CN109913643A - A method of Pb-Zn deposits are handled with damaged tire - Google Patents

A method of Pb-Zn deposits are handled with damaged tire Download PDF

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Publication number
CN109913643A
CN109913643A CN201910170476.2A CN201910170476A CN109913643A CN 109913643 A CN109913643 A CN 109913643A CN 201910170476 A CN201910170476 A CN 201910170476A CN 109913643 A CN109913643 A CN 109913643A
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China
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deposits
damaged tire
gas
particle
powder
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李红娟
李磊
王竟成
王�华
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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Abstract

The present invention relates to a kind of methods with damaged tire processing Pb-Zn deposits, belong to energy-saving and emission-reduction and technical field of resource comprehensive utilization.It is first 74um Pb-Zn deposits powder below by Pb-Zn deposits ore grinding to granularity, damaged tire is then broken into 0.1mm~0.3mm damaged tire particle, it is 8~12mm pelletizing that diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water;In the case where being passed through the gas condition that flow is 0.2~0.6L/min, obtained pelletizing is warming up at 950~1150 DEG C and keeps the temperature 40~80min progress reduction roasting, after high-temperature flue gas is by surface-cooler cooling in the process, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas passes through washer again and removes pernicious gas, reach after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.The present invention makes full use of waste tire to can produce reducing gas and contain and lead zinc high temperature is easy to the characteristics of volatilizing, and solves the problems, such as waste tire bulk deposition, has achieved the purpose that energy-saving and emission-reduction.

