CN109913102A - A kind of anion plate and preparation method thereof - Google Patents
A kind of anion plate and preparation method thereof Download PDFInfo
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- CN109913102A CN109913102A CN201910409267.9A CN201910409267A CN109913102A CN 109913102 A CN109913102 A CN 109913102A CN 201910409267 A CN201910409267 A CN 201910409267A CN 109913102 A CN109913102 A CN 109913102A
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Abstract
A kind of preparation method of anion plate, by the way that medical stone, zirconium oxide and rare earth are prepared into composition A, multi-hydroxy carboxy acid's ester and unsaturated polyester (UP) are prepared into pre- coating B, and then the two is mixed to get coating composition C.And it is coated on and handles clean plate surface and obtains anion plate.The plate one side structure is closely knit, and intensity is superior, on the other hand also capable of releasing negative ion, is effectively improved the quality of air, belongs to the plate in new material industry with high added value.
Description
Technical field
The invention belongs to have high added value plate field in new material industry, and in particular to a kind of anion plate and its
Preparation method.
Background technique
In recent years, with the promotion of people's living standard, start extensive concern health, environmental protection.And indoor living environment
Safety and environmental protection all has a great impact to the physically and mentally healthy or mental status of people.Household plate is as Household fit-up and decoration indispensability
Material, the safe antibacterial of materials, laying, maintenance etc. link material directly determine floor environmental protection whether.Currently, city
Antibacterial or sterilization floor on field mostly use the chemicals with bacteriostasis efficacy to apply on the surface of plate materials, to play sterilization
Function.On the one hand, chemicals itself is mostly inorganic or organic matter macromolecular, is incompatible with human health；On the other hand,
The chemicals of these antibacterials can loss failure as time went on.As record in 201710937737.X using carbendazim,
Bravo, streptomysin, zinc oxide etc. are used as antibacterial agent, and OBPA, sodium fluoride etc. promote the antibacterial and mouldproof of plate as mould inhibitor
Effect；For another example it describes in 201310146472.3 and modified chlorine oxygen is prepared using magnesia oxychloride cement slurry and metakaolin and phosphoric acid
Magnesium cement slurry improves the antibiotic health care effect of artificial stone；It for another example is that negative ion powder and amino is rich in 201811339912.6
It strangles alkene and carries out mixing dispersion in ultrasound environments, make full use of the hydrophobicity of amino fullerene, to reduce anion embedding, make it
It is as exposed in coating surface as possible, and fail to be promoted the burst size of anion in itself.In addition, though also there is part currently on the market
Still its releasable negative ion amount is extremely limited on anion floor, it is difficult to generate effective bactericidal effect.
Therefore it is significant and lasting to need to provide a kind of antibacterial effect, the timber intensity anion floor also to be met the requirements.
Summary of the invention
In view of the above-mentioned problems, the object of the present invention is to provide a kind of anion plates and preparation method thereof.
Technical scheme is as follows:
(1) it after crushing medical stone, zirconium oxide abrasive, is mixed in organic solvent with rare earth element, and be in power
Handle 30-60min under the ultrasonic environment of 6.5-7.5kW, using rare earth element to the anion in medical stone and zirconium oxide into
Line activating, to obtain composition A；
(2) after mixing multi-hydroxy carboxy acid's ester in organic solvent with unsaturated type polyester, Fluorspar Powder, the 3- of 10-15wt% is added
The trbasic zinc phosphate of 8wt%, the black glue powder of 3-5wt% and the dispersing agent of 2-5wt%, the defoaming agent of 1-3wt%, 5-8wt% emulsifier,
Pre- coating B of the solid content 40% or more is made after mixing evenly；
(3) the composition A that step (1) is prepared is with 1:(10-15) mass ratio be added step (2) in pre- coating B in,
And the heat-resistant agent of 2-5wt% is added, the foam copper of 1-3wt% stirs evenly and coating composition C is prepared；
(4) by the coating composition C uniform distribution in step (3) is clean in removing surface, polishing is smooth artificial slabstone table
On face, storage is examined after conventional press polish ornamenting, surface cure, trimming flash removed to get anion plate is arrived.
Preferably, the usage amount of the rare earth is 15wt%-25wt%.
Preferably, the additive amount of the medical stone is 20wt%-30wt%.
Preferably, the additive amount of the zirconium oxide is 5wt%-10wt%.
