CN109912959A - The latex balloon of metallic travel water-based metal mill base and preparation method and latex balloon - Google Patents
The latex balloon of metallic travel water-based metal mill base and preparation method and latex balloon Download PDFInfo
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- CN109912959A CN109912959A CN201910165697.0A CN201910165697A CN109912959A CN 109912959 A CN109912959 A CN 109912959A CN 201910165697 A CN201910165697 A CN 201910165697A CN 109912959 A CN109912959 A CN 109912959A
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Abstract
The invention discloses a kind of latex balloon of metallic travel water-based metal mill base and preparation methods and latex balloon.The water-based metal mill base is made of the component A and component B of parts by weight；Component A includes 1-5 parts of aqueous CAB resin dispersion liquid, 20-30 parts of based aluminum pigment, 10-20 parts of water-based acrylic resin lotion, 20-30 parts of waterborne polyurethane resin dispersion liquid, 1-5 parts of nano silica, 10-15 parts of cosolvent, 0.5-3 parts of auxiliary agent, 10-30 parts of deionized water；Component B includes 10-30 parts of aqueous transparent pigment mill base.Novel aqueous metal mill base made from preparation method through the invention, effectively and thoroughly solve the problems, such as that aluminium pigment is added to gelatinization in strong basicity natural emulsion, the metal latex gas being prepared into is set not only to have strong metallic travel, and surface is smooth, do not fall aluminium pigment, the features such as the adhesive force and good flexibility of balloon product.The latex metal balloon being prepared into simultaneously with water-based metal mill base of the invention is nontoxic, tasteless.
Description
Technical field
The present invention relates to one kind can make water-based metal mill base of the latex part with metallic travel, and the present invention also relates to simultaneously
And the preparation method of the latex balloon using above-mentioned mill base, the invention further relates to use above-mentioned water-based metal mill base and preparation side
The latex balloon of method production.
Background technique
Currently, external especially America and Europe and country in Southeast Asia are gradually increased the demand of metal balloon, due to its color
It is bright-coloured, beautiful, it firmly gets user and likes.Although China is the main grown place for producing latex balloon, due to making metal balloon
The generation that not can solve between aluminium powder (in both sexes) and balloon raw material natural emulsion (strong basicity) of the bulk aqueous aluminium paste country it is swollen
Gas gelatinization technical problem, always by the import of external Pioneer Electronic Corp., the U.S..My company, which voluntarily researches and develops, has captured this problem, fills out
Domestic blank is mended.
Summary of the invention
The object of the present invention is to provide a kind of latex part water-based metal mill bases of metallic travel, are prepared with the mill base
Latex metal balloon, product surface is smooth, high photosensitiveness, metal sense are strong, water resistance, flexibility are excellent, and product is non-toxic and tasteless.
The water-based metal mill base is added to not gelatinization in natural emulsion simultaneously, and the storage stability time is up to 1 year.
Another purpose of the invention is to carry out preparing to above-mentioned water-based metal mill base while by above-mentioned water-based metal color
Slurry is applied on latex balloon.
The latex balloon of metallic travel water-based metal mill base, the composition of raw materials of the mill base by parts by weight component A
It is constituted with component B；Component A includes 20-30 parts of based aluminum pigment, 20-30 parts of waterborne polyurethane resin, 10-20 parts
Aqueous acrylic emulsion, 1-5 parts of aqueous CAB, 10-15 parts of cosolvent, 0.5-3 parts of compound auxiliary, 1-5 parts of nanometer
Silica, 10-30 parts of deionized water；The aqueous transparent pigment mill base that component B is 10-30 parts.
The based aluminum pigment is contained in 50%-80% admittedly, and fineness D90 is less than 30 μm, D50 less than 15 μm.
The waterborne polyurethane resin is the aqueous aliphatic polyurethane resin with anionic, admittedly containing 35% ± 2%,
100% modulus > 4mpa, elongation > 400%.
The aqueous acrylic emulsion is water nano pure-acrylic emulsion, admittedly contain 48 ± 1%, partial size 50-80nm.
The aqueous CAB of 20% concentration is aqueous acetic acid cellulose butyrate, and wherein CMCAB content is 20%.