Description

A method of Pb-Zn deposits are handled with damaged tire
Technical field
The present invention relates to a kind of methods with damaged tire processing Pb-Zn deposits, belong to energy-saving and emission-reduction and resource comprehensive utilization technology Field.
Background technique
Waste tire is a kind of common waste, and the whole world can produce a large amount of waste tires every year, and (2017 are 2,700,000,000 Item).Country does not allow to be poured upon in refuse landfill, therefore these wastes should be effectively addressed.So far, gasification or Pyrolysis can be used as the main method of recycling waste tire.The pyrolysis of waste tire is usually in 400 DEG C to 800 DEG C of temperature range It is interior, hydrocarbon and charcoal are produced after pyrolysis processing.However, when the sulfur content in these thermal decomposition products increases, it will It can hinder their direct use.Therefore, set forth herein waste tire and Pb-Zn deposits copyrolysis is handled, by valuable metal lead Zinc evaporates, while waste tire sulfur-bearing problem will be addressed.
Summary of the invention
For the above-mentioned problems of the prior art and deficiency, the present invention provides a kind of side with damaged tire processing Pb-Zn deposits Method.The present invention on the basis of Method And Principle of reduction roasting, make full use of waste tire can produce reducing gas and contain and Lead zinc high temperature is easy to the characteristics of volatilizing, and solves the problems, such as waste tire bulk deposition, has achieved the purpose that energy-saving and emission-reduction.This hair It is bright to be achieved through the following technical solutions.
A method of Pb-Zn deposits being handled with damaged tire, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits ore grinding to granularity be 74um Pb-Zn deposits powder below, damaged tire is then broken into 0.1mm ~0.3mm damaged tire particle, it is 8~12mm pelletizing that diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water;
Step 2, in the case where being passed through the gas condition that flow is 0.2~0.6L/min, the pelletizing that step 1 is obtained is warming up to 950~ 40~80min is kept the temperature at 1150 DEG C and carries out reduction roasting, after high-temperature flue gas is by surface-cooler cooling in the process, through receiving Dirt system recycles it containing the led-zinc-silver deposit in Pb-Zn dust, and flue gas removes pernicious gas by washer again, reaches emptying and requires After be discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
Oxygen quality is 1.6 according to the mass ratio of C/O with carbonaceous amount in damaged tire particle in Pb-Zn deposits powder in the step 1 Pb-Zn deposits powder and damaged tire particle are uniformly mixed by~1.8:1, and water additional amount is the 3%~5% of Pb-Zn deposits silty amount.
Step 2 gas is the mixed gas with weak oxide.
Mixed gas in the step 2 with weak oxide is the air of arbitrary proportion and the mixed gas of inert gas Or carbon dioxide and inert gas mixed gas.
The present invention puts forward to handle waste tire and Pb-Zn deposits copyrolysis, valuable metal lead zinc is evaporated, simultaneously Waste tire sulfur-bearing problem will be addressed.In this reaction process, detailed reaction is as follows:
PbO+CO(g)=Pb+CO2(g) (1)
ZnO+CO(g)=Zn+CO2(g) (2)
ZnS+CO(g)=Zn+COS(g) (3)
Saturated vapour pressure is larger at high temperature for the lead zinc of generation, can quickly evaporate from Pb-Zn deposits.At the same time, more by force Reduction atmosphere the oxide of iron will be reduced to reduced iron, detailed reaction is as follows:
3Fe2O3+CO(g)=2Fe3O4+CO2(g) (4)
Fe3O4+CO(g)=3FeO+CO2(g) (5)
FeO+CO(g)=Fe+CO2(g) (6)
Based on the principle of above-mentioned reduction roasting, the present invention uses waste tire and the baking mixed carry out Pb-Zn separation of Pb-Zn deposits, can Achieve the purpose that energy-saving and emission-reduction and comprehensive utilization of resources.
The beneficial effects of the present invention are:
(1) wherein led-zinc-silver deposit and iron resource can be recycled from low-grade lead zinc ore, realize the comprehensive utilization of resource.
(2) waste tire and Pb-Zn deposits mixing reduction roasting are utilized, provides new thinking for the utilization of waste tire.
Detailed description of the invention
Fig. 1 is process flow chart of the invention.
Specific embodiment
With reference to the accompanying drawings and detailed description, the invention will be further described.
Embodiment 1
As shown in Figure 1, the method with damaged tire processing Pb-Zn deposits, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits (Pb2.13wt.%, Zn8.42wt.%) ore grinding to granularity be 74um Pb-Zn deposits powder below, Then damaged tire is broken into 0.2mm damaged tire particle, diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water is 10mm pelletizing;Carbonaceous amount according to the mass ratio of C/O is 1.7:1 by Pb-Zn deposits powder in oxygen quality and damaged tire particle in Pb-Zn deposits powder It is uniformly mixed with damaged tire particle, water additional amount is the 4% of Pb-Zn deposits silty amount, and binder is bentonite, and additional amount is Pb-Zn deposits Silty amount 1.5%;
Step 2 is passed through under the conditions of the gas (air of volume ratio 10:90 and the mixed gas of nitrogen) that flow is 0.3L/min, The pelletizing that step 1 is obtained, which is warming up at 1100 DEG C, keeps the temperature 40min progress reduction roasting, and high-temperature flue gas passes through table in the process After aerator is cooling, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas has by washer removing again Evil gas reaches after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
Lead zinc is down to 0.15wt.% and 0.55wt.% respectively in clinker after above-mentioned steps are handled, and magneticly elects the iron of reduced iron Content is 93wt.%.
Embodiment 2
As shown in Figure 1, the method with damaged tire processing Pb-Zn deposits, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits (Pb3.45wt.%, Zn6.55wt.%) ore grinding to granularity be 74um Pb-Zn deposits powder below, Then damaged tire is broken into 0.2mm damaged tire particle, diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water is 10mm pelletizing;Carbonaceous amount according to the mass ratio of C/O is 1.6:1 by Pb-Zn deposits powder in oxygen quality and damaged tire particle in Pb-Zn deposits powder It is uniformly mixed with damaged tire particle, water additional amount is the 4% of Pb-Zn deposits silty amount, and binder is bentonite, and additional amount is Pb-Zn deposits Silty amount 1.5%;
