CN109862871A - Keratin fiber treatment compositions - Google Patents
Keratin fiber treatment compositions Download PDFInfo
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- CN109862871A CN109862871A CN201780065859.2A CN201780065859A CN109862871A CN 109862871 A CN109862871 A CN 109862871A CN 201780065859 A CN201780065859 A CN 201780065859A CN 109862871 A CN109862871 A CN 109862871A
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- Prior art keywords
- treatment compositions
- keratin fiber
- fiber treatment
- resin
- hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5424—Polymers characterized by specific structures/properties characterized by the charge anionic
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
The purpose of the present invention is to provide a kind of sustainable shapes (moulding) for keeping keratin fiber for a long time, and use sense of touch also excellent keratin fiber treatment compositions.The present invention relates to a kind of keratin fiber treatment compositions, it is characterised in that contains sugar alcohol.Keratin fiber treatment compositions of the invention preferably contain urea and/or urea derivative or any one of resin or both of haircuting in turn.Its pH value is preferably set as in the range of 4.0~7.5 by keratin fiber treatment compositions of the invention.
Description
Technical field
The present invention relates to a kind of keratin fiber treatment compositions.More specifically, the present invention relates to one kind can form angle
The moulding of azelon, particularly hair or eyelashes simultaneously keeps the moulding for a long time, and also excellent keratin is fine for use feeling
Tie up treatment compositions.
Background technique
It is daily to perform the following operation for keratin fiber, especially hair: whole using high temperature such as hair iron or curling irons
Hair utensil makes it crimp or be straightened, and thus carries out moulding as desired.However, the moulding be it is temporary, at any time
Between pass through and moulding is flat collapses.In addition, there is also lead to the problem of causing damage to hair because being handled at high temperature.
To solve the above-mentioned problems, it proposes to have and is with the damage that long-time maintenance is formed by hair style or repairs hair
The various hair cosmetic compositions (hair styling agent) of purpose.
The carboxylic acid and benzylalcohol containing glucose, carbon number and pKa through limiting are recorded in patent document 1, and pH value is 2.5
~4 Hiar treatment compositions.The Hiar treatment compositions are considered as can inhibit the hair damage caused by high temperature haircuts utensil,
But do not refer to the improvement for (moulding) effect of haircuting at all.In turn, the composition of such highly acid region (pH value=2.5~4)
There are problems that decomposing if cooperating the urea with water tariff collection function and generating foreign odor.
The resin containing (A) amido containing oxidation with specific structure is disclosed in patent document 2, is selected from alkalinity with (B)
The hair cosmetic composition of one or more of amino acid, acidic amino acid, 2-pyrrolidone-5-carboxylic acid, urea and panthenol, especially with volume
Constancy, sizing retentivity when the situation of hair device or hot crimper production wave volume and prevent the hair damages as caused by heat
Excellent effect.However, keeping the cosmetics of moulding to feel to the stiff sense caused by resin by resin (cardability is poor)
Situation.
On the other hand, disclosed the hydrolysis of keratin of (a) average molecular weight 25000~35000 in patent document 3 and
(b) moulding cosmetics made of the protein isolate matter from wool or people's hair is cooperated with specific ratios, tree will not be assigned by being considered as
Rouge sense and moulding can be kept well.
About eyelashes, the hydrolyzed-silk egg by cooperating the hydrolysate as protein is recorded in the same manner as patent document 3
It is white, and the adhesion or rolled efficiency to eyelashes improve (patent document 4).However, the cosmetics of patent document 4 must be by matching
Wax or resin are closed to assign three-dimensional sense.
That is, these previous cosmetics make the formation of shape (moulding) and holding depend on tree joined together in most cases
Rouge, and not can avoid the stiff sense of touch caused by resin.Although being reached in addition, the cosmetics of patent document 3 are not necessarily to resin
At moulding keep and for the use of the sense of touch on and it is insufficient.
Existing technical literature
Patent document
Patent document 1: No. 5779399 bulletins of Japanese Patent No.
Patent document 2: No. 4136965 bulletins of Japanese Patent No.
