CN109929360A - A kind of aqueous UV high rigidity white finish paint - Google Patents
A kind of aqueous UV high rigidity white finish paint Download PDFInfo
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- CN109929360A CN109929360A CN201910169046.9A CN201910169046A CN109929360A CN 109929360 A CN109929360 A CN 109929360A CN 201910169046 A CN201910169046 A CN 201910169046A CN 109929360 A CN109929360 A CN 109929360A
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- agent
- aqueous
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- titanium dioxide
- finish paint
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- 239000003973 paint Substances 0.000 title claims abstract description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 29
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000839 emulsion Substances 0.000 claims abstract description 16
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 10
- 239000002002 slurry Substances 0.000 claims abstract description 10
- 239000000080 wetting agent Substances 0.000 claims abstract description 10
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- 239000006185 dispersion Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 8
- 239000000417 fungicide Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000008367 deionised water Substances 0.000 claims abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000001993 wax Substances 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- -1 poly- Siloxanes Chemical class 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000000118 dimethyl group Polymers [H]C([H])([H])* 0.000 claims description 3
- 229920001903 high density polyethylene Polymers 0.000 claims description 3
- 239000004700 high-density polyethylene Substances 0.000 claims description 3
- 239000006210 lotion Substances 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 229920003009 polyurethane dispersion Polymers 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 3
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229920001400 block copolymer Polymers 0.000 claims description 2
- 238000010422 painting Methods 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000011435 rock Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 2
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 235000010215 titanium dioxide Nutrition 0.000 description 10
- 238000010276 construction Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000009955 starching Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 240000002989 Euphorbia neriifolia Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
A kind of aqueous UV high rigidity white finish paint, raw material components are as follows: the aqueous dedicated acrylic emulsion 45~60% of UV, water-borne dispersions 0~20%, defoaming agent 0.3~0.6%, wetting agent 0.2~0.5%, dispersing agent 0.3~0.5%, ammonia neutralizer 0.1~0.2%, levelling agent 0.2~0.5%, mute powder 0~2%, photoinitiator 1~2%, coalescing agent 2~5%, deionized water 2~10%, fungicide 0.05~0.1% in tank, titanium dioxide slurry 25~35%, wax emulsion 1~5%, thickener 0.1~2%；The aqueous UV white paint filming performance prepared using above-mentioned technology is good, and solidification effect is good, and hardness is high, and scratch resistance effect is good, and feel is smooth.
Description
Technical field
The present invention relates to IPC classification C09D paint composition production and production application, especially a kind of aqueous UV high is hard
Spend white finish paint.
Background technique
UV coating refers to the coating using UV radiation curing.The coating material solidified ink that can be applied to of UV prints and is exposed to UV spoke
According to.Its solid content may be up to 100%, therefore free from environmental pollution without volatile component.High solids content can also be such that it is applied to very
Thin film.UV is coating material solidified to apply also for coated glass and plastics, timber, aluminum beverage bottle etc..
Meet the performance of the water paint of environmental consciousness also in the case where market and consumer demand push, use ratio is also more next
It is bigger, the tables and chairs bed necessaries from the wardrobe of storing to rest, to the dining table and chair of dining, to the cabinet in kitchen, the bathroom in bathroom
Cabinet all begins with the one seat of water paint.
Chinese patent application 201810925000.0 is related to a kind of optical curing of UV coating and preparation method thereof, including following heavy
Measure the raw material of part: 30-35 parts of solvent type acrylic resin, 5-8 parts of trifunctional aliphatic urethane acrylate, six functional groups
10-15 parts of aliphatic urethane acrylate, 5-10 parts of PMMA frosting powder, Ployethylene Wax starch 25-30 parts, 2-3 parts of flatting silica,
0.5-1 parts of TPO, 1-2 parts of organosilicon levelling agent, 8-12 parts of butyl ester, 5-8 parts of ethyl ester, plain boiled water 3-5 parts anti-, the optical curing of UV coating
Coating is not when having better smooth feel compared with bi-component UV frosted coating currently on the market, and being sprayed on the surface of product
Will appear and after-tack phenomenon, RCA wear-resisting test can by 500 times not show-through, QUV burn-in test can be non-discolouring by 240 hours,
Suncream test can not be changed by 72 hours paint films.
