CN109880573A - A kind of preparation method of adhesive label - Google Patents
A kind of preparation method of adhesive label Download PDFInfo
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- CN109880573A CN109880573A CN201910121113.XA CN201910121113A CN109880573A CN 109880573 A CN109880573 A CN 109880573A CN 201910121113 A CN201910121113 A CN 201910121113A CN 109880573 A CN109880573 A CN 109880573A
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- adhesive
- attapulgite
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- diethyl phosphonate
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Abstract
The invention discloses a kind of preparation methods of adhesive label, are related to adhesive sticker technical field, are combined by viscose glue surface layer, adhesive and release base stock, and there is adhesive label prepared by the present invention excellent adhesive property and the Yishui River to wash removal capacity.
Description
Technical field
The invention belongs to adhesive sticker technical fields, and in particular to a kind of preparation method of adhesive label.
Background technique
Adhesive sticker is chiefly used in TAG field, and usually it is with paper, plastic film etc. for fabric, and the back side is coated with adhesive,
To apply a kind of composite material that silicon bottom is release base stock, it is made after the processing such as printing, being die cut.However existing adhesive sticker
Label initial cohesiveness and hold viscosity energy are general, and using washing removal, adhesive residual is more, and difficulty or ease removal is clean, causes
Biggish inconvenience.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of preparation method of adhesive label is provided.
The present invention is achieved by the following technical solutions:
A kind of preparation method of adhesive label is combined by viscose glue surface layer, adhesive and release base stock;The viscose glue surface layer
It is made by weight of following component: the attapulgite modified 7- of acrylic resin 88-90,1- aminoethyl base diethyl phosphonate
10, plasticizer 1-2;
The adhesive is made of following methods: after polyaminoester emulsion and coupling starch are mixed by 55:6 mass ratio, 40
10min is stirred at DEG C, under inert gas protection, adds promotor, temperature quickly heats up between 88-90 DEG C, with 1800r/
Min revolving speed stirs 2 hours, is subsequently cooled to 54 DEG C, adds zinc Isoocatanoate, stirs 45min with 1200r/min revolving speed, stands
Heat preservation 2 hours, cooled to room temperature obtain adhesive, the polyaminoester emulsion, coupling starch, promotor and zinc Isoocatanoate
Mass ratio be 60-65: 6-8: 0.1-0.2:0.5-0.7;The release base stock is Ge Laxin paper;
It is then again that release base stock is compound by adhesive and viscose glue surface layer by the way that adhesive to be coated in the one side of viscose glue surface layer
To together.
Further, the attapulgite modified preparation method of the 1- aminoethyl base diethyl phosphonate the following steps are included:
1- aminoethyl base diethyl phosphonate is dissolved in acetone, the 1- aminoethyl base diethyl phosphonate that mass fraction is 8.5% is obtained
Solution adds the sulfuric acid of its quality 1.2% and 0.8% nitric acid into 1- aminoethyl base diethyl phosphonate solution, is heated to 65 DEG C,
5min is stirred with 120r/min revolving speed, then adds the attapulgite of 1- aminoethyl base diethyl phosphonate solution quality 20% again, after
It is continuous to be heated to 88 DEG C, 40min is stirred with 300r/min revolving speed, is then filtered, obtain it is pre- attapulgite modified, using ethyl alcohol
Solution to it is pre- it is attapulgite modified clean, drying to constant weight, then again will be pre- attapulgite modified by 100g:350mL
Ratio uniform is distributed in alkaline solution, at 55 DEG C, is stirred 30min with 120r/min revolving speed, is obtained attapulgite slurry, so
It adjusts attapulgite slurry pH to 5.2 again afterwards, continues to stir 10min, then add its quality into attapulgite slurry again
The ethylenediamine tetra-acetic acid of 1.25-1.3%, ultrasonication 2min, then again with 1500r/min revolving speed stirring 1 hour, then into
Row filtering, is cleaned using deionized water to neutrality, drying to constant weight to get 1- aminoethyl base diethyl phosphonate modified attapulgite
Soil.
Further, the attapulgite granularity is 1250 mesh.
Further, the ultrasonic frequency is 35kHz, power 800W.
Further, the plasticizer is epoxidized soybean oil.
Further, the inert gas is nitrogen.
Further, the promotor is triethanolamine.
