CN109880413A - A kind of disinsection mold-proof interior wall coating and preparation method thereof - Google Patents
A kind of disinsection mold-proof interior wall coating and preparation method thereof Download PDFInfo
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- 238000000576 coating method Methods 0.000 title claims abstract description 46
- 239000011248 coating agent Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
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- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 239000003921 oil Substances 0.000 claims abstract description 11
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 11
- 239000010703 silicon Substances 0.000 claims abstract description 11
- 239000000284 extract Substances 0.000 claims abstract description 9
- 239000004088 foaming agent Substances 0.000 claims abstract description 9
- 235000004611 garlic Nutrition 0.000 claims abstract description 8
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 7
- 239000002562 thickening agent Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims description 10
- 239000004156 Azodicarbonamide Substances 0.000 claims description 9
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 claims description 9
- 235000019399 azodicarbonamide Nutrition 0.000 claims description 9
- JDLKFOPOAOFWQN-VIFPVBQESA-N Allicin Natural products C=CCS[S@](=O)CC=C JDLKFOPOAOFWQN-VIFPVBQESA-N 0.000 claims description 8
- JDLKFOPOAOFWQN-UHFFFAOYSA-N allicin Chemical group C=CCSS(=O)CC=C JDLKFOPOAOFWQN-UHFFFAOYSA-N 0.000 claims description 8
- 235000010081 allicin Nutrition 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 240000002234 Allium sativum Species 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
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- 238000003756 stirring Methods 0.000 claims description 5
- 150000001336 alkenes Chemical class 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- 239000001815 (2R)-2-phenylpropan-1-ol Substances 0.000 claims description 2
- RNDNSYIPLPAXAZ-UHFFFAOYSA-N 2-Phenyl-1-propanol Chemical compound OCC(C)C1=CC=CC=C1 RNDNSYIPLPAXAZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000006210 lotion Substances 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 239000006000 Garlic extract Substances 0.000 claims 1
- 235000020706 garlic extract Nutrition 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
- LVMWHJXAPYZSSX-UHFFFAOYSA-N quinoline 1,2-thiazole Chemical compound N1=CC=CC2=CC=CC=C12.S1N=CC=C1 LVMWHJXAPYZSSX-UHFFFAOYSA-N 0.000 claims 1
- 241000894006 Bacteria Species 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 9
- 230000001681 protective effect Effects 0.000 abstract description 5
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- 244000245420 ail Species 0.000 abstract 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- -1 polysiloxane Polymers 0.000 description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 3
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
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- 239000002917 insecticide Substances 0.000 description 2
- 210000004681 ovum Anatomy 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical compound C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
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- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- ATMLPEJAVWINOF-UHFFFAOYSA-N acrylic acid acrylic acid Chemical class OC(=O)C=C.OC(=O)C=C ATMLPEJAVWINOF-UHFFFAOYSA-N 0.000 description 1
- 230000000507 anthelmentic effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
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- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to technical field of coatings, specifically disclose a kind of disinsection mold-proof interior wall coating and preparation method thereof.The disinsection mold-proof interior wall coating includes the following raw material components of mass fraction: 25-30 parts of elastic emulsion；20-25 parts of butyl acrylate；15-20 parts of dibutyl phthalate；20-25 parts of titanium dioxide；10-15 parts of emulsifier；10-15 parts of thickener；15-30 parts of foaming agent；25-35 parts of mould inhibitor；10-20 parts of water-soluble silicon oil；20-30 parts of deionized water；3-5 parts of garlic P.E；3-5 parts of orange peel extract.Disinsection mold-proof interior wall coating provided by the invention, film have effects that water-fast, moisture-proof, bacteria mildew-proof and expelling parasite desinsection, and metope is made not by mould and damp worm puzzlement, to play good beautification and protective effect to wall for a long time.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of disinsection mold-proof interior wall coating and preparation method thereof.
Background technique
The many buildings in China are all perplexed by mould at present, mould be it is ubiquitous, as basement, wall, ceiling warp
It often will appear " becoming mildewed " situation, or even bathroom tile can all have the occurrence of " becoming mildewed ".In addition, moist environment is also suitble to
The existence of some insects, some areas rainy weather is more, adds atmospheric moisture weight, it is easy to which mould growth multiplies damp worm.It is mould
Bacterium growth can discharge pernicious gas, be detrimental to health.Damp worm but will destroy metope, influence indoor environment beauty.
Desinsection main method is exactly to use insecticide, but insecticide toxicity is big at present, and mould is even more that not can avoid.Therefore, it grinds
Sending out a kind of can not only maintain indoor environment beautiful but also have effects that the interior wall coating of disinsection mold-proof is significant.
