CN109913643A - A method of Pb-Zn deposits are handled with damaged tire - Google Patents
A method of Pb-Zn deposits are handled with damaged tire Download PDFInfo
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- CN109913643A CN109913643A CN201910170476.2A CN201910170476A CN109913643A CN 109913643 A CN109913643 A CN 109913643A CN 201910170476 A CN201910170476 A CN 201910170476A CN 109913643 A CN109913643 A CN 109913643A
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- deposits
- damaged tire
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- powder
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- 229910020218 Pb—Zn Inorganic materials 0.000 title claims abstract description 87
- 238000000034 method Methods 0.000 title claims abstract description 29
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000007789 gas Substances 0.000 claims abstract description 36
- 239000002245 particle Substances 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 34
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000001816 cooling Methods 0.000 claims abstract description 18
- 239000003546 flue gas Substances 0.000 claims abstract description 18
- 238000005453 pelletization Methods 0.000 claims abstract description 18
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 17
- 239000001301 oxygen Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000428 dust Substances 0.000 claims abstract description 16
- 239000011230 binding agent Substances 0.000 claims abstract description 15
- 229910052742 iron Inorganic materials 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 229910052709 silver Inorganic materials 0.000 claims abstract description 10
- 239000004332 silver Substances 0.000 claims abstract description 10
- 230000004888 barrier function Effects 0.000 claims abstract description 9
- 238000007885 magnetic separation Methods 0.000 claims abstract description 9
- 238000011084 recovery Methods 0.000 claims abstract description 9
- 238000010792 warming Methods 0.000 claims abstract description 9
- 230000000505 pernicious effect Effects 0.000 claims abstract description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 17
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 11
- 239000001569 carbon dioxide Substances 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000010920 waste tyre Substances 0.000 abstract description 15
- JQJCSZOEVBFDKO-UHFFFAOYSA-N lead zinc Chemical compound [Zn].[Pb] JQJCSZOEVBFDKO-UHFFFAOYSA-N 0.000 abstract description 10
- 230000008021 deposition Effects 0.000 abstract description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 229910000278 bentonite Inorganic materials 0.000 description 6
- 239000000440 bentonite Substances 0.000 description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical group O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 238000005276 aerator Methods 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
The present invention relates to a kind of methods with damaged tire processing Pb-Zn deposits, belong to energy-saving and emission-reduction and technical field of resource comprehensive utilization.It is first 74um Pb-Zn deposits powder below by Pb-Zn deposits ore grinding to granularity, damaged tire is then broken into 0.1mm~0.3mm damaged tire particle, it is 8~12mm pelletizing that diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water;In the case where being passed through the gas condition that flow is 0.2~0.6L/min, obtained pelletizing is warming up at 950~1150 DEG C and keeps the temperature 40~80min progress reduction roasting, after high-temperature flue gas is by surface-cooler cooling in the process, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas passes through washer again and removes pernicious gas, reach after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.The present invention makes full use of waste tire to can produce reducing gas and contain and lead zinc high temperature is easy to the characteristics of volatilizing, and solves the problems, such as waste tire bulk deposition, has achieved the purpose that energy-saving and emission-reduction.
Description
Technical field
The present invention relates to a kind of methods with damaged tire processing Pb-Zn deposits, belong to energy-saving and emission-reduction and resource comprehensive utilization technology
Field.
Background technique
Waste tire is a kind of common waste, and the whole world can produce a large amount of waste tires every year, and (2017 are 2,700,000,000
Item).Country does not allow to be poured upon in refuse landfill, therefore these wastes should be effectively addressed.So far, gasification or
Pyrolysis can be used as the main method of recycling waste tire.The pyrolysis of waste tire is usually in 400 DEG C to 800 DEG C of temperature range
It is interior, hydrocarbon and charcoal are produced after pyrolysis processing.However, when the sulfur content in these thermal decomposition products increases, it will
It can hinder their direct use.Therefore, set forth herein waste tire and Pb-Zn deposits copyrolysis is handled, by valuable metal lead
Zinc evaporates, while waste tire sulfur-bearing problem will be addressed.
