CN102765830A - Reaction tank and method for treating acidic mine wastewater - Google Patents
Reaction tank and method for treating acidic mine wastewater Download PDFInfo
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- CN102765830A CN102765830A CN2012102404195A CN201210240419A CN102765830A CN 102765830 A CN102765830 A CN 102765830A CN 2012102404195 A CN2012102404195 A CN 2012102404195A CN 201210240419 A CN201210240419 A CN 201210240419A CN 102765830 A CN102765830 A CN 102765830A
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- acidic mine
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- 238000000034 method Methods 0.000 title claims abstract description 57
- 239000002351 wastewater Substances 0.000 title claims abstract description 57
- 230000002378 acidificating effect Effects 0.000 title claims abstract description 27
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 20
- 230000008569 process Effects 0.000 claims abstract description 32
- 239000002253 acid Substances 0.000 claims abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 19
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 16
- 238000001556 precipitation Methods 0.000 claims abstract description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 239000013618 particulate matter Substances 0.000 claims description 15
- 230000008021 deposition Effects 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 6
- 238000004062 sedimentation Methods 0.000 claims description 6
- 230000008676 import Effects 0.000 claims description 4
- 239000002699 waste material Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000003786 synthesis reaction Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 25
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 8
- 150000002500 ions Chemical class 0.000 abstract description 6
- 239000002245 particle Substances 0.000 abstract description 6
- 230000003472 neutralizing effect Effects 0.000 abstract description 5
- 238000004065 wastewater treatment Methods 0.000 abstract description 4
- 238000000926 separation method Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000010979 pH adjustment Methods 0.000 abstract 2
- 238000005516 engineering process Methods 0.000 description 10
- 239000004579 marble Substances 0.000 description 7
- 238000006386 neutralization reaction Methods 0.000 description 7
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000010865 sewage Substances 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 239000008239 natural water Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
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- 239000012895 dilution Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
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- 244000005700 microbiome Species 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000000247 postprecipitation Methods 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
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- 239000000047 product Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002688 soil aggregate Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000010878 waste rock Substances 0.000 description 1
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- Removal Of Specific Substances (AREA)
Abstract
本发明公开了一种处理酸性矿山废水的反应池及方法，包括池体，池体中土建构筑物的表面上镶嵌了碱性材料层，将酸性矿山废水的颗粒物沉淀过程和pH调节过程综合于一个反应池内，利用镶嵌在土建构筑物表面上的碱性材料层构成土建构筑物的一部分，同时进行颗粒物沉淀和pH调节，完成酸性矿山废水的处理。本发明的有益效果是：中和了酸性矿山废水，较好的提升了酸性废水的pH值，加速了重金属离子颗粒物的沉淀，降低了废水处理工艺的工作量，同时也避免了碳酸钙颗粒与水的浑浊液分离这一复杂程序，简化了工艺的操作难度，具有成本费用低，可操作性好的特点。
The invention discloses a reaction pool and a method for treating acid mine wastewater, which comprises a pool body in which an alkaline material layer is inlaid on the surface of a civil structure, and integrates the particle precipitation process and pH adjustment process of acid mine wastewater into one In the reaction pool, the alkaline material layer embedded on the surface of the civil structure is used to form a part of the civil structure, and the particle precipitation and pH adjustment are carried out at the same time to complete the treatment of acid mine wastewater. The beneficial effects of the present invention are: neutralizing the acidic mine wastewater, better improving the pH value of the acidic wastewater, accelerating the precipitation of heavy metal ion particles, reducing the workload of the wastewater treatment process, and avoiding the separation of calcium carbonate particles and The complicated procedure of water turbid liquid separation simplifies the operation difficulty of the process, and has the characteristics of low cost and good operability.
Description
Technical field
The present invention relates to a kind of reaction tank and method of same for treating acidic mine wastewater, belong to technical field of sewage.
Background technology
A large amount of mineral metal products and colliery resource are contained the southwest in China, and most of metal mine and colliery all exist with the form of metallic sulfide.The sulfide with in obsolete metal mine or the colliery of existing exploitation is exposed in the air; Under oxygen and action of microorganisms; After
process, form sulphate cpd and be dissolved in the water; So; Not only increase the concentration of heavy metal ion in the water, and improved the acidity (promptly having reduced the pH value of water body) of water body.
