CN109897739A - Intelligent robot cleaning agent and preparation method thereof - Google Patents

Intelligent robot cleaning agent and preparation method thereof Download PDF

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Publication number
CN109897739A
CN109897739A CN201910270205.4A CN201910270205A CN109897739A CN 109897739 A CN109897739 A CN 109897739A CN 201910270205 A CN201910270205 A CN 201910270205A CN 109897739 A CN109897739 A CN 109897739A
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China
Prior art keywords
photoinitiator
cleaning
intelligent robot
surfactant
cleaning agent
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CN201910270205.4A
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CN109897739B (en
Inventor
刘学
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Yantai Xuanwei Intelligent Technology Co.,Ltd.
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Huazhi (yantai) Intelligent Technology Co Ltd
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Abstract

The present invention relates to intelligent robot cleaning agents and preparation method thereof, and cleaning agent is made of surfactant and water, by it is characterized in that, containing defoaming agent.It is apparent that the present invention can be such that the image of cleaned material is imaged in the vision system of cleaning robot, be used cooperatively, can improve the cleaning efficiency with cleaning robot, and cleans cleaner.

Description

Intelligent robot cleaning agent and preparation method thereof
Technical field
The present invention relates to intelligent robot cleaning agents and preparation method thereof.
Background technique
Cleaning robot is very high in American-European Korea Spro's popularization degree, and China was also applying in recent years, in particular for the family of building The cleaning of outer glass.Since building is higher, there is very big risk using artificial cleaning, especially encounter in the process of cleaning Strong wind, then may to cleaning personnel personal safety constitute a threat to, therefore at present using cleaning robot to outdoors building into Row cleaning becomes the first choice of each large enterprises.
Scavenger surface information is fed back to vision positioning system, vision positioning system root in cleaning by cleaning robot Cleaning operation is carried out according to the information of feedback, cleaning agent currently on the market is mostly the product of organic acid and surfactant compound, This products application has the following problems the 1) presence due to organic acid in intelligent robot, topples in use, may be to skin It damages;Equipment may be caused to corrode when use;2) existing cannot make the vision positioning system of cleaning robot obtain standard True information has seriously affected the cleaning efficiency of cleaning robot.
Since intelligent robot belongs to Newly Sprouted Things in China, existing market there is no compatibility therewith, to human body and Equipment is corrosion-free, and can be improved the cleaning agent of cleaning efficiency.
Summary of the invention
The present invention provides intelligent robot cleaning agent and preparation method thereof, solves technical problem 1) regard cleaning robot Feel system obtains accurate information;2) cleaning quality and efficiency are improved;3) organic acid is free of, corruption will not be caused to human body and equipment Erosion.
In order to solve the above-mentioned technical problem, the invention adopts the following technical scheme:
Intelligent robot cleaning agent, is made of surfactant and water, contains defoaming agent.
Further, also contain photoinitiator.
Further, the photoinitiator be free radical polymerization photoinitiator, it is Cationic photoinitiator, visible light-initiated Two kinds of one of agent, water-soluble photoinitiator and macromolecular photoinitiator or arbitrary proportion.
Further, the photoinitiator is the composition of visible light initiator and Cationic photoinitiator.
Surfactant, water and photoinitiator are added in container, stir by the preparation method of intelligent robot cleaning agent It mixes uniformly, defoaming agent is added to get intelligent robot cleaning agent;
Surfactant, water, photoinitiator and defoaming agent mass ratio be 3~98.8:1~96:0~7:0.1~3.
Invention has following advantageous effects:
1. since cleaning agent contains surfactant and water, when in use, a large amount of bubbles can be generated, and the presence of bubble Be unfavorable for the wetting of cleaned material, and due to the presence of air in bubble, can the surface of cleaned material formed one layer of air every Absolutely, cause the surface of cleaned material to image in the vision system of cleaning robot unintelligible, and then affect cleaning efficiency, this After defoaming agent is added in application, the presence of bubble can be significantly reduced, the isolation of air is reduced, makes the surface of cleaning materials in cleaning machine It is clear to image in the vision system of device people, improves cleaning efficiency.