The aqueous cosolvent is ethyl alcohol, ethylene glycol, n-butanol, isobutanol, propylene glycol, diethylene glycol ether at least two
Kind or more mixture.
The auxiliary agent is at least one of levelling agent, low molecular weight dispersing agent and high molecular weight dispersant.
For the partial size of the nano silica in 10-12nm, crystal is spherical, Gu containing being 30 ± 1%；The aqueous transparent
Consolidating for dispersible pigment color paste is contained in 20-30%, and Particle size requirements are less than 300nm.
The compound auxiliary is hydroxy acid salt, polyoxyethylene-type, poly N-ethylene yl acetamide mix.
The latex balloon of metallic travel water-based metal mill base preparation method, the water-based metal color of the latex balloon
The composition of raw materials of slurry is made of the component A of parts by weight and component B；The following steps are included:
Step 1: raw material is prepared according to following component and parts by weight: the based aluminum pigment that A:20-30 part of component, 20-30 parts of water
Property polyurethane resin, 10-20 parts of aqueous acrylic emulsion, 1-5 parts of aqueous CMCAB, 10-15 parts of cosolvent, 0.5-3
The compound auxiliary of part, 1-5 parts of nano silica, 10-30 parts of deionized water；The aqueous transparent that component B is 10-30 parts
Dispersible pigment color paste；
Step 2: cosolvent, based aluminum pigment, nano silica and aqueous CAB mixing in the step 1 component A, slowly
Speed stirs evenly, and stands, impregnates 12-48 hours；
Step 3: by mixture high-speed stirred 1-5 hours in the step 2, revolving speed is controlled less than 1000 revs/min, is thoroughly stirred
It mixes uniformly；
Step 4: aqueous polyurethane, water-based acrylic resin, compound auxiliary and the deionized water in the step 1 are added to
In product after the step 3 stirring, high-speed stirred 1-3 hours, revolving speed was less than 1000 revs/min；
Step 5: the step 1 component B aqueous transparent mill base is added in the product after the step 4 stirring, high-speed stirring
20-30min is mixed, revolving speed can be packed less than 1000 revs/min.
Latex balloon uses the latex balloon of metallic travel water-based metal mill base and latex mixes and drying
It forms.
The beneficial effects of the present invention are:
1, aqueous CAB, that is, CMCAB of the invention and nano silica effectively inhibit day by the package to aluminium powder surface
The reaction of amine and KOH to aluminium powder in right latex, solves the technical problem of not gelatinization.
2, the selection and use of water nano pure-acrylic emulsion, neither influences the flash effect of aluminium powder, and plays further
Intrusion of the aluminium powder not by the amine in latex is protected, while increasing the intermiscibility with natural emulsion.
3, the selection and use of aqueous fatty acid polyurethane resin mentions simultaneously first is that increasing the intermiscibility with natural emulsion
Flexibility, elasticity and the glossiness of the latex balloon product itself risen.
4, the selection and use of levelling agent and dispersing agent, levelling agent BASF AGAS1130, or
BYK2013, dispersing agent are compound auxiliary hydroxy acid salt, polyoxyethylene-type, poly N-ethylene yl acetamide, and ratio 1-2:1-3:1-4 is protected
The high photosensitiveness and latex balloon smoothness of latex balloon of the present invention are hindered.
