CN109830560B - Back plate of solar cell module - Google Patents

Back plate of solar cell module Download PDF

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Publication number
CN109830560B
CN109830560B CN201910024051.0A CN201910024051A CN109830560B CN 109830560 B CN109830560 B CN 109830560B CN 201910024051 A CN201910024051 A CN 201910024051A CN 109830560 B CN109830560 B CN 109830560B
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layer
pattern
ultraviolet absorber
substrate
solar cell
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CN109830560A (en
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薛文娟
周艳方
陈宏月
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Shanghai Ja Solar Pv Technology Co ltd
JA Solar Technology Yangzhou Co Ltd
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Shanghai Ja Solar Pv Technology Co ltd
JA Solar Technology Yangzhou Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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Abstract

The invention discloses a back plate of a solar cell module. The back sheet includes a substrate, and a pattern layer containing an ultraviolet absorber having a predetermined pattern disposed on an inner side surface of the substrate. According to the back plate provided by the invention, the pattern layer containing the ultraviolet absorbent is arranged on the inner side surface of the substrate, so that the back plate has a good ultraviolet resistance effect, and the power of the solar cell module is favorably improved.

Description

Back plate of solar cell module
Technical Field
The invention belongs to the technical field of solar cells, and particularly relates to a back plate of a solar cell module.
Background
At present, the basic structure of a crystalline silicon solar cell module sequentially comprises front glass, an upper layer packaging material, a cell sheet layer, a lower layer packaging material and a back plate or back glass, wherein the commonly used back plate is a white polymer composite layer. The polymer composite layer consists of an outer layer, a middle layer and an inner layer, wherein bonding materials are arranged between the outer layer and the middle layer and between the middle layer and the inner layer. In the market, solar cell back sheets are mainly classified into fluorine-containing back sheets and fluorine-free back sheets. The fluorine-containing back plate comprises two types, namely double-sided fluorine-containing (such as TPT, KPK and KPF, wherein the first letter represents an outer layer, the middle letter represents a middle layer, and the last letter represents an inner layer) and single-sided fluorine-containing (such as TPE, KPE and KPO, wherein the first letter represents the outer layer, the middle letter represents the middle layer, and the last letter represents the inner layer), wherein T refers to a polyvinyl fluoride (PVF) film, K refers to a polyvinylidene fluoride (PVDF) film, and F refers to a fluorine coating resin coating; p refers to biaxially oriented polyethylene terephthalate film (BOPET); e denotes a polyethylene film or Ethylene Vinyl Acetate (EVA) resin, and O is a polyolefin resin. The back sheet without fluorine is mostly formed by gluing and compounding multiple layers of PET or PA by using an adhesive.
However, the existing back plate has poor ultraviolet resistance.
Disclosure of Invention
The invention aims to provide a back plate of a solar cell module with good ultraviolet resistance effect.
In order to achieve the above object, the present invention provides the following technical solutions.
A back sheet for a solar cell module includes a substrate, and a pattern layer containing an ultraviolet absorber having a predetermined pattern disposed on an inner side surface of the substrate.
Optionally, the solar cell module sequentially comprises front glass, an upper layer of packaging material, a cell sheet layer, a lower layer of packaging material and a back plate, and the pattern of the pattern layer containing the ultraviolet absorber is matched with the pattern of the non-shielded region of the cell sheet in the cell sheet layer.
Optionally, the pattern in the pattern layer containing the ultraviolet absorber is in a grid shape or a strip shape.
Optionally, the pattern layer containing the ultraviolet absorber is formed by curing the ultraviolet absorber-containing paint with the preset pattern arranged on the inner side surface of the substrate.
In the present invention, the ultraviolet absorber-containing coating may be a heat-curable ultraviolet absorber-containing coating, preferably a low-temperature curable ultraviolet absorber-containing coating (curing temperature is 60 ℃ or lower). When preparing the pattern layer containing the ultraviolet absorber, coating the paint containing the ultraviolet absorber on the inner side surface of the substrate according to the pattern of the pattern layer containing the ultraviolet absorber, and curing the paint containing the ultraviolet absorber to form the pattern layer containing the ultraviolet absorber.
The uv absorber-containing coating may be applied to the inside surface of the substrate by cross-hatch coating, printing, spraying, painting, or the like.
The above-mentioned ultraviolet absorber-containing paint may be selected from conventional commercially available ultraviolet absorber-containing paints, and more preferably, the ultraviolet absorber-containing paint used for the backsheet, such as the ultraviolet absorber-containing paint disclosed in patent CN107759983a, etc.
Optionally, the substrate comprises a fluorine-containing outer layer, a non-fluorine-containing intermediate layer disposed on the outer layer, and an inner layer disposed on the intermediate layer, the pattern layer comprising the ultraviolet absorber being disposed on the inner layer; and bonding layers are arranged between the outer layer and the middle layer and between the middle layer and the inner layer.