2. the application can be absorbed part ultraviolet light and visible light, prevent cleaning robot clear by the way that photoinitiator is added When washing, since visible reflectance interferes, the collimation error of cleaning robot vision positioning system is caused, what cleaning robot obtained Information inaccuracy, and then influence cleaning efficiency and cleaning effect.
3. cationic initiator is added in the application, so as to omit the addition of organic acid, without influencing using effect. When not in use, it is stored in light protected environment or in light resistant container, there is no the generations of organic acid at this time therefore can't be right Human body and equipment cause to corrode;Outdoors in use, being not used when being stored in container, the not presence of light, does not just have yet at this time Super strong proton acid, and when cleaning solution sprays irradiation of the cationic initiator in light at this time in use, cleaning solution is exposed under sunlight Under decompose reaction, the final super strong proton acid that generates also is bronsted acid, the effect of organic acid in cleaning agent can be played, Therefore cleaning effect is substantially unaffected.
Detailed description of the invention
Fig. 1 is the transmission electron microscope photo using embodiment 1.
Fig. 2 is the transmission electron microscope photo using embodiment 2.
Fig. 3 is the transmission electron microscope photo using comparison 1.
Specific embodiment
The present invention is further illustrated below with reference to specific example.
Embodiment 1
Intelligent robot cleaning agent, is made of surfactant and water, contains defoaming agent.
The preparation method of intelligent robot cleaning agent, surfactant and water are added in container, are stirred evenly, and are added Defoaming agent is to get intelligent robot cleaning agent;
The mass ratio of surfactant, water and defoaming agent is 7:92.9:0.1.
The surfactant is composition of the AEO-9 and op-10 according to mass ratio 5:1;The defoaming agent buying is in north Jing Xingmeiya Chemical Co., Ltd.;Model SA362.
Embodiment 2
Intelligent robot cleaning agent, is made of surfactant and water, contains defoaming agent;Also contain photoinitiator.
The surfactant is composition of the AEO-9 and op-10 according to mass ratio 5:1;The defoaming agent buying is in north Jing Xingmeiya Chemical Co., Ltd., model SA362;The photoinitiator be fluorinated diphenyl titanium luxuriant (Irgacure 784) and Diaryl iodonium salt according to mass ratio 1:1 composition.
Surfactant, water and photoinitiator are added in container, stir by the preparation method of intelligent robot cleaning agent It mixes uniformly, defoaming agent is added to get intelligent robot cleaning agent.
Surfactant, water, photoinitiator and defoaming agent mass ratio be 7:92.4:0.5:0.1.
Embodiment 3
Intelligent robot cleaning agent, is made of surfactant and water, contains defoaming agent and photoinitiator.
The surfactant is composition of the AEO-9 and op-10 according to mass ratio 5:1;The defoaming agent disappears for polyethers Infusion;The photoinitiator is diaryl iodonium salt.
Surfactant, water and photoinitiator are added in container, stir by the preparation method of intelligent robot cleaning agent It mixes uniformly, defoaming agent is added to get intelligent robot cleaning agent;
Surfactant, water, photoinitiator and defoaming agent mass ratio be 96:3:0.5:0.5.
Embodiment 4
Intelligent robot cleaning agent, is made of surfactant and water, contains defoaming agent and essence.
The surfactant is composition of the neopelex according to mass ratio 5:1;The defoaming agent is silicon Oily defoaming agent;The essence buying is in Shanghai Chun Ya flavors and fragrances Co., Ltd.
The preparation method of intelligent robot cleaning agent, surfactant and water are added in container, are stirred evenly, and are added Enter defoaming agent and essence to get intelligent robot cleaning agent;
Surfactant, water, defoaming agent and essence mass ratio be 7:92.55:0.44:0.01.
Embodiment 5
Intelligent robot cleaning agent, is made of surfactant and water, contains photoinitiator;Also contain defoaming agent.
The surfactant is composition of the AEO-9 and op-10 according to mass ratio 3:4;The photoinitiator is fluorination Diphenyl titanium luxuriant (Irgacure 784) and diaryl iodonium salt according to mass ratio 3:1 composition.
Surfactant, water and photoinitiator are added in container, stir by the preparation method of intelligent robot cleaning agent It mixes uniformly, defoaming agent is added to get intelligent robot cleaning agent;The defoaming agent buying is in the limited public affairs of Beijing Xing Meiya chemical industry Department;Model SA362.
Surfactant, water, photoinitiator and defoaming agent mass ratio be 54:45.4:0.5:0.1.
Embodiment 6
Intelligent robot cleaning agent, is made of surfactant and water, contains defoaming agent.
The surfactant is peregal;The defoaming agent is the composition of dimethicone and tributyl phosphate.
Surfactant, water and defoaming agent are added in container, stirred evenly to get intelligent robot cleaning agent.
Embodiment 7