Summary of the invention
For the above-mentioned problems of the prior art and deficiency, the present invention provides a kind of side with damaged tire processing Pb-Zn deposits
Method.The present invention on the basis of Method And Principle of reduction roasting, make full use of waste tire can produce reducing gas and contain and
Lead zinc high temperature is easy to the characteristics of volatilizing, and solves the problems, such as waste tire bulk deposition, has achieved the purpose that energy-saving and emission-reduction.This hair
It is bright to be achieved through the following technical solutions.
A method of Pb-Zn deposits being handled with damaged tire, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits ore grinding to granularity be 74um Pb-Zn deposits powder below, damaged tire is then broken into 0.1mm
~0.3mm damaged tire particle, it is 8~12mm pelletizing that diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water;
Step 2, in the case where being passed through the gas condition that flow is 0.2~0.6L/min, the pelletizing that step 1 is obtained is warming up to 950~
40~80min is kept the temperature at 1150 DEG C and carries out reduction roasting, after high-temperature flue gas is by surface-cooler cooling in the process, through receiving
Dirt system recycles it containing the led-zinc-silver deposit in Pb-Zn dust, and flue gas removes pernicious gas by washer again, reaches emptying and requires
After be discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
Oxygen quality is 1.6 according to the mass ratio of C/O with carbonaceous amount in damaged tire particle in Pb-Zn deposits powder in the step 1
Pb-Zn deposits powder and damaged tire particle are uniformly mixed by~1.8:1, and water additional amount is the 3%~5% of Pb-Zn deposits silty amount.
Step 2 gas is the mixed gas with weak oxide.
Mixed gas in the step 2 with weak oxide is the air of arbitrary proportion and the mixed gas of inert gas
Or carbon dioxide and inert gas mixed gas.
The present invention puts forward to handle waste tire and Pb-Zn deposits copyrolysis, valuable metal lead zinc is evaporated, simultaneously
Waste tire sulfur-bearing problem will be addressed.In this reaction process, detailed reaction is as follows:
PbO+CO(g)=Pb+CO2(g) (1)
ZnO+CO(g)=Zn+CO2(g) (2)
ZnS+CO(g)=Zn+COS(g) (3)
Saturated vapour pressure is larger at high temperature for the lead zinc of generation, can quickly evaporate from Pb-Zn deposits.At the same time, more by force
Reduction atmosphere the oxide of iron will be reduced to reduced iron, detailed reaction is as follows:
3Fe2O3+CO(g)=2Fe3O4+CO2(g) (4)
Fe3O4+CO(g)=3FeO+CO2(g) (5)
FeO+CO(g)=Fe+CO2(g) (6)
Based on the principle of above-mentioned reduction roasting, the present invention uses waste tire and the baking mixed carry out Pb-Zn separation of Pb-Zn deposits, can
Achieve the purpose that energy-saving and emission-reduction and comprehensive utilization of resources.
The beneficial effects of the present invention are:
(1) wherein led-zinc-silver deposit and iron resource can be recycled from low-grade lead zinc ore, realize the comprehensive utilization of resource.
(2) waste tire and Pb-Zn deposits mixing reduction roasting are utilized, provides new thinking for the utilization of waste tire.
Detailed description of the invention
Fig. 1 is process flow chart of the invention.
Specific embodiment
With reference to the accompanying drawings and detailed description, the invention will be further described.
