CN109830717A - It is a kind of based on calcium stannate/strontium iron molybdenum composite material low-temperature solid oxide fuel cell - Google Patents
It is a kind of based on calcium stannate/strontium iron molybdenum composite material low-temperature solid oxide fuel cell Download PDFInfo
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- CN109830717A CN109830717A CN201811547084.5A CN201811547084A CN109830717A CN 109830717 A CN109830717 A CN 109830717A CN 201811547084 A CN201811547084 A CN 201811547084A CN 109830717 A CN109830717 A CN 109830717A
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- solid oxide
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- 239000000446 fuel Substances 0.000 title claims abstract description 63
- 239000002131 composite material Substances 0.000 title claims abstract description 47
- 239000007787 solid Substances 0.000 title claims abstract description 29
- HNQGTZYKXIXXST-UHFFFAOYSA-N calcium;dioxido(oxo)tin Chemical compound [Ca+2].[O-][Sn]([O-])=O HNQGTZYKXIXXST-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 229910052712 strontium Inorganic materials 0.000 title claims abstract description 12
- DSMZRNNAYQIMOM-UHFFFAOYSA-N iron molybdenum Chemical compound [Fe].[Fe].[Mo] DSMZRNNAYQIMOM-UHFFFAOYSA-N 0.000 title claims abstract 8
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 title claims abstract 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 70
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 35
- 239000006260 foam Substances 0.000 claims abstract description 34
- 239000003792 electrolyte Substances 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims description 28
- 239000000843 powder Substances 0.000 claims description 20
- 239000011259 mixed solution Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 6
- 238000005245 sintering Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 claims 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims 1
- 235000011613 Pinus brutia Nutrition 0.000 claims 1
- 241000018646 Pinus brutia Species 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 229940055577 oleyl alcohol Drugs 0.000 claims 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 claims 1
- 230000000630 rising effect Effects 0.000 claims 1
- 238000003487 electrochemical reaction Methods 0.000 abstract description 3
- DVLWCGGXLOMGRO-UHFFFAOYSA-N [Mo].[Fe].[Sr] Chemical compound [Mo].[Fe].[Sr] DVLWCGGXLOMGRO-UHFFFAOYSA-N 0.000 abstract description 2
- 230000010287 polarization Effects 0.000 abstract description 2
- 230000006835 compression Effects 0.000 description 8
- 238000007906 compression Methods 0.000 description 8
- -1 oxygen ion Chemical class 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 239000004065 semiconductor Substances 0.000 description 7
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 5
- KJNGJIPPQOFCSK-UHFFFAOYSA-N [H][Sr][H] Chemical compound [H][Sr][H] KJNGJIPPQOFCSK-UHFFFAOYSA-N 0.000 description 4
- KWUUWVQMAVOYKS-UHFFFAOYSA-N iron molybdenum Chemical compound [Fe].[Fe][Mo][Mo] KWUUWVQMAVOYKS-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 229910017018 Ni0.8Co0.15Al0.05 Inorganic materials 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 2
- 230000037427 ion transport Effects 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002114 nanocomposite Substances 0.000 description 2
- 238000000643 oven drying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- RBNWAMSGVWEHFP-UHFFFAOYSA-N trans-p-Menthane-1,8-diol Chemical compound CC(C)(O)C1CCC(C)(O)CC1 RBNWAMSGVWEHFP-UHFFFAOYSA-N 0.000 description 2
- 229910001148 Al-Li alloy Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- JTCFNJXQEFODHE-UHFFFAOYSA-N [Ca].[Ti] Chemical compound [Ca].[Ti] JTCFNJXQEFODHE-UHFFFAOYSA-N 0.000 description 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 1
- FCVHBUFELUXTLR-UHFFFAOYSA-N [Li].[AlH3] Chemical compound [Li].[AlH3] FCVHBUFELUXTLR-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000002001 electrolyte material Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
Abstract
The invention discloses a kind of based on calcium stannate/strontium iron molybdenum composite material low-temperature solid oxide fuel cell, and the cathode and anode of the fuel cell are the nickel foam that surface is coated with NCAL, and the electrolyte layer of the fuel cell is CSO/SFM composite material.The structure of fuel cell i.e. of the present invention are as follows: nickel foam //NCAL//CSO/SFM//NCAL//nickel foam.Low-temperature solid oxide fuel cell of the present invention, as its electrolyte layer, substantially reduces the electrode polarization loss during electrochemical reaction of fuel battery using the calcium stannate of perovskite structure and the composite material of strontium iron molybdenum；The electrolyte has good output power in low-temperature zone, to make efficient stable to run for a long time using the solid oxide fuel cell of the electrolyte in low-temperature zone (300-600 degree).