Step 2 is passed through under the conditions of the gas (air of volume ratio 10:90 and the mixed gas of nitrogen) that flow is 0.3L/min, The pelletizing that step 1 is obtained, which is warming up at 1150 DEG C, keeps the temperature 40min progress reduction roasting, and high-temperature flue gas passes through table in the process After aerator is cooling, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas has by washer removing again Evil gas reaches after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
Lead zinc is down to 0.18wt.% and 0.25wt.% respectively in clinker after above-mentioned steps are handled, and magneticly elects the iron of reduced iron Content is 91wt.%.
Embodiment 3
As shown in Figure 1, the method with damaged tire processing Pb-Zn deposits, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits (Pb2.95wt.%, Zn10.42wt.%) ore grinding to granularity be 74um Pb-Zn deposits powder below, Then damaged tire is broken into 0.2mm damaged tire particle, diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water is 10mm pelletizing;Carbonaceous amount according to the mass ratio of C/O is 1.8:1 by Pb-Zn deposits powder in oxygen quality and damaged tire particle in Pb-Zn deposits powder It is uniformly mixed with damaged tire particle, water additional amount is the 4% of Pb-Zn deposits silty amount, and binder is bentonite, and additional amount is Pb-Zn deposits Silty amount 1.5%;
Step 2 is passed through gas (carbon dioxide of volume ratio 5:90 and the mixed gas of nitrogen) condition that flow is 0.3L/min Under, the pelletizing that step 1 is obtained, which is warming up at 1100 DEG C, keeps the temperature 60min progress reduction roasting, and high-temperature flue gas is logical in the process After crossing surface-cooler cooling, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas is removed by washer again Pernicious gas is removed, reaches after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
Lead zinc is down to 0.13wt.% and 0.32wt.% respectively in clinker after above-mentioned steps are handled, and magneticly elects the iron of reduced iron Content is 96wt.%.
Embodiment 4
As shown in Figure 1, the method with damaged tire processing Pb-Zn deposits, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits (Pb3.23wt.%, Zn11.67wt.%) ore grinding to granularity be 74um Pb-Zn deposits powder below, Then damaged tire is broken into 0.1mm damaged tire particle, diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water is 8mm pelletizing;Carbonaceous amount according to the mass ratio of C/O is 1.8:1 by Pb-Zn deposits powder in oxygen quality and damaged tire particle in Pb-Zn deposits powder It is uniformly mixed with damaged tire particle, water additional amount is the 4% of Pb-Zn deposits silty amount, and binder is bentonite, and additional amount is Pb-Zn deposits Silty amount 1.5%;
Step 2 is passed through gas (carbon dioxide of volume ratio 3:90 and the mixed gas of nitrogen) condition that flow is 0.35L/min Under, the pelletizing that step 1 is obtained, which is warming up at 1150 DEG C, keeps the temperature 60min progress reduction roasting, and high-temperature flue gas is logical in the process After crossing surface-cooler cooling, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas is removed by washer again Pernicious gas is removed, reaches after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
Lead zinc is down to 0.09wt.% and 0.18wt.% respectively in clinker after above-mentioned steps are handled, and magneticly elects the iron of reduced iron Content is 96wt.%.
Embodiment 5
As shown in Figure 1, the method with damaged tire processing Pb-Zn deposits, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits (Pb3.23wt.%, Zn11.67wt.%) ore grinding to granularity be 74um Pb-Zn deposits powder below, Then damaged tire is broken into 0.2mm damaged tire particle, diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water is 8mm pelletizing;Carbonaceous amount according to the mass ratio of C/O is 1.8:1 by Pb-Zn deposits powder in oxygen quality and damaged tire particle in Pb-Zn deposits powder It is uniformly mixed with damaged tire particle, water additional amount is the 3% of Pb-Zn deposits silty amount, and binder is bentonite, and additional amount is Pb-Zn deposits Silty amount 1.5%;
Step 2 is passed through gas (carbon dioxide of volume ratio 3:90 and the mixed gas of nitrogen) condition that flow is 0.2L/min Under, the pelletizing that step 1 is obtained, which is warming up at 1150 DEG C, keeps the temperature 60min progress reduction roasting, and high-temperature flue gas is logical in the process After crossing surface-cooler cooling, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas is removed by washer again Pernicious gas is removed, reaches after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
Embodiment 6
As shown in Figure 1, the method with damaged tire processing Pb-Zn deposits, the specific steps of which are as follows:
Step 1, first by Pb-Zn deposits (Pb3.23wt.%, Zn11.67wt.%) ore grinding to granularity be 74um Pb-Zn deposits powder below, Then damaged tire is broken into 0.3mm damaged tire particle, diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water is 12mm pelletizing;Carbonaceous amount according to the mass ratio of C/O is 1.8:1 by Pb-Zn deposits powder in oxygen quality and damaged tire particle in Pb-Zn deposits powder It is uniformly mixed with damaged tire particle, water additional amount is the 5% of Pb-Zn deposits silty amount, and binder is bentonite, and additional amount is Pb-Zn deposits Silty amount 1.5%;
Step 2 is passed through gas (carbon dioxide of volume ratio 3:90 and the mixed gas of nitrogen) condition that flow is 0.6L/min Under, the pelletizing that step 1 is obtained, which is warming up at 950 DEG C, keeps the temperature 80min progress reduction roasting, and high-temperature flue gas passes through in the process After surface-cooler is cooling, it is recycled containing the led-zinc-silver deposit in Pb-Zn dust through dust collecting system, flue gas is removed by washer again Pernicious gas reaches after emptying requires and is discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
In conjunction with attached drawing, the embodiment of the present invention is explained in detail above, but the present invention is not limited to above-mentioned Embodiment within the knowledge of a person skilled in the art can also be before not departing from present inventive concept Put that various changes can be made.

