CN109825356A - A kind of hydraulic support oil emulsion and preparation method thereof - Google Patents
A kind of hydraulic support oil emulsion and preparation method thereof Download PDFInfo
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- CN109825356A CN109825356A CN201910234365.3A CN201910234365A CN109825356A CN 109825356 A CN109825356 A CN 109825356A CN 201910234365 A CN201910234365 A CN 201910234365A CN 109825356 A CN109825356 A CN 109825356A
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- 239000000839 emulsion Substances 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims description 26
- 238000004945 emulsification Methods 0.000 title description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 90
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 59
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 59
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 59
- 239000012188 paraffin wax Substances 0.000 claims abstract description 37
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 30
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 29
- 239000011734 sodium Substances 0.000 claims abstract description 29
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 29
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 27
- 229930182490 saponin Natural products 0.000 claims abstract description 27
- 150000007949 saponins Chemical class 0.000 claims abstract description 27
- 239000003208 petroleum Substances 0.000 claims abstract description 25
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims abstract description 24
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 24
- 239000004094 surface-active agent Substances 0.000 claims abstract description 24
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 23
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 23
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 23
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000004327 boric acid Substances 0.000 claims abstract description 21
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 19
- 229910000162 sodium phosphate Inorganic materials 0.000 claims abstract description 19
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims abstract description 19
- 238000002156 mixing Methods 0.000 claims description 29
- 238000003756 stirring Methods 0.000 claims description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- -1 glycoside compounds Chemical class 0.000 claims description 7
- 239000003495 polar organic solvent Substances 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 5
- 235000019441 ethanol Nutrition 0.000 claims description 5
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 3
- 241000218691 Cupressaceae Species 0.000 claims description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 3
- 235000011613 Pinus brutia Nutrition 0.000 claims description 3
- 241000018646 Pinus brutia Species 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 3
- 238000010411 cooking Methods 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 229930182478 glucoside Natural products 0.000 claims description 3
- 125000005456 glyceride group Chemical group 0.000 claims description 3
- 229950008882 polysorbate Drugs 0.000 claims description 3
- 229920000136 polysorbate Polymers 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 229930182470 glycoside Natural products 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 2
- 239000004575 stone Substances 0.000 claims 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
- 244000269722 Thea sinensis Species 0.000 claims 1
- 241000894007 species Species 0.000 claims 1
- 239000001993 wax Substances 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000003921 oil Substances 0.000 description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000002699 waste material Substances 0.000 description 7
- 239000003245 coal Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 240000003553 Leptospermum scoparium Species 0.000 description 2
- 235000015459 Lycium barbarum Nutrition 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- XTLNYNMNUCLWEZ-UHFFFAOYSA-N ethanol;propan-2-one Chemical compound CCO.CC(C)=O XTLNYNMNUCLWEZ-UHFFFAOYSA-N 0.000 description 2
- 239000010808 liquid waste Substances 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000008093 supporting effect Effects 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- 244000147058 Derris elliptica Species 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- ZUMNJDGBYXHASJ-UHFFFAOYSA-N ethyl 2-[5-[4-(3-methylsulfonylphenyl)phenyl]-3-(trifluoromethyl)pyrazol-1-yl]acetate Chemical compound CCOC(=O)CN1N=C(C(F)(F)F)C=C1C1=CC=C(C=2C=C(C=CC=2)S(C)(=O)=O)C=C1 ZUMNJDGBYXHASJ-UHFFFAOYSA-N 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000013595 glycosylation Effects 0.000 description 1
- 238000006206 glycosylation reaction Methods 0.000 description 1
- 230000001976 improved effect Effects 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000005425 throughfall Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Landscapes
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The present invention provides a kind of hydraulic support oil emulsions, comprise the following components in parts by weight: 15-30 parts of paraffin, 4-9 parts of Tea Saponin, 10-15 parts of n-butanol, 8-12 parts of bark soak, 10-15 parts of emulsifier, 35-50 parts of triethanolamine, 40-60 parts of boric acid, 15-25 parts of petroleum sodium sulfonate, 15-20 parts of sodium phosphate, 10-15 parts of allyl polyethenoxy ether, 10-20 parts of polyethyleneglycol ether, 15-30 parts of rosin, 10-20 parts of surfactant.Hydraulic support oil emulsion proposed by the present invention replaces petroleum to prepare oil emulsion using rosin, and rosin is renewable resource, compared with traditional emulsified oil, mitigates resource and environmental pressure significantly.
