CN109942063A - A kind of reactor of Beneficiation Wastewater - Google Patents
A kind of reactor of Beneficiation Wastewater Download PDFInfo
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- CN109942063A CN109942063A CN201910116146.5A CN201910116146A CN109942063A CN 109942063 A CN109942063 A CN 109942063A CN 201910116146 A CN201910116146 A CN 201910116146A CN 109942063 A CN109942063 A CN 109942063A
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- reactor
- carbon dioxide
- dross
- screw rod
- barium
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/38—Treatment of water, waste water, or sewage by centrifugal separation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
Abstract
The invention discloses a kind of reactors of Beneficiation Wastewater.The eddy flow wall attachment effect of this reactor creativeness being utilized in hydrodynamics, when eddying motion occurs for the liquid in container, if applying in the vortex center position reversely rotate power simultaneously, it is allowed to generate reverse vortex, eddy flow wall attachment effect can occur for the barium ions in liquid, gradually converge at the anti-narrow zone being vortexed between external positive vortex in inside, localized ion concentration is caused to increase, at this time, introducing carbon dioxide gas makes it dissolve forms carbanion in solution, barium ions can be in conjunction with the carbanion, generate the barium salt precipitating of indissoluble, and the narrow zone between two strands of vortexs floats, ultimately form barium salt dross, to enable the barium ions in solution to remove.
Description
Technical field
The present invention relates to a kind of reactor of Beneficiation Wastewater, belong to the field of waste water treatment in environmental protection.
Background technique
Mineral resources are the important material bases of human social development and the development of the national economy, and mining industry is that China's history is most long-drawn-out
Long industry, while being the basic industry of the national economic development again, it is related to agricultural, light industry, chemical industry, metallurgy, machinery, builds
Build, the energy, traffic, national defence and people's daily life multiple fields.As it can be seen that mining industry, which plays China's expanding economy, to be replaced
The important function in generation.However, mine needs a large amount of industrial water in recovery process, while giving off a large amount of waste water, this
The indices such as a little heavy metal ions in wastewater concentration, solid suspension concentration and COD, all considerably beyond country
Discharge standard, this is just easy to cause tremendous influence to dressing plant's surrounding enviroment.Moreover, from the purification of domestic and international beneficiation wastewater
From the point of view of disposal status, qualified discharge is handled beneficiation wastewater and is allowed to, not only processing technique difficulty is big, but also processing cost
It is very high.Therefore, how beneficiation wastewater is effectively treated, is China's mining industry important topic urgently to be resolved.
Various organic and Inorganic floatation medicine when main harmful substance is heavy metal ion, ore floatation in beneficiation wastewater
Agent, cyanide, cyanogen chromium complex etc. including severe toxicity.Also contain various undissolved coarse grain and fine particle impurity in waste water.Choosing
Contain the sulfate, chloride or hydroxide of sodium, magnesium, calcium etc. in mine waste water toward contact.Acid in beneficiation wastewater mainly contains
Sulfur mineral is mixed with water through air oxidation and is formed.
In all multi-pollutants of beneficiation wastewater, heavy metal ion pollutant be it is very important, as copper, lead, zinc, chromium,
The harm of mercury and arsenic plasma and its compound, is generally well known.Meanwhile it may be neglected by people there are also a metal ion species
Depending on, that is, barium ions.Although barium ions has harm very serious unlike above-mentioned several high toxicity heavy metal ion
Property, but if improvement is not added and is allowed to be emitted into surface water body environment, barium ions can be followed into nature food chain quickly
Ring, final still to be taken in and be absorbed by human body, less serious case cause nausea,vomiting,diarrhea, abdominal pain, body may occur when serious
Paralysis, facial livid purple, coldness of extremities, muscular tremor, twitch, lingualis and throat paralysis, or even aphasis occurs.
