CN109928712A - A kind of unburned floor tile of aqueous inorganic and preparation method thereof - Google Patents
A kind of unburned floor tile of aqueous inorganic and preparation method thereof Download PDFInfo
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- CN109928712A CN109928712A CN201910324660.8A CN201910324660A CN109928712A CN 109928712 A CN109928712 A CN 109928712A CN 201910324660 A CN201910324660 A CN 201910324660A CN 109928712 A CN109928712 A CN 109928712A
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Abstract
The present invention relates to buildings decoration Material Field, espespecially a kind of unburned floor tile of aqueous inorganic and preparation method thereof.The unburned floor tile intensity of hair aqueous inorganic of the invention is high, not only flexural strength, compression strength, impact strength greatly improve, brightness is also very high, and the feature of environmental protection is good, ceramics, natural marble and resinae artificial quartz stone can be substituted, the destruction of energy consumption and people to natural environment is reduced, requirement of the people to the decorative effect of family and public place is met；The health of natural environment and labourer is protected to escape injury again.
Description
Technical field
The present invention relates to buildings decoration Material Field, the unburned floor tile of espespecially a kind of aqueous inorganic and its preparation side
Method.
Background technique
Currently, ceramics need to consume the huge energy and a large amount of greenhouse gases of discharge and are had during production
The harmful substance of poison；Wherein, natural marble can generate a large amount of dust during exploitation and cause to natural environment
Huge destruction, and resin type artificial quartz stone the process of production can generate pungent smell endanger labourer body it is strong
Health.As country is using conservation of natural environment as the raising of a kind of state basic policy and people's quality of life, it is therefore desirable to fitting-up
Material can not only meet the decoration demand of people, but also can meet the requirement of national environmental protection.
Summary of the invention
For current ceramics, natural marble, artificial resin stone diamond stone plate, there are highly energy-consumings, cause to environment and labourer
Huge injury, the problems such as not meeting national environmental protection policy, the present invention provide a kind of unburned floor tile of aqueous inorganic and its preparation side
Method.
To achieve the above object, the technical solution adopted by the present invention is that: a kind of unburned floor tile of aqueous inorganic, the floor
The raw material and its weight percent of brick are respectively as follows: inorganic coagulation material 25-35%, swelling agent 5-10%, water-reducing agent 1-3%, promote to coagulate
Agent 0.5-2%, toughener 0.8-3%, anti-wear agent 1-4%, reinforcing agent 1-3%, anti-fouling agent 2-6%, filler 35-60%, water 6-15%, on
Stating the sum of weight percent of all raw materials is 100%.
Wherein, the inorganic gel materials are fluoroaluminate cement, phosphor aluminate cement, alpha type high-strength gypsum, hexa metaphosphoric acid
One of sodium is several.
Wherein, the swelling agent is one of magnesia, calcium aluminate, alunite or several, and the water-reducing agent is wood
One or more of quality sulfonic acid magnesium, coumarone resin, methylene dimethyl sodium dinaphthalenesulfonate polymer.
Wherein, the coagulant is one of calcium chloride, sodium chloride, potassium chloride, ammonium chloride or several, the toughening
Agent is one of graphene, carbon nanotube, nanometer calcium carbonate or several.
Wherein, the anti-wear agent is one of mullite, silicon nitride, silicon carbide, zirconium oxide or several；The enhancing
Agent is one of potassium silicate and lithium metasilicate or two kinds.
Wherein, the anti-fouling agent is organic silicon emulsion, aqueous chlorotrifluoroethylene lotion, one in fluorine monomer copolymer emulsion
Kind is several, and the filler is one or more of quartz sand, silica flour, glass particle；The water is tap water.
In order to preferably realize foregoing invention purpose, the present invention also provides a kind of above-mentioned unburned floor tiles of aqueous inorganic
Preparation method, the preparation method comprises the following steps:
S1 weighs each raw material according to weight percent；
S2 sequentially adds inorganic coagulation material, swelling agent, water-reducing agent, coagulant, toughener, anti-wear agent, reinforcing agent in raw material
And filler, and be stirred；
S3, in raw material water and anti-fouling agent be added in the raw material of S2, then pour at once in mold and carry out vacuum compacting；
S4 after the raw material hardened forming in mold, carries out natural curing indoors；
S5 after being demoulded, carries out natural curing again；
S6 is finally polished directly, and obtains finished product.