Patent document 3: No. 4881567 bulletins of Japanese Patent No.
Patent document 4: Japanese Patent Laid-Open 2016-41673 bulletin
Summary of the invention
Problems to be solved by the invention
Therefore, the issue of the present invention is to provide it is a kind of it is sustainable keep for a long time include hair and eyelashes keratin fibre
The shape (moulding) of dimension, and use sense of touch also excellent keratin fiber treatment compositions.
The solution to the problem
The present inventor has carried out making great efforts research in order to solve the above problems, as a result finds for the first time: sugar alcohol has keratin
Fiber modeling function.As a result, being based on following opinion so that completing the present invention: by using the combination for being combined with sugar alcohol
Object, and the excellent effect of the moulding of keratin fiber is kept for a long time, and is also improved using sense of touch.
That is, the present invention provides a kind of keratin fiber treatment compositions, which is characterized in that contain sugar alcohol.
Keratin fiber treatment compositions of the invention are preferably and then containing in urea and/or urea derivative or resin of haircuting
Either or both.In addition, its pH value is preferably set as 4.0~7.5 model by keratin fiber treatment compositions of the invention
In enclosing.
The effect of invention
Keratin fiber treatment compositions of the invention are applied to the keratin fibers such as hair or eyelashes, are preferable over heating
Lower carry out moulding, the resulting moulding are able to continue to keep for a long time.In turn, keratin fiber treatment compositions of the invention
It is extremely excellent in terms of use sense of touch in application.
Specific embodiment
Keratin fiber treatment compositions (hereinafter, also referred to as " treatment compositions ") of the invention contain sugar alcohol conduct must
It must ingredient.
So-called " keratin fiber " in the present invention refers to, fibrous keratin substances and becomes moulding object, special
Do not refer to hair and eyelashes.
As long as the sugar alcohol as essential component of the invention can be matched with during keratin fiber applies some make up etc., example
For example selected from one or more of antierythrite, D-sorbite, maltitol, mannitol and xylitol.Wherein, red
Moss sugar alcohol is especially effective.
Sugar alcohol be in previous hair cosmetic composition etc. cooperate as " wetting agent " or " moisturizer " etc., but the present invention
In for the first time find: sugar alcohol have keratin fiber modeling function, that is, the modeling agent as keratin fiber is effective.
The use level of sugar alcohol in treatment compositions of the invention be 0.1 mass % or more and 5.0 mass % hereinafter, it is preferred that
0.2~3.0 mass %, more preferable 0.5~2.0 mass %.If use level is lower than 0.1 mass %, it can not obtain and adequately make
Type keeps effect, if use level becomes 5.0 mass % or more, has the tendency that generating sticky sense.
Treatment compositions of the invention are aqueous base made of being dissolved in sugar alcohol in aqueous medium, are preferably made solvable
The water-based composition of system or the form of O/W emulsion composition.
Preferably cooperate urea and/or urea derivative in treatment compositions of the invention in turn, passes through determining for the cooperation moulding
Type power further increases.
So-called urea derivative refers to, the chemical combination for the structure that at least one hydrogen atom with urea replaces through functional groups such as alkyl
Object.The compound that a preferably at least hydrogen atom replaces through the hydroxy alkyl of carbon number 1~10, can example hydroxyethyl urea, hydroxyl
Methylurea, hydroxypropyl urea etc..
The use level of urea and/or urea derivative in treatment compositions of the invention is 0.1 mass % or more and 5.0 matter
% is measured hereinafter, it is preferred that 0.2~3.0 mass %, more preferable 0.5~2.0 mass %.If use level is lower than 0.1 mass %, can not
It obtains by addition bring shaping force improvement effect.
If cooperating the curling haircuted under resin, especially high temperature and humidity environment in treatment compositions of the invention in turn
Persistence improves.It is haircuted in resin used in the present invention comprising Amphiphatic high polymer resin compound, cationic macromolecule
Resin compound, anionic property macromolecule resin compound, nonionic macromolecule resin compound, can be from wherein appropriate selection
Any one is two or more.Wherein, preferably cooperate the resin of anionic property.