Description
Technical field
The present invention relates to hydraulic support oil fields, in particular to a kind of hydraulic support oil emulsion and its preparation
Method.
Background technique
Hydraulic support is to realize the movements such as lifting, Forward with hydraulic for power, generates support force simultaneously using fluid pressure
Automatic mobile device is realized to carry out a kind of hydraulic power unit of roof timbering and management, is coal mine fully-mechanized mining
Key equipment is the important link that In Modern Mine realizes all process steps full mechanizations such as coal mining, transport and supporting, to the modern times
Coal production is significant.
Oil emulsion is the power transmitting medium for coal mine hydraulic supporting, and hydraulic system can be effectively protected, and extending it makes
With the service life, oil emulsion after use, since its performance and efficiency have all consumed substantially, then becomes industrial wastes, China one
It is all directly in the economic environment of construction sustainable development, hydraulic support oil emulsion is as China is to the continuous of environment environmental requirement
It improves, it is desirable that the waste liquid of industrial oil emulsion is by liquid waste processing and reaches domestic and place three waste discharge standard, Fang Kejin
Row discharge, therefore, each factory when choosing industrial oil emulsion, also its liquid waste processing complexity be included in selection standard it
One.
China Patent Publication No.: CN103387869B discloses a kind of emulsified oil for a coal mine hydraulic support and its preparation side
Method comprising water, sodium hydroxide, EDTA, aphthenic acids, phosphate, sodium nitrite, triethanolamine, benzotriazole, A-110 cream
Agent, glycerol, urea.It is primarily present insufficient:
First, there are a large amount of nitrogens in above-mentioned emulsified oil for a coal mine hydraulic support, the waste liquid row that is discharged after using
It puts and be easy to cause water eutrophication, influence the water quality of water body, cause the transparency of water to reduce, so that sunlight is difficult to through-fall
Layer, to influence the photosynthesis of aquatic plant, may cause the hypersaturated state of dissolved oxygen, to aquatic animal nocuousness.
Second, oily substance forms thin film in water surface, and the oxygen hindered in air is dissolved in the water, causes
Oxygen in water declines, and the planktonic organism in water body is dead due to anoxic；Oil film also counteracts the photosynthetic work of water plant simultaneously
With influencing water body self-purification ability, oil droplet size is atomic small, and most of is 0.1~2 μm, is difficult to realize water-oil separating.
Summary of the invention
For this purpose, the present invention is directed to overcome in the prior art hydraulic support emulsified oils be easy to cause asking for water pollution
Topic.
To achieve the above object, on the one hand, the invention proposes a kind of hydraulic support oil emulsions, including following parts by weight
Component: 15-30 parts of paraffin, 4-9 parts of Tea Saponin, 10-15 parts of n-butanol, 8-12 parts of bark soak, 10-15 parts of emulsifier,
35-50 parts of triethanolamine, 40-60 parts of boric acid, 15-25 parts of petroleum sodium sulfonate, 15-20 parts of sodium phosphate, allyl polyethenoxy ether
10-15 parts, 10-20 parts of polyethyleneglycol ether, 15-30 parts of rosin, 10-20 parts of surfactant.
Further, hydraulic support oil emulsion comprises the following components in parts by weight: 20 parts of paraffin, 6 parts of Tea Saponin, just
12 parts of butanol, 9 parts of bark soak, 13 parts of emulsifier, 44 parts of triethanolamine, 42 parts of boric acid, 19 parts of petroleum sodium sulfonate, sodium phosphate
17 parts, 13 parts of allyl polyethenoxy ether, 15 parts of polyethyleneglycol ether, 20 parts of rosin, 15 parts of surfactant.
On the other hand, the present invention also provides a kind of preparation method of hydraulic support oil emulsion, its step are as follows:
Step a, heating rosin melt it and are gradually warmed to 230 DEG C, then in three second that 20%-30% is wherein added
Hydramine stirs 45-70min to get modified rosin is arrived, and is kept for 190 DEG C of constant temperature save backup；
Wherein first stage mixing speed meets following relationship:
In formula, v1Indicate rosin and to the mixed real-time mixing speed of triethanolamine；T1Indicate mixeding liquid temperature；T10Table
Show preset temperature value, temperature value is 225 DEG C；g1Indicate that the quality of rosin, G is added in the first stage10The gross mass of current mixed liquor；
The specific heat capacity of c expression rosin；v10It indicates preset mixing speed, is 330r/min；
Tea Saponin is dissolved in n-butanol by step b, and bark soak is added and stirs evenly obtained Tea Saponin solution for standby.
