface atom sputtering
Out across arc notch, deposit to form metallic threadlike film in fiber surface;
B4, synchronous driving membrane tube and driving material receiving roller rotation, so that the arc notch rotation on membrane tube surface and fiber are in membrane tube
It moves forward internally, plates screw type nickel layer, titanium layer and silver layer to synchronize in fiber surface;
C, the fiber for being coated with metal layer is passed through to the spiral of microwave applicator into fiber tube, starting microwave applicator carries out fiber
Microwave heating, control heating temperature are 150-300 DEG C, and heating time is 10 ~ 15min, with the elasticity of reinforcing fiber;
D, cooling treatment is carried out to the conductive fiber after heating, fiber temperature is down to room temperature, forms conductive fiber.
2. a kind of preparation method of conductive fiber according to claim 1, it is characterised in that: membrane tube in the step b4
Rotation speed is 5r/min, and the speed of advancement of fiber is 5 ~ 10m/min.
3. a kind of preparation method of conductive fiber according to claim 1, it is characterised in that: anhydrous second in the step a
The temperature of alcohol is 40 ~ 50 DEG C.
4. a kind of preparation method of conductive fiber according to claim 1, it is characterised in that: in the step b, magnetic control splashes
It penetrates in machine and vacuumizes, vacuum degree control is between (1~9) × 10-2Pa~(1~9) × 10-5Pa.
5. a kind of preparation method of conductive fiber according to claim 1, it is characterised in that: the shape of the arc notch
It is smoothly connected and is constituted with 1/4-1/3 elliptic arc by the circular arc of 1/5-1/4, to guarantee during fiber movement, in fiber surface
Form helical metal cable architecture.
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CN201910271359.5A CN109957963B (en) | 2019-04-04 | 2019-04-04 | Preparation method of conductive fiber |
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CN103741109A (en) * | 2013-12-31 | 2014-04-23 | 北京工业大学 | Device and method for continuously coating fiber with metallic conductive function film through magnetron sputtering |
CN105887473A (en) * | 2016-06-01 | 2016-08-24 | 苏州瑞众新材料科技有限公司 | Tensile electromagnetic shielding yarn and manufacturing device thereof |
CN106521931A (en) * | 2016-08-25 | 2017-03-22 | 北京浩运盛跃新材料科技有限公司 | Method for plating carbon nanotube fibers with nickel |
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CN2450227Y (en) * | 2000-11-27 | 2001-09-26 | 湖南三才光电信息材料有限公司 | Foamed nickel magnetic control sputtering winding film coating machine |
CN1687507A (en) * | 2005-04-12 | 2005-10-26 | 夏芝林 | Method for preparing silver metallized organic fiber and textile |
CN101581036A (en) * | 2008-05-15 | 2009-11-18 | 中国科学院金属研究所 | Preparation method of continuous SiC fiber surface C/AIN composite gradient coating. |
CN101876140A (en) * | 2009-04-30 | 2010-11-03 | 昆山市同福电子材料厂 | Preparation method of electromagnetic shielding conductive fabric |
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CN105887473A (en) * | 2016-06-01 | 2016-08-24 | 苏州瑞众新材料科技有限公司 | Tensile electromagnetic shielding yarn and manufacturing device thereof |
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