Summary of the invention
For existing structure in wet condition wall mould easy to breed, multiply damp worm, be detrimental to health and ring
The problems such as border is beautiful, the present invention provide a kind of disinsection mold-proof interior wall coating and preparation method thereof.
To achieve the above object of the invention, the embodiment of the present invention uses the following technical solution:
A kind of disinsection mold-proof interior wall coating, including the following raw material components of mass fraction: 25-30 parts of elastic emulsion；Propylene
20-25 parts of acid butyl ester；15-20 parts of dibutyl phthalate；20-25 parts of titanium dioxide；10-15 parts of emulsifier；Thickener 10-15
Part；15-30 parts of foaming agent；25-35 parts of mould inhibitor；10-20 parts of water-soluble silicon oil；20-30 parts of deionized water；Garlic P.E 3-
5 parts；3-5 parts of orange peel extract.
Further, the elastic emulsion is organosilicon-modified acrylate emulsion, the organosilicon-modified acrylate
Acrylate prepolymer body condensation for the polysiloxane pre polymers body and hydroxyl and/or carboxyl of hydroxyl is made, elastic emulsion tool
There are a performances such as excellent resilience, flexibility, cementability, weatherability, resistance to dirt retention and UV resistant, and organic-silicon-modified propylene
Acid esters lotion has more excellent stain resistance and water resistance, and coating is made to play good beautification and protective effect to wall.
Further, the emulsifier be alkyl phenol polyoxyethylene ether, have it is good wetting, infiltration, emulsification, dispersion,
Solubilization improves the dispersion stabilization of coating, and the foaming agent is azodicarbonamide, so that film is generated microcellular structure, greatly
Greatly while improve paint film intensity, facilitate effective component in garlic P.E and orange peel extract persistently longer
The effect of distributing, reaching bacteria mildew-proof and expelling parasite desinsection；It can also cooperate with machine fluorine-silicon modified acrylic ester, make to enter in micropore
Moisture reduces the water for reaching substrate through paint film, reduces the water penetration of paint film in conjunction with hydrophilic carboxyl or hydroxyl group.
Further, the garlic P.E is allicin, can inhibit fungus growth, has anthelminthic effect.The orange peel
The effect of extract is orange peel ethanol extract, has and inhibits worm's ovum growth, and then kills worm's ovum.
Further, the thickener is polyacrylate-type thickeners, improves coating mobility, levelability and anti-splashing
Property；And microorganism and enzyme are stablized.
Further, the mould inhibitor is 1,2- phenylpropyl alcohol isothiazoline -3- ketone (BIT), can effectively kill various mushrooms,
Bactericidal mould proof effect broad-spectrum long-acting, does not develop drug resistance.
Compared with the existing technology, disinsection mold-proof interior wall coating provided by the invention, using elastic emulsion as main film forming substance,
Interact with butyl acrylate, dibutyl phthalate and titanium dioxide, improve the tensile strength of film, fracture elongation and
Water resistance, and by addition foaming agent, make film that there is microcellular structure, facilitates mould inhibitor, garlic P.E and orange peel and extract
Effective component in object is persistently dispersed into film coated surface longer and reaches bacteria mildew-proof and insecticidal action, and Multiple components collaboration is made
With, so that film is had effects that water-fast, moisture-proof, bacteria mildew-proof and expelling parasite desinsection, perplex metope by mould and damp worm for a long time,
Good beautification and protective effect are played to wall.
The present invention also provides the preparation methods of above-mentioned disinsection mold-proof interior wall coating, comprising the following steps:
(1) each component is weighed according to the raw material proportioning；
(2) elastic emulsion, butyl acrylate, dibutyl phthalate, emulsifier and deionized water are mixed
Material processing, obtains premix；
(3) by the titanium dioxide, foaming agent, mould inhibitor, water-soluble silicon oil, garlic P.E, orange peel extract and thickening
Agent is added to the premix, and agitated processing obtains disinsection mold-proof interior wall coating.
Further, the mixing speed of the mixing treatment is 500-800rpm, time 3-8min.
Further, the mixing speed of the stir process is 800-1200rpm, time 15-25min.
Compared with the existing technology, the preparation method of disinsection mold-proof interior wall coating provided by the invention, simple process, operation side
Just, raw materials used environmentally protective, safe and non-toxic, the interior wall coating being prepared has effects that disinsection mold-proof.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Embodiment 1
A kind of disinsection mold-proof interior wall coating, including the following raw material components of mass fraction: organosilicon-modified acrylate cream
27 parts of liquid；22 parts of butyl acrylate；17 parts of dibutyl phthalate；23 parts of titanium dioxide；12 parts of nonyl polyoxyethylene ether；Poly- third
13 parts of olefin(e) acid sodium；27 parts of azodicarbonamide；BIT26 parts of mould inhibitor；15 parts of water-soluble silicon oil；26 parts of deionized water；Allicin 4
Part；4 parts of orange peel ethanol extract.