Step c, by heating paraffin to 47-62 DEG C make its melt and insulated and stirred 20-30min, add boric acid and emulsification
Agent recycles microwave reactor microwave return stirring to react 30-60min；
Wherein second stage heating paraffin mixing speed meets following relationship:
In formula, v2Indicate the real-time mixing speed of heating paraffin wax；T2Indicate paraffin real time temperature；T20Indicate preset temperature
Value, temperature value are 55 DEG C；t2Indicate the real-time mixing time of paraffin；t20It indicates default mixing time, is 12 minutes；v20Indicate pre-
If mixing speed, be 800r/min；
After boric acid and emulsifier is added in phase III, mixed liquor microwave vibrations frequency is f3:
In formula, f3Indicate the microwave vibrations frequency that boric acid and emulsifier is added；T3Indicate the real time temperature of mixed liquor；T30Table
Show preset temperature value, temperature value is 60 DEG C；f30It indicates phase III preset vibration frequency, is 30kHz；
The mixed liquor of phase III is placed in 55 DEG C of hot bath by step d, and remaining three ethyl alcohol is added thereto
Amine and petroleum sodium sulfonate, sodium phosphate, allyl polyethenoxy ether, polyethyleneglycol ether stir 15-20min；
Wherein, remaining triethanolamine and petroleum sodium sulfonate, sodium phosphate, allyl polyethenoxy is added in fourth stage
Ether, polyethyleneglycol ether, stirring rate are as follows:
In formula, v is indicated4Remaining triethanolamine and petroleum sodium sulfonate, sodium phosphate, allyl polyoxy is added in fourth stage
The real-time mixing speed of vinethene, polyethyleneglycol ether；v40It indicates the preset mixing speed of fourth stage, is 200r/min,；
g4It indicates that remaining triethanolamine and petroleum sodium sulfonate, sodium phosphate, allyl polyethenoxy ether, polyethyleneglycol ether is added
Quality, G4Indicate the gross mass of fourth stage mixed liquor, c1Indicate the specific heat capacity of triethanolamine；
Modified rosin and Tea Saponin solution are added into the mixed liquor of fourth stage, heats up under the protection of nitrogen by step e
To 240 DEG C, surfactant, microwave vibrations 40-90min is added；
Wherein, the microwave vibrations frequency after modified rosin and surfactant was added in the 5th stage are as follows:
In formula, f5Microwave vibrations frequency after indicating the 5th stage addition modified rosin and surfactant；f50Indicate the
Five stages preset vibration frequency, is 25kHz；g5Indicate that the quality of modified rosin, G was added in the 5th stage5Indicated for the 5th stage
The gross mass of mixed liquor, c2Indicate the specific heat capacity of modified rosin, c3Indicate the specific heat capacity of Tea Saponin solution.
Above-mentioned hydraulic support oil emulsion is in preservation it should be noted that the following:
(1) it should be stored in dry, shady and cool ventilation storehouse；
(2) solarization should be avoided in transporting procedures, drench with rain；
(3) 5~35 DEG C of storage temperature；
(4) in the case of normal shelf, the shelf-life is 1 year.
In above-mentioned steps a, when heating rosin, it is electrically heated using rosin size cooking kettle, through heat-conducting oil to pot body, the thermal efficiency
Height, temperature automatically controlled, heating power stepping is adjustable, and Non-burnt pot in use process, over-emitting black exhaust, does not effectively delay rosin to carbonize, and saves
Rosin.
Further, in the preparation method of above-mentioned hydraulic support oil emulsion, the paraffin is semi-refined paraffin wax.
Further, in the preparation method of above-mentioned hydraulic support oil emulsion, the Tea Saponin is to extract in tea tree seed
Glycoside compounds out.
Further, in the preparation method of above-mentioned hydraulic support oil emulsion, the bark soak is pine tree, cypress etc.
Oil bark impregnates resulting extracting solution through polar organic solvent, and the polar organic solvent can be methanol/ethanol acetone
Deng.
Further, in the preparation method of above-mentioned hydraulic support oil emulsion, the emulsifier is polyacrylamide emulsification
Agent.