Embodiment 1
As shown in Figure 1, the method with damaged tire processing Pb-Zn deposits, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits (Pb2.13wt.%, Zn8.42wt.%) ore grinding to granularity be 74um Pb-Zn deposits powder below,
Then damaged tire is broken into 0.2mm damaged tire particle, diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water is
10mm pelletizing;Carbonaceous amount according to the mass ratio of C/O is 1.7:1 by Pb-Zn deposits powder in oxygen quality and damaged tire particle in Pb-Zn deposits powder
It is uniformly mixed with damaged tire particle, water additional amount is the 4% of Pb-Zn deposits silty amount, and binder is bentonite, and additional amount is Pb-Zn deposits
Silty amount 1.5%;
Step 2 is passed through under the conditions of the gas (air of volume ratio 10:90 and the mixed gas of nitrogen) that flow is 0.3L/min,
The pelletizing that step 1 is obtained, which is warming up at 1100 DEG C, keeps the temperature 40min progress reduction roasting, and high-temperature flue gas passes through table in the process
After aerator is cooling, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas has by washer removing again
Evil gas reaches after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
Lead zinc is down to 0.15wt.% and 0.55wt.% respectively in clinker after above-mentioned steps are handled, and magneticly elects the iron of reduced iron
Content is 93wt.%.
Embodiment 2
As shown in Figure 1, the method with damaged tire processing Pb-Zn deposits, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits (Pb3.45wt.%, Zn6.55wt.%) ore grinding to granularity be 74um Pb-Zn deposits powder below,
Then damaged tire is broken into 0.2mm damaged tire particle, diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water is
10mm pelletizing;Carbonaceous amount according to the mass ratio of C/O is 1.6:1 by Pb-Zn deposits powder in oxygen quality and damaged tire particle in Pb-Zn deposits powder
It is uniformly mixed with damaged tire particle, water additional amount is the 4% of Pb-Zn deposits silty amount, and binder is bentonite, and additional amount is Pb-Zn deposits
Silty amount 1.5%;
Step 2 is passed through under the conditions of the gas (air of volume ratio 10:90 and the mixed gas of nitrogen) that flow is 0.3L/min,
The pelletizing that step 1 is obtained, which is warming up at 1150 DEG C, keeps the temperature 40min progress reduction roasting, and high-temperature flue gas passes through table in the process
After aerator is cooling, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas has by washer removing again
Evil gas reaches after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
Lead zinc is down to 0.18wt.% and 0.25wt.% respectively in clinker after above-mentioned steps are handled, and magneticly elects the iron of reduced iron
Content is 91wt.%.
Embodiment 3
As shown in Figure 1, the method with damaged tire processing Pb-Zn deposits, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits (Pb2.95wt.%, Zn10.42wt.%) ore grinding to granularity be 74um Pb-Zn deposits powder below,
Then damaged tire is broken into 0.2mm damaged tire particle, diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water is
10mm pelletizing;Carbonaceous amount according to the mass ratio of C/O is 1.8:1 by Pb-Zn deposits powder in oxygen quality and damaged tire particle in Pb-Zn deposits powder
It is uniformly mixed with damaged tire particle, water additional amount is the 4% of Pb-Zn deposits silty amount, and binder is bentonite, and additional amount is Pb-Zn deposits
Silty amount 1.5%;
Step 2 is passed through gas (carbon dioxide of volume ratio 5:90 and the mixed gas of nitrogen) condition that flow is 0.3L/min
Under, the pelletizing that step 1 is obtained, which is warming up at 1100 DEG C, keeps the temperature 60min progress reduction roasting, and high-temperature flue gas is logical in the process
After crossing surface-cooler cooling, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas is removed by washer again
Pernicious gas is removed, reaches after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
Lead zinc is down to 0.13wt.% and 0.32wt.% respectively in clinker after above-mentioned steps are handled, and magneticly elects the iron of reduced iron
Content is 96wt.%.