Currently, China is mainly the following processing method for the beneficiation wastewater containing heavy metal ion:
(1) neutralization precipitation method:
Neutralization precipitation method is the method for heavy metal ion comparative maturity in current treatment of acidic wastewater.This method can will be in waste water
Valuable metal ions form of a hydroxide under different pH value conditions is precipitated out, and achievees the purpose that recycling.Neutralizer
Lime stone or lime are mainly used, also there are Some Enterprises using alkaline waste liquor or waste residue (flyash, gangue, carbide slag, lime
Slag etc.) neutralize acid waste water.This method has many advantages, such as that technically simple easy, primary construction investment is lower, operation and maintenance are convenient,
But the disadvantage is that treatment effect is not ideal enough, effluent index is unstable, it is secondary to be easily caused in treatment process using a large amount of neutralizers
Pollution.
(2) sulphide precipitation:
Sulfurization-precipitation method is to convert insoluble or indissoluble sulfide precipitation for the heavy metal ion in waste water using vulcanizing agent, so
The method that surfactant makes sediment float is added afterwards.Sulphide precipitation metal removal rate is high, and the precipitating quantity of slag is less, precipitating
Metal in the dreg grade is high, convenient for the recycling in later period, the heavy metals such as arsenic, mercury, lead of removal more difficult for neutralization precipitation method from
Son, sulphide precipitation can remove.But vulcanizing agent price is more expensive, so that the processing cost of this method is very high, no
It is suitable for large-scale promotion.
(3) absorption method:
The method for removing dirty pollutant in water with solid absorbent, the referred to as absorption method of wastewater treatment.According to adsorbent type
Difference can be divided into material absorption method and biosorption process.Material absorption mainly utilizes the heavy metal in active carbon removal waste water
Ion, and biological adsorption is then to utilize heavy metal ion toxic in microorganism removal waste water.Absorption method because its handle material at
This is low, removal effect is good and is constantly subjected to the favor of people, but simultaneously, and there is also long processing period, facilities to take up an area face for absorption method
The disadvantages of product is big, primary construction high investment.
(4) membrane separation technique:
All separation processes of membrane separation technique are divided using the difference of the mixture each component property in certain environment
From.The principle of UF membrane is: penetrating film as separating medium using selectivity, is subject to certain thrust in two sides, stock blend is selectively
Through film, thereby achieving the purpose of separation and purification.Membrane separation technique has many advantages, such as low consumption, efficient, easy to operate, in heavy metal
Field of waste water treatment gradually draws attention.But since membrane module is expensive, fouling membrane and flux decline in use process, at present
The application study of membrane separation technique is concentrated mainly on experiment mechanism at present.
Currently, the generally existing disadvantages mentioned above of the method for barium ions in existing Beneficiation Wastewater.Therefore, it is necessary to get rid of
Existing processing technique thinking, hews out the new way of processing baric beneficiation wastewater, and then develops a kind of ore dressing of new type
The processing technique of barium ions in waste water.
Summary of the invention
To solve the deficiencies in the prior art, the present invention provides a kind of reactor of Beneficiation Wastewater, reactions
Device left lower is equipped with inlet valve, and right upper portion is equipped with water discharging valve, and 5 positive agitating paddles have been mounted side by side in reactor bottom
Leaf, reactor center are equipped with 1 hollow type carbon dioxide aeration reverse agitating function screw rod, and hollow type carbon dioxide aeration reversely stirs
The hollow space for mixing screw rod is connected to carbon dioxide storage tank by gas-guide tube, and hollow type carbon dioxide is aerated reverse agitating function screw rod shaft
On be uniformly provided with several air guide micropores, so that the gas inside screw rod hollow space is entered in waste water in the form of microvesicle, in
1 driving motor is connected at the top of empty formula carbon dioxide aeration reverse agitating function screw rod, hollow type carbon dioxide aeration reversely stirs
It mixes and surrounds 1 set of unidirectional strainer of pore on the outside of screw rod, reactor head is equipped with 1 set of dross and attracts separator, lower end installation
There are 4 dross suction pipes, the nozzle of dross suction pipe protrudes into reactor liquid level hereinafter, dross, which attracts, is equipped with waste residue on the right side of separator
Arrange mouth.