Further, in the preparation method of above-mentioned hydraulic support oil emulsion, the surfactant is non-ionic surface
Activating agent can be alkyl glucoside, fatty glyceride, fatty acid sorbitan, one or more of polysorbate.
Compared with prior art, the beneficial effects of the present invention are hydraulic support oil emulsion proposed by the present invention utilizes
Rosin replace petroleum prepare oil emulsion, rosin is renewable resource, compared with traditional emulsified oil, significantly mitigation resource and
Environmental pressure.
Especially, the steady of oil emulsion can be effectively improved by being added to paraffin in hydraulic support oil emulsion of the present invention
It is qualitative, inhibit oil soap precipitation, improve the utilization rate of oil emulsion, saves resource for enterprise.
Further, the paraffin is semi-refined paraffin wax, and chemical stability is good, and oil content is moderate, is had good anti-
Tide and insulation performance, can effectively enhance the stability of oil emulsion, while promoting the extreme pressure property of oil emulsion.
Further, it also added the Tea Saponin added with bark extract in hydraulic support oil emulsion of the present invention
Solution can obviously increase its lubricating action, and keep activity, be unlikely to deteriorate.
Also, in the preparation method of hydraulic support oil emulsion of the invention, modified rosin is prepared in the first stage, is reduced
Paraffin is added in second stage in fat content in rosin, improves the extreme pressure property of oil emulsion, and the phase III carry out it is micro-
Wave vibration, keeps paraffin fully emulsified, modified rosin and surfactant is added in the mixed liquor of fourth stage, in the guarantor of nitrogen
The lower heating of shield, the chemical property of nitrogen is stablized, nontoxic, and oxygen and the mixed liquor that nitrogen can completely cut off in air is added
In substance chemically react, keep the activity of surfactant, again microwave vibrations, merge it sufficiently, keep one
Stable state makes it easier to save.
Specific embodiment
Below with reference to specific embodiment, the technical scheme of the present invention will be further described, but claimed range is simultaneously
It is not limited to this.
The embodiment of the present invention proposes a kind of hydraulic support oil emulsion, comprises the following components in parts by weight: paraffin 15-30
Part, 4-9 parts of Tea Saponin, 10-15 parts of n-butanol, 8-12 parts of bark soak, 10-15 parts of emulsifier, 35-50 parts of triethanolamine,
40-60 parts of boric acid, 15-25 parts of petroleum sodium sulfonate, 15-20 parts of sodium phosphate, 10-15 parts of allyl polyethenoxy ether, polyethylene glycol
Single ether 10-20 parts, 15-30 parts of rosin, 10-20 parts of surfactant.
On the other hand, the embodiment of the present invention also provides a kind of preparation method of hydraulic support oil emulsion, and its step are as follows:
Step a, heating rosin melt it and are gradually warmed to 230 DEG C, then in three second that 20%-30% is wherein added
Hydramine stirs 45-70min to get modified rosin is arrived, and is kept for 190 DEG C of constant temperature save backup；
Wherein first stage mixing speed meets following relationship:
In formula, v1Indicate rosin and to the mixed real-time mixing speed of triethanolamine；T1Indicate mixeding liquid temperature；T10Table
Show preset temperature value, temperature value is 225 DEG C；g1Indicate that the quality of rosin, G is added in the first stage10The gross mass of current mixed liquor；
The specific heat capacity of c expression rosin；v10It indicates preset mixing speed, is 330r/min；
Tea Saponin is dissolved in n-butanol by step b, and bark soak is added and stirs evenly obtained Tea Saponin solution for standby.
Step c, by heating paraffin to 47-62 DEG C make its melt and insulated and stirred 20-30min, add boric acid and emulsification
Agent recycles microwave reactor microwave return stirring to react 30-60min；
Wherein second stage heating paraffin mixing speed meets following relationship:
In formula, v2Indicate the real-time mixing speed of heating paraffin wax；T2Indicate paraffin real time temperature；T20Indicate preset temperature
Value, temperature value are 55 DEG C；t2Indicate the real-time mixing time of paraffin；t20It indicates default mixing time, is 12 minutes；v20Indicate pre-
If mixing speed, be 800r/min；
After boric acid and emulsifier is added in phase III, mixed liquor microwave vibrations frequency is f3:
In formula, f3Indicate the microwave vibrations frequency that boric acid and emulsifier is added；T