As Amphiphatic high polymer resin compound, such as there is logical formula (I):
(in formula, the range of n:m=2:8~8:2, the range that molecular weight is 50000~500000.R1And R6For hydrogen atom or
Methyl, R3And R4For the alkyl with 1~4 carbon atom, R2And R5For the alkylidene with 1~4 carbon atom, R7For with 1
The saturated or unsaturated alkyl of~24 carbon atoms, A are oxygen atom or NH base or are not present) represented by make acrylic acid
Dialkylamino ethyl, methacrylic acid dialkylamino ethyl, Diacetone Acrylamide etc. and acrylic acid, methacrylic acid,
Alkyl acrylate, alkyl methacrylate etc. are copolymerized, and are subject to compound made of amphoterisation using halogenated acetic acids
[commercially available product: Yuka Former AM75 (Mitsubishi Chemical Ind's manufacture)];Or Amphomer (manufacture of AkzoNobel company) institute's generation
Hydroxypropyl acrylate, butylaminoethyl, acrylic acid caprylamide copolymer of table etc..
As cationic macromolecule resin compound, for instance that (manufacture of Lubrizol company) the institute's generation of Marcoat 100
Poly- [dimethyl diallyl ammonium halide] the type cationic polymer of table;(manufacture of Lubrizol company) the institute's generation of Marcoat 550
The dimethyl diallyl ammonium halide of table and the copolymer cation polymer of acrylamide;Polymer JR-400, polymer
Cellulose ether containing quaternary nitrogen representated by JR-125 and polymer JR-30M (the above are the manufactures of Union Carbide company);
Polyethylene glycol representated by Polycoat H (manufacture of Henkel company), epichlorohydrin, allylamine, tallow amide copolymer;
Polyethylene glycol, epichlorohydrin, coconutalkyl amine, dipropylenetriamine representated by Polycoat NH (manufacture of Henkel company)
Copolymer;H.C. polymer 1, H.C. polymer 1N, H.C. polymer 2, (the above are Osaka Organic Chemical Industry companies by HCP-3A
Manufacture), vinyl pyrrolidone, methacrylic acid two representated by Gafquat 755 and 734 (the above are the manufactures of ISP company)
Methylamino methacrylate copolymers cation compound etc..
It as nonionic macromolecule resin compound, such as can enumerate: PVP/VA (manufacture of ISP company), Luviskol
Vinyl pyrrolidone and second representated by VA (BASF AG's manufacture) and PVA6450 (manufacture of Osaka Organic Chemical Industry company)
Polyvinyl representated by the copolymer of vinyl acetate, PVPK (manufacture of ISP company) and Luviskol K (BASF AG's manufacture)
Pyrrolidones, Luviflex D4101 (BASF AG's manufacture), polyvinyl alcohol, vinylpyrrolidone/vinyl acetate-propylene
Dialkylaminobenzoic acid amino ethyl ester copolymer, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, methylcellulose, second
Base cellulose, dextrin, poly- galactolipin, pulullan polysaccharide etc..
As anionic property macromolecule resin compound, specifically have: the block copolymer of anionic property, such as
Diahold A-403 (Mitsubishi Chemical Ind's manufacture), ANISET, KB-1000, KB-100H, B-1015, HS-3000 (the above are
Osaka Organic Chemical Industry company manufacture), Plus size L-33, L-53, L-9909B and L-6330 (the above are mutual induction chemistry
Industrial group manufacture) representated by anionic property acrylic acid series polymeric compounds (indicate title: (acrylate/methacrylate
(C12,13) ester/methoxyethyl acrylate) cross-linked polymer, alkyl acrylate copolymer AMP, (acrylate/acrylic acid
Alkyl (C1-18) ester/alkyl (C1-8) acrylamide) copolymer A MP, (acrylate/diacetone acrylamide) copolymer
Deng), BEM-42S, WEM-22S (the above are the manufactures of Osaka Organic Chemical Industry company), Gantrez ES-425, ES-225, ES-
Copolymer, the Resin of methyl vinyl ether and maleic acid monoalkyl ester representated by 33 (the above are the manufactures of ISP company)
28-1310, Resin 28-2930 (the above are the manufactures of AkzoNobel company), Luviset CE5055 (BASF AG's manufacture),
Acrylic acid and alkyl acrylate representated by the copolymer of vinyl acetate and butenoic acid, Ultrahold 8 (BASF AG's manufacture)
Copolymer, carboxymethyl cellulose, carboxyl vinyl polymer, Xanthan gum, the carrageenan, sea of base ester and N- alkyl acrylamide
Mosanom, Arabic gum, pectin etc..