Further, the coupling starch preparation method are as follows:
Tapioca is added in the Malaysia acid ammonium solution that mass fraction is 10% in the ratio of 95g:350mL, is heated to 78
DEG C, 40min is stirred with 150r/min revolving speed, is then filtered, is cleaned using deionized water to neutrality, drying to constant weight, obtains
To maleic acid ammonium modified tapioca starch, then by maleic acid ammonium modified tapioca starch, then by maleic acid ammonium modified tapioca starch and gather
After caprolactone is by the mixing of 10:3 mass ratio, using stannous octoate as catalyst, using potassium peroxydisulfate as initiator, reacted at 85 DEG C
2 as a child, then adds organo silane coupling agent, reacted at 79 DEG C 1 hour to get;The stannous octoate additive amount is to gather oneself
The 1% of lactone quality, the potassium peroxydisulfate additive amount are the 2.5% of polycaprolactone quality, and organo silane coupling agent additive amount is poly-
The 3.6% of caprolactone quality.
The utility model has the advantages that adhesive label prepared by the present invention has excellent tack and holds viscosity, the present invention by
It is attapulgite modified that a certain amount of 1- aminoethyl base diethyl phosphonate is added in viscose glue surface layer, 1- aminoethyl base diethyl phosphonate changes
Property attapulgite can be evenly dispersed in viscose glue surface layer, is taken by the attapulgite modified surface of 1- aminoethyl base diethyl phosphonate
The active group of band can be connected to effectively raise the mechanical property of viscose glue surface layer with acrylic resin macromolecular chain,
So that viscose glue surface layer is not easy to break, simultaneously as 1- aminoethyl base diethyl phosphonate is attapulgite modified in viscose glue facing surface
It is evenly dispersed, so as to firmly mutually adsorbed with gluing agent molecule, so that being easier between adhesive and release base stock
It separates, opens use convenient for adhesive label, meanwhile, it is capable to effectively improve the tack of adhesive and hold viscosity, pass through
The coupling starch prepared in adhesive using the present invention, can be evenly dispersed in adhesive, is coupled on starch molecule and introduces
Various active group, can between substrate quick adsorption, form close mesh skeleton, thus reach higher tack and
Hold viscosity;Adhesive label prepared by the present invention, which can wash with water, quickly to be removed, and be easy to use and remove, the present invention
Water can be made to soak adhesive sticker mark faster by using a certain amount of 1- aminoethyl base diethyl phosphonate is attapulgite modified
Sign surface, by the coupling starch of addition, water absorbing properties are more preferable, can effective water swelling, reduce the viscosity of adhesive, with
Adhesive force between substrate quickly reduces, and falls off, and adhesive residual is low, and removing speed is fast.
Specific embodiment
Embodiment 1
A kind of preparation method of adhesive label is combined by viscose glue surface layer, adhesive and release base stock;The viscose glue surface layer
It is made by weight of following component: the attapulgite modified 7- of acrylic resin 88-90,1- aminoethyl base diethyl phosphonate
10, plasticizer 1-2;
The adhesive is made of following methods: after polyaminoester emulsion and coupling starch are mixed by 55:6 mass ratio, 40
10min is stirred at DEG C, under inert gas protection, adds promotor, temperature quickly heats up between 88-90 DEG C, with 1800r/
Min revolving speed stirs 2 hours, is subsequently cooled to 54 DEG C, adds zinc Isoocatanoate, stirs 45min with 1200r/min revolving speed, stands
Heat preservation 2 hours, cooled to room temperature obtain adhesive, the polyaminoester emulsion, coupling starch, promotor and zinc Isoocatanoate
Mass ratio be 60-65: 6-8: 0.1-0.2:0.5-0.7;The release base stock is Ge Laxin paper;
It is then again that release base stock is compound by adhesive and viscose glue surface layer by the way that adhesive to be coated in the one side of viscose glue surface layer
To together.
Further, the attapulgite modified preparation method of the 1- aminoethyl base diethyl phosphonate the following steps are included:
1- aminoethyl base diethyl phosphonate is dissolved in acetone, the 1- aminoethyl base diethyl phosphonate that mass fraction is 8.5% is obtained
Solution adds the sulfuric acid of its quality 1.2% and 0.8% nitric acid into 1- aminoethyl base diethyl phosphonate solution, is heated to 65 DEG C,
5min is stirred with 120r/min revolving speed, then adds the attapulgite of 1- aminoethyl base diethyl phosphonate solution quality 20% again, after
It is continuous to be heated to 88 DEG C, 40min is stirred with 300r/min revolving speed, is then filtered, obtain it is pre- attapulgite modified, using ethyl alcohol
Solution to it is pre- it is attapulgite modified clean, drying to constant weight, then again will be pre- attapulgite modified by 100g:350mL
Ratio uniform is distributed in alkaline solution, at 55 DEG C, is stirred 30min with 120r/min revolving speed, is obtained attapulgite slurry, so
It adjusts attapulgite slurry pH to 5.2 again afterwards, continues to stir 10min, then add its quality into attapulgite slurry again
The ethylenediamine tetra-acetic acid of 1.25-1.3%, ultrasonication 2min, then again with 1500r/min revolving speed stirring 1 hour, then into
Row filtering, is cleaned using deionized water to neutrality, drying to constant weight to get 1- aminoethyl base diethyl phosphonate modified attapulgite
Soil.