Embodiment 4
As shown in Figure 1, the method with damaged tire processing Pb-Zn deposits, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits (Pb3.23wt.%, Zn11.67wt.%) ore grinding to granularity be 74um Pb-Zn deposits powder below,
Then damaged tire is broken into 0.1mm damaged tire particle, diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water is
8mm pelletizing;Carbonaceous amount according to the mass ratio of C/O is 1.8:1 by Pb-Zn deposits powder in oxygen quality and damaged tire particle in Pb-Zn deposits powder
It is uniformly mixed with damaged tire particle, water additional amount is the 4% of Pb-Zn deposits silty amount, and binder is bentonite, and additional amount is Pb-Zn deposits
Silty amount 1.5%;
Step 2 is passed through gas (carbon dioxide of volume ratio 3:90 and the mixed gas of nitrogen) condition that flow is 0.35L/min
Under, the pelletizing that step 1 is obtained, which is warming up at 1150 DEG C, keeps the temperature 60min progress reduction roasting, and high-temperature flue gas is logical in the process
After crossing surface-cooler cooling, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas is removed by washer again
Pernicious gas is removed, reaches after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
Lead zinc is down to 0.09wt.% and 0.18wt.% respectively in clinker after above-mentioned steps are handled, and magneticly elects the iron of reduced iron
Content is 96wt.%.
Embodiment 5
As shown in Figure 1, the method with damaged tire processing Pb-Zn deposits, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits (Pb3.23wt.%, Zn11.67wt.%) ore grinding to granularity be 74um Pb-Zn deposits powder below,
Then damaged tire is broken into 0.2mm damaged tire particle, diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water is
8mm pelletizing;Carbonaceous amount according to the mass ratio of C/O is 1.8:1 by Pb-Zn deposits powder in oxygen quality and damaged tire particle in Pb-Zn deposits powder
It is uniformly mixed with damaged tire particle, water additional amount is the 3% of Pb-Zn deposits silty amount, and binder is bentonite, and additional amount is Pb-Zn deposits
Silty amount 1.5%;
Step 2 is passed through gas (carbon dioxide of volume ratio 3:90 and the mixed gas of nitrogen) condition that flow is 0.2L/min
Under, the pelletizing that step 1 is obtained, which is warming up at 1150 DEG C, keeps the temperature 60min progress reduction roasting, and high-temperature flue gas is logical in the process
After crossing surface-cooler cooling, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas is removed by washer again
Pernicious gas is removed, reaches after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
Embodiment 6
As shown in Figure 1, the method with damaged tire processing Pb-Zn deposits, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits (Pb3.23wt.%, Zn11.67wt.%) ore grinding to granularity be 74um Pb-Zn deposits powder below,
Then damaged tire is broken into 0.3mm damaged tire particle, diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water is
12mm pelletizing;Carbonaceous amount according to the mass ratio of C/O is 1.8:1 by Pb-Zn deposits powder in oxygen quality and damaged tire particle in Pb-Zn deposits powder
It is uniformly mixed with damaged tire particle, water additional amount is the 5% of Pb-Zn deposits silty amount, and binder is bentonite, and additional amount is Pb-Zn deposits
Silty amount 1.5%;
Step 2 is passed through gas (carbon dioxide of volume ratio 3:90 and the mixed gas of nitrogen) condition that flow is 0.6L/min
Under, the pelletizing that step 1 is obtained, which is warming up at 950 DEG C, keeps the temperature 80min progress reduction roasting, and high-temperature flue gas passes through in the process
After surface-cooler is cooling, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas is removed by washer again
Pernicious gas reaches after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
In conjunction with attached drawing, the embodiment of the present invention is explained in detail above, but the present invention is not limited to above-mentioned
Embodiment within the knowledge of a person skilled in the art can also be before not departing from present inventive concept
Put that various changes can be made.
