CN109942941A - A kind of formula and manufacture production technology for plastic additive - Google Patents

A kind of formula and manufacture production technology for plastic additive Download PDF

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Publication number
CN109942941A
CN109942941A CN201910221686.XA CN201910221686A CN109942941A CN 109942941 A CN109942941 A CN 109942941A CN 201910221686 A CN201910221686 A CN 201910221686A CN 109942941 A CN109942941 A CN 109942941A
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China
Prior art keywords
parts
formula
plastic additive
deionized water
polyethylene
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Pending
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CN201910221686.XA
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Chinese (zh)
Inventor
李宝兴
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Guangdong Bao Hing Technology Co Ltd
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Guangdong Bao Hing Technology Co Ltd
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Priority to CN201910221686.XA priority Critical patent/CN109942941A/en
Publication of CN109942941A publication Critical patent/CN109942941A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of formulas for plastic additive, it is related to plastic additive formula and technology field, including following parts by weight of component: 20-25 parts of polyethylene, 1-2 parts of polyethylene wax, sarin resin 10-15,1-3 parts of catalyst, 5-9 parts of glycerol, 1-4 parts of fireproof agent, 10-15 parts of sodium carbonate, aliphatic polyester 10-15, polylactic acid 10-15, deionized water 50-70.The present invention can play natural degradation effect by the addition of aliphatic polyester, glycerol and polylactic acid, burning disposal is not necessarily to after discarded, manpower and financial resources has been saved, and natural environment will not have been damaged, has had the effect of environmental protection, increase practicability, it is added to polyethylene wax, not only there is excellent cold resistance and heat resistance, while also there is stronger lubricating action, it can be convenient demoulding in plastic processing, so that frosting more satin.