Also had to while water paint is promoted in face of following two problem: the drying of water paint is slow and hardness is low.This
Two factors seriously constrain the construction efficiency and use of water paint.Therefore being bound to for the improvement of this two o'clock and breakthrough being capable of pole
The earth improves the construction efficiency and application range of water paint.
Summary of the invention
The object of the present invention is to provide a kind of aqueous UV high rigidity white finish paint, fast drying, hardness is high, adhesive force, storage characteristics
Can be good, feel and adhesion strength are superior.
The purpose of the present invention will be realized by following technical measures: raw material components are as follows:
Preparation process: 45~60% parts of the dedicated acrylic emulsion of aqueous UV and 0~20% water-borne dispersions are added to
In painting cylinder, defoaming agent, wetting agent, dispersing agent, ammonia neutralizer, levelling agent, mute is gradually added under 800~1000rpm revolving speed
Powder and photoinitiator, high speed dispersion is first by coalescing agent and deionized water to fineness≤25 μm under 1200~1500rpm revolving speed
Premix, is then slowly added under 800~1000rpm revolving speed, then be gradually added fungicide in tank, titanium dioxide slurry, wax emulsion, finally
2# glasss of rock field is sticked to 70-80 seconds with thickener tune.
Wherein, water-borne dispersions are a kind of acrylic emulsion or aqueous polyurethane dispersion.
Wherein, defoaming agent is aqueous non-silicon ketofatty acid polymer, modified polypropene acid polymer, polyoxyethylene ether or changes
Property polysiloxanes it is one such, two or more combination.
Wherein, wetting agent is one of Siloxane-Oxyalkylene Copolymers or polyether-modified dimethyl silicone polymer or two kinds
Combination.
Wherein, dispersing agent is one of copolymer or high-molecular block copolymer of the affinity groups containing pigment.
Wherein, ammonia neutralizer is the AMP-95 of DOW.
Wherein, levelling agent is one of polyethers or polyester-modified polysiloxanes or two kinds of combinations.
Wherein, flatting silica is a kind of silica flatting silica.
Wherein, photoinitiator be one of alpha-alkyl ketone or acylphosphine oxide photoinitiator, two kinds or
Two kinds of combination of the above.
Wherein, one kind of coalescing agent is DPnB (dipropylene), DPM (dipropylene glycol methyl ether), two kinds or two
Kind combination of the above.
Wherein, titanium dioxide slurry mass percent concentration is 65-75%, specifically the preparation method comprises the following steps: by 25~35% deionization
Water is added in cylinder, and middle addition 3-6% dispersing agent, is then gradually adding 65-75% titanium dioxide under 800~1000rpm of revolving speed, high speed
Dispersion, adds fungicide in 0.2% tank.
Wherein, wax emulsion is a kind of high density polyethylene waxes lotion of ultra-fine grain.
Wherein, thickener is polyurethane thickener.
Advantages of the present invention and effect: the aqueous UV white paint filming performance using the preparation of above-mentioned technology is good, and solidification effect is good,
Hardness is high, and scratch resistance effect is good, and feel is smooth.
Specific embodiment
In the present invention:
The aqueous dedicated acrylic emulsion of UV is a certain acrylic emulsion of Opel enlightening, Cohan wound company.
Water-borne dispersions are Opel enlightening, Royal DSM, a certain acrylic emulsion of Niu Peisi or aqueous polyurethane dispersion
Body.
Defoaming agent is the aqueous non-silicon ketofatty acid polymer, modified poly- that Bi Ke company, Digao company or BASF provide
Acrylate copolymer, polyoxyethylene ether or modified polyorganosiloxane are one such or combinations thereof.
Wetting agent be one of Bi Ke company Siloxane-Oxyalkylene Copolymers or polyether-modified dimethyl silicone polymer or
A combination thereof.