Preferably, multi-hydroxy carboxy acid's ester is vinyl acetate, hydroxy-ethyl acrylate, one in isobornyl acrylate
Kind is a variety of.
Preferably, contain M-phthalic acid in the structure of the unsaturated type polyester.
Preferably, the molar ratio of multi-hydroxy carboxy acid's ester and unsaturated type polyester is 5:(1-1.5).
Preferably, the applied amounts of the coating composition C are 100-180g/m2, coating thickness 1-5mm.
Preferably, the density of the anion plate is greater than 3.5 × 103kg/m3, hardness >=8H, thermal expansion coefficient≤5 ×
10-5, 3000-4000/cm of anion burst size3。
Beneficial effects of the present invention:
By being mixed after medical stone, zirconium oxide abrasive crushing in a solvent with rare earth element, and super in the present invention
The anion in medical stone and zirconium oxide is activated using rare earth in sound wave environment, significantly improves medical stone and zirconium oxide
In anion releasing effect, be higher by 2-4 times than common plate anion burst size.Medical stone, zirconium oxide and rare earth element
Solvent it is evenly dispersed under, make full use of the cavitation effect and vibration characteristics of ultrasonic wave, promote the structure of medical stone, zirconium oxide
Puffing accelerates the release of anion；Moreover, by the promotion of medical stone, zirconium oxide accessibility, facilitate rare earth element into
Enter, to effectively promote the activation effect of anion.
Further, after by mixing multi-hydroxy carboxy acid's ester in a solvent with unsaturated type polyester, Fluorspar Powder, phosphoric acid is added
Pre- coating B is made in zinc, black glue powder and dispersing agent, defoaming agent, emulsifier after mixing evenly, greatly improves plate surface painting
Layer at film hardness and abrasion resistant effect, be conducive to being used for a long time for plate.
In addition, foam copper as a kind of novel porous functional material, has the function of expanding noise reduction and micropore noise reduction, it will
It is used in plate coating can be effectively reduced during plate is trampled etc. and uses noise.In addition, the present invention is in implementation process
In, the coating of artificial slabstone, surface cure, trimming flash removed, examines the technical parameters such as storage and common slabstone at press polish ornamenting
The coating process of material is identical.Plate one side structure prepared by the present invention is closely knit, and intensity is superior, on the other hand also releasable
Anion is effectively improved the quality of air, belongs to the plate in new material industry with high added value.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without creative efforts belongs to the model that the present invention protects
It encloses.
Embodiment one
A kind of preparation method of anion plate, which is characterized in that including following preparation step:
(1) it after crushing medical stone, zirconium oxide abrasive, is mixed in organic solvent with rare earth element, and 6.5kW's
60min is handled under ultrasonic environment, the anion in medical stone and zirconium oxide is activated using rare earth, to obtain composition
A；Wherein the usage amount of the rare earth is 15wt%, and the additive amount of the medical stone is 30wt%, and the additive amount of the zirconium oxide is
5wt%, organic solvent 50wt%；
(2) after mixing multi-hydroxy carboxy acid's ester that molar ratio is 5:1 in organic solvent with unsaturated type polyester, 10wt% is added
Fluorspar Powder, the trbasic zinc phosphate of 8wt%, the black glue powder of 5wt% and the dispersing agent of 2wt%, the defoaming agent of 3wt%, 8wt% emulsification
The pre- coating B that solid content is 42% is made in agent after mixing evenly；Multi-hydroxy carboxy acid's ester is vinyl acetate and acrylic acid hydroxyl
The mixture of ethyl ester contains M-phthalic acid in the structure of the unsaturation type polyester；
(3) the composition A that step (1) is prepared is added in the pre- coating B in step (2) with the mass ratio of 1:10, and is added
Enter the heat-resistant agent of 5wt%, the foam copper of 1wt% stirs evenly and coating composition C is prepared；
(4) by the coating composition C uniform distribution in step (3) is clean in removing surface, polishing is smooth artificial slabstone table
On face, storage is examined after conventional press polish ornamenting, surface cure, trimming flash removed to get anion plate is arrived；The painting
The applied amounts of feed composition C are 120g/m2, coating thickness 1mm.