Acidic mine waste water pH value is low, acidity is big, and contains plurality of heavy metal, generally directly recycle; Usually enter water bodys such as near river, mine, lake; The pH value of water body is changed, suppress or stoped bacterium and microbial growth, hinder the self-cleaning of water body.Mineral substance in sour water and the water body interacts and generates some salt; Growth to limnobios and plant produces detrimentally affect; Cause water body severe contamination around the mining area, cause that most hydrobionts such as fish, algae, planktonic organism are dead, and destroy soil aggregate; Make the hardening soil, farm crop are withered and yellow; Under anoxic condition, a large amount of in the acidic mine waste water
Receive the effect of sulfate reduction mushroom, produce H
2S gas, H
2S gas has serious toxic action to organism; Acid waste water produces the effect of intensive corrosion failure to water pump accessory, tubing, tunnel equipment, causes ME frequent.If natural water body receives acid pollution for a long time; Can make water quality acidifying gradually, thereby mining industry production and ecotope have been caused serious negative impact, and in case get into and will constantly accumulate behind the environment and be difficult to remove; Cause the chronic pollution of environment; Also can polluted underground water, take place in case pollute, be difficult to administer.So the processing to acid waste water seems particularly important.
The pollution of acidic mine waste water is a worldwide problem, mainly is washup, the mine tailing wastewater that discharge in drench with rain sewage and the dressing-works of the exploitation of colliery and the metal mine pit water, the waste rock pile that are discharged.The domestic and international at present improvement method about acid wastewater in mine mainly contains physics method (absorption method), chemical method (flocculence, the precipitator method, chelate method), membrane processing method and artificial swamp method etc.And the neutralization precipitation method is the same for treating acidic mine wastewater mature methods.
The neutralization precipitation method is to adopt Wingdale or lime to carry out neutralizing treatment as neutralizing agent. utilizes the acid-base neutralisation reaction to generate the precipitation of hydroxide that is insoluble in water, purifies waste water, improve the pH value of waste water.The feeding mode of neutralization precipitation method has 3 kinds of technical process usually:
1, directly adds lime method
Lime is mixed with milk of lime drops into reactive channel and flow into reaction tank, again in the settling tank post precipitation is removed and resultant;
2, in the Wingdale and drum process
Wingdale is placed in the cylinder,, neutralization reaction is continued by the rotation expansion sour water of cylinder and the contact surface of Wingdale;
3, flow lifting type becomes filtering velocity expansion neutralisation
With fine particle Wingdale or the rhombspar neutralizing tower of packing into, neutralization reaction takes place from top to bottom through filtrate in current;
Except that above 3 kinds of process for treating acidic sewage flow processs; Other technology mainly is in equalizing tank, to carry out for the processing of pH; The method of regulating can also be through adding other alkaline reagentss (like soda-lime, slaked lime, flying dust, lime carbonate, blast furnace slag, rhombspar, yellow soda ash, caustic alkali etc.), to reach the effect that improves acidic solution pH.And in most process for treating acidic sewage; For the main mostly treatment process that adopts preliminary sedimentation tank, second pond and filtering basin etc. to unite use of the processing of PM for particulate matter, in settling tank often through increase baffle plate with residence time of increasing waste water add flocculation agent or sedimentary method that coagulating agent quickens PM for particulate matter to remove PM for particulate matter.
Existing acid wastewater in mine treatment process all each has certain shortcoming at present, mainly comprises:
(1) be prone to form larger particles in the reaction tank and be deposited at the bottom of the pond, reduce the utilization ratio of lime, the body refuse amount is big, complex management.
(2) because of a large amount of CaSO
4Produce deposition at inner wall of rotary drum water outlet place, cause cylinder internal diameter effective dimensions to reduce, stop up water outlet,, reduce plant factor, and equipment is huge so need often to clean, complex structure, investment is big, and noise is big during running.
(3) contain a large amount of suspended substances in the acid mine water, cause the obstruction in flow lifting type expansion filter tank easily. so particle diameter of filter medium is strict, simultaneously; Contain acid concentration for waste water restriction is arranged; It is lower to handle back pH value, needs to replenish to handle and could discharge, and treatment facility can not overload operation.