Intelligent robot cleaning agent, is made of surfactant and water, contains defoaming agent and photoinitiator.
The surfactant be sodium sulfate of polyethenoxy ether of fatty alcohol, neopelex, AES and AEO-9 by According to the composition of mass ratio 5:3:2:1;
The photoinitiator is 2- hydroxy-2-methyl -1- [4- (2- hydroxyl-oxethyl) phenyl] -1- acetone, the double first of styrax Ether, bis- (pentafluorophenyl group) titanium cyclopentadienyls and 2,4 dihydroxyl benzophenone according to mass ratio 3:2:4:1 composition.
The defoaming agent is dimethicone.
Surfactant, water and photoinitiator are added in container, stir by the preparation method of intelligent robot cleaning agent It mixes uniformly, defoaming agent is added to get intelligent robot cleaning agent;
Surfactant, water, photoinitiator and defoaming agent mass ratio be 15:81:2:2.
Beneficial effects of the present invention are further illustrated below with reference to experimental data:
Experiment one
1 materials and methods:
1.1 test sites: Yantai analysis center;
1.2 experiment detections: same glass slide uses the microscope view of different disposal;
1.3 experimental subjects: embodiment 1, embodiment 2 and comparison 1(be not in addition to being added defoaming agent, other preparation methods and embodiment 1 It is consistent);
1.4 experimental designs: the one side of glass slide is uniformly smeared into embodiment 1, another side is not processed, and is placed in microscopically observation Its
Imaging;Embodiment 2 is uniformly applied to embodiment 1 and smears position by embodiment of erasing 1, be placed under microscope square its at Picture;Embodiment of erasing 2, by comparison 1(in addition to photoinitiator is not added, other preparation methods are consistent with embodiment 1) uniformly apply It smears and smears position in embodiment 2, be placed in its imaging of microscopically observation;
This experiment other experiment conditions in addition to experiment process is different are consistent
2 results and analysis
By experiment as can be seen that smear the application image compared to compare 1(in addition to photoinitiator is not added, other preparation sides Method
It is consistent with embodiment 3) image it is apparent;The image of the embodiment 2 of defoaming agent and photoinitiator had wherein both been added most Clearly
Experiment two
1, material to be tested is tested
1 materials and methods:
1.1 test sites: Yantai analysis center;
1.2 experiment detections: wavelength is the reflectivity of the range of 200~850nm;
1.3 experimental subjects: embodiment 1, embodiment 2 and comparison 1(be not in addition to being added defoaming agent, other preparation methods and embodiment 1 It is consistent);
1.4 experimental facilities: USB4000 spectrometer;
1.5 experimental designs: by embodiment 1, embodiment 2 and comparison 1(in addition to defoaming agent is not added, other preparation methods and implementation Example 1 is consistent) uniformly it is applied on glass plate, it measures;
This experiment other experiment conditions in addition to experiment process is different are consistent
2 results and analysis
Respectively influence of the processing to glass-reflected rate of table 1
By embodiment 1 in table 1, embodiment 2 and compares 1 data and compare as can be seen that the embodiment 2 of addition photoinitiator can be with It is bright
The aobvious reflection for reducing light.Experiment three
1, material to be tested is tested
1 materials and methods:
1.1 test sites: Yantai City economic and technological development zone Wanke city;
1.2 experiment detections: cleaning robot puts the speed of glass on the skin and is carried out an acceptance inspection by property personnel for this experiment
Examination is divided into: being satisfied with, is satisfied in the main, is good, poor four grades;
1.3 materials to be tested: embodiment 1, embodiment 2 and comparison 1(be not in addition to being added defoaming agent, other preparation methods and embodiment 1 It is consistent);
1.4 experimental designs: being arbitrarily grouped the 3 side by side building of selection, respectively corresponds embodiment 1, embodiment 2 and comparison For 1(in addition to defoaming agent is not added, other preparation methods are consistent with embodiment 1);Selected story height is 30 layers;
Cleaning robot selected by this experiment is provided by Yantai Hai Telin automation Science and Technology Ltd.;
This experiment other experiment conditions in addition to experiment process is different are consistent
2 results and analysis
Cleaning robot puts the speed and customer satisfaction evaluation testing result of glass on the skin, is shown in Table 2
By experimental data in table 2 compare it can be seen from the application can significantly improve the cleaning efficiency of cleaning robot, and it is clear
It is good to wash effect, it can be with cleaning robot compatible use;And 1(is compared in addition to defoaming agent is not added, other preparation methods and reality It is consistent to apply example 1), then cleaning speed is slow, and cleaning effect is poor, is not fine with cleaning robot compatible use effect.