Description
Technical field
The present invention relates to a kind of based on calcium stannate/strontium iron molybdenum composite material low-temperature solid oxide fuel cell, belongs to
Field of new energy technologies.
Background technique
Chemical energy in fuel (such as hydrogen, methane) can be efficiently converted to electric energy by solid oxide fuel cell.
Transfer efficiency is not limited by Carnot cycle, and efficiency is much higher than thermal power generation unit.Fuel cell is electrolysed qualitative classification by it can
It is divided into Proton Exchange Membrane Fuel Cells, solid oxide fuel cell, alkaline fuel cell, molten carbonate fuel cell, phosphorus
Hydrochlorate fuel cell, wherein solid oxide fuel does not need that noble metal catalyst, material selection range be wide, high conversion efficiency
The advantages that, it receives significant attention.But current solid oxide fuel cell mainly uses yttria-stabilized zirconia
(YSZ) it is used as electrolyte, YSZ needs that higher catalytic activity could be obtained in high temperature (900 degree or so).Therefore traditional solid
Oxide fuel cell generally all operates in the condition of high temperature.Hot operation all proposes that harshness is wanted to battery material, connecting material
It asks, in addition, hot operation proposes challenge to solid oxide fuel cell long-time stability.Therefore research low-temperature zone (300-
600 degree) solid oxide fuel cell in recent years, cause extensive concern.
Currently, the electrolyte of the solid oxide fuel cell based on cathode-electrolyte-anode structure is using relatively broad
YSZ (zirconium oxide of stabilized with yttrium oxide) complete fuel cell in 900 degree or so oxygen ion conduction abilities with higher
Electrochemical reaction, electromotive power output.But the material (YSZ) only just has good oxygen ion transport ability at high temperature,
When temperature is reduced to 600 degree hereinafter, almost without oxygen ion conduction ability.Therefore, in recent years, about reduction soild oxide combustion
Expect that the technology of battery is more and more, be concentrated mainly on two technology paths, first is that developing thin film technique, is thinned electrolyte YSZ's
Thickness so that its middle-temperature section also can ion transport capability with higher, but due to technical limitations, thickness can not
It is unlimited to be thinned, and thin film technique yield rate is also not very high；Second is that developing new material, ion can be transmitted in low-temperature zone by finding
New material.
Fuel cell is a typical electrochemical device, and the effect of intermediate electrolyte is transmission ion and prevention electronics
Transmission.Electrolyte according to semiconductor material as fuel cell, it is easy to people be allowed to associate the hair of short circuit phenomenon
Raw, just because of this, the material with semiconductor property is so far without using in a fuel cell.The a large amount of experimental study of the present invention
Show by the semiconductor material Application of composite with perovskite structure or perovskite-like structure fuel cell electrolysis material
In material, any short circuit phenomenon does not occur, and electrolyte composite material also has good output power in low-temperature zone.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of based on calcium stannate/strontium iron molybdenum composite material low-temperature solid
Oxide fuel cell, the electrolyte in the fuel cell use the N-type semiconductor material stannic acid with perovskite structure
Calcium (CSO) and p-type semiconductor material strontium iron molybdenum (SFM) with perovskite structure are compound, and obtained electrolyte composite material is not
The transmission of electronics can be only prevented, but also there is high ionic conductivity, therefore the electrolyte composite material is in low-temperature zone
With good output power, to enable using the solid oxide fuel cell efficient operation of the electrolyte low
Temperature section (300-600 degree).
In order to solve the above technical problems, the technical scheme adopted by the invention is as follows:
It is a kind of based on calcium stannate/strontium iron molybdenum composite material low-temperature solid oxide fuel cell, the yin of the fuel cell
Pole and anode are the nickel foam that surface is coated with NCAL, and the electrolyte layer of the fuel cell is CSO/SFM composite material.