The preparation method of above-mentioned disinsection mold-proof interior wall coating, comprising the following steps:
(1) each component is weighed according to the raw material proportioning；
(2) by the organosilicon-modified acrylate emulsion, butyl acrylate, dibutyl phthalate, nonyl polyoxy
Vinethene and deionized water obtain premix with 600rpm progress mixing treatment 5min；
(3) titanium dioxide, azodicarbonamide, mould inhibitor BIT, water-soluble silicon oil, allicin, orange peel ethyl alcohol are extracted
Object and Sodium Polyacrylate are added to the premix, with 1000rpm stir process 20min, obtain disinsection mold-proof interior wall coating.
Embodiment 2
A kind of disinsection mold-proof interior wall coating, including the following raw material components of mass fraction: organosilicon-modified acrylate cream
25 parts of liquid；20 parts of butyl acrylate；15 parts of dibutyl phthalate；20 parts of titanium dioxide；11 parts of nonyl polyoxyethylene ether；Poly- third
10 parts of olefin(e) acid sodium；15 parts of azodicarbonamide；BIT25 parts of mould inhibitor；10 parts of water-soluble silicon oil；20 parts of deionized water；Allicin 3
Part；3 parts of orange peel ethanol extract.
The preparation method of above-mentioned disinsection mold-proof interior wall coating, comprising the following steps:
(1) each component is weighed according to the raw material proportioning；
(2) by the organosilicon-modified acrylate emulsion, butyl acrylate, dibutyl phthalate, nonyl polyoxy
Vinethene and deionized water obtain premix with 500rpm progress mixing treatment 8min；
(3) titanium dioxide, azodicarbonamide, mould inhibitor BIT, water-soluble silicon oil, allicin, orange peel ethyl alcohol are extracted
Object and Sodium Polyacrylate are added to the premix, with 800rpm stir process 25min, obtain disinsection mold-proof interior wall coating.
Embodiment 3
A kind of disinsection mold-proof interior wall coating, including the following raw material components of mass fraction: organosilicon-modified acrylate cream
30 parts of liquid；25 parts of butyl acrylate；20 parts of dibutyl phthalate；25 parts of titanium dioxide；15 parts of nonyl polyoxyethylene ether；Poly- third
15 parts of olefin(e) acid sodium；30 parts of azodicarbonamide；BIT31 parts of mould inhibitor；20 parts of water-soluble silicon oil；30 parts of deionized water；Allicin 5
Part；5 parts of orange peel ethanol extract.
The preparation method of above-mentioned disinsection mold-proof interior wall coating, comprising the following steps:
(1) each component is weighed according to the raw material proportioning；
(2) by the organosilicon-modified acrylate emulsion, butyl acrylate, dibutyl phthalate, nonyl polyoxy
Vinethene and deionized water obtain premix with 800rpm progress mixing treatment 3min；
(3) titanium dioxide, azodicarbonamide, mould inhibitor BIT, water-soluble silicon oil, allicin, orange peel ethyl alcohol are extracted
Object and Sodium Polyacrylate are added to the premix, with 1200rpm stir process 15min, obtain disinsection mold-proof interior wall coating.
In order to better illustrate the present invention embodiment provide disinsection mold-proof interior wall coating characteristic, below by embodiment 1,
2, the disinsection mold-proof interior wall coating of 3 preparations carries out the test of respective performances, and the results are shown in Table 1.
Table 1
Above data shows that disinsection mold-proof interior wall coating provided in an embodiment of the present invention has preferable application property, alkaline-resisting
Property, abrasion resistance and water resistance.
Technical solution in order to better illustrate the present invention is done by comparative example and the embodiment of the present invention into one further below
The comparison of step.
Comparative example 1
By azodicarbonamide (foaming agent) the ingredient removal in embodiment 1, other components are constant, and preparation method is the same as real
Example 1 is applied, disinsection mold-proof interior wall coating is obtained.
The characteristic for the disinsection mold-proof interior wall coating that embodiment provides in order to better illustrate the present invention, below by embodiment 1-
3 and comparative example 1 prepare disinsection mold-proof interior wall coating carry out bacteria mildew-proof effect test, by bacterium solution (Escherichia coli, aspergillus niger
Bacterium) it is spread evenly across on the load glass side for being coated with above-mentioned coating, bacterium solution, which is picked, after 0,4,12,24,48,100 hour is placed in physiology
It in salt water, takes 0.5m1 in culture dish, culture medium is added, cultivate 48 hours in the incubator, take out statistics clump count (wherein,
Processing in 0 hour is used as blank control, and clump count can be used as initial clump count), according to formula calculating sterilizing rate: sterilizing rate=
(clump count after initial clump count-sterilization)/initial clump count x100%, the results are shown in Table 2.