Claims (4)
1. a kind of method with damaged tire processing Pb-Zn deposits, it is characterised in that specific step is as follows:
Step 1, first by Pb-Zn deposits ore grinding to granularity be 74um Pb-Zn deposits powder below, damaged tire is then broken into 0.1mm
~0.3mm damaged tire particle, it is 8~12mm pelletizing that diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water;
Step 2, in the case where being passed through the gas condition that flow is 0.2~0.6L/min, the pelletizing that step 1 is obtained is warming up to 950~
40~80min is kept the temperature at 1150 DEG C and carries out reduction roasting, after high-temperature flue gas is by surface-cooler cooling in the process, through receiving
Dirt system recycles it containing the led-zinc-silver deposit in Pb-Zn dust, and flue gas removes pernicious gas by washer again, reaches emptying and requires
After be discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
2. the method according to claim 1 with damaged tire processing Pb-Zn deposits, it is characterised in that: the lead in the step 1
Carbonaceous amount is 1.6~1.8:1 by Pb-Zn deposits powder according to the mass ratio of C/O and useless takes turns in oxygen quality and damaged tire particle in zinc ore powder
Tire particle is uniformly mixed, and water additional amount is the 3%~5% of Pb-Zn deposits silty amount.
3. the method according to claim 1 with damaged tire processing Pb-Zn deposits, it is characterised in that: step 2 gas is
Mixed gas with weak oxide.
4. the method according to claim 3 with damaged tire processing Pb-Zn deposits, it is characterised in that: have in the step 2
The mixed gas of weak oxide is that the air of arbitrary proportion and the mixed gas or carbon dioxide and inert gas of inert gas are mixed
Close gas.
Priority Applications (1)
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CN201910170476.2A CN109913643A (en) | 2019-03-07 | 2019-03-07 | A method of Pb-Zn deposits are handled with damaged tire |
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CN201910170476.2A CN109913643A (en) | 2019-03-07 | 2019-03-07 | A method of Pb-Zn deposits are handled with damaged tire |
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Publication Number | Publication Date |
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CN109913643A true CN109913643A (en) | 2019-06-21 |
Family
ID=66963706
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114921656A (en) * | 2022-05-17 | 2022-08-19 | 有研亿金新材料有限公司 | Method for reducing carbon content of high-purity gold |
CN115558796A (en) * | 2022-11-04 | 2023-01-03 | 昆明理工大学 | Method for resource extraction of zinc oxide from waste tire coupled blast furnace ash |
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CN105483371A (en) * | 2015-12-21 | 2016-04-13 | 武钢集团昆明钢铁股份有限公司 | Method for comprehensively recycling lead and zinc containing blast furnace dust |
CN106086457A (en) * | 2016-08-16 | 2016-11-09 | 白银有色集团股份有限公司 | A kind of lead Zinc oxide processing method for pyrometallurgical smelting |
CN106755962A (en) * | 2016-12-14 | 2017-05-31 | 昆明理工大学 | A kind of method with recyclable domestic rubbish disposal tin-iron mine |
CN107460327A (en) * | 2017-07-28 | 2017-12-12 | 重庆科技学院 | A kind of comprehensive reutilization method of the leaded zinc powder dirt of electric furnace steel making |
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CN104404246A (en) * | 2014-11-24 | 2015-03-11 | 北京神雾环境能源科技集团股份有限公司 | Method for improving metallization rate of metallurgical slag pellet |
CN105483371A (en) * | 2015-12-21 | 2016-04-13 | 武钢集团昆明钢铁股份有限公司 | Method for comprehensively recycling lead and zinc containing blast furnace dust |
CN106086457A (en) * | 2016-08-16 | 2016-11-09 | 白银有色集团股份有限公司 | A kind of lead Zinc oxide processing method for pyrometallurgical smelting |
CN106755962A (en) * | 2016-12-14 | 2017-05-31 | 昆明理工大学 | A kind of method with recyclable domestic rubbish disposal tin-iron mine |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN114921656A (en) * | 2022-05-17 | 2022-08-19 | 有研亿金新材料有限公司 | Method for reducing carbon content of high-purity gold |
CN114921656B (en) * | 2022-05-17 | 2024-01-26 | 有研亿金新材料有限公司 | Method for reducing high-purity gold carbon content |
CN115558796A (en) * | 2022-11-04 | 2023-01-03 | 昆明理工大学 | Method for resource extraction of zinc oxide from waste tire coupled blast furnace ash |
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