The structure of fuel cell of the present invention are as follows: nickel foam //NCAL//CSO/SFM//NCAL//nickel foam.
Wherein, the nickel foam that surface is coated with nickel cobalt aluminium lithium (NCAL) is prepared with the following method: will be the desired amount of
NCAL(Ni0.8Co0.15Al0.05LiO2-δ) powder is gradually added into terpinol, until mixture is starchiness, starchy will mix
It closes object to be uniformly applied in nickel foam, the nickel foam after smearing is put into baking oven drying 2 hours at 200 DEG C, can be obtained
Surface is coated with the nickel foam of NCAL.
Wherein, it is 1: 2 mixed that the CSO/SFM composite material is by nanometer CSO powder and nanometer SFM powder in mass ratio
It closes, is fully ground acquisition.
The preparation method of above-mentioned CSO/SFM composite material, specifically comprises the following steps:
Step 1, CSO (CaSnO is prepared3) powder:
The tin tetrachloride of 0.025mol is dissolved in the ethylene glycol of 1mol, obtains mixed solution A, is added into mixed solution A
0.25mol citric acid stirs 2 hours under 60 degree, after completely dissolution, obtains mixed solution B, be added into mixed solution B
The CaCO of 0.025mol3, under 80 degree of constant temperature, stirs 6 hours, obtains mixed solution C, mixed solution C is heated to 135 degree,
Heating 12 hours or more, transparent gel is obtained, gel is heated 3 hours under 350 degree, obtains xerogel, then Ca will be contained
Xerogel be put into heating furnace heat 700 degree, sintering 4 hours, cooled to room temperature after the completion of sintering, fills sinter
Divide grinding, obtains CSO powder；
Step 2, CSO/SFM composite material is prepared:
By CSO powder made from step 1 and SFM (Sr2Fe1.5Mo0.5O6-δ) mixing of powder in mass ratio 1: 2, it is fully ground
After can be obtained CSO/SFM composite material.
Wherein, in step 1, the heating of gel is divided into two processes: firstly, with the heating rate of 5 DEG C/min, from room temperature
350 degree are risen to, is sintered 3 hours, then rises to 700 DEG C from 350 temperature, is sintered 4 hours, cooled to room temperature.
The preparation of low-temperature solid oxide fuel cell of the present invention:
The nickel foam that surface is coated with NCAL is fabricated to electrode, electrode size is circle, and diameter D=i3mm, electrode is being received
It the both sides nano composite material CSO/SFM, will in symmetrical structure, i.e. nickel foam //NCAL//CSO/SFM//NCAL//nickel foam structure
Piece of foam nickel //NCAL is put into compression mold bottom, and surface is coated with the one side of NCAL upward, takes the CSO/SFM of 0.35g compound
Material is put into compression mold, then another nickel foam //NCAL is put into compression mold, is placed on CSO/SFM composite material
Face, surface be coated with NCAL one down, compression mold is put into tablet press machine, is forced into 8Mpa, after pressure maintaining 5 seconds, take out battery
Piece obtains low-temperature solid oxide fuel cell of the invention.
Compared with the prior art, technical solution of the present invention has the beneficial effect that
Low-temperature solid oxide fuel cell of the present invention has the CSO material of perovskite structure using Moist chemical synthesis, then
The SFM of CSO material obtained and perovskite structure is subjected to dry mixed, composite electrolyte of the invention is obtained after being fully ground
Material C SO/SFM, obtained electrolyte composite material can not only prevent the transmission of electronics, but also have high ionic conduction
Ability, therefore the electrolyte composite material has good output power in low-temperature zone, while composite material also substantially reduces
Electrode polarization loss during electrochemical reaction of fuel battery；Therefore make the soild oxide using the electrolyte composite material
Fuel cell being capable of long-term efficient stable operation in low-temperature zone (300-600 degree).