Table 2
Above data can obtain, and disinsection mold-proof interior wall coating provided in an embodiment of the present invention has the function of good bacteria mildew-proof
Effect, perplexs metope by mould for a long time, plays good beautification and protective effect to wall.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modification, equivalent replacement or improvement etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (9)
1. a kind of disinsection mold-proof interior wall coating, it is characterised in that: including the following raw material components of mass fraction: elastic emulsion 25-
30 parts；20-25 parts of butyl acrylate；15-20 parts of dibutyl phthalate；20-25 parts of titanium dioxide；10-15 parts of emulsifier；Increase
Thick dose 10-15 parts；15-30 parts of foaming agent；25-35 parts of mould inhibitor；10-20 parts of water-soluble silicon oil；20-30 parts of deionized water；Greatly
3-5 parts of garlic extract；3-5 parts of orange peel extract.
2. disinsection mold-proof interior wall coating as described in claim 1, it is characterised in that: the elastic emulsion is organic-silicon-modified third
Olefin(e) acid ester lotion.
3. disinsection mold-proof interior wall coating as described in claim 1, it is characterised in that: the emulsifier is alkylphenol-polyethenoxy
Ether, the foaming agent are azodicarbonamide.
4. disinsection mold-proof interior wall coating as described in claim 1, it is characterised in that: the garlic P.E is allicin, institute
Stating orange peel extract is orange peel ethanol extract.
5. disinsection mold-proof interior wall coating as described in claim 1, it is characterised in that: the thickener is polyacrylate increasing
Thick dose.
6. disinsection mold-proof interior wall coating as described in claim 1, it is characterised in that: the mould inhibitor is 1,2- phenylpropyl alcohol isothiazole
Quinoline -3- ketone.
7. a kind of preparation method of disinsection mold-proof interior wall coating, it is characterised in that: the following steps are included:
(1) each component is weighed according to raw material proportioning as described in any one of claims 1 to 6；
(2) elastic emulsion, butyl acrylate, dibutyl phthalate, emulsifier and deionized water are carried out at mixing
Reason, obtains premix；
(3) titanium dioxide, foaming agent, mould inhibitor, water-soluble silicon oil, garlic P.E, orange peel extract and thickener are added
Enter to the premix, agitated processing obtains disinsection mold-proof interior wall coating.
8. the preparation method of disinsection mold-proof interior wall coating as claimed in claim 7, it is characterised in that: the mixing treatment is stirred
Mixing speed is 500-800rpm, time 3-8min.
9. the preparation method of disinsection mold-proof interior wall coating as claimed in claim 7, it is characterised in that: the stir process is stirred
Mixing speed is 800-1200rpm, time 15-25min.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112430403A (en) * | 2020-10-19 | 2021-03-02 | 江苏汉卫环境安全科技有限公司 | Antibacterial coating for mobile laboratory |
| CN112812607A (en) * | 2020-12-30 | 2021-05-18 | 南京逸科景润科技有限公司 | Mildew-proof insect-expelling environment-friendly coating and preparation method thereof |
| WO2022133661A1 (en) * | 2020-12-21 | 2022-06-30 | 张辉航 | Ultraviolet-curable white primer for fireproof layer |
| CN115058162A (en) * | 2022-07-06 | 2022-09-16 | 广西维一涂料制造有限公司 | High-strength bright interior wall coating |
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| CN106221331A (en) * | 2016-08-31 | 2016-12-14 | 张家口市凯博风房地产开发有限公司 | A kind of inner wall mold-proof paint and preparation method thereof |
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| CN112430403A (en) * | 2020-10-19 | 2021-03-02 | 江苏汉卫环境安全科技有限公司 | Antibacterial coating for mobile laboratory |
| WO2022133661A1 (en) * | 2020-12-21 | 2022-06-30 | 张辉航 | Ultraviolet-curable white primer for fireproof layer |
| CN112812607A (en) * | 2020-12-30 | 2021-05-18 | 南京逸科景润科技有限公司 | Mildew-proof insect-expelling environment-friendly coating and preparation method thereof |
| CN115058162A (en) * | 2022-07-06 | 2022-09-16 | 广西维一涂料制造有限公司 | High-strength bright interior wall coating |
| CN115058162B (en) * | 2022-07-06 | 2024-03-26 | 广西维一涂料制造有限公司 | Mildew preventive containing ZPT |
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