Because in the process of PM for particulate matter deposition and pH regulator, need to add various industrial reagent with settling velocity that improves PM for particulate matter and the pH value that improves waste water, this makes the cost of entire treatment technology increase.And owing to need to add other particulate matter, this has also increased workload and intractability for the subsequent processing steps of technology such as solid-liquid separation etc.The adjusting of pH is simultaneously carried out in different ponds respectively with the deposition of PM for particulate matter, and this makes the floor space increase of treatment process, and then has increased the processing cost of technology and increased the workload of technology.
Summary of the invention
The object of the present invention is to provide a kind of reaction tank and method of same for treating acidic mine wastewater, the pH value of ability adjustment of acidity waste water is removed heavy metal ion.
The objective of the invention is to realize: a kind of reaction tank of same for treating acidic mine wastewater through following technical scheme; Comprise the pond body; Inlayed the basic material layer in the body of pond on the surface of civil engineering structures, the civil engineering structures comprise the pond body around pool wall, pond at the bottom of and the baffle plate that is provided with of Chi Tizhong.
Described basic material layer is a calcium carbonate layer.
It is preliminary sedimentation tank, second pond, filtering basin or waste liquid pool in the acid waste water treating processes.
Be provided with import on its end pool wall, be provided with outlet (6) on the other end pool wall.
A kind of method of same for treating acidic mine wastewater; With the PM for particulate matter precipitation process of acidic mine waste water and pH regulator process synthesis in a reaction tank; Utilization is embedded in the part that the lip-deep basic material layer of civil engineering structures constitutes the civil engineering structures; Carry out PM for particulate matter deposition and pH regulator simultaneously, accomplish Treating Acid Mine Wastewater.
The beneficial effect of the inventive method is: the acidic mine waste water that neutralized, promoted the pH value of acid waste water preferably, and quickened the deposition of heavy metal ion PM for particulate matter; Reduced the workload of waste water treatment process; Simultaneously also avoided calcium carbonate granule to separate this complicated process with the turbid solution of water, simplified the operation easier of technology, it is low to have cost; The characteristics that operability is good are specially adapted to the processing small-sized or acid waste water that abandoned mine discharges.
Description of drawings
Fig. 1 is a structure diagram of the present invention.
Wherein, 1-pond body, 2-basic material layer, the 3-pool wall, the 4-baffle plate, the 5-import, the 6-outlet is at the bottom of the 7-pond.
Embodiment
Further describe technical scheme of the present invention below in conjunction with accompanying drawing, but require the scope of protection to be not limited to said.
Like Fig. 1, a kind of reaction tank of same for treating acidic mine wastewater comprises pond body 1, has inlayed basic material layer 2 in the pond body 1 on the surface of civil engineering structures, the civil engineering structures comprise pond body 1 around pool wall 3, pond at the bottom of 7 and pond body 1 in the baffle plate 4 that is provided with.
Described basic material layer 2 is a calcium carbonate layer.
It is preliminary sedimentation tank, second pond, filtering basin or waste liquid pool in the acid waste water treating processes.
Be provided with import 5 on its end pool wall 3, be provided with outlet 6 on the other end pool wall 3.
A kind of method of same for treating acidic mine wastewater; With the PM for particulate matter precipitation process of acidic mine waste water and pH regulator process synthesis in a reaction tank; Utilization is embedded in the part that the lip-deep basic material layer 2 of civil engineering structures constitutes the civil engineering structures; Carry out PM for particulate matter deposition and pH regulator simultaneously, accomplish Treating Acid Mine Wastewater.