Optionally, the inner layer contains fluorine or no fluorine.
Optionally, the inner layer covers the entire intermediate layer, or the inner layer covers a partial region of the intermediate layer.
Optionally, the inner layer has the same pattern as the pattern layer containing the ultraviolet absorber.
Optionally, the substrate is formed by compounding multiple layers of fluorine-free polymer material layers.
Technical effects
The invention has the following beneficial effects:
(1) according to the invention, the pattern layer containing the ultraviolet absorbent is arranged on the surface of the inner side of the back plate, so that the inner side of the back plate has good ultraviolet resistance, especially the ultraviolet resistance of the inner layer of the back plate at the position corresponding to the non-shielding region of the cell in the cell group of the solar cell module is enhanced, the yellowing is reduced, and the maximization of the module power is realized;
(2) the material of the pattern layer containing the ultraviolet absorbent can be selected from the pattern layer containing the ultraviolet absorbent, which is prepared by directly adopting ultraviolet absorbent coating arranged in a spraying, coating or printing mode and the like and curing at low temperature, and the method is easy to realize.
Drawings
In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings used in the description of the embodiments will be briefly introduced below.
Fig. 1 is a plan view of a solar photovoltaic module in example 1-2;
fig. 2 is a top view of a solar photovoltaic module in example 3;
FIG. 3 is a schematic structural view of a solar photovoltaic module according to embodiment 1-2;
fig. 4 is a schematic structural view of a solar photovoltaic module in example 3;
fig. 5 is a schematic structural view of a solar photovoltaic module back sheet containing a uv absorber pattern layer in example 1-2;
fig. 6 is a schematic structural view of a solar photovoltaic module backsheet comprising a uv absorber pattern layer in example 3;
the reference numerals in the drawings denote:
1 is an outer layer;
2 is an intermediate layer;
3 is an inner layer;
31 is a pattern layer containing an ultraviolet absorber;
4 is a bonding layer;
5 is front glass;
6 is an upper layer packaging material;
7 is a battery sheet layer;
8 is a lower layer packaging material;
9 is a back plate;
10 is a cell in the cell layer;
and 11 is a battery piece non-shielding area in the battery piece layer.
Detailed Description
Hereinafter, embodiments of the present invention will be described in detail.
In the invention, the inner side of the back plate refers to the side of the back plate facing the battery piece after the back plate is installed in the solar battery module; it is understood that the side of the back plate away from the battery piece is the outer side of the back plate.
Fig. 1 illustrates a structure of a back sheet for a solar cell module according to the present invention, and as shown in fig. 1, the back sheet includes a substrate, and a pattern layer 31 containing an ultraviolet absorber having a predetermined pattern disposed on an inner surface of the substrate.
According to the back plate of the solar cell module, the pattern layer containing the ultraviolet absorbent is arranged on the inner side surface of the substrate, namely the ultraviolet-resistant functional material layer is arranged on the local area of the inner side surface of the substrate, so that the ultraviolet absorbent absorbs ultraviolet light, the damage of the ultraviolet light to other parts of the back plate is reduced, the ultraviolet-resistant performance of the inner side of the back plate is enhanced, and the power of the module is improved.
Fig. 3 and 4 respectively show the structure of a solar cell module, which comprises a front glass 5, an upper layer of an encapsulating material 6, a cell sheet layer 7, a lower layer of an encapsulating material 8, and a back sheet 9 in this order, as shown in fig. 3 and 4.
In one possible implementation manner of the present invention, the pattern in the pattern layer 31 containing the ultraviolet absorber is matched with the pattern of the non-shielded region 11 of the cell 10 in the cell layer 7, that is, the pattern layer 31 containing the ultraviolet absorber is disposed on the inner side surface of the back sheet at the position corresponding to the non-shielded region 11 of the cell 10 in the cell layer of the back sheet 9 of the solar cell module. It can be understood that due to the shielding of the battery piece 10, the ultraviolet light does not irradiate the area of the back plate shielded by the battery piece 10.
As shown in fig. 5, the pattern of the pattern layer 31 containing the uv absorber is in a grid shape, and the back sheet is suitable for a solar cell module in which cells are connected by solder ribbons and a certain gap is formed between the cells.
As shown in fig. 6, the pattern of the pattern layer 31 containing the uv absorber is a stripe shape, and the back sheet is suitable for a laminated assembly, that is, adjacent cells in a cell string of the same string are connected in a laminated manner, there is no gap between adjacent cells in the cell string of the same string, and there is a gap between two adjacent strings.
Of course, in the present invention, the pattern of the pattern layer 31 containing the ultraviolet absorber is not limited to a grid or a strip, and may be set according to the type of the module, and the pattern may correspond to an area of the battery piece layer that is not blocked by the battery piece.
In the present invention, the ultraviolet absorber-containing pattern layer 31 may be formed by curing an ultraviolet absorber-containing paint having a predetermined pattern disposed on the inner surface of the substrate.