The beneficiation wastewater containing barium ions of (pH value is 6.0 ~ 7.0 after processing) is by being located at after pH value adjusting processing
The inlet valve of reactor left lower enters inside reactor, at this point, the positive stirrer paddle of 5 for being located at reactor bottom is opened
Beginning rotates in the forward direction, and waste water is made to generate positive vortex in inside reactor, meanwhile, the hollow type titanium dioxide positioned at reactor center
Carbon aeration reverse agitating function screw rod starts to reversely rotate under the driving of driving motor, to apply in the center rotated in the forward direction
Add a reverse rotation power, is allowed to generate reverse vortex, eddy flow wall attachment effect can occur for the barium ions in waste water, gradually converge
Narrow zone between internal anti-vortex and outside are just being vortexed, causes localized ion concentration to increase, at this point, carbon dioxide storage tank
Hollow space transport of carbon dioxide gas into hollow type carbon dioxide aeration reverse agitating function screw rod, carbon dioxide gas pass through
Hollow type carbon dioxide is aerated several air guide micropores on reverse agitating function screw rod shaft, and waste water is dissolved in the form of gas microbubbles
In and form carbanion, barium ions in conjunction with the carbanion, can generate the barium salt precipitating of indissoluble, since pore is unidirectional
The presence of strainer, so that barium salt precipitating can not be diffused into the region except strainer, barium salt precipitating can only be along between two strands of vortexs
Narrow zone float, barium salt dross is ultimately formed, and be drawn into dross through dross suction pipe and attract separator, by separation
Obtained the Barium Residue attracts waste residue row's mouth on the right side of separator to be discharged by being located at dross, is recycled after recycling, meanwhile,
Waste water after purified treatment, reactor is discharged in the water discharging valve by being located at reactor right upper portion, and enters next place
Science and engineering sequence;Meanwhile the barium salt dross can be after attracting separation, recycling and reusing.
Wherein, the dischargeable capacity of reactor is 245m3, the operating voltage of positive stirrer paddle is 380V, revolving speed 270
Turn/min.
Wherein, the operating voltage of the driving motor of reactor be 380V, rated power 4.2kW, revolving speed be 360 turns/
min。
Wherein, the unidirectional strainer of the pore of reactor uses 304 stainless steel materials, and tensile strength 560MPa, aperture is
0.8mm。
By the waste water after this reactor for treatment, the removal efficiency of barium ions is up to 99.3%.
The present invention has the advantages that
(1) this reactor gets rid of the processing technique thinking of barium ions in existing beneficiation wastewater, and creative is utilized fluid
Eddy flow wall attachment effect in mechanics makes baric waste water that eddying motion occur in a reservoir, and applies instead in the vortex center position
It to rotary power, is allowed to generate reverse vortex, eddy flow wall attachment effect can occur for the barium ions in waste water, gradually converge at internal anti-
The narrow zone being vortexed between external positive vortex, causes localized ion concentration to increase, at this point, introducing carbon dioxide gas makes it
It being dissolved in solution and forms carbanion, barium ions in conjunction with the carbanion, can generate the barium salt precipitating of indissoluble, and
Narrow zone between two strands of vortexs floats, and ultimately forms barium salt dross, to achieve the purpose that remove barium ions in waste water.
(2) generated barium salt dross can be by attracting lock out operation during this reactor purified treatment baric waste water
It extracts, finally for recycling, therefore not will cause secondary pollution and certain economic benefit can be created.
(3) this reactor uses pure physical effect as purified treatment means, does not use any chemical agent, from
And eliminate the risk for introducing and endangering bigger chemical pollutant.
(4) this reactor technology route is advanced, can reach ideal clean-up effect, and operation expense is lower, favorably
It is promoted and applied in a wide range of.
Detailed description of the invention
Fig. 1 is the schematic diagram of the reactor of Beneficiation Wastewater.
In figure: 1- sump, 2- coarse rack, 3- primary sedimentation basin, 4-pH value conditioning tank, 5- carbon dioxide vortex convection current are floating
Slag separate reactor, the aeration tank 6-, 7- biological oxidation filter tank, 8- secondary sedimentation tank, 9- water purifying tank
Fig. 2 is the schematic diagram of the reactor of Beneficiation Wastewater.