Wherein, in S2, raw material is put into star-like a mixing bowl and is stirred, mixing time 10-20min；In S3,
The time of vacuum compacting is 60-90s.
Wherein, in S4, the natural curing time is 1 day；In S5, natural curing 3 days.
Wherein, in S6, polishing mesh number is 80-5000 mesh.
The beneficial effects of the present invention are the unburned floor tile intensity of: hair aqueous inorganic of the invention is high, not only flexural strength,
Compression strength, impact strength greatly improve, and brightness is also very high, and the feature of environmental protection is good, can substitute ceramics, natural marble
With resinae artificial quartz stone, the destruction of energy consumption and people to natural environment is reduced, meets people to family and public field
Decorative effect requirement；The health of natural environment and labourer is protected to escape injury again.
Specific embodiment
Below by specific embodiment, invention is further described in detail.The application can be with a variety of different
Form is realized, however it is not limited to embodiment described in the present embodiment.The purpose for providing following specific embodiments is easy for
Thorough explanation is become apparent to present disclosure.
Embodiment 1
The present embodiment provides a kind of unburned floor tile of aqueous inorganic, each raw material and its weight percent in the plate are as follows: inorganic
Cementitious material 27%, swelling agent 6%, water-reducing agent 1.5%, coagulant 1%, toughener 1%, anti-wear agent 2%, reinforcing agent 1.2%, anti-fouling agent
2.6%, filler 49.7%, water 8%.
Wherein, inorganic gel materials are by following weight percent at being grouped as: fluoroaluminate cement 40%, aluminophosphates
Cement 30%, alpha type high-strength gypsum 20%, calgon 10%；Swelling agent is by following weight percent at being grouped as: magnesia
30%, calcium aluminate 45%, alunite 25%；Water-reducing agent is by following weight percent at being grouped as: magnesium lignosulfonate 36%, Gu Ma
Grand resin 23%, methylene dimethyl sodium dinaphthalenesulfonate polymer 41%；Coagulant is by following weight percent at being grouped as: chlorine
Change calcium 26%, sodium chloride 28%, potassium chloride 25%, ammonium chloride 21%；Toughener is by following weight percent at being grouped as: graphene
28%, carbon nanotube 45%, nanometer calcium carbonate 27%.
Anti-wear agent is by following weight percent at being grouped as: mullite 34%, silicon carbide 27%, zirconium oxide 17%, silicon nitride
22%；Reinforcing agent uses potassium silicate；Anti-fouling agent is by following weight percent at being grouped as: organic silicon emulsion 28%, aqueous trifluoro
Vinyl chloride emulsion 37%, fluorine monomer copolymer emulsion 35%；The following weight percent of filler at being grouped as: quartz sand 46%, quartz
Powder 30%, glass particle 24%；Water is tap water.
The preparation method of the above-mentioned unburned floor tile of aqueous inorganic the following steps are included:
All raw materials are weighed according to weight percent, sequentially add inorganic coagulation material, swelling agent, water-reducing agent, coagulant, toughening
Agent, anti-wear agent, reinforcing agent, filler are sequentially placed into star-like a mixing bowl and are stirred mixing, and the mixing time is 13min, and
After add water and anti-fouling agent, pour into mold rapidly, shakeout carry out vacuum compacting, the vacuum pressing time be 70s, hardened forming
Sample natural curing indoors, demould after 1d, then carry out maintenance 3 days, be finally polished directly again, polishing mesh number is from 80 mesh
Finished product can be obtained to 5000 mesh.
Embodiment 2
The present embodiment provides a kind of unburned floor tile of aqueous inorganic, each raw material and its weight percent in the plate are as follows: inorganic
Cementitious material 29%, swelling agent 7.5%, water-reducing agent 2%, coagulant 1.5%, toughener 1.2%, anti-wear agent 2.6%, reinforcing agent 1.5%,
Anti-fouling agent 3%, filler 42.7%, water 9%.