The density of the anion plate is 4.5 × 103kg/m3, hardness 8H, thermal expansion coefficient is 4.5 × 10-5, bear
Ion release is about 4000/cm3。
Embodiment two
A kind of preparation method of anion plate, which is characterized in that including following preparation step:
(1) it after crushing medical stone, zirconium oxide abrasive, is mixed in organic solvent with rare earth element, and be in power
45min is handled under the ultrasonic environment of 7kW, the anion in medical stone and zirconium oxide is activated using rare earth, to obtain
Composition A；Wherein the usage amount of the rare earth is 20wt%, and the additive amount of the medical stone is 20wt%, and the zirconium oxide adds
Dosage is 10wt%, organic solvent 50wt%；
(2) it after mixing multi-hydroxy carboxy acid's ester that molar ratio is 5:1.5 in organic solvent with unsaturated type polyester, is added
The Fluorspar Powder of 15wt%, the trbasic zinc phosphate of 3wt%, the black glue powder of 3wt% and the dispersing agent of 5wt%, the defoaming agent of 1wt%, 5wt%
The pre- coating B that solid content is 45% is made in emulsifier after mixing evenly；Multi-hydroxy carboxy acid's ester is vinyl acetate and propylene
The mixture of sour hydroxyl ethyl ester contains M-phthalic acid in the structure of the unsaturation type polyester；
(3) the composition A that step (1) is prepared is added in the pre- coating B in step (2) with the mass ratio of 1:15, and is added
Enter the heat-resistant agent of 2wt%, the foam copper of 3wt% stirs evenly and coating composition C is prepared；
(4) by the coating composition C uniform distribution in step (3) is clean in removing surface, polishing is smooth artificial slabstone table
On face, storage is examined after conventional press polish ornamenting, surface cure, trimming flash removed to get anion plate is arrived；The painting
The applied amounts of feed composition C are 140g/m2, coating thickness 3mm.
The density of the anion plate is 4.0 × 103kg/m3, hardness 8H, thermal expansion coefficient is 4.0 × 10-5, bear
Ion release is about 3800/cm3。
Embodiment three
A kind of preparation method of anion plate, which is characterized in that including following preparation step:
(1) it after crushing medical stone, zirconium oxide abrasive, is mixed in organic solvent with rare earth element, and 7.5kW's
30min is handled under ultrasonic environment, the anion in medical stone and zirconium oxide is activated using rare earth, to obtain composition
A；Wherein the usage amount of the rare earth is 25wt%, and the additive amount of the medical stone is 25wt%, and the additive amount of the zirconium oxide is
9wt%, organic solvent 41wt%；
(2) it after mixing multi-hydroxy carboxy acid's ester that molar ratio is 5:1.2 in organic solvent with unsaturated type polyester, is added
The Fluorspar Powder of 12wt%, the trbasic zinc phosphate of 7wt%, the black glue powder of 4wt% and the dispersing agent of 4wt%, the defoaming agent of 3wt%, 6wt%
The pre- coating B that solid content is 44% is made in emulsifier after mixing evenly；Multi-hydroxy carboxy acid's ester is vinyl acetate and propylene
The mixture of sour hydroxyl ethyl ester contains M-phthalic acid in the structure of the unsaturation type polyester；
(3) the composition A that step (1) is prepared is added in the pre- coating B in step (2) with the mass ratio of 1:14, and is added
Enter the heat-resistant agent of 4wt%, the foam copper of 2wt% stirs evenly and coating composition C is prepared；
(4) by the coating composition C uniform distribution in step (3) is clean in removing surface, polishing is smooth artificial slabstone table
On face, storage is examined after conventional press polish ornamenting, surface cure, trimming flash removed to get anion plate is arrived；The painting
The applied amounts of feed composition C are 160g/m2, coating thickness 4mm.