51- inlet valve, 52- forward direction stirrer paddle, 53- hollow type carbon dioxide aeration hollow type carbon dioxide aeration reversely stir
Mix screw rod, the unidirectional strainer of 54- pore, 55- dross suction pipe, 56- driving motor, 57- carbon dioxide storage tank, the attraction point of 58- dross
Mouth, 510- water discharging valve are arranged from device, 59- waste residue.
Specific embodiment
As shown in Figure 1, the reactor of Beneficiation Wastewater, dischargeable capacity 245m3, enclosure material is hard glass steel,
Reactor left lower is equipped with inlet valve 51, and right upper portion is equipped with water discharging valve 510, and reactor bottom has been mounted side by side 5
Positive stirrer paddle 52, reactor center are equipped with 1 hollow type carbon dioxide aeration reverse agitating function screw rod 53, hollow type dioxy
The hollow space for changing carbon aeration reverse agitating function screw rod 53 is connected to carbon dioxide storage tank 57 by gas-guide tube, and hollow type carbon dioxide exposes
Several air guide micropores are uniformly provided on 53 shaft of gas reverse agitating function screw rod, enable the gas inside screw rod hollow space with micro-
Bubble form enters in waste water, also, the top of hollow type carbon dioxide aeration reverse agitating function screw rod 53 is connected to 1 driving motor
56, hollow type carbon dioxide, which is aerated on the outside of reverse agitating function screw rod 53, surrounds the unidirectional strainer 54 of 1 set of pore, and reactor head is also installed
There is 1 set of dross to attract separator 58, lower end is equipped with 4 dross suction pipes 55, and the nozzle of dross suction pipe 55 protrudes into reaction
Device liquid level is equipped with waste residue row's mouth 59 hereinafter, dross attracts on the right side of separator 58;(the pH value after processing after pH value adjusting processing
Be 6.0 ~ 7.0) the beneficiation wastewater containing barium ions by be located at reactor left lower inlet valve 51 enter reactor
Inside makes waste water in inside reactor at this point, 5 positive stirrer paddles 52 for being located at reactor bottom start to rotate in the forward direction
Positive vortex is generated, meanwhile, the hollow type carbon dioxide aeration beginning of reverse agitating function screw rod 53 positioned at reactor center is driving
It is reversely rotated under the driving of motor 56, to apply a reverse rotation power in the center rotated in the forward direction, is allowed to produce
Eddy flow wall attachment effect can occur for raw reverse vortex, the barium ions in waste water, gradually converge at internal anti-be vortexed and positive be vortexed with external
Between narrow zone, cause localized ion concentration to increase, at this point, carbon dioxide storage tank 57 is anti-to hollow type carbon dioxide aeration
Hollow space transport of carbon dioxide gas into agitating screw 53, carbon dioxide gas are anti-by hollow type carbon dioxide aeration
Several air guide micropores on 53 shaft of agitating screw, be dissolved in the form of gas microbubbles in waste water and formed carbonate from
Son, barium ions in conjunction with the carbanion, can generate the barium salt precipitating of indissoluble, due to the presence of the unidirectional strainer 54 of pore, make
The region that barium salt precipitating can not be diffused into except strainer is obtained, barium salt precipitating can only be along on the narrow zone between two strands of vortexs
It is floating, barium salt dross is ultimately formed, and inhale 55 through dross suction pipe and introduce and attract separator 58 into dross, contained by isolated
Barium waste residue attracts waste residue row's mouth 59 on 58 right side of separator to be discharged by being located at dross, is recycled after recycling, meanwhile, pass through
Waste water after purified treatment, reactor is discharged in the water discharging valve 510 by being located at reactor right upper portion, and enters next processing
Process;Meanwhile the barium salt dross can be after attracting separation, recycling and reusing.Wherein, the separation of carbon dioxide vortex convection current dross is anti-
Device 5 is answered, the operating voltage of positive stirrer paddle 52 is 380V, and revolving speed is 270 turns/min;Wherein, the driving electricity of reactor
The operating voltage of machine 56 is 380V, and rated power 4.2kW, revolving speed is 360 turns/min;The unidirectional use of strainer 54 304 of pore is not
Rust steel material, tensile strength 560MPa, aperture 0.8mm.