Wherein, inorganic gel materials are by following weight percent at being grouped as: fluoroaluminate cement 37%, aluminophosphates
Cement 38%, alpha type high-strength gypsum 25%；Swelling agent is by following weight percent at being grouped as: magnesia 39%, calcium aluminate 21%,
Alunite 40%；Water-reducing agent is by following weight percent at being grouped as: magnesium lignosulfonate 51%, coumarone resin 28%, methylene
Base dimethyl sodium dinaphthalenesulfonate polymer 21%；Coagulant is by following weight percent at being grouped as: calcium chloride 29%, sodium chloride
51%, potassium chloride 20%；Toughener is by following weight percent at being grouped as: graphene 56%, carbon nanotube 23%, nano-calcium carbonate
Calcium 21%.
Anti-wear agent is by following weight percent at being grouped as: mullite 35%, silicon carbide 21%, zirconium oxide 19%, silicon nitride
25%；Reinforcing agent is by following weight percent at being grouped as: potassium silicate 50%, lithium metasilicate 50%；Anti-fouling agent is by following weight percent
Ratio at being grouped as: organic silicon emulsion 56%, aqueous chlorotrifluoroethylene lotion 25%, fluorine monomer copolymer emulsion 19%；Below filler
Weight percent at being grouped as: quartz sand 62%, silica flour 20%, glass particle 18%；Water is tap water.
The preparation method of the above-mentioned unburned floor tile of aqueous inorganic the following steps are included:
All raw materials are weighed according to weight percent, sequentially add inorganic coagulation material, swelling agent, water-reducing agent, coagulant, toughening
Agent, anti-wear agent, filler, which are sequentially placed into, to be stirred dispersion in star-like a mixing bowl and is stirred, and the mixing time is
15min then adds water and anti-fouling agent, pours into mold rapidly, shakeouts progress vacuum compacting, and the vacuum pressing time is 75s,
The natural curing indoors of the sample of hardened forming demoulds after 1d, then carries out maintenance 3 days, is finally polished directly again, polishes mesh
Finished product can be obtained from 80 mesh to 5000 mesh in number.
Embodiment 3
The present embodiment provides a kind of unburned floor tile of aqueous inorganic, each raw material and its weight percent in the plate are as follows: inorganic
Cementitious material 29%, swelling agent 5.5%, water-reducing agent 1.2%, coagulant 0.8%, toughener 1%, anti-wear agent 1.5%, reinforcing agent 1.5%,
Anti-fouling agent 3.1%, filler 49.4%, water 7%.
Wherein, inorganic gel materials are by following weight percent at being grouped as: fluoroaluminate cement 39%, aluminophosphates
Cement 31%, alpha type high-strength gypsum 16%, calgon 14%；Swelling agent is by following weight percent at being grouped as: magnesia
38%, calcium aluminate 51%, alunite 11%；Water-reducing agent is by following weight percent at being grouped as: magnesium lignosulfonate 43%, Gu Ma
Grand resin 32%, methylene dimethyl sodium dinaphthalenesulfonate polymer 25%；Coagulant is by following weight percent at being grouped as: chlorine
Change calcium 41%, sodium chloride 32%, potassium chloride 18%, ammonium chloride 9%；Toughener is by following weight percent at being grouped as: graphene
65%, carbon nanotube 32%, nanometer calcium carbonate 3%.
Anti-wear agent is by following weight percent at being grouped as: mullite 56%, silicon carbide 12%, zirconium oxide 20%, silicon nitride
12%；Reinforcing agent is by following weight percent at being grouped as: potassium silicate 40%, lithium metasilicate 60%；Anti-fouling agent is by following weight percent
Ratio at being grouped as: organic silicon emulsion 67%, aqueous chlorotrifluoroethylene lotion 10%, fluorine monomer copolymer emulsion 23%；Below filler
Weight percent at being grouped as: quartz sand 34%, silica flour 25%, glass particle 41%；Water is tap water.