Specific embodiment
Embodiment 1
The latex balloon of metallic travel water-based metal mill base, the composition of raw materials of the mill base by parts by weight component A and group
Part B is constituted；Component A include 20 parts of based aluminum pigment, 20 parts of waterborne polyurethane resin, 10 parts of aqueous acrylic emulsion,
1 part of aqueous CAB, 10 parts of cosolvent, 0.5 part of compound auxiliary, 1 part of nano silica, 10 parts of deionized water；
Remaining number is component B, and component B is aqueous transparent pigment mill base.Based aluminum pigment is contained in 50% admittedly, and fineness D90 is less than 30 μ
M, D50 is less than 15 μm.Waterborne polyurethane resin is the aqueous aliphatic polyurethane resin with anionic, admittedly containing 33%,
100% modulus > 4mpa, elongation > 400%.Aqueous acrylic emulsion is water nano pure-acrylic emulsion, admittedly contain 47%, partial size
50-80mm.The aqueous CAB of 20% concentration is aqueous acetic acid cellulose butyrate, and wherein CMCAB content is 20%.Aqueous cosolvent
For the mixture of ethyl alcohol diethylene glycol ether.Auxiliary agent is levelling agent BASFA1130.The partial size of nano silica is in 10nm, crystalline substance
Body is spherical, Gu containing being 29%；Consolidating for aqueous transparent pigment mill base is contained in 20%, and Particle size requirements are less than 300nm.Compound auxiliary
It is mixed for hydroxy acid salt, polyoxyethylene-type, poly N-ethylene yl acetamide, mixed proportion 1:1.5:1.5.Flash metal luster
The latex balloon of effect water-based metal mill base preparation method, the composition of raw materials of the water-based metal mill base of the latex balloon by
The component A and component B of parts by weight are constituted；The following steps are included:
Step 1: deployed according to the ratio component A and component B of the embodiment；
Step 2: cosolvent, based aluminum pigment, nano silica and aqueous CAB mixing in the step 1 component A, slowly
Speed stirs evenly, and stands, impregnates 12 hours；
Step 3: by mixture high-speed stirred 1 hour in the step 2, revolving speed control is thoroughly stirred less than 1000 revs/min
Uniformly；
Step 4: aqueous polyurethane, water-based acrylic resin, compound auxiliary and the deionized water in the step 1 are added to
In product after the step 3 stirring, high-speed stirred 1 hour, revolving speed was less than 1000 revs/min；
Step 5: the step 1 component B aqueous transparent mill base is added in the product after the step 4 stirring, high-speed stirring
20min is mixed, revolving speed can be packed less than 1000 revs/min.
Latex balloon uses the latex balloon of metallic travel water-based metal mill base and latex mixes and drying
It forms.
Embodiment 2
The latex balloon of metallic travel water-based metal mill base, the composition of raw materials of the mill base by parts by weight component A and group
Part B is constituted；Component A include 30 parts of based aluminum pigment, 30 parts of waterborne polyurethane resin, 20 parts of aqueous acrylic emulsion,
5 parts of aqueous CAB, 15 parts of cosolvent, 3 parts of compound auxiliary, 5 parts of nano silica, 30 parts of deionized water；It is surplus
Remaining number is component B, and component B is aqueous transparent pigment mill base.Based aluminum pigment is contained in 80% admittedly, fineness D90 less than 30 μm,
D50 is less than 15 μm.Waterborne polyurethane resin is the aqueous aliphatic polyurethane resin with anionic, admittedly contain 37%, 100%
Modulus > 4mpa, elongation > 400%.Aqueous acrylic emulsion is water nano pure-acrylic emulsion, admittedly contain 49%, partial size 80mm.
The aqueous CAB of 20% concentration is aqueous acetic acid cellulose butyrate, and wherein CMCAB content is 20%.Aqueous cosolvent is second two
The mixture of alcohol, n-butanol.Levelling agent is BYK2013.For the partial size of nano silica in 12nm, crystal is spherical, Gu containing being
31%；Consolidating for aqueous transparent pigment mill base is contained in 30%, and Particle size requirements are less than 300nm.Compound auxiliary is hydroxy acid salt, polyoxy second
Ene-type, poly N-ethylene yl acetamide mix, mixed proportion 2:1:1.
The latex balloon of metallic travel water-based metal mill base preparation method, the water-based metal color of the latex balloon
The composition of raw materials of slurry is made of the component A of parts by weight and component B；The following steps are included:
Step 1: deployed according to the ratio component A and component B of the embodiment；
Step 2: cosolvent, based aluminum pigment, nano silica and aqueous CAB mixing in the step 1 component A, slowly
Speed stirs evenly, and stands, impregnates 48 hours；
Step 3: by mixture high-speed stirred 5 hours in the step 2, revolving speed control is thoroughly stirred less than 1000 revs/min
Uniformly；
Step 4: aqueous polyurethane, water-based acrylic resin, compound auxiliary and the deionized water in the step 1 are added to
In product after the step 3 stirring, high-speed stirred 3 hours, revolving speed was less than 1000 revs/min；
Step 5: the step 1 component B aqueous transparent mill base is added in the product after the step 4 stirring, high-speed stirring
30min is mixed, revolving speed can be packed less than 1000 revs/min.