The density of the anion plate is 4.8 × 103kg/m3, hardness 8H, thermal expansion coefficient is 4.7 × 10-5, bear
Ion release is about 3500/cm3。
Comparative example one
A kind of preparation method of anion plate, which is characterized in that including following preparation step:
(1) it after crushing medical stone, zirconium oxide abrasive, is mixed in organic solvent with rare earth element, to be combined
Object A；Wherein the usage amount of the rare earth is 15wt%, and the additive amount of the medical stone is 30wt%, the additive amount of the zirconium oxide
For 5wt%, organic solvent 50wt%；
(2) after mixing multi-hydroxy carboxy acid's ester that molar ratio is 5:1 in organic solvent with unsaturated type polyester, 10wt% is added
Fluorspar Powder, the trbasic zinc phosphate of 8wt%, the black glue powder of 5wt% and the dispersing agent of 2wt%, the defoaming agent of 3wt%, 8wt% emulsification
The pre- coating B that solid content is 42% is made in agent after mixing evenly；Multi-hydroxy carboxy acid's ester is vinyl acetate and acrylic acid hydroxyl
The mixture of ethyl ester contains M-phthalic acid in the structure of the unsaturation type polyester；
(3) the composition A that step (1) is prepared is added in the pre- coating B in step (2) with the mass ratio of 1:10, and is added
Enter the heat-resistant agent of 5wt%, the foam copper of 1wt% stirs evenly and coating composition C is prepared；
(4) by the coating composition C uniform distribution in step (3) is clean in removing surface, polishing is smooth artificial slabstone table
On face, storage is examined after conventional press polish ornamenting, surface cure, trimming flash removed to get anion plate is arrived；The painting
The applied amounts of feed composition C are 120g/m2, coating thickness 1mm.
The density of the anion plate is 4.5 × 103kg/m3, hardness 8H, thermal expansion coefficient is 4.5 × 10-5, bear
Ion release is about 800/cm3。
Comparative example two
A kind of preparation method of anion plate, which is characterized in that including following preparation step:
(1) it after crushing medical stone, zirconium oxide abrasive, is mixed in organic solvent with rare earth element, and be in power
45min is handled under the ultrasonic environment of 7kW, the anion in medical stone and zirconium oxide is activated using rare earth, to obtain
Composition A；Wherein the usage amount of the rare earth is 20wt%, and the additive amount of the medical stone is 20wt%, and the zirconium oxide adds
Dosage is 10wt%, organic solvent 50wt%；
(2) after mixing multi-hydroxy carboxy acid's ester that molar ratio is 5:1.5 in organic solvent with unsaturated type polyester, 5wt% is added
Dispersing agent, the defoaming agent of 1wt%, 5wt% emulsifier, the pre- coating B that solid content is 45% is made after mixing evenly；It is described more
Hydroxycarboxylic acid esters are the mixture of vinyl acetate and hydroxy-ethyl acrylate, contain isophthalic in the structure of the unsaturation type polyester
Dioctyl phthalate；
(3) the composition A that step (1) is prepared is added in the pre- coating B in step (2) with the mass ratio of 1:15, and is added
Enter the heat-resistant agent of 2wt%, the foam copper of 3wt% stirs evenly and coating composition C is prepared；
(4) by the coating composition C uniform distribution in step (3) is clean in removing surface, polishing is smooth artificial slabstone table
On face, storage is examined after conventional press polish ornamenting, surface cure, trimming flash removed to get anion plate is arrived；The painting
The applied amounts of feed composition C are 140g/m2, coating thickness 3mm.
The density of the anion plate is 4.0 × 103kg/m3, hardness 5H, thermal expansion coefficient is 7.8 × 10-5, bear
Ion release is about 3500/cm3。
Comparative example three
A kind of preparation method of anion plate, which is characterized in that including following preparation step:
(1) it after crushing medical stone, zirconium oxide abrasive, is mixed in organic solvent with rare earth element, and 7.5kW's
30min is handled under ultrasonic environment, the anion in medical stone and zirconium oxide is activated using rare earth, to obtain composition
A；Wherein the usage amount of the rare earth is 25wt%, and the additive amount of the medical stone is 25wt%, and the additive amount of the zirconium oxide is
9wt%, organic solvent 41wt%；
(2) after mixing in multi-hydroxy carboxy acid's ester and organic solvent, the Fluorspar Powder of 12wt%, the trbasic zinc phosphate of 7wt%, 4wt% is added
The dispersing agent of black glue powder and 4wt%, the defoaming agent of 3wt%, 6wt% emulsifier, it is 44% that solid content is made after mixing evenly
Pre- coating B；Multi-hydroxy carboxy acid's ester is the mixture of vinyl acetate and hydroxy-ethyl acrylate, the unsaturation type polyester
Contain M-phthalic acid in structure；
(3) the composition A that step (1) is prepared is added in the pre- coating B in step (2) with the mass ratio of 1:14, and is added
Enter the heat-resistant agent of 4wt%, the foam copper of 2wt% stirs evenly and coating composition C is prepared；
(4) by the coating composition C uniform distribution in step (3) is clean in removing surface, polishing is smooth artificial slabstone table
On face, storage is examined after conventional press polish ornamenting, surface cure, trimming flash removed to get anion plate is arrived；The painting
The applied amounts of feed composition C are 160g/m2, coating thickness 4mm.