The preparation method of the above-mentioned unburned floor tile of aqueous inorganic the following steps are included:
All raw materials are weighed according to weight percent, sequentially add inorganic coagulation material, swelling agent, water-reducing agent, coagulant, toughening
Agent, anti-wear agent, filler, which are sequentially placed into, to be stirred dispersion in star-like a mixing bowl and is stirred, and the mixing time is
17min then adds water and anti-fouling agent, pours into mold rapidly, shakeouts progress vacuum compacting, and the vacuum pressing time is 80s,
The natural curing indoors of the sample of hardened forming demoulds after 1d, then carries out maintenance 3 days, is finally polished directly again, polishes mesh
Finished product can be obtained from 80 mesh to 5000 mesh in number.
Embodiment 4
The present embodiment provides a kind of unburned floor tile of aqueous inorganic, each raw material and its weight percent in the plate are as follows: inorganic
Cementitious material 26%, water-reducing agent 1%, coagulant 0.7%, toughener 1.9%, anti-wear agent 2.8%, reinforcing agent 1.2%, is prevented swelling agent 5%
Dirty agent 2.1%, filler 49.2%, water 10.1%.
Wherein, inorganic gel materials are by following weight percent at being grouped as: fluoroaluminate cement 67%, aluminophosphates
Cement 11%, alpha type high-strength gypsum 8%, calgon 14%；Swelling agent is by following weight percent at being grouped as: magnesia
45%, calcium aluminate 40%, alunite 15%；Water-reducing agent is by following weight percent at being grouped as: magnesium lignosulfonate 24%, Gu Ma
Grand resin 56%, methylene dimethyl sodium dinaphthalenesulfonate polymer 20%；Coagulant is by following weight percent at being grouped as: chlorine
Change calcium 35%, sodium chloride 29%, potassium chloride 21%, ammonium chloride 15%；Toughener is by following weight percent at being grouped as: graphene
49%, carbon nanotube 41%, nanometer calcium carbonate 10%.
Anti-wear agent is by following weight percent at being grouped as: mullite 37%, silicon carbide 23%, zirconium oxide 10%, silicon nitride
30%；Reinforcing agent is by following weight percent at being grouped as: potassium silicate 60%, lithium metasilicate 40%；Anti-fouling agent is by following weight percent
Ratio at being grouped as: organic silicon emulsion 31%, aqueous chlorotrifluoroethylene lotion 38%, fluorine monomer copolymer emulsion 39%；Below filler
Weight percent at being grouped as: quartz sand 67%, silica flour 14%, glass particle 19%；Water is tap water.
The preparation method of the above-mentioned unburned floor tile of aqueous inorganic the following steps are included:
All raw materials are weighed according to weight percent, sequentially add inorganic coagulation material, swelling agent, water-reducing agent, coagulant, toughening
Agent, anti-wear agent, filler, which are sequentially placed into, to be stirred dispersion in star-like a mixing bowl and is stirred, and the mixing time is
19min then adds water and anti-fouling agent, pours into mold rapidly, shakeouts progress vacuum compacting, and the vacuum pressing time is 85s,
The natural curing indoors of the sample of hardened forming demoulds after 1d, then carries out maintenance 3 days, is finally polished directly again, polishes mesh
Finished product can be obtained from 80 mesh to 5000 mesh in number.
Comparative test
The unburned floor tile of the aqueous inorganic of 1-4 of the embodiment of the present invention is subjected to performance detection respectively, the results are shown in Table 1.
Table 1: product of the present invention and the conventional products performance detection table of comparisons:
As can be seen from the data in table 1: the above-mentioned detection project of the unburned floor tile of the aqueous inorganic of 1-4 of the embodiment of the present invention, other physics
Performance is superior to conventional product.
Embodiment of above be only preferred embodiments of the present invention will be described, not to the scope of the present invention into
Row limits, and without departing from the spirit of the design of the present invention, this field ordinary engineering and technical personnel is to technical side of the invention
The various changes and improvements that case is made, should fall within the scope of protection determined by the claims of the present invention.