By this system treated waste water, the removal efficiency of barium ions is up to 99.3%.
Claims (2)
1. a kind of reactor of Beneficiation Wastewater, which is characterized in that reactor left lower is equipped with inlet valve, right upper portion
Equipped with water discharging valve, 5 positive stirrer paddles have been mounted side by side in reactor bottom, and reactor center is equipped with 1 hollow type two
Carbonoxide is aerated reverse agitating function screw rod, and the hollow space of hollow type carbon dioxide aeration reverse agitating function screw rod is connected to by gas-guide tube
Carbon dioxide storage tank, hollow type carbon dioxide are aerated on reverse agitating function screw rod shaft and are uniformly provided with several air guide micropores, make spiral shell
Gas inside bar hollow space can be entered in waste water in the form of microvesicle, and hollow type carbon dioxide is aerated reverse agitating function screw rod
Top is connected to 1 driving motor, and hollow type carbon dioxide, which is aerated on the outside of reverse agitating function screw rod, surrounds 1 set of unidirectional strainer of pore,
Reactor head is equipped with 1 set of dross and attracts separator, and lower end is equipped with 4 dross suction pipes, and the nozzle of dross suction pipe is equal
Reactor liquid level is protruded into hereinafter, dross, which attracts, is equipped with waste residue row's mouth on the right side of separator, the operating voltage of positive stirrer paddle is
380V, revolving speed are 270 turns/min, and the operating voltage of driving motor is 380V, rated power 4.2kW, revolving speed is 360 turns/
Min, the aperture of the unidirectional strainer of pore are 0.8mm.
2. reactor according to claim 1, which is characterized in that pH value is about 6.0 ~ 7.0 after pH value adjusting processing
The beneficiation wastewater containing barium ions by be located at reactor left lower inlet valve enter inside reactor, at this point, position
Start to rotate in the forward direction in 5 positive stirrer paddles of reactor bottom, so that waste water is generated positive vortex in inside reactor, together
When hollow type carbon dioxide aeration reverse agitating function screw rod positioned at reactor center start to do under the driving of driving motor it is reversed
Rotation is allowed to generate reverse vortex, the barium in waste water to apply a reverse rotation power in the center rotated in the forward direction
Eddy flow wall attachment effect can occur for ion, gradually converge at the anti-narrow zone being vortexed between external positive vortex in inside, cause office
Portion's ion concentration increases, and hollow space of the carbon dioxide storage tank into hollow type carbon dioxide aeration reverse agitating function screw rod is defeated at this time
Carbon dioxide gas is sent, carbon dioxide gas is aerated several air guides on reverse agitating function screw rod shaft by hollow type carbon dioxide
Micropore, is dissolved in waste water in the form of gas microbubbles and is formed carbanion, barium ions can in conjunction with the carbanion,
The barium salt precipitating for generating indissoluble, due to the presence of the unidirectional strainer of pore, so that barium salt precipitating can not be diffused into the area except strainer
Domain, barium salt precipitating can only float along the narrow zone between two strands of vortexs, ultimately form barium salt dross, and inhale through dross suction pipe
It introduces and attracts separator into dross, by isolated the Barium Residue by being located at the waste residue on the right side of dross attraction separator
Mouth discharge is arranged, is recycled after recycling, the waste water after purified treatment, by the drain valve for being located at reactor right upper portion
Door discharge reactor, and enter next treatment process;The barium salt dross is after attracting separation, recycling and reusing.
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CN201910116146.5A CN109942063A (en) | 2016-08-16 | 2016-08-16 | A kind of reactor of Beneficiation Wastewater |
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CN201910116146.5A CN109942063A (en) | 2016-08-16 | 2016-08-16 | A kind of reactor of Beneficiation Wastewater |
CN201610671401.9A CN106277246B (en) | 2016-08-16 | 2016-08-16 | A kind of reactor of Beneficiation Wastewater |
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