The present invention inlays one deck basic material on inwall, bottom and the settling tank Internal baffle surface of the civil engineering structures such as preliminary sedimentation tank, second pond, filtering basin and waste liquid pool in the acid waste water treating processes, comprises ls materials such as marble, Wingdale, calcite, rhombspar.Utilize the weakly alkaline of basic material, can reduce on the one hand the acidity of waste water, improve the pH value of waste water, for the adjusting of acid waste water pH provides guarantee.Experimental study proves that in long duration of contact, waste water ph after treatment remains within the 7-8.So, both having prevented that waste water ph is too high or too low does not exist the pollution problems of the potential of hydrogen of water outlet to natural water body to the corrosion on Equipment effect yet.In addition, can the part waste water that pass through after the precipitation process be carried out internal reflux to preliminary sedimentation tank, get into the mine wastewater of settling tank, improve water inlet pH value with dilution.The raising of pH simultaneously can reduce the solubleness (solubleness of most of heavy metal raises with the reduction of pH) of heavy metal ion to a certain extent, is convenient to the removal of heavy metal ion; On the other hand, acidic mine waste water flows into from the import 5 of reaction tank, flows out from exporting 6; Arrow is depicted as the flow direction of current among the figure; The entire treatment process is incorporated into the precipitation process of PM for particulate matter and two steps of adjusting of pH in the reaction tank with current spontaneous generation, thus the expense of having saved technology floor space and required medicament item; Reduce the cost of waste water treatment process to a certain extent, improved the possibility that this technology is promoted.Moreover, after civil engineering structures inwall and lower surface are inlayed the last layer marble material, can reduce the contact area of acid waste water and civil engineering structures, reduce its extent of corrosion to the civil engineering structures, play the purpose of protection civil engineering structures.The present invention is with the part as civil engineering structures such as settling tanks such as the basic material of marble etc.; Rather than regulate waste water ph through adding calcium carbonate granule merely; So, both avoid the continuous adding of calcium carbonate granule, reduced the workload of waste water treatment process; Simultaneously also avoided calcium carbonate granule to separate this complicated process, simplified the operation easier of technology with the turbid solution of water.After for many years, when the basic material neutralising capacity of marble etc. descends, can inlay one deck marble material on the surface of structures inwall and bottom again.
In order to guarantee the pH value of water outlet; Under a stable condition, also can in settling tank, throw in block Wingdale or the marble and acidic mine waste water; But this method is after adding block Wingdale or marble to settling tank; May have influence on the cleaning of mud in the settling tank, therefore need do some improvement to the settling tank structure, this invention also should be included within the protection domain.
Claims (5)
1. the reaction tank of a same for treating acidic mine wastewater; Comprise pond body (1); It is characterized in that: inlayed basic material layer (2) on the surface of civil engineering structures in the pond body (1), the civil engineering structures comprise pond body (1) around pool wall (3), pond at the bottom of the baffle plate (4) of setting in (7) and the pond body (1).
2. the reaction tank of same for treating acidic mine wastewater according to claim 1 is characterized in that: described basic material layer (2) is calcium carbonate layer.
3. the reaction tank of same for treating acidic mine wastewater according to claim 1 is characterized in that: it is preliminary sedimentation tank, second pond, filtering basin or waste liquid pool in the acid waste water treating processes.
4. the reaction tank of same for treating acidic mine wastewater according to claim 1 is characterized in that: be provided with import (5) on its end pool wall (3), be provided with outlet (6) on the other end pool wall (3).