Detailed description of the invention
Fig. 1 is the structural schematic diagram of low-temperature solid oxide fuel cell of the present invention；
Fig. 2 is that the I-V when test temperature is 550 degree and I-P is special respectively for the fuel cell of CSO and SFM different quality ratio
Linearity curve；Under 550 degree of service condition, when the mass ratio of CSO and SFM is 1: 2, peak power output reaches 629mW/cm2；
Fuel cell when Fig. 3 is CSO and the mass ratio of SFM is 1: 2 is respectively when test temperature is 550,525,500 degree
I-V and I-P characteristic curve；Peak power output is respectively 629mW/cm2, 460mW/cm2, 316mW/cm2；
Ac impedance characteristic curve when Fig. 4 is CSO and the mass ratio of SFM is 1: 2 under hydrogen-oxygen atmosphere；
Fig. 5 is ac impedance characteristic curve of the pure CSO under hydrogen-oxygen atmosphere；
Fig. 6 is the space-charge region formed after electrolyte composite material combines.
Specific embodiment
According to following embodiments, the present invention may be better understood.However, as it will be easily appreciated by one skilled in the art that real
It applies content described in example and is merely to illustrate the present invention, without sheet described in detail in claims should will not be limited
Invention.
As shown in Figure 1, the nickel foam that surface is coated with NCAL constitutes symmetry electrode, fuel battery negative pole of the present invention and anode are equal
It is coated with the nickel foam of NCAL using surface, core electrolyte layer is CSO and SFM composite material, therefore the structure of the fuel cell
Are as follows: nickel foam //NCAL//CSO/SFM//NCAL//nickel foam；Wherein, NCAL Ni0.8Co0.15Al0.05LiO2-δMaterial is (commercially available
Buy or be prepared using disclosed method), CSO is commercially available or is made using the method for the present invention that SFM is commercially available；Nickel foam is
The nickel material of commercially available foam-like.
The preparation method of fuel cell of the present invention:
First prepare the nickel foam (anode and cathode as fuel cell) that surface is coated with NCAL: by NCAL
(Ni0.8Co0.15Al0.05LiO2-δ) powder is gradually added into terpinol, until mixture is starchiness, by starchy mixture
It is uniformly applied in nickel foam, the nickel foam after smearing is put into baking oven drying 2 hours at 200 DEG C, surface can be obtained
It is coated with the nickel foam of NCAL；
CSO/SFM composite material (electrolyte layer-generating element as fuel cell) is prepared again:
Step 1, CSO (CaSnO is prepared3) powder:
The tin tetrachloride of 0.025mol is dissolved in the ethylene glycol of 1mol, obtains mixed solution A, is added into mixed solution A
0.25mol citric acid stirs 2 hours under 60 degree, after completely dissolution, obtains mixed solution B, be added into mixed solution B
The CaCO of 0.025mol3, under 80 degree of constant temperature, stirs 6 hours, obtains mixed solution C, mixed solution C is heated to 135 degree,
Heating 12 hours or more, transparent gel is obtained, gel is heated 3 hours under 350 degree, obtains xerogel, then Ca will be contained
Xerogel be put into heating furnace heat 700 degree, sintering 4 hours, cooled to room temperature after the completion of sintering, fills sinter
Divide grinding, obtains CSO powder；Has perovskite structure using CSO prepared by sol-gel method；
Step 2, SFM (Sr is bought2Fe1.5Mo0.5O6-δ) powder:
Step 3, CSO/SFM composite material is prepared:
CSO powder made from step 1 is mixed with the SFM powder in mass ratio 1: 2 of purchase, can be obtained after being fully ground
CSO/SFM composite material.
Finally, combining electrode material obtained with electrolyte, low-temperature solid oxide fuel of the invention is obtained
Battery:
The nickel foam that surface is coated with NCAL is fabricated to electrode, electrode size is circle, and diameter D=13mm, electrode is being received
The both sides nano composite material CSO/SFM are in symmetrical structure, i.e. nickel foam //NCAL//CSO/SFM//NCAL//nickel foam structure, first
Piece of foam nickel //NCAL is put into compression mold bottom, surface is coated with the one side of NCAL upward, then takes the CSO/SFM of 0.35g
Composite material is put into compression mold, and another nickel foam //NCAL is finally put into compression mold, it is compound to be placed on CSO/SFM
Above material, surface be coated with NCAL one down, compression mold is put into tablet press machine, 8Mpa is forced into and is taken after pressure maintaining 5 seconds
Cell piece out obtains low-temperature solid oxide fuel cell of the invention.