Further, the attapulgite granularity is 1250 mesh.
Further, the ultrasonic frequency is 35kHz, power 800W.
Further, the plasticizer is epoxidized soybean oil.
Further, the inert gas is nitrogen.
Further, the promotor is triethanolamine.
Further, the coupling starch preparation method are as follows:
Tapioca is added in the Malaysia acid ammonium solution that mass fraction is 10% in the ratio of 95g:350mL, is heated to 78
DEG C, 40min is stirred with 150r/min revolving speed, is then filtered, is cleaned using deionized water to neutrality, drying to constant weight, obtains
To maleic acid ammonium modified tapioca starch, then by maleic acid ammonium modified tapioca starch, then by maleic acid ammonium modified tapioca starch and gather
After caprolactone is by the mixing of 10:3 mass ratio, using stannous octoate as catalyst, using potassium peroxydisulfate as initiator, reacted at 85 DEG C
2 as a child, then adds organo silane coupling agent, reacted at 79 DEG C 1 hour to get;The stannous octoate additive amount is to gather oneself
The 1% of lactone quality, the potassium peroxydisulfate additive amount are the 2.5% of polycaprolactone quality, and organo silane coupling agent additive amount is poly-
The 3.6% of caprolactone quality.
Embodiment 2
A kind of preparation method of adhesive label is combined by viscose glue surface layer, adhesive and release base stock;The viscose glue surface layer
It is made by weight of following component: the attapulgite modified 7- of acrylic resin 88-90,1- aminoethyl base diethyl phosphonate
10, plasticizer 1-2;
The adhesive is made of following methods: after polyaminoester emulsion and coupling starch are mixed by 55:6 mass ratio, 40
10min is stirred at DEG C, under inert gas protection, adds promotor, temperature quickly heats up between 88-90 DEG C, with 1800r/
Min revolving speed stirs 2 hours, is subsequently cooled to 54 DEG C, adds zinc Isoocatanoate, stirs 45min with 1200r/min revolving speed, stands
Heat preservation 2 hours, cooled to room temperature obtain adhesive, the polyaminoester emulsion, coupling starch, promotor and zinc Isoocatanoate
Mass ratio be 60-65: 6-8: 0.1-0.2:0.5-0.7;The release base stock is Ge Laxin paper;
It is then again that release base stock is compound by adhesive and viscose glue surface layer by the way that adhesive to be coated in the one side of viscose glue surface layer
To together.
Further, the attapulgite modified preparation method of the 1- aminoethyl base diethyl phosphonate the following steps are included:
1- aminoethyl base diethyl phosphonate is dissolved in acetone, the 1- aminoethyl base diethyl phosphonate that mass fraction is 8.5% is obtained
Solution adds the sulfuric acid of its quality 1.2% and 0.8% nitric acid into 1- aminoethyl base diethyl phosphonate solution, is heated to 65 DEG C,
5min is stirred with 120r/min revolving speed, then adds the attapulgite of 1- aminoethyl base diethyl phosphonate solution quality 20% again, after
It is continuous to be heated to 88 DEG C, 40min is stirred with 300r/min revolving speed, is then filtered, obtain it is pre- attapulgite modified, using ethyl alcohol
Solution to it is pre- it is attapulgite modified clean, drying to constant weight, then again will be pre- attapulgite modified by 100g:350mL
Ratio uniform is distributed in alkaline solution, at 55 DEG C, is stirred 30min with 120r/min revolving speed, is obtained attapulgite slurry, so
It adjusts attapulgite slurry pH to 5.2 again afterwards, continues to stir 10min, then add its quality into attapulgite slurry again
The ethylenediamine tetra-acetic acid of 1.25-1.3%, ultrasonication 2min, then again with 1500r/min revolving speed stirring 1 hour, then into
Row filtering, is cleaned using deionized water to neutrality, drying to constant weight to get 1- aminoethyl base diethyl phosphonate modified attapulgite
Soil.