Latex balloon uses the latex balloon of metallic travel water-based metal mill base and latex mixes and drying
It forms.
Embodiment 3
The latex balloon of metallic travel water-based metal mill base, the composition of raw materials of the mill base by parts by weight component A and group
Part B is constituted；Component A include 25 parts of based aluminum pigment, 25 parts of waterborne polyurethane resin, 15 parts of aqueous acrylic emulsion,
3 parts of aqueous CAB, 12 parts of cosolvent, 1 part of compound auxiliary, 2 parts of nano silica, 24 parts of deionized water；Group
The aqueous transparent pigment mill base that part B is 16 parts.Based aluminum pigment is contained in 70% admittedly, and fineness D90 is less than 30 μm, D50 less than 15 μ
m.Waterborne polyurethane resin be the aqueous aliphatic polyurethane resin with anionic, admittedly containing 35%, 100% modulus > 4mpa,
Elongation > 400%.Aqueous acrylic emulsion is water nano pure-acrylic emulsion, admittedly contain 48%, partial size 70mm.20% concentration
Aqueous CAB is aqueous acetic acid cellulose butyrate, and wherein CMCAB content is 20%.Aqueous cosolvent is ethylene glycol, propylene glycol
Mixture.Levelling agent BYK2013.For the partial size of nano silica in 11nm, crystal is spherical, Gu containing being 30%；Aqueous transparent
Consolidating for dispersible pigment color paste is contained in 26%, and Particle size requirements are less than 300nm.Compound auxiliary is hydroxy acid salt, polyoxyethylene-type, poly N-ethylene
Yl acetamide mixes, mixed proportion 1:1:3
The latex balloon of metallic travel water-based metal mill base preparation method, the water-based metal mill base of the latex balloon
Composition of raw materials is made of the component A of parts by weight and component B；The following steps are included:
Step 1: deployed according to the ratio component A and component B of the embodiment；
Step 2: cosolvent, based aluminum pigment, nano silica and aqueous CAB mixing in the step 1 component A, slowly
Speed stirs evenly, and stands, impregnates 30 hours；
Step 3: by mixture high-speed stirred 4 hours in the step 2, revolving speed control is thoroughly stirred less than 1000 revs/min
Uniformly；
Step 4: aqueous polyurethane, water-based acrylic resin, compound auxiliary and the deionized water in the step 1 are added to
In product after the step 3 stirring, high-speed stirred 2 hours, revolving speed was less than 1000 revs/min；
Step 5: the step 1 component B aqueous transparent mill base is added in the product after the step 4 stirring, high-speed stirring
26min is mixed, revolving speed can be packed less than 1000 revs/min.
Latex balloon uses the latex balloon of metallic travel water-based metal mill base and latex mixes and drying
It forms.
Comparative test is as follows:
Comparative example 1-3 the performance test results
One argentine balloon is prepared by component A to example 1
One champagne gold balloon is made by component A and component B to example 2.Aqueous transparent pigment mill base selects transparent yellow in component B
It is formed with transparent red.
One blue metal balloon is made by component A and component B to example 3.Aqueous transparent pigment mill base selects in component B
It is formed with transparent blue.
Claims (10)
1. the latex balloon of metallic travel water-based metal mill base, it is characterised in that: the composition of raw materials of the mill base is by weight
The component A and component B of part are constituted；Component A includes 20-30 parts of based aluminum pigment, 20-30 parts of waterborne polyurethane resin, 10-
20 parts of aqueous acrylic emulsion, 1-5 parts of aqueous CAB, 10-15 parts of cosolvent, 0.5-3 parts of compound auxiliary, 1-5 parts
Nano silica, 10-30 parts of deionized water；The aqueous transparent pigment mill base that component B is 10-30 parts.