It should be noted that being simple example above, and the resin of haircuting in the present invention is not limited to these.This hair
In bright, the acrylic acid series macromolecule resin of anionic property for example can particularly preferably use Japanese Patent Laid-Open 2012-162519
The block polymer etc. recorded in bulletin.
The use level of resin of haircuting in treatment compositions of the invention be 0.01 mass % or more and 2.0 mass % with
Under, preferably 0.01~1.0 mass %, more preferable 0.01~0.5 mass %.If use level is lower than 0.01 mass %, can not obtain
It obtains by addition bring improvement effect, if use level is more than 2.0 mass %, generates the stiff sense caused by resin, and can not
Obtain slim and graceful and soft sense of touch.
In the range of its pH value is preferably modulated to 4.0~7.5 by treatment compositions of the invention, more preferable 4.3~7.2,
Preferably 4.6~7.0 range in turn.By the way that pH value to be set as in above range, and while smearing, will not be tacky, slim and graceful and soft
It is further promoted using sense of touch.
The pH value for the treatment of compositions of the invention can be by cooperating the pH regulator that can usually cooperate (packet in cosmetics etc.
Containing acid agent, alkaline agent, buffer system) and adjust.As buffer system, lactic acid/sodium lactate etc. can be enumerated, but is not limited to
This.
In addition, amino acid, particularly aliphatic amino acid, especially the third ammonia of L- can be cooperated in treatment compositions of the invention
Acid can further improve moulding and keep effect by cooperating mentioned component.
It, can also be in the range of interfering effect of the invention in treatment compositions of the invention, cooperation can be matched with
To the other compositions in the composition of keratin fiber processing, particularly the moulding of hair or eyelashes etc..As other compositions,
Such as it can enumerate: polyalcohol, lower alcohol, surfactant, higher alcohol, carbohydrate (disaccharides such as monosaccharide, trehalose, oligosaccharides
Class), ceramide, phosphatide, plant extract, silicone and silicone derivative, various dyestuffs, metal ion blocking agent, preservative,
Ultraviolet absorbing agent, antioxidant, fragrance etc..
Treatment compositions of the invention can be used as to form curling to keratin fibers such as hair or eyelashes or straight make
The flushing-free of type is haircuted or moulding cosmetics.Its dosage form is not particularly limited, and liquid, mist, white shape, glue, bubble can be made
The various forms such as shape, aerosol form.
Treatment compositions of the invention preferably can form moulding by keratin fiber under heating.
As specific application method, as long as such as smearing processing of the invention on the keratin fibers such as hair or eyelashes
Composition carries out moulding formation using hair iron or hot crimper, curling iron, lash curler etc..As heating temperature, preferably
40~200 DEG C, for hair, it is preferably set to 160~200 DEG C of range.Then, can also arbitrarily implement to utilize hair dryer
Blowing sizing.
Embodiment
It is exemplified below embodiment the present invention is described in further detail, but the present invention is not by any restriction of these embodiments.Cooperation
As long as amount is recorded without special, indicated with the quality % relative to the total composition for being combined with the ingredient.
Keratin fiber treatment compositions are prepared by formula documented by 1~table of table 3 below.It please professional functional panelist
Using the composition (sample) of each example, project below (1)~(6) are evaluated according to following methods and benchmark.