The ultraviolet absorber-containing coating may be a heat-curable ultraviolet absorber-containing coating, preferably a low-temperature-curable (curing temperature 60 ℃ or lower) ultraviolet absorber-containing coating. When preparing the pattern layer 31 containing the ultraviolet absorber, a coating material containing the ultraviolet absorber is disposed on the inner surface of the substrate according to the pattern of the pattern layer 31 containing the ultraviolet absorber (for example, the region 11 of the battery sheet 10 that is not covered by the battery sheet), and the coating material containing the ultraviolet absorber is cured to form the pattern layer 31 containing the ultraviolet absorber.
The uv absorber-containing coating may be applied to the inside surface of the substrate by cross-hatch coating, spraying, coating, printing, and the like.
It is understood that the uv absorber-containing coating material contains at least the necessary matrix resin in addition to the uv absorber.
The specific type of the ultraviolet absorber is not critical to the present invention, and conventional ultraviolet absorbers are acceptable. One ultraviolet absorbent can be used independently, and a plurality of ultraviolet absorbents can be compounded for use. For example, the uv absorber may be one or a combination of several of the following: 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-n-octyloxybenzophenone, 2, 4-dihydroxybenzophenone, 2, 4-trihydroxybenzophenone, 2- (2 '-hydroxy-3' -tert-butyl-5 '-methylphenyl) -5-chlorobenzotriazole, 2- (2' -hydroxy-3 ', 5' -di-tert-butyl-5 '-methylphenyl) -5-chlorobenzotriazole, 3- [3- (2-H-benzotriazol-2-yl) -4-hydroxy-5-tert-butylphenyl ] -propionic acid-polyethylene glycol ester, 2- (2' -hydroxy-5 '-tert-octyl) -benzotriazole, 2-hydroxy-5' -tert-octylbenzophenone, 2-hydroxy-3 '-tert-butylbenzotriazole, 5-chlorobenzotriazole, 2-hydroxy-5' -methyl, 2,2 ' -methylene- (6- (2H-benzotriazole) -4-tert-octyl) phenol, 2- (2H-benzotriazol-2-yl) -6-dodecyl-4-methylphenol, 2- (2 ' -hydroxy-5 ' -tert-octylphenyl) benzotriazole, 2- (4, 6-bis (2, 4-dimethylphenyl) -1,3, 5-triazin-2-yl) -5-octyloxyphenol, 2- [4- [ 2-hydroxy-3-tridecyloxypropyl ] oxy ] -2-hydroxyphenyl ] -4, 6-bis (2, 4-dimethylphenyl) -1,3, 5-triazine, 2-methyl-phenyl-4-methyl-phenyl-5-methyl-phenyl-4, 6-triazine, 2- [4- [ 2-hydroxy-3-dodecyloxypropyl ] oxy ] -2-hydroxyphenyl ] -4, 6-bis (2, 4-dimethylphenyl) -1,3, 5-triazine.
The ultraviolet absorber-containing paint can be transparent or white paint containing an ultraviolet absorber, so that the back plate has better ultraviolet resistance in the non-shielding region of the battery piece.
The ultraviolet absorber-containing paint can be selected from conventional commercially available ultraviolet absorber-containing paints, and is more preferably an ultraviolet absorber-containing paint used on a backsheet, such as an ultraviolet absorber-containing paint disclosed in patent CN107759983 a.
In the present invention, as shown in fig. 1 and 2, the substrate may include: an outer layer 1 containing fluorine, an intermediate layer 2 containing no fluorine provided on the outer layer 1, and an inner layer 3 provided on the intermediate layer 2, a pattern layer 31 containing an ultraviolet absorber provided on the inner layer 3; bonding layers 4 are arranged between the outer layer 1 and the middle layer 2 and between the middle layer 2 and the inner layer 3.
In this embodiment, the inner surface of the inner layer 3 is the inner surface of the substrate.
The outer layer 1 may be a film made of a fluorine-containing material such as a polyvinyl fluoride (PVF) film or a polyvinylidene fluoride (PVDF) film, and the intermediate layer 2 may be a biaxially oriented polyethylene terephthalate (BOPET), a Polyethylene (PE) film or a Polyamide (PA) film.
The inner layer 3 may be a fluorine-containing film such as a vinyl fluoride film or a vinylidene fluoride film, or may be a film containing no fluorine such as a polyethylene film, an ethylene-vinyl acetate resin film, or a polyolefin resin film.
In the present invention, the inner layer 3 of the substrate may cover the entire intermediate layer 2 (as shown in fig. 1) or may cover only a partial region of the intermediate layer 2 (as shown in fig. 2). In one possible implementation, the inner layer 3 has the same pattern as the pattern layer 31 containing the ultraviolet absorber.
For backsheets in which the inner layer 3 of the substrate covers all of the intermediate layer 2, the pattern layer 31 containing the uv absorber may be provided directly on the inner layer of an existing double-sided fluorine-containing backsheet or single-sided fluorine-containing backsheet.
For the back sheet having the substrate with the inner layer 3 covering the partial area of the intermediate layer 2, the composite film of the outer layer 1 and the intermediate layer 2 may be prepared according to the existing back sheet preparation process, and then the inner layer 3 is bonded to the partial area of the intermediate layer 2, and then the pattern layer 31 containing the ultraviolet absorber is prepared on the inner layer 3.
In the present invention, the substrate may also be formed by laminating a plurality of fluorine-free polymer material layers, such as a plurality of PET films or a plurality of PA films. In this embodiment, the pattern layer 31 containing the ultraviolet absorber is directly provided on the surface of the fluorine-free polymer material layer in the innermost layer.
In the present invention, the material of the adhesive layer 4 at each position is not particularly limited as long as each part of the backsheet can be adhesively fixed. For example, the adhesive layer formulations disclosed in examples 1 to 5 of CN107759983A can be used.
The back sheet of a solar cell module according to the present invention is further described with reference to the following specific examples.
Example 1