Claims (5)

1. intelligent robot cleaning agent, is made of surfactant and water, by it is characterized in that, containing defoaming agent.
2. intelligent robot cleaning agent as described in claim 1, which is characterized in that also contain photoinitiator.
3. intelligent robot cleaning agent as claimed in claim 2, which is characterized in that the photoinitiator is radical polymerization light combination One of initiator, Cationic photoinitiator, visible light initiator, water-soluble photoinitiator and macromolecular photoinitiator or Two kinds of arbitrary proportion.
4. intelligent robot cleaning agent as claimed in claim 3, which is characterized in that the photoinitiator is visible light initiator With the composition of Cationic photoinitiator.
5. the preparation method of intelligent robot cleaning agent, which is characterized in that surfactant, water and photoinitiator to be added to It in container, stirs evenly, defoaming agent is added to get intelligent robot cleaning agent;
Surfactant, water, photoinitiator and defoaming agent mass ratio be 3~98.8:1~96:0~7:0.1~3.
CN201910270205.4A 2019-04-04 2019-04-04 Cleaning agent for intelligent robot and preparation method thereof Active CN109897739B (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012078950A1 (en) * 2010-12-09 2012-06-14 Isp Investments Inc. A visually perceivable image-forming dye scavenging article
CN103320240A (en) * 2013-07-05 2013-09-25 宋子奎 Bleaching agent composition and detergent composition
CN104342302A (en) * 2014-10-26 2015-02-11 青岛克立克信息技术有限公司 Long-acting and traceless cleaning agent
CN107446723A (en) * 2017-09-29 2017-12-08 成都意町工业产品设计有限公司 A kind of cleaning robot glass cleaner
CN107686780A (en) * 2017-09-29 2018-02-13 成都意町工业产品设计有限公司 A kind of cleaning robot cleaning agent
CN108728281A (en) * 2018-07-27 2018-11-02 唐敏峰 Cleaning robot detergent
CN109135944A (en) * 2018-08-20 2019-01-04 南京工业职业技术学院 A kind of cleaning solution and preparation method thereof based on free radical ultraviolet polymerization

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012078950A1 (en) * 2010-12-09 2012-06-14 Isp Investments Inc. A visually perceivable image-forming dye scavenging article
CN103320240A (en) * 2013-07-05 2013-09-25 宋子奎 Bleaching agent composition and detergent composition
CN104342302A (en) * 2014-10-26 2015-02-11 青岛克立克信息技术有限公司 Long-acting and traceless cleaning agent
CN107446723A (en) * 2017-09-29 2017-12-08 成都意町工业产品设计有限公司 A kind of cleaning robot glass cleaner
CN107686780A (en) * 2017-09-29 2018-02-13 成都意町工业产品设计有限公司 A kind of cleaning robot cleaning agent
CN108728281A (en) * 2018-07-27 2018-11-02 唐敏峰 Cleaning robot detergent
CN109135944A (en) * 2018-08-20 2019-01-04 南京工业职业技术学院 A kind of cleaning solution and preparation method thereof based on free radical ultraviolet polymerization

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