Experimental study shows that pure CSO can also be used as the electrolyte of fuel cell, but output performance is poor, and unstable
It is fixed, can be seen that from Fig. 2, Fig. 3, by CSO material by different quality ratio and SFM carry out it is compound after, when the mass ratio of CSO and SFM is 1
: when 2, chemical property reaches 629mW/cm2, change the mass ratio of CSO and SFM, apparent variation, CSO occurs in battery performance
With SFM mass ratio be 1: 1 when, the maximum output power of fuel cell be 403mW/cm2, when CSO and SFM mass ratio are 1: 2
When, the maximum output power of fuel cell is 629mW/cm2, when CSO is 1: 3 with SFM mass ratio, fuel cell is maximum
Output power is 517mW/cm2, compared with output power when CSO: SFM mass ratio is 1: 2, it is declined slightly, if further added
The quality accounting of SFM in big composite material, the performance of composite material will be close to pure SFM, gradually reduce, when SFM accounting is close to 1
When (in composite material be almost pure SFM), cell output almost disappears；As CSO in further increasing composite material
Quality accounting, performance are gradually intended to the output performance of pure CSO.To sum up result of study is it is found that CSO and SFM is pressed centainly
Ratio is compound, and obtained composite material has high ionic conductivity in low-temperature zone, to have big output power, passes through
Experimental study shows that the two optimum quality ratio is 1: 2.
In Fig. 4, first intersection point of ac impedance characteristic curve and the imaginary axis when CSO and SFM mass ratio are 1: 2 represents Europe
Nurse loss, value is about 0.31 Ω cm2, second intersection point of ac impedance characteristic curve and the imaginary axis represent crystal boundary loss,
Value is of about for 0.38 Ω cm2.In Fig. 5, the ac impedance characteristic curve of pure CSO and first intersection point of the imaginary axis represent ohm damage
It loses, value is about 0.52 Ω cm2, second intersection point of ac impedance characteristic curve and the imaginary axis represent crystal boundary loss, and value reaches
About 0.93 Ω cm2。
Through comparison diagram 4, Fig. 5 it is found that compared with the impedance operator of pure CSO, ohm of the composite material of CSO and SFM is damaged
It loses and crystal boundary loss all substantially reduces, greatly promoted to prove that the performance of composite material has.
The structure of fuel cell of the present invention, nickel foam are respectively used to anode and cathode to promote the redox reaction at the two poles of the earth
Process and play the role of electronics collection.The present invention is by the N-type semiconductor material CSO with perovskite structure and has calcium titanium
The p-type semiconductor material SFM of mine structure is compound, as shown in fig. 6, can be formed in electrolyte layer by nanostructure P-type material and N
The space-charge region that profile material is established, space-charge region can cause band curvature to establish strong built in field at the interface (P-N), into
And accelerate the conduction of velocity (oxonium ion is accelerated in space-charge region) of oxonium ion, while the space-charge region can prevent electricity
The transmission of son；Traditional electrolyte is to transmit ion in the electrolyte, i.e. left side oxygen ion concentration
It is continuously increased, so that the oxygen ion concentration of bath surface is continuously increased, at high temperature, oxonium ion is spread into electrolyte, gradually
Another side is gradually reached to react with hydrogen ion, and compound electrolyte material of the present invention does not need to be can be realized at high temperature by oxonium ion
It is quickly transmitted to hydrogen ion side, therefore electrolyte composite material of the present invention has good output power in low-temperature zone.
Claims (6)
1. a kind of based on calcium stannate/strontium iron molybdenum composite material low-temperature solid oxide fuel cell, it is characterised in that: the combustion
The electrolyte layer for expecting battery is CSO/SFM composite material.
2. it is according to claim 1 based on calcium stannate/strontium iron molybdenum composite material low-temperature solid oxide fuel cell,
Be characterized in that: the cathode and anode of the fuel cell are the nickel foam that surface is coated with NCAL.
3. it is according to claim 2 based on calcium stannate/strontium iron molybdenum composite material low-temperature solid oxide fuel cell,
Be characterized in that: the nickel foam that surface is coated with NCAL is prepared with the following method: the desired amount of NCAL powder is added to pine
In oleyl alcohol, starchy mixture is obtained, starchy mixture is uniformly applied in nickel foam, table can be obtained after drying
Face is coated with the nickel foam of NCAL.