As shown in fig. 1, the back sheet of a solar cell module provided in this embodiment includes a substrate and a pattern layer 31 containing an ultraviolet absorber disposed on an inner side surface of the substrate.
Wherein, the base is current single face fluorine-containing TPE backplate, and the base includes outer 1 promptly, locates intermediate level 2 on outer 1, locates inlayer 3 on intermediate level 2 and sets up between outer 1 and intermediate level 2, tie coat 4 between intermediate level 2 and inlayer 3, and the skin is the polyvinyl fluoride film, and intermediate level 2 is the polyethylene terephthalate film, and inlayer 3 is the polyethylene film.
A pattern layer 31 containing an ultraviolet absorber is disposed on the inner layer 3.
The ultraviolet absorber-containing pattern layer 31 is formed by curing an ultraviolet absorber-containing paint having a predetermined pattern printed on the inner layer 3 at a low temperature.
The formulation of the above UV absorber-containing coating is, for example, the formulation of the weather-resistant layer described in CN107759983A, as follows (mass fraction)
Fluororesin 41088 (changxing chemical) 80%; epoxy resin B4010P (Mitsubishi yang, Japan) 5%; mica powder (Botong chemical Co., Ltd.) 5%; mixed etherified poly (methylol melamine resin) (maja chemical company) 9.99%; ultraviolet absorber 2- (2-hydroxy-3-tert-butyl-5-methylphenyl) -5-chlorobenzotriazole (BASF, Germany) 0.006%; light stabilizer bis (1-octyloxy-2, 2,6, 6-tetramethyl-4-piperidyl) sebacate (taiwan permanent photochemical company, china) 0.001%; antioxidant triethylene glycol ether-bis (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate (Pasteur, Germany) 0.003%.
The curing temperature was 60 ℃.
As shown in fig. 3, the solar cell module sequentially comprises front glass 5, an upper layer of packaging material 6, a cell sheet layer 7, a lower layer of packaging material 8 and a back sheet 9, wherein the cell sheets 10 in the cell sheet layer 7 are connected through solder strips, and gaps are formed among the cell sheets 10. The pattern of the pattern layer 31 containing the ultraviolet absorber is matched with the pattern of the non-shielded area 11 of the cell 10 in the cell layer, and is in a grid shape as shown in fig. 5.
Example 2
As shown in fig. 1, the back sheet of a solar cell module provided in this embodiment includes a substrate and a pattern layer 31 containing an ultraviolet absorber disposed on an inner side surface of the substrate.
Wherein, the base is current two-sided fluorine-containing TPT backplate, and the base includes outer 1 promptly, locates intermediate level 2 on outer 1, locates inlayer 3 on intermediate level 2 and sets up between outer 1 and intermediate level 2, tie coat 4 between intermediate level 2 and inlayer 3, and the skin is the polyvinyl fluoride film, and intermediate level 2 is the polyethylene glycol terephthalate film, and inlayer 3 is the polyvinyl fluoride film.
A pattern layer 31 containing an ultraviolet absorber is disposed on the inner layer 3.
The ultraviolet absorber-containing pattern layer 31 is formed by low-temperature curing of an ultraviolet absorber-containing paint having a predetermined pattern sprayed on the inner layer 3.
The formulation of the above-described UV absorber-containing coating was the same as in example 1.
As shown in fig. 3, the solar cell module sequentially comprises front glass 5, an upper layer of packaging material 6, a cell sheet layer 7, a lower layer of packaging material 8 and a back sheet 9, wherein the cell sheets 10 in the cell sheet layer 7 are connected through solder strips, and gaps are formed among the cell sheets 10. The pattern of the pattern layer 31 containing the ultraviolet absorber is matched with the pattern of the non-shielded area 11 of the cell 10 in the cell layer, and is in a grid shape as shown in fig. 5.
Example 3
As shown in fig. 2, the back sheet of a solar cell module provided in this embodiment includes a substrate and a pattern layer 31 containing an ultraviolet absorber disposed on an inner side surface of the substrate.
The substrate comprises an outer layer 1, an intermediate layer 2 arranged on the outer layer 1, an inner layer 3 arranged on the intermediate layer 2 and bonding layers 4 arranged between the outer layer 1 and the intermediate layer 2 and between the intermediate layer 2 and the inner layer 3, wherein the inner layer 3 covers a local area of the intermediate layer 2, and the pattern of the inner layer 3 is the same as that of a pattern layer 31 containing an ultraviolet absorbent.
The outer layer 1 is a polyvinyl fluoride film, the middle layer 2 is a polyethylene terephthalate film, and the inner layer 3 is a polyvinyl fluoride film.
A pattern layer 31 containing an ultraviolet absorber is disposed on the inner layer 3.
The ultraviolet absorber-containing pattern layer 31 is formed by curing an ultraviolet absorber-containing paint having a predetermined pattern printed on the inner layer 3 at a low temperature.
The formulation of the uv absorber containing coating in this example was the same as in example 1.
As shown in fig. 4, the solar cell module sequentially comprises front glass 5, an upper layer of packaging material 6, a cell sheet layer 7, a lower layer of packaging material 8 and a back plate 9, wherein the cells in the cell sheet layer 7 are connected in a shingled manner, and no gap exists between the cells in the same string of cells; the pattern in the pattern layer 31 containing the ultraviolet absorber and the pattern of the inner layer 3 are both matched with the pattern of the non-shielded area 11 of the battery piece 10 in the battery piece layer and are in a strip shape as shown in fig. 6.
The present invention is illustrated by the following examples, which are not intended to limit the scope of the invention. Other insubstantial modifications and adaptations of the present invention can be made without departing from the scope of the present invention.