Claims (4)

1. a kind of method with damaged tire processing Pb-Zn deposits, it is characterised in that specific step is as follows:
Step 1, first by Pb-Zn deposits ore grinding to granularity be 74um Pb-Zn deposits powder below, damaged tire is then broken into 0.1mm ~0.3mm damaged tire particle, it is 8~12mm pelletizing that diameter, which is made, in Pb-Zn deposits powder, damaged tire particle, binder and water;
Step 2, in the case where being passed through the gas condition that flow is 0.2~0.6L/min, the pelletizing that step 1 is obtained is warming up to 950~ 40~80min is kept the temperature at 1150 DEG C and carries out reduction roasting, after high-temperature flue gas is by surface-cooler cooling in the process, through receiving Dirt system recycles it containing the led-zinc-silver deposit in Pb-Zn dust, and flue gas removes pernicious gas by washer again, reaches emptying and requires After be discharged into atmosphere, the magnetic separation recovery wherein iron resource after oxygen barrier cooling of the clinker after reaction.
2. the method according to claim 1 with damaged tire processing Pb-Zn deposits, it is characterised in that: the lead in the step 1 Carbonaceous amount is 1.6~1.8:1 by Pb-Zn deposits powder according to the mass ratio of C/O and useless takes turns in oxygen quality and damaged tire particle in zinc ore powder Tire particle is uniformly mixed, and water additional amount is the 3%~5% of Pb-Zn deposits silty amount.
3. the method according to claim 1 with damaged tire processing Pb-Zn deposits, it is characterised in that: step 2 gas is Mixed gas with weak oxide.
4. the method according to claim 3 with damaged tire processing Pb-Zn deposits, it is characterised in that: have in the step 2 The mixed gas of weak oxide is that the air of arbitrary proportion and the mixed gas or carbon dioxide and inert gas of inert gas are mixed Close gas.
CN201910170476.2A 2019-03-07 2019-03-07 A method of Pb-Zn deposits are handled with damaged tire Pending CN109913643A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114921656A (en) * 2022-05-17 2022-08-19 有研亿金新材料有限公司 Method for reducing carbon content of high-purity gold
CN115558796A (en) * 2022-11-04 2023-01-03 昆明理工大学 Method for resource extraction of zinc oxide from waste tire coupled blast furnace ash

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104404246A (en) * 2014-11-24 2015-03-11 北京神雾环境能源科技集团股份有限公司 Method for improving metallization rate of metallurgical slag pellet
CN105483371A (en) * 2015-12-21 2016-04-13 武钢集团昆明钢铁股份有限公司 Method for comprehensively recycling lead and zinc containing blast furnace dust
CN106086457A (en) * 2016-08-16 2016-11-09 白银有色集团股份有限公司 A kind of lead Zinc oxide processing method for pyrometallurgical smelting
CN106755962A (en) * 2016-12-14 2017-05-31 昆明理工大学 A kind of method with recyclable domestic rubbish disposal tin-iron mine
CN107460327A (en) * 2017-07-28 2017-12-12 重庆科技学院 A kind of comprehensive reutilization method of the leaded zinc powder dirt of electric furnace steel making

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104404246A (en) * 2014-11-24 2015-03-11 北京神雾环境能源科技集团股份有限公司 Method for improving metallization rate of metallurgical slag pellet
CN105483371A (en) * 2015-12-21 2016-04-13 武钢集团昆明钢铁股份有限公司 Method for comprehensively recycling lead and zinc containing blast furnace dust
CN106086457A (en) * 2016-08-16 2016-11-09 白银有色集团股份有限公司 A kind of lead Zinc oxide processing method for pyrometallurgical smelting
CN106755962A (en) * 2016-12-14 2017-05-31 昆明理工大学 A kind of method with recyclable domestic rubbish disposal tin-iron mine
CN107460327A (en) * 2017-07-28 2017-12-12 重庆科技学院 A kind of comprehensive reutilization method of the leaded zinc powder dirt of electric furnace steel making

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114921656A (en) * 2022-05-17 2022-08-19 有研亿金新材料有限公司 Method for reducing carbon content of high-purity gold
CN114921656B (en) * 2022-05-17 2024-01-26 有研亿金新材料有限公司 Method for reducing high-purity gold carbon content
CN115558796A (en) * 2022-11-04 2023-01-03 昆明理工大学 Method for resource extraction of zinc oxide from waste tire coupled blast furnace ash

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