5. the method for a same for treating acidic mine wastewater; It is characterized in that: with the PM for particulate matter precipitation process of acidic mine waste water and pH regulator process synthesis in a reaction tank; Utilization is embedded in the part that the lip-deep basic material layers of civil engineering structures (2) constitute the civil engineering structures; Carry out PM for particulate matter deposition and pH regulator simultaneously, accomplish Treating Acid Mine Wastewater.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102404195A CN102765830A (en) | 2012-07-11 | 2012-07-11 | Reaction tank and method for treating acidic mine wastewater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102404195A CN102765830A (en) | 2012-07-11 | 2012-07-11 | Reaction tank and method for treating acidic mine wastewater |
Publications (1)
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| CN102765830A true CN102765830A (en) | 2012-11-07 |
Family
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| CN2012102404195A Pending CN102765830A (en) | 2012-07-11 | 2012-07-11 | Reaction tank and method for treating acidic mine wastewater |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103449671A (en) * | 2013-09-05 | 2013-12-18 | 安徽工程大学 | Treatment system for acid coal mine drainage and treatment process thereof |
| CN103466778A (en) * | 2013-10-09 | 2013-12-25 | 桂林理工大学 | Method for making full use of acid neutralization potential of carbonate rock to process acid mine drainage |
| CN106277246A (en) * | 2016-08-16 | 2017-01-04 | 涂瑞强 | A kind of reactor of Beneficiation Wastewater |
| CN106395967A (en) * | 2016-11-04 | 2017-02-15 | 中钢集团鞍山热能研究院有限公司 | Heavy metal pollution control system and method of soil around ore mountain body |
| CN110040881A (en) * | 2019-05-29 | 2019-07-23 | 脚爬客(武汉)信息技术有限公司 | A kind of disintegrating system in waste pipe |
| CN112978985A (en) * | 2021-02-09 | 2021-06-18 | 中国电建集团西北勘测设计研究院有限公司 | System and method for treating acidic wastewater in abandoned mine area |
| CN115650437A (en) * | 2022-09-29 | 2023-01-31 | 金川集团股份有限公司 | A method for source treatment of acidic wastewater from non-ferrous metal mines |
| CN115974317A (en) * | 2022-12-29 | 2023-04-18 | 湖南中森环境科技有限公司 | Multi-unit passive ecological treatment integrated device for acid mine wastewater |
| CN116161801A (en) * | 2023-03-30 | 2023-05-26 | 中国科学院地球化学研究所 | Treatment device, treatment system and treatment method for acidic wastewater of coal mine |
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| CN1618742A (en) * | 2004-11-24 | 2005-05-25 | 李泽唐 | Method of treating nonferrons metal mine acidic waste water source |
| KR20080110255A (en) * | 2007-06-15 | 2008-12-18 | 세명대학교 산학협력단 | Acid Mine Drainage Neutralization System by Permeable Concrete Block with Alkaline Recharge Function |
| CN101693567A (en) * | 2009-10-09 | 2010-04-14 | 贵州大学 | Method for treating acid mine waste water by utilizing carbonatite |
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Patent Citations (3)
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| CN1618742A (en) * | 2004-11-24 | 2005-05-25 | 李泽唐 | Method of treating nonferrons metal mine acidic waste water source |
| KR20080110255A (en) * | 2007-06-15 | 2008-12-18 | 세명대학교 산학협력단 | Acid Mine Drainage Neutralization System by Permeable Concrete Block with Alkaline Recharge Function |
| CN101693567A (en) * | 2009-10-09 | 2010-04-14 | 贵州大学 | Method for treating acid mine waste water by utilizing carbonatite |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103449671A (en) * | 2013-09-05 | 2013-12-18 | 安徽工程大学 | Treatment system for acid coal mine drainage and treatment process thereof |
| CN103466778A (en) * | 2013-10-09 | 2013-12-25 | 桂林理工大学 | Method for making full use of acid neutralization potential of carbonate rock to process acid mine drainage |
| CN106277246A (en) * | 2016-08-16 | 2017-01-04 | 涂瑞强 | A kind of reactor of Beneficiation Wastewater |
| CN106395967A (en) * | 2016-11-04 | 2017-02-15 | 中钢集团鞍山热能研究院有限公司 | Heavy metal pollution control system and method of soil around ore mountain body |
| CN106395967B (en) * | 2016-11-04 | 2019-07-23 | 中钢集团鞍山热能研究院有限公司 | A kind of ore mountain massif Soil Surrounding heavy metal pollution control system and method |
| CN110040881A (en) * | 2019-05-29 | 2019-07-23 | 脚爬客(武汉)信息技术有限公司 | A kind of disintegrating system in waste pipe |
| CN112978985A (en) * | 2021-02-09 | 2021-06-18 | 中国电建集团西北勘测设计研究院有限公司 | System and method for treating acidic wastewater in abandoned mine area |
| CN115650437A (en) * | 2022-09-29 | 2023-01-31 | 金川集团股份有限公司 | A method for source treatment of acidic wastewater from non-ferrous metal mines |
| CN115974317A (en) * | 2022-12-29 | 2023-04-18 | 湖南中森环境科技有限公司 | Multi-unit passive ecological treatment integrated device for acid mine wastewater |
| CN116161801A (en) * | 2023-03-30 | 2023-05-26 | 中国科学院地球化学研究所 | Treatment device, treatment system and treatment method for acidic wastewater of coal mine |
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Application publication date: 20121107 |