Claims (5)

1. A solar cell module is characterized by comprising front glass (5), an upper layer packaging material (6), a cell sheet layer (7), a lower layer packaging material (8) and a back plate (9) in sequence,
the back plate (9) comprises a substrate and a pattern layer (31) containing an ultraviolet absorbent, wherein the pattern layer (31) is arranged on the inner side surface of the substrate and has a preset pattern, the pattern of the pattern layer (31) containing the ultraviolet absorbent is matched with the pattern of the non-shielding area of the battery piece in the battery piece layer (7),
the pattern in the pattern layer (31) containing the ultraviolet absorbent is in a grid shape or a strip shape;
the substrate comprises a fluorine-containing outer layer (1), a non-fluorine-containing intermediate layer (2) disposed on the outer layer (1), and an inner layer (3) disposed on the intermediate layer (2), the pattern layer (31) containing the ultraviolet absorber being disposed on the inner layer (3);
the inner layer (3) has the same pattern as the pattern layer (31) containing the ultraviolet absorber.
2. The solar cell module of claim 1, wherein: the pattern layer (31) containing the ultraviolet absorber is formed by curing the ultraviolet absorber-containing paint with the preset pattern arranged on the inner side surface of the substrate.
3. Solar module according to claim 1, characterised in that an adhesive layer (4) is arranged between the outer layer (1) and the intermediate layer (2) and between the intermediate layer (2) and the inner layer (3).
4. Solar cell module according to claim 1, characterized in that the inner layer (3) contains fluorine or no fluorine.
5. The solar cell module as claimed in claim 1, wherein the substrate is formed by compounding a plurality of fluorine-free polymer material layers.
CN201910024051.0A 2019-01-10 2019-01-10 Back plate of solar cell module Active CN109830560B (en)