Flatting silica is a kind of silica flatting silica of special organic process.
Fungicide is fungicide in a kind of environment-friendly type tank of DOW or THOR in tank.
Thickener is the polyurethane thickener of Ming Ling company.
Wax emulsion is a kind of high density polyethylene waxes lotion of ultra-fine grain, and the wax emulsion feel is smooth, and transparency is good
Gloss retention is excellent.
Below with reference to embodiment, the invention will be further described.
Embodiment 1: raw material components are as follows:
Wherein: defoaming agent is BYK 024；Wetting agent is BYK 346, and ammonia neutralizer is AMP 95, and mute powder is ED2, titanium white
Starching mass percent concentration is 75%.
Embodiment 2: raw material components are as follows:
Wherein: defoaming agent is BYK 024；Wetting agent is BYK 346, and ammonia neutralizer is AMP 95, and mute powder is ED2, titanium white
Starching mass percent concentration is 75%.
This invention provides aqueous woodware paint and is tested for the property, and following three kinds of sample oils Tu be attached on workpiece, real
Test performance after dry:
It can be seen that UV white paint prepared by the present invention and common water borne one-component white paint phase from above table test result
Than, hardness significantly improves, and the dry time significantly shortens, and patience and adhesion strength are more preferable, have higher construction efficiency and
Paint film property.
In the embodiment of the present invention, dispersing agent used in too white slurry is consistent with dispersing agent used in system；It is used in the titanium dioxide slurry
Tank in fungicide it is consistent in system；Titanium dioxide used is the titanium white of the rutile-type of chloridising production in the titanium dioxide slurry
Powder, the titanium dioxide glossiness is high, and covering power is significant, strong coloring force, good weatherability.Alpha-alkyl ketone-type photoinitiators stability is excellent
It is good, there is good yellowing resistance；It is poor that acylphosphine oxide photoinitiator is mainly used for colored coating, thick coating and translucency
System.Wax emulsion feel is smooth, and the good gloss retention of transparency is excellent.
Claims (4)
1. a kind of aqueous UV high rigidity white finish paint, which is characterized in that raw material components are as follows:
Preparation process: 45~60% parts of the dedicated acrylic emulsion of aqueous UV and 0~20% water-borne dispersions are added to painting
In cylinder, be gradually added under 800~1000rpm revolving speed defoaming agent, wetting agent, dispersing agent, ammonia neutralizer, levelling agent, mute powder and
Photoinitiator, high speed dispersion is first pre- with deionized water by coalescing agent to fineness≤25 μm under 1200~1500rpm revolving speed
It is mixed, it is then slowly added under 800~1000rpm revolving speed, then be gradually added fungicide in tank, titanium dioxide slurry, wax emulsion, finally uses
Thickener tune sticks to 2# glasss of rock field 70-80 seconds.
2. a kind of aqueous UV high rigidity white finish paint as described in claim 1, which is characterized in that wherein, water-borne dispersions one
Kind acrylic emulsion or aqueous polyurethane dispersion；
Wherein, defoaming agent is aqueous non-silicon ketofatty acid polymer, modified polypropene acid polymer, polyoxyethylene ether or modified poly-
Siloxanes is one such, two or more is combined；
Wherein, wetting agent is one of Siloxane-Oxyalkylene Copolymers or polyether-modified dimethyl silicone polymer or two kinds of groups
It closes；
Wherein, dispersing agent is one of copolymer or high-molecular block copolymer of the affinity groups containing pigment；
Wherein, ammonia neutralizer is the AMP-95 of DOW；
Wherein, levelling agent is one of polyethers or polyester-modified polysiloxanes or two kinds of combinations；
Wherein, flatting silica is a kind of silica flatting silica；
Wherein, photoinitiator is one of alpha-alkyl ketone or acylphosphine oxide photoinitiator, two kinds or two kinds
Combination of the above；
Wherein, one kind of coalescing agent is DPnB (dipropylene), DPM (dipropylene glycol methyl ether), two kinds or two kinds with
Upper combination；
Wherein, titanium dioxide slurry mass percent concentration is 65-75%, specifically the preparation method comprises the following steps: the deionized water by 25~35% adds
Enter in cylinder, middle addition 3-6% dispersing agent under 800~1000rpm of revolving speed, is then gradually adding 65-75% titanium dioxide, high speed point
It dissipates, adds fungicide in 0.2% tank；
Wherein, wax emulsion is a kind of high density polyethylene waxes lotion of ultra-fine grain；
Wherein, thickener is polyurethane thickener.