The density of the anion plate is 4.8 × 103kg/m3, hardness 7H, thermal expansion coefficient is 6.3 × 10-5, bear
Ion release is about 2500/cm3。
By above-described embodiment 1-3 and comparative example 1-3 it is found that the plate in the present invention in order to reach brilliant physical hardness,
The lower coefficient of expansion and efficient anion burst size, are handled by activation under ultrasonic environment, add Fluorspar Powder, phosphoric acid
The hardening material such as zinc, black glue powder, and it is added to unsaturated type polyester, finally make plate comprehensive performance stronger, meets physical and chemical strong
While spending, there is preferable stability and antibiotic health care effect.
Artificial board is made by the embodiments of the present invention, one side structure is closely knit, and intensity is superior, on the other hand may be used also
Anion is discharged, the quality of air is effectively improved, belongs to the plate in new material industry with high added value, can be widely used for ground
Plate material, stairway step, ground laying etc. Material Field.
Finally it should be noted that the above examples are only used to illustrate the technical scheme of the present invention rather than protects to the present invention
The limitation of range, although the invention is described in detail with reference to the preferred embodiments, those skilled in the art should be managed
Solution, can with modification or equivalent replacement of the technical solution of the present invention are made, without departing from technical solution of the present invention essence and
Range.
Claims (9)
1. a kind of preparation method of anion plate, which is characterized in that including following preparation step:
(1) it after crushing medical stone, zirconium oxide abrasive, is mixed in organic solvent with rare earth element, and be in power
Handle 30-60min under the ultrasonic environment of 6.5-7.5kW, using rare earth element to the anion in medical stone and zirconium oxide into
Line activating, to obtain composition A；
(2) after mixing multi-hydroxy carboxy acid's ester in organic solvent with unsaturated type polyester, Fluorspar Powder, the 3- of 10-15wt% is added
The trbasic zinc phosphate of 8wt%, the black glue powder of 3-5wt% and the dispersing agent of 2-5wt%, the defoaming agent of 1-3wt%, 5-8wt% emulsifier,
Pre- coating B of the solid content 40% or more is made after mixing evenly；
(3) the composition A that step (1) is prepared is with 1:(10-15) mass ratio be added step (2) in pre- coating B in,
And the heat-resistant agent of 2-5wt% is added, the foam copper of 1-3wt% stirs evenly and coating composition C is prepared；
(4) by the coating composition C uniform distribution in step (3) is clean in removing surface, polishing is smooth artificial slabstone table
On face, storage is examined after conventional press polish ornamenting, surface cure, trimming flash removed to get anion plate is arrived.
2. the preparation method of anion plate according to claim 1, which is characterized in that the usage amount of the rare earth is
15wt%-25wt%。
3. the preparation method of anion plate according to claim 1, which is characterized in that the additive amount of the medical stone is
20wt%-30wt%。
4. the preparation method of anion plate according to claim 1, which is characterized in that the additive amount of the zirconium oxide is
5wt%-10wt%。
5. the preparation method of anion plate according to claim 1, which is characterized in that multi-hydroxy carboxy acid's ester is second
One of vinyl acetate, hydroxy-ethyl acrylate, isobornyl acrylate are a variety of.
6. the preparation method of anion plate according to claim 1, which is characterized in that the knot of the unsaturation type polyester
Contain M-phthalic acid in structure.
7. the preparation method of anion plate according to claim 1, which is characterized in that multi-hydroxy carboxy acid's ester with not
The molar ratio of saturation type polyester is 5:(1-1.5).
8. the preparation method of anion plate according to claim 1, which is characterized in that the coating composition C's applies
Painting amount is 100-180g/m2, coating thickness 1-5mm.
9. the plate that the preparation method of anion plate according to claim 1-8 is prepared, feature exist
In the density of the anion plate is greater than 3.5 × 103kg/m3, hardness >=8H, thermal expansion coefficient≤5 × 10-5, anion releases
High-volume 3000-4000/cm3。
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