Further, the attapulgite granularity is 1250 mesh.
Further, the ultrasonic frequency is 35kHz, power 800W.
Further, the plasticizer is epoxidized soybean oil.
Further, the inert gas is nitrogen.
Further, the promotor is triethanolamine.
Further, the coupling starch preparation method are as follows:
Tapioca is added in the Malaysia acid ammonium solution that mass fraction is 10% in the ratio of 95g:350mL, is heated to 78
DEG C, 40min is stirred with 150r/min revolving speed, is then filtered, is cleaned using deionized water to neutrality, drying to constant weight, obtains
To maleic acid ammonium modified tapioca starch, then by maleic acid ammonium modified tapioca starch, then by maleic acid ammonium modified tapioca starch and gather
After caprolactone is by the mixing of 10:3 mass ratio, using stannous octoate as catalyst, using potassium peroxydisulfate as initiator, reacted at 85 DEG C
2 as a child, then adds organo silane coupling agent, reacted at 79 DEG C 1 hour to get;The stannous octoate additive amount is to gather oneself
The 1% of lactone quality, the potassium peroxydisulfate additive amount are the 2.5% of polycaprolactone quality, and organo silane coupling agent additive amount is poly-
The 3.6% of caprolactone quality.
Embodiment 3
A kind of preparation method of adhesive label is combined by viscose glue surface layer, adhesive and release base stock;The viscose glue surface layer
It is made by weight of following component: the attapulgite modified 7- of acrylic resin 88-90,1- aminoethyl base diethyl phosphonate
10, plasticizer 1-2;
The adhesive is made of following methods: after polyaminoester emulsion and coupling starch are mixed by 55:6 mass ratio, 40
10min is stirred at DEG C, under inert gas protection, adds promotor, temperature quickly heats up between 88-90 DEG C, with 1800r/
Min revolving speed stirs 2 hours, is subsequently cooled to 54 DEG C, adds zinc Isoocatanoate, stirs 45min with 1200r/min revolving speed, stands
Heat preservation 2 hours, cooled to room temperature obtain adhesive, the polyaminoester emulsion, coupling starch, promotor and zinc Isoocatanoate
Mass ratio be 60-65: 6-8: 0.1-0.2:0.5-0.7;The release base stock is Ge Laxin paper;
It is then again that release base stock is compound by adhesive and viscose glue surface layer by the way that adhesive to be coated in the one side of viscose glue surface layer
To together.
Further, the attapulgite modified preparation method of the 1- aminoethyl base diethyl phosphonate the following steps are included:
1- aminoethyl base diethyl phosphonate is dissolved in acetone, the 1- aminoethyl base diethyl phosphonate that mass fraction is 8.5% is obtained
Solution adds the sulfuric acid of its quality 1.2% and 0.8% nitric acid into 1- aminoethyl base diethyl phosphonate solution, is heated to 65 DEG C,
5min is stirred with 120r/min revolving speed, then adds the attapulgite of 1- aminoethyl base diethyl phosphonate solution quality 20% again, after
It is continuous to be heated to 88 DEG C, 40min is stirred with 300r/min revolving speed, is then filtered, obtain it is pre- attapulgite modified, using ethyl alcohol
Solution to it is pre- it is attapulgite modified clean, drying to constant weight, then again will be pre- attapulgite modified by 100g:350mL
Ratio uniform is distributed in alkaline solution, at 55 DEG C, is stirred 30min with 120r/min revolving speed, is obtained attapulgite slurry, so
It adjusts attapulgite slurry pH to 5.2 again afterwards, continues to stir 10min, then add its quality into attapulgite slurry again
The ethylenediamine tetra-acetic acid of 1.25-1.3%, ultrasonication 2min, then again with 1500r/min revolving speed stirring 1 hour, then into
Row filtering, is cleaned using deionized water to neutrality, drying to constant weight to get 1- aminoethyl base diethyl phosphonate modified attapulgite
Soil.
Further, the attapulgite granularity is 1250 mesh.
Further, the ultrasonic frequency is 35kHz, power 800W.
Further, the plasticizer is epoxidized soybean oil.
Further, the inert gas is nitrogen.
Further, the promotor is triethanolamine.