2. the latex balloon of metallic travel according to claim 1 water-based metal mill base, it is characterised in that: institute
It states based aluminum pigment and is contained in 50%-80% admittedly, fineness D90 is less than 30 μm, D50 less than 15 μm.
3. the latex balloon of metallic travel according to claim 1 water-based metal mill base, it is characterised in that: institute
Stating waterborne polyurethane resin is the aqueous aliphatic polyurethane resin with anionic, admittedly contain 35% ± 2%, 100% modulus >
4mpa, elongation > 400%.
4. the latex balloon of metallic travel according to claim 1 water-based metal mill base, it is characterised in that: institute
Stating aqueous acrylic emulsion is water nano pure-acrylic emulsion, admittedly contain 48 ± 1%, partial size 50-80mm.
5. the latex balloon of metallic travel according to claim 1 water-based metal mill base, it is characterised in that: institute
The aqueous CAB for stating 20% concentration is aqueous acetic acid cellulose butyrate, and wherein CMCAB content is 20%.
6. according to claim 1, it is characterised in that: the aqueous cosolvent is ethyl alcohol, ethylene glycol, n-butanol, different
Butanol, propylene glycol, at least two or more diethylene glycol ethers mixture.
7. according to claim 1, it is characterised in that: the auxiliary agent is levelling agent, low molecular weight dispersing agent and high score
At least one of son amount dispersing agent.
8. according to claim 1, it is characterised in that: the partial size of the nano silica is in 10-12nm, crystal
It is spherical, Gu containing being 30 ± 1%；Consolidating for the aqueous transparent pigment mill base is contained in 20-30%, and Particle size requirements are less than 300nm.
9. the latex balloon of metallic travel water-based metal mill base preparation method, it is characterised in that: the latex balloon
The composition of raw materials of water-based metal mill base is made of the component A of parts by weight and component B；The following steps are included:
Step 1: raw material is prepared according to following component and parts by weight: the based aluminum pigment that A:20-30 part of component, 20-30 parts of water
Property polyurethane resin, 10-20 parts of aqueous acrylic emulsion, 1-5 parts, 10-15 parts of cosolvent, 0.5-3 parts of compounding help
Agent, 1-5 parts of nano silica, 10-30 parts of deionized water；The aqueous transparent pigment mill base that component B is 10-30 parts；
Step 2: cosolvent, based aluminum pigment, nano silica and aqueous CAB mixing in the step 1 component A, slowly
Speed stirs evenly, and stands, impregnates 12-48 hours；
Step 3: by mixture high-speed stirred 1-5 hours in the step 2, revolving speed is controlled less than 1000 revs/min, is thoroughly stirred
It mixes uniformly；
Step 4: aqueous polyurethane, water-based acrylic resin, compound auxiliary and the deionized water in the step 1 are added to
In product after the step 3 stirring, high-speed stirred 1-3 hours, revolving speed was less than 1000 revs/min；
Step 5: the step 1 component B aqueous transparent mill base is added in the product after the step 4 stirring, high-speed stirring
20-30min is mixed, revolving speed can be packed less than 1000 revs/min.
10. latex balloon, it is characterised in that: the cream of its metallic travel prepared according to the method described in claim 9
Simultaneously drying forms for glue balloon water-based metal mill base and latex mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910165697.0A CN109912959B (en) | 2019-03-06 | 2019-03-06 | Water-based metal color paste with metal flashing effect for latex balloons, preparation method of water-based metal color paste and latex balloons |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910165697.0A CN109912959B (en) | 2019-03-06 | 2019-03-06 | Water-based metal color paste with metal flashing effect for latex balloons, preparation method of water-based metal color paste and latex balloons |
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|---|---|
| CN109912959A true CN109912959A (en) | 2019-06-21 |
| CN109912959B CN109912959B (en) | 2022-07-29 |
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| CN201910165697.0A Active CN109912959B (en) | 2019-03-06 | 2019-03-06 | Water-based metal color paste with metal flashing effect for latex balloons, preparation method of water-based metal color paste and latex balloons |
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| CN109912959B (en) | 2022-07-29 |
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