(1) shaping force (ability of moulding (curling into) is carried out to hair such as ideal)
(2) persistence (ability for keeping (keep) to be formed by curly form) crimped
(3) the not sticky degree (and no-trump sample felt when being applied on hair tacky feel) when smearing
(4) the not stiff degree crimped (after curling into, moves towards the combing stiff sense of hair Shu Shiwu along hair with finger
Feel, be also " good degree of cardability ")
(5) pliability (flexible touch for being formed by curling itself) crimped
(6) the slim and graceful degree (the slim and graceful sense of touch for being formed by curling) crimped
< evaluation method and evaluation criteria >
(1) shaping force (curling into ability)
The sample 0.3g that each example is equably smeared on the hair beam of the hair (1g) comprising length 10cm keeps it naturally dry
It after dry 2 hours, is wound on the hair iron for having been set to 180 DEG C, measures the apparent length for the hair beam removed from hair iron
(L1).Based on measured value (L1), diameter (L0) unanimous circumstances of the diameter of the hair beam of curling and hair iron are considered as ideal
It is worth (100%), shaping force is defined by following formula.
Shaping force (%)=100- (L1-L0) ÷ (10-L0) × 100
(value is closer to 100%, then it represents that shaping force is higher)
A++: shaping force is 70% or more
A+: shaping force is 60% or more
A: shaping force is 50% or more
B: shaping force is lower than 50%
(2) persistence (retentivity) crimped
For the pieces after the sizing (curling into) in the same manner as above-mentioned (1), in 25 DEG C, the thermostatic constant wet chamber of humidity 80%
Middle one end is fixed and suspend in midair, taken out after 120 minutes, again measure pieces apparent length (L2).According to measured value (L2), lead to
Cross the persistence (retentivity) that following formula defines curling.
Retentivity (%)=100- (L2-L0) ÷ (10-L0) × 100
(value is bigger, then it represents that the persistence (retentivity) of curling is more excellent)
A++: shaping force is 25% or more
A+: retentivity is 20% or more
A: retentivity is 10% or more
B: retentivity is lower than 10%
(3) other assessment items of~(6)
It is carried out being based on following scoring benchmark using test by 10 professional functional panelists, evaluation takes the sample of each example
To on hand and when being applied to hair not sticky degree, curl into after not stiff degree, pliability or slim and graceful degree.
(scoring benchmark)
5 points: confirming
4 points: slightly confirming
3 points: only can fine confirm
2 points: being almost not confirmed
0 point: it is fully validated less than
(evaluation criteria)
A+: total is divided into 40 points or more
A: total is divided into 25 points more than or lower than 40 points
B: total score is lower than 25 points
[table 1]
As shown in table 1, the Examples 1 to 3 for being combined with the antierythrite as sugar alcohol, D-sorbite or maltitol is institute
There is evaluation excellent in project.Wherein, antierythrite is the most excellent.In contrast, be combined with as monosaccharide glucose or
In patent document 3 in the comparative example 1 and 2 of documented hydrolysis of keratin, the persistence especially crimped is poor.
[table 2]
(*) Diaformer Z732 (Mitsubishi Chemical Ind's manufacture)
As shown in table 2, by also cooperating urea other than sugar alcohol, and shaping force further increases (embodiment 4).In addition,
It adjusts about will be independently matched with sugar alcohol or be combined with the pH value of combined composition of sugar alcohol and urea to 4.0~7.5 implementation
Example 5~9, the persistence especially crimped is extremely excellent, and pH value, which is adjusted the embodiment 6 and 7 in the range of 4.6~7.0, is
The result of extremely excellent (A+) is obtained in all items evaluated.
It is contrasted with these embodiments, about the amido containing oxidation recorded in the patent document 2 by 2 mass % of cooperation
Resin (cationic resin) and reached it is good curling persistence comparative example 3 and 4, no matter whether there is or not sugar alcohol and ureas, have
The stiff sense caused by resin is felt in sticky sense when smearing, does not obtain soft and slim and graceful use feeling.