Further, the coupling starch preparation method are as follows:
Tapioca is added in the Malaysia acid ammonium solution that mass fraction is 10% in the ratio of 95g:350mL, is heated to 78
DEG C, 40min is stirred with 150r/min revolving speed, is then filtered, is cleaned using deionized water to neutrality, drying to constant weight, obtains
To maleic acid ammonium modified tapioca starch, then by maleic acid ammonium modified tapioca starch, then by maleic acid ammonium modified tapioca starch and gather
After caprolactone is by the mixing of 10:3 mass ratio, using stannous octoate as catalyst, using potassium peroxydisulfate as initiator, reacted at 85 DEG C
2 as a child, then adds organo silane coupling agent, reacted at 79 DEG C 1 hour to get;The stannous octoate additive amount is to gather oneself
The 1% of lactone quality, the potassium peroxydisulfate additive amount are the 2.5% of polycaprolactone quality, and organo silane coupling agent additive amount is poly-
The 3.6% of caprolactone quality.
Comparative example 1: it is only that with the difference of embodiment 1 and replaces with 1- aminoethyl base diethyl phosphonate is attapulgite modified not
Modified attapulgite.
Comparative example 2: the tapioca for being only that coupling starch replaces with unmodified processing is distinguished with embodiment 1.
Comparative example 3: it is only that with the difference of embodiment 1 and coupling starch is replaced with into modified starch (application number
2007101915915).
Comparative example 4: adhesive is replaced with into adhesive prepared by application number 201711277210.5.
To embodiment, comparative example and control group using the adhesive label of the same size of conventional same process preparation, press
It is tested according to GB 4852, JIS Z0237 standard (pressure sensitive adhesive tape tack test method-rolling ball method);
The test of adhesive label holding power holds viscosity test method according to GB 4851(pressure sensitive adhesive tape) it is tested, as a result as follows:
Table 1
Tack/steel ball size mm | Hold viscosity/fall off time h | |
Embodiment 1 | 25.4 | 12.3 |
Embodiment 2 | 25.4 | 12. 6 |
Embodiment 3 | 25.4 | 12.4 |
Comparative example 1 | 19.05 | 10.8 |
Comparative example 2 | 13.49 | 7.5 |
Comparative example 3 | 16.66 | 8.6 |
Comparative example 4 | 10.31 | 6.0 |
Adhesive label prepared by the present invention has excellent tack and holds viscosity as can be seen from Table 1, the present invention by
It is attapulgite modified that a certain amount of 1- aminoethyl base diethyl phosphonate is added in viscose glue surface layer, 1- aminoethyl base diethyl phosphonate changes
Property attapulgite can be evenly dispersed in viscose glue surface layer, is taken by the attapulgite modified surface of 1- aminoethyl base diethyl phosphonate
The active group of band can be connected to effectively raise the mechanical property of viscose glue surface layer with acrylic resin macromolecular chain,
So that viscose glue surface layer is not easy to break, simultaneously as 1- aminoethyl base diethyl phosphonate is attapulgite modified in viscose glue facing surface
It is evenly dispersed, so as to firmly mutually adsorbed with gluing agent molecule, so that being easier between adhesive and release base stock
It separates, opens use convenient for adhesive label, meanwhile, it is capable to effectively improve the tack of adhesive and hold viscosity, pass through
The coupling starch prepared in adhesive using the present invention, can be evenly dispersed in adhesive, is coupled on starch molecule and introduces
Various active group, can between substrate quick adsorption, form close mesh skeleton, thus reach higher tack and
Hold viscosity.
To embodiment, comparative example using the same size of conventional same process preparation adhesive label be bonded in it is identical
Board surface, 10 were placed under identical environment as a child, clean with the clear water of equivalent, compare each group adhesive label fall off it is clean
Time:
Table 2
Fall off the clean time/s | |
Embodiment 1 | 2.92 |
Embodiment 2 | 2.98 |
Embodiment 3 | 2.95 |
Comparative example 1 | 4.58 |
Comparative example 2 | 7.42 |
Comparative example 3 | 8.72 |
Comparative example 4 | 10.45 |
As can be seen from Table 2, adhesive label prepared by the present invention, which can wash with water, quickly to remove, be easy to use and
Removal, the present invention can make water moisten faster by using a certain amount of 1- aminoethyl base diethyl phosphonate is attapulgite modified
Wet adhesive label surface, by the coupling starch of addition, water absorbing properties are more preferable, can effective water swelling, reduce gluing
The viscosity of agent, the adhesive force between substrate are quickly reduced, are fallen off, and adhesive residual is low, and removing speed is fast.