3. a kind of aqueous UV high rigidity white finish paint as described in claim 1, which is characterized in that raw material components are as follows:
Wherein: defoaming agent is BYK 024；Wetting agent is BYK 346, and ammonia neutralizer is AMP 95, and mute powder is ED 2, titanium dioxide slurry matter
Measuring percent concentration is 75%.
4. a kind of aqueous UV high rigidity white finish paint as described in claim 1, which is characterized in that raw material components are as follows:
Wherein: defoaming agent is BYK 024；Wetting agent is BYK 346, and ammonia neutralizer is AMP 95, and mute powder is ED 2, titanium dioxide slurry matter
Measuring percent concentration is 75%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910169046.9A CN109929360A (en) | 2019-03-06 | 2019-03-06 | A kind of aqueous UV high rigidity white finish paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910169046.9A CN109929360A (en) | 2019-03-06 | 2019-03-06 | A kind of aqueous UV high rigidity white finish paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109929360A true CN109929360A (en) | 2019-06-25 |
Family
ID=66986550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910169046.9A Pending CN109929360A (en) | 2019-03-06 | 2019-03-06 | A kind of aqueous UV high rigidity white finish paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109929360A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115703940A (en) * | 2021-08-09 | 2023-02-17 | 深圳有为技术控股集团有限公司 | Anti-new-corona-virus aqueous LED white matte finish paint and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449305A (en) * | 2013-09-23 | 2015-03-25 | 青岛兴国涂料有限公司 | Water-based UV wood lacquer |
| CN104592883A (en) * | 2015-01-31 | 2015-05-06 | 广东华兹卜化学工业有限公司 | Water-based UV coating and preparation method thereof |
| CN106590386A (en) * | 2016-12-13 | 2017-04-26 | 君子兰化工（上海）有限公司 | Waterborne double-component scratch-resistant brilliant white paint |
| CN106675378A (en) * | 2016-11-15 | 2017-05-17 | 惠州市长润发涂料有限公司 | Waterborne UV matt varnish |
| CN108300170A (en) * | 2016-08-27 | 2018-07-20 | 江苏冠军涂料科技集团股份有限公司 | A kind of water-based ultraviolet (UV) curable coating and its preparation process |
-
2019
- 2019-03-06 CN CN201910169046.9A patent/CN109929360A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449305A (en) * | 2013-09-23 | 2015-03-25 | 青岛兴国涂料有限公司 | Water-based UV wood lacquer |
| CN104592883A (en) * | 2015-01-31 | 2015-05-06 | 广东华兹卜化学工业有限公司 | Water-based UV coating and preparation method thereof |
| CN108300170A (en) * | 2016-08-27 | 2018-07-20 | 江苏冠军涂料科技集团股份有限公司 | A kind of water-based ultraviolet (UV) curable coating and its preparation process |
| CN106675378A (en) * | 2016-11-15 | 2017-05-17 | 惠州市长润发涂料有限公司 | Waterborne UV matt varnish |
| CN106590386A (en) * | 2016-12-13 | 2017-04-26 | 君子兰化工（上海）有限公司 | Waterborne double-component scratch-resistant brilliant white paint |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115703940A (en) * | 2021-08-09 | 2023-02-17 | 深圳有为技术控股集团有限公司 | Anti-new-corona-virus aqueous LED white matte finish paint and preparation method thereof |
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| PB01 | Publication | ||
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Application publication date: 20190625 |