Description

A kind of formula and manufacture production technology for plastic additive
Technical field
The present invention relates to plastic additive formula and technology field, specifically a kind of formula for plastic additive And manufacture production technology.
Background technique
Additive, which refers to, to be dispersed in plastic molecules structure, will not the serious molecular structure for influencing plastics, and can improve Its property or the chemical substance for reducing cost, the addition of additive can promote plastics to improve the processability of substrate, physical, change The functions such as the property learned and the Wuli-Shili-Renli system approach for increasing substrate.
Plastic additive on the market has deficiency with fire-retardant aspect in environmental protection at present, can not play natural degradation Effect, the not only labor intensive financial resources in burning or landfill disposal, also will cause environmental pollution, so that causing one to natural environment The harm for determining degree seriously affects environment for the survival of mankind.Therefore, those skilled in the art provide a kind of for plastics The formula and manufacture production technology of additive, to solve the problems mentioned in the above background technology.
Summary of the invention
It is above-mentioned to solve the purpose of the present invention is to provide a kind of formula for plastic additive and manufacture production technology The problem of being proposed in background technique.
To achieve the above object, the invention provides the following technical scheme: a kind of formula for plastic additive, including with Lower parts by weight of component: 20-25 parts of polyethylene, 1-2 parts of polyethylene wax, sarin resin 10-15,1-3 parts of catalyst, 5-9 parts of glycerol, 1-4 parts of fireproof agent, 10-15 parts of sodium carbonate, aliphatic polyester 10-15, polylactic acid 10-15, deionized water 50-70.
As further scheme of the invention: including following parts by weight of component: 22-24 parts of polyethylene, polyethylene wax 1-2 Part, sarin resin 12-14,2-3 parts of catalyst, 6-8 parts of glycerol, 2-3 parts of fireproof agent, 12-14 parts of sodium carbonate, aliphatic polyester 12-14, polylactic acid 12-14, deionized water 55-65.
As further scheme of the invention: including following parts by weight of component: 23 parts of polyethylene, 2 parts of polyethylene wax, sand Woods resin 13,2 parts of catalyst, 7 parts of glycerol, 2.5 parts of fireproof agent, 13 parts of sodium carbonate, aliphatic polyester 13, polylactic acid 13, go from Sub- water 60.
As further scheme of the invention: the following steps are included:
Step 1), will polyethylene, sarin resin, polyethylene wax and deionized water be placed in reaction kettle in stirring it is complete to material Dissolution;
Step 2), addition sodium carbonate, catalyst and fireproof agent continue to stir, until material in the pasty state, is then allowed to stand 30min-45min;
Step 3), addition aliphatic polyester, glycerol and polylactic acid are again stirring for obtaining semi-finished product in solid-like to material;
Semi-finished product taking-up is put into heat drying in heater box by step 4), and temperature is controlled in 60-70 degree, duration 120min;
Step 5) will be ground to powdered in the product merging grinder after drying, obtain plastic additive.
As further scheme of the invention: the mixing speed in step 1) controls 25-34rpm, and temperature is controlled in 40- 60 degree.
As further scheme of the invention: the catalyst in the step 2) uses sodium chloride.
As further scheme of the invention: the fire retardant in the step 2) includes following parts by weight of component: silicon is molten Glue 35-40, boric acid 15-20, urea 15-20, sodium carbonate 17-25, phosphatase 11-5, deionized water 17-25.
As further scheme of the invention: the preparation method of the fire retardant is further comprising the steps of:
S1, phosphoric acid, boric acid are added in reaction kettle and stir 15-20min, temperature is maintained at 60-70 degree;
S2, urea is sequentially added and sodium carbonate continues to stir evenly;
S3, deionized water and silica solution is added after mixing evenly, natural cooling obtains fire retardant.
Compared with prior art, the beneficial effects of the present invention are: formulation ratio of the invention is superior, pass through aliphatic poly The addition of ester, glycerol and polylactic acid can play natural degradation effect, and burning disposal is not necessarily to after discarded, has saved manpower and wealth Power, and natural environment will not be damaged, have the effect of environmental protection, increase practicability, is added to polyethylene wax, not only has There are excellent cold resistance and heat resistance, while also there is stronger lubricating action, can be convenient demoulding in plastic processing, so that Frosting more satin, is added to fireproof agent, can play flameproof effect, is effectively increased safety precaution, reduces safety Hidden danger.
Detailed description of the invention
Fig. 1 is a kind of formula figure for plastic additive;
Fig. 2 is a kind of formula manufacture production craft step figure for plastic additive.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Embodiment 1
Please refer to Fig. 1~2, in the embodiment of the present invention, a kind of formula for plastic additive, including following parts by weight group Point: 20-25 parts of polyethylene, 1-2 parts of polyethylene wax, sarin resin 10-15,1-3 parts of catalyst, 5-9 parts of glycerol, fireproof agent 1-4 Part, 10-15 parts of sodium carbonate, aliphatic polyester 10-15, polylactic acid 10-15, deionized water 50-70.
Further, a kind of formula for plastic additive manufactures production technology, comprising the following steps:
Step 1), will polyethylene, sarin resin, polyethylene wax and deionized water be placed in reaction kettle in stirring it is complete to material Dissolution;
Step 2), addition sodium carbonate, catalyst and fireproof agent continue to stir, until material in the pasty state, is then allowed to stand 30min-45min;
Step 3), addition aliphatic polyester, glycerol and polylactic acid are again stirring for obtaining semi-finished product in solid-like to material;
Semi-finished product taking-up is put into heat drying in heater box by step 4), and temperature is controlled in 60-70 degree, duration 120min;
Step 5) will be ground to powdered in the product merging grinder after drying, obtain plastic additive.
Further, the mixing speed in step 1) controls 25-34rpm, and temperature is controlled in 40-60 degree.
Further, the catalyst in step 2) uses sodium chloride.
Further, the fire retardant in step 2) includes following parts by weight of component: silica solution 35-40, boric acid 15-20, urine Plain 15-20, sodium carbonate 17-25, phosphatase 11-5, deionized water 17-25, preparation method are further comprising the steps of:
S1, phosphoric acid, boric acid are added in reaction kettle and stir 15-20min, temperature is maintained at 60-70 degree;
S2, urea is sequentially added and sodium carbonate continues to stir evenly;
S3, deionized water and silica solution is added after mixing evenly, natural cooling obtains fire retardant.
Embodiment 2
Embodiment 1 is repeated according to same steps, different from embodiment 1: 22-24 parts of polyethylene, polyethylene wax 1-2 Part, sarin resin 12-14,2-3 parts of catalyst, 6-8 parts of glycerol, 2-3 parts of fireproof agent, 12-14 parts of sodium carbonate, aliphatic polyester 12-14, polylactic acid 12-14, deionized water 55-65.
Embodiment 3
Embodiment 1 is repeated according to same steps, different from embodiment 1 and embodiment 2: 23 parts of polyethylene, polyethylene 2 parts of wax, sarin resin 13,2 parts of catalyst, 7 parts of glycerol, 2.5 parts of fireproof agent, 13 parts of sodium carbonate, aliphatic polyester 13, polylactic acid 13, deionized water 60.
Test case
Soil buries method test:
The finished product for extracting equivalent part respectively from embodiment 1, embodiment 2 and embodiment 3 is wrapped up with gauze, is placed it in In closed space, soil on heap is placed in different temperature environments, takes out weighing at regular intervals, while using distilled water It after washing, weighs again after drying to constant weight, is averaged for average experiment 3 times and to obtain following data:
Limit oxygen index test:
The finished product for extracting equivalent part respectively from embodiment 1, embodiment 2 and embodiment 3, is sequentially placed into limit oxygen index instrument Middle progress combustibility detection, it is as follows to measure data:
Embodiment Embodiment 1 Embodiment 2 Embodiment 3
Limit oxygen refers to 37% 39% 40%
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.Any reference signs in the claims should not be construed as limiting the involved claims.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (8)