Claims (8)
1. a kind of preparation method of adhesive label, which is characterized in that by viscose glue surface layer, adhesive and release base stock it is compound and
At;The viscose glue surface layer is made of following component by weight: acrylic resin 88-90,1- aminoethyl base diethyl phosphonate
Attapulgite modified 7-10, plasticizer 1-2;
The adhesive is made of following methods: after polyaminoester emulsion and coupling starch are mixed by 55:6 mass ratio, 40
10min is stirred at DEG C, under inert gas protection, adds promotor, temperature quickly heats up between 88-90 DEG C, with 1800r/
Min revolving speed stirs 2 hours, is subsequently cooled to 54 DEG C, adds zinc Isoocatanoate, stirs 45min with 1200r/min revolving speed, stands
Heat preservation 2 hours, cooled to room temperature obtain adhesive, the polyaminoester emulsion, coupling starch, promotor and zinc Isoocatanoate
Mass ratio be 60-65: 6-8: 0.1-0.2:0.5-0.7;The release base stock is Ge Laxin paper;
It is then again that release base stock is compound by adhesive and viscose glue surface layer by the way that adhesive to be coated in the one side of viscose glue surface layer
To together.
2. a kind of preparation method of adhesive label as described in claim 1, which is characterized in that the 1- aminoethyl base
The attapulgite modified preparation method of diethyl phosphonate the following steps are included:
1- aminoethyl base diethyl phosphonate is dissolved in acetone, the 1- aminoethyl base diethyl phosphonate that mass fraction is 8.5% is obtained
Solution adds the sulfuric acid of its quality 1.2% and 0.8% nitric acid into 1- aminoethyl base diethyl phosphonate solution, is heated to 65 DEG C,
5min is stirred with 120r/min revolving speed, then adds the attapulgite of 1- aminoethyl base diethyl phosphonate solution quality 20% again, after
It is continuous to be heated to 88 DEG C, 40min is stirred with 300r/min revolving speed, is then filtered, obtain it is pre- attapulgite modified, using ethyl alcohol
Solution to it is pre- it is attapulgite modified clean, drying to constant weight, then again will be pre- attapulgite modified by 100g:350mL
Ratio uniform is distributed in alkaline solution, at 55 DEG C, is stirred 30min with 120r/min revolving speed, is obtained attapulgite slurry, so
It adjusts attapulgite slurry pH to 5.2 again afterwards, continues to stir 10min, then add its quality into attapulgite slurry again
The ethylenediamine tetra-acetic acid of 1.25-1.3%, ultrasonication 2min, then again with 1500r/min revolving speed stirring 1 hour, then into
Row filtering, is cleaned using deionized water to neutrality, drying to constant weight to get 1- aminoethyl base diethyl phosphonate modified attapulgite
Soil.
3. a kind of preparation method of adhesive label as claimed in claim 2, which is characterized in that the attapulgite granularity is
1250 mesh.
4. a kind of preparation method of adhesive label as claimed in claim 2, which is characterized in that the ultrasonic frequency is
35kHz, power 800W.
5. a kind of preparation method of adhesive label as described in claim 1, which is characterized in that the plasticizer is that epoxy is big
Soya-bean oil.
6. a kind of preparation method of adhesive label as described in claim 1, which is characterized in that the inert gas is nitrogen
Gas.
7. a kind of preparation method of adhesive label as described in claim 1, which is characterized in that the promotor is three ethyl alcohol
Amine.
8. a kind of preparation method of adhesive label as described in claim 1, which is characterized in that the coupling starch preparation side
Method are as follows:
Tapioca is added in the Malaysia acid ammonium solution that mass fraction is 10% in the ratio of 95g:350mL, is heated to 78
DEG C, 40min is stirred with 150r/min revolving speed, is then filtered, is cleaned using deionized water to neutrality, drying to constant weight, obtains
To maleic acid ammonium modified tapioca starch, then by maleic acid ammonium modified tapioca starch, then by maleic acid ammonium modified tapioca starch and gather
After caprolactone is by the mixing of 10:3 mass ratio, using stannous octoate as catalyst, using potassium peroxydisulfate as initiator, reacted at 85 DEG C
2 as a child, then adds organo silane coupling agent, reacted at 79 DEG C 1 hour to get;The stannous octoate additive amount is to gather oneself
The 1% of lactone quality, the potassium peroxydisulfate additive amount are the 2.5% of polycaprolactone quality, and organo silane coupling agent additive amount is poly-
The 3.6% of caprolactone quality.
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