Claims (10)
1. a kind of unburned floor tile of aqueous inorganic, which is characterized in that the raw material and its weight percent of the floor tile are respectively as follows:
Inorganic coagulation material 25-35%, swelling agent 5-10%, water-reducing agent 1-3%, coagulant 0.5-2%, toughener 0.8-3%, anti-wear agent 1-
4%, reinforcing agent 1-3%, anti-fouling agent 2-6%, filler 35-60%, water 6-15%, the sum of the weight percent of above-mentioned all raw materials are
100%。
2. the unburned floor tile of a kind of aqueous inorganic according to claim 1, it is characterised in that: the inorganic gel materials are
One of fluoroaluminate cement, phosphor aluminate cement, alpha type high-strength gypsum, calgon are several.
3. the unburned floor tile of a kind of aqueous inorganic according to claim 1, it is characterised in that: the swelling agent is oxidation
One of magnesium, calcium aluminate, alunite are several, and the water-reducing agent is magnesium lignosulfonate, coumarone resin, methylene two
One or more of methyl sodium dinaphthalenesulfonate polymer.
4. the unburned floor tile of a kind of aqueous inorganic according to claim 1, it is characterised in that: the coagulant is chlorination
One of calcium, sodium chloride, potassium chloride, ammonium chloride are several, and the toughener is graphene, carbon nanotube, nano-calcium carbonate
One of calcium is several.
5. the unburned floor tile of a kind of aqueous inorganic according to claim 1, it is characterised in that: the anti-wear agent is not come
One of stone, silicon nitride, silicon carbide, zirconium oxide are several；The reinforcing agent be one of potassium silicate and lithium metasilicate or
Two kinds of person.
6. the unburned floor tile of a kind of aqueous inorganic according to claim 1, it is characterised in that: the anti-fouling agent is organosilicon
One of lotion, aqueous chlorotrifluoroethylene lotion, fluorine monomer copolymer emulsion are several, and the filler is quartz sand, stone
One or more of Ying Fen, glass particle；The water is tap water.
7. a kind of preparation method of the unburned floor tile of aqueous inorganic as described in claim 1, which is characterized in that including following preparation
Step:
S1 weighs each raw material according to weight percent；
S2 sequentially adds inorganic coagulation material, swelling agent, water-reducing agent, coagulant, toughener, anti-wear agent, reinforcing agent in raw material
And filler, and be stirred；
S3, in raw material water and anti-fouling agent be added in the raw material of S2, then pour at once in mold and carry out vacuum compacting；
S4 after the raw material hardened forming in mold, carries out natural curing indoors；
S5 after being demoulded, carries out natural curing again；
S6 is finally polished directly, and obtains finished product.
8. the preparation method of the unburned floor tile of aqueous inorganic according to claim 7, it is characterised in that: in S2, original
Material, which is put into star-like a mixing bowl, to be stirred, mixing time 10-20min；In S3, the time of vacuum compacting is 60-90s.
9. the preparation method of the unburned floor tile of aqueous inorganic according to claim 7, it is characterised in that: natural in S4
Curing time is 1 day；In S5, natural curing 3 days.
10. the preparation method of the unburned floor tile of aqueous inorganic according to claim 7, it is characterised in that: in S6, polishing
Mesh number is 80-5000 mesh.
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| CN201910324660.8A CN109928712A (en) | 2019-04-22 | 2019-04-22 | A kind of unburned floor tile of aqueous inorganic and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910324660.8A CN109928712A (en) | 2019-04-22 | 2019-04-22 | A kind of unburned floor tile of aqueous inorganic and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114315230A (en) * | 2022-02-11 | 2022-04-12 | 福建汉荣石业有限公司 | Environment-friendly antifouling marble slab and production process thereof |
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2019
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| EP0003761A1 (en) * | 1978-02-27 | 1979-09-05 | Österreichisch-Amerikanische Magnesit Aktiengesellschaft | Basic refractory mixes and unfired bricks. |
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Application publication date: 20190625 |