1. a kind of formula for plastic additive, which is characterized in that including following parts by weight of component: 20-25 parts of polyethylene gathers 1-2 parts of ethylene waxes, sarin resin 10-15,1-3 parts of catalyst, 5-9 parts of glycerol, 1-4 parts of fireproof agent, 10-15 parts of sodium carbonate, rouge Fat adoption ester 10-15, polylactic acid 10-15, deionized water 50-70.
2. a kind of formula for plastic additive according to claim 1, which is characterized in that including following parts by weight group Point: 22-24 parts of polyethylene, 1-2 parts of polyethylene wax, sarin resin 12-14,2-3 parts of catalyst, 6-8 parts of glycerol, fireproof agent 2-3 Part, 12-14 parts of sodium carbonate, aliphatic polyester 12-14, polylactic acid 12-14, deionized water 55-65.
3. a kind of formula for plastic additive according to claim 1, which is characterized in that including following parts by weight group Point: 23 parts of polyethylene, 2 parts of polyethylene wax, sarin resin 13,2 parts of catalyst, 7 parts of glycerol, 2.5 parts of fireproof agent, sodium carbonate 13 Part, aliphatic polyester 13, polylactic acid 13, deionized water 60.
4. a kind of formula manufacture production technology for plastic additive described in any one of -3 according to claim 1, It is characterized in that, comprising the following steps:
Step 1), will polyethylene, sarin resin, polyethylene wax and deionized water be placed in reaction kettle in stirring it is completely molten to material Solution;
Step 2), addition sodium carbonate, catalyst and fireproof agent continue to stir, until material in the pasty state, is then allowed to stand 30min- 45min;
Step 3), addition aliphatic polyester, glycerol and polylactic acid are again stirring for obtaining semi-finished product in solid-like to material;
Semi-finished product taking-up is put into heat drying in heater box by step 4), and temperature is controlled in 60-70 degree, duration 120min;
Step 5) will be ground to powdered in the product merging grinder after drying, obtain plastic additive.
5. a kind of formula for plastic additive according to claim 4 manufactures production technology, which is characterized in that described Mixing speed in step 1) controls 25-34rpm, and temperature is controlled in 40-60 degree.
6. a kind of formula for plastic additive according to claim 4 manufactures production technology, which is characterized in that described Catalyst in step 2) uses sodium chloride.
7. a kind of formula for plastic additive according to claim 4 manufactures production technology, which is characterized in that described Fire retardant in step 2) includes following parts by weight of component: silica solution 35-40, boric acid 15-20, urea 15-20, sodium carbonate 17- 25, phosphatase 11-5, deionized water 17-25.
8. a kind of formula for plastic additive according to claim 7 manufactures production technology, which is characterized in that described The preparation method of fire retardant is further comprising the steps of:
S1, phosphoric acid, boric acid are added in reaction kettle and stir 15-20min, temperature is maintained at 60-70 degree;
S2, urea is sequentially added and sodium carbonate continues to stir evenly;
S3, deionized water and silica solution is added after mixing evenly, natural cooling obtains fire retardant.
CN201910221686.XA 2019-03-22 2019-03-22 A kind of formula and manufacture production technology for plastic additive Pending CN109942941A (en)

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Application Number Priority Date Filing Date Title
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060148914A1 (en) * 2005-01-04 2006-07-06 Connor Daniel M Methods and compositions for decolorizing thermoplastics and articles made using such decolorized thermoplastics
CN101161221A (en) * 2006-10-13 2008-04-16 屈德加薄膜产品股份有限公司 Dry top formed film
EP2324094A2 (en) * 2008-08-12 2011-05-25 Board of Supervisors of Lousiana State University Thermoplastic cellulosic fiber blends as lost circulation materials
CN103289171A (en) * 2013-06-24 2013-09-11 苏州新区佳合塑胶有限公司 Preparation method of high-strength easy-degradation master batch for plastic bags
CN106009241A (en) * 2016-07-21 2016-10-12 合肥市智源包装科技有限公司 Environmentally friendly degradable tear-resistant polyethylene film material and preparation method thereof
CN109467865A (en) * 2018-02-05 2019-03-15 江南大学 A kind of degradable green plastic master batch and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060148914A1 (en) * 2005-01-04 2006-07-06 Connor Daniel M Methods and compositions for decolorizing thermoplastics and articles made using such decolorized thermoplastics
CN101161221A (en) * 2006-10-13 2008-04-16 屈德加薄膜产品股份有限公司 Dry top formed film
EP2324094A2 (en) * 2008-08-12 2011-05-25 Board of Supervisors of Lousiana State University Thermoplastic cellulosic fiber blends as lost circulation materials
CN103289171A (en) * 2013-06-24 2013-09-11 苏州新区佳合塑胶有限公司 Preparation method of high-strength easy-degradation master batch for plastic bags
CN106009241A (en) * 2016-07-21 2016-10-12 合肥市智源包装科技有限公司 Environmentally friendly degradable tear-resistant polyethylene film material and preparation method thereof
CN109467865A (en) * 2018-02-05 2019-03-15 江南大学 A kind of degradable green plastic master batch and preparation method thereof

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Application publication date: 20190628

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