4. it is according to claim 1 based on calcium stannate/strontium iron molybdenum composite material low-temperature solid oxide fuel cell,
Be characterized in that: the CSO/SFM composite material is by after the CSO powder for preparing wet process and SFM powder dry mixed, sufficiently
It grinds and is made.
5. it is according to claim 4 based on calcium stannate/strontium iron molybdenum composite material low-temperature solid oxide fuel cell,
Be characterized in that: the preparation method of the CSO/SFM composite material specifically comprises the following steps:
Step 1, CSO powder is prepared:
The tin tetrachloride of 0.025mol is dissolved in the ethylene glycol of 1mol, obtains mixed solution A, is added into mixed solution A
0.25mol citric acid stirs 2 hours under 60 degree, after completely dissolution, obtains mixed solution B, be added into mixed solution B
The CaCO of 0.025mol3, under 80 degree of constant temperature, stirs 6 hours, obtains mixed solution C, mixed solution C is heated to 135 degree,
Heating 12 hours or more, transparent gel is obtained, gel is heated 3 hours under 350 degree, obtains xerogel, then Ca will be contained
Xerogel be put into heating furnace heat 700 degree, sintering 4 hours, cooled to room temperature after the completion of sintering, fills sinter
Divide grinding, obtains CSO powder；
Step 2, CSO/SFM composite material is prepared:
CSO powder made from step 1 is mixed with SFM powder in mass ratio 1: 2, it is multiple to can be obtained CSO/SFM after being fully ground
Condensation material.
6. it is according to claim 5 based on calcium stannate/strontium iron molybdenum composite material low-temperature solid oxide fuel cell,
Be characterized in that: in step 1, the heating of gel is divided into two processes: firstly, with the heating rate of 5 DEG C/min, rising to from room temperature
It 350 degree, is sintered 3 hours, then rises to 700 DEG C from 350 temperature, be sintered 4 hours, cooled to room temperature.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101320814A (en) * | 2008-06-25 | 2008-12-10 | 施秀英 | Electrolyte material of low temperature oxide fuel battery and preparation method thereof |
| CN105428677A (en) * | 2015-12-02 | 2016-03-23 | 中北大学 | BaSnO3 based multiphase electrolyte material and preparation method thereof |
| CN105655617A (en) * | 2014-11-14 | 2016-06-08 | 南京蕴纳纳米科技有限公司 | A novel new-generation advanced fuel cell developed from a perovskite solar cell technique |
| CN107221679A (en) * | 2017-05-27 | 2017-09-29 | 李俊娇 | Symmetrical electrode structure fuel cell prepared by a kind of nano composite material |
| CN108808047A (en) * | 2018-05-07 | 2018-11-13 | 湖北大学 | LSCF/Na2CO3Nanocomposite is the preparation method of fuel cell ion transport layer |
-
2018
- 2018-12-17 CN CN201811547084.5A patent/CN109830717B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101320814A (en) * | 2008-06-25 | 2008-12-10 | 施秀英 | Electrolyte material of low temperature oxide fuel battery and preparation method thereof |
| CN105655617A (en) * | 2014-11-14 | 2016-06-08 | 南京蕴纳纳米科技有限公司 | A novel new-generation advanced fuel cell developed from a perovskite solar cell technique |
| CN105428677A (en) * | 2015-12-02 | 2016-03-23 | 中北大学 | BaSnO3 based multiphase electrolyte material and preparation method thereof |
| CN107221679A (en) * | 2017-05-27 | 2017-09-29 | 李俊娇 | Symmetrical electrode structure fuel cell prepared by a kind of nano composite material |
| CN108808047A (en) * | 2018-05-07 | 2018-11-13 | 湖北大学 | LSCF/Na2CO3Nanocomposite is the preparation method of fuel cell ion transport layer |
Non-Patent Citations (2)
| Title |
|---|
| YONGDAN LI ET AL.: "Single layer fuel cell based on a composite of Ce0.8Sm0.2O2-δ-Na2CO3 and a mixed ionic and electronic conductor Sr2Fe1.5Mo0.5O6-δ", 《 JOURNAL OF POWER SOURCES》 * |
| 钱东等: "MSnO3( M =Ca, Sr, Ba) 的溶胶-凝胶法合成及性能", 《电池》 * |
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