[table 3]
(*) Diahold A-403 (Mitsubishi Chemical Ind's manufacture) [indicates title: (acrylate/methacrylate
(C12,13) ester/methoxyethyl acrylate) cross-linked polymer]
As a result, if also adding urea and l-Alanine, Yu Suoyou other than sugar alcohol (antierythrite) according to shown in table 3
Assessment item in it is extremely excellent.Even if cooperating 2 mass % anionic properties below to haircut resin in these compositions, also not
The sticky sense or stiff sense of touch when smearing can be generated, soft and slim and graceful curling is formd.In contrast, about unmated sugar alcohol
And be only combined with anionic property and haircut the comparative example 5 and 6 of resin, stiff sense of touch is produced, does not obtain soft curling.
Claims (10)
1. a kind of keratin fiber treatment compositions, which is characterized in that contain sugar alcohol.
2. keratin fiber treatment compositions according to claim 1, and then contain urea and/or urea derivative.
3. keratin fiber treatment compositions according to claim 1, and then contain resin of haircuting.
4. keratin fiber treatment compositions according to claim 1, so contain urea and/or urea derivative and
It haircuts resin.
5. keratin fiber treatment compositions according to any one of claim 1 to 4, the pH value of its composition is 4.0
In the range of~7.5.
6. keratin fiber treatment compositions according to any one of claim 1 to 5, wherein the sugar alcohol is red moss
Sugar alcohol.
7. keratin fiber treatment compositions according to any one of claim 3 to 6, wherein the resin of haircuting is
Anionic property resin.
8. keratin fiber treatment compositions according to claim 7, wherein the anionic property resin is block copolymerization
Object.
9. the keratin fiber treatment compositions according to any one of claim 3 to 8, wherein the resin of haircuting
Use level is 2.0 mass % or less.
10. keratin fiber treatment compositions according to any one of claim 1 to 9 are used for the hot moulding of hair.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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JP2016229949 | 2016-11-28 | ||
JP2016-229949 | 2016-11-28 | ||
PCT/JP2017/042482 WO2018097304A1 (en) | 2016-11-28 | 2017-11-28 | Keratin fiber treatment composition |
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Publication Number | Publication Date |
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CN109862871A true CN109862871A (en) | 2019-06-07 |
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CN201780065859.2A Pending CN109862871A (en) | 2016-11-28 | 2017-11-28 | Keratin fiber treatment compositions |
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JP (1) | JP7161407B2 (en) |
KR (1) | KR20190089853A (en) |
CN (1) | CN109862871A (en) |
AU (1) | AU2017364814A1 (en) |
SG (1) | SG11201901985XA (en) |
TW (1) | TW201829021A (en) |
WO (1) | WO2018097304A1 (en) |
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- 2017-11-28 KR KR1020197011796A patent/KR20190089853A/en unknown
- 2017-11-28 JP JP2018553011A patent/JP7161407B2/en active Active
- 2017-11-28 SG SG11201901985XA patent/SG11201901985XA/en unknown
- 2017-11-28 WO PCT/JP2017/042482 patent/WO2018097304A1/en active Application Filing
- 2017-11-28 CN CN201780065859.2A patent/CN109862871A/en active Pending
- 2017-11-28 AU AU2017364814A patent/AU2017364814A1/en not_active Abandoned
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JP2004217589A (en) * | 2003-01-16 | 2004-08-05 | Shiseido Co Ltd | Permanent hair treatment agent for dyed hair and method for preventing fading of dyed hair |
CN1535672A (en) * | 2003-02-25 | 2004-10-13 | �ź㴫 | Cosmetic composition containing polymer granules, acid and polyol ester dispersion |
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Title |
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孙常文等: "赤藓糖醇的特性分析及应用优势", 《精细与专用化学品》 * |
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JPWO2018097304A1 (en) | 2019-10-17 |
SG11201901985XA (en) | 2019-04-29 |
KR20190089853A (en) | 2019-07-31 |
JP7161407B2 (en) | 2022-10-26 |
AU2017364814A1 (en) | 2019-04-11 |
WO2018097304A1 (en) | 2018-05-31 |
TW201829021A (en) | 2018-08-16 |
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