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Citations (2)

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CN108767042A (en) * 2018-05-24 2018-11-06 苏州中来光伏新材股份有限公司 A kind of reflection gain type high transmittance solar battery back film and preparation method thereof

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FR2946459B1 (en) * 2009-06-05 2011-08-05 Centre Nat Etd Spatiales STRUCTURAL ELEMENT FOR SOLAR PANEL, AND STRUCTURE COMPRISING SUCH A ELEMENT
CN105609575B (en) * 2015-12-31 2017-12-15 杭州福斯特应用材料股份有限公司 A kind of high reflection photovoltaic component back plate material
CN106960888B (en) * 2017-03-03 2018-10-16 杭州福斯特应用材料股份有限公司 A kind of high reflection gain-type photovoltaic encapsulation glued membrane and purposes
CN107759983B (en) * 2017-10-13 2020-03-24 杭州福斯特应用材料股份有限公司 Patterned transparent back plate material
CN109244167A (en) * 2018-09-03 2019-01-18 杭州福斯特应用材料股份有限公司 A kind of enhanced transparent gridding backboard of power

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Publication number Priority date Publication date Assignee Title
CN106024946A (en) * 2016-06-16 2016-10-12 杭州福斯特光伏材料股份有限公司 Patterned power-gain type solar back plate material
CN108767042A (en) * 2018-05-24 2018-11-06 苏州中来光伏新材股份有限公司 A kind of reflection gain type high transmittance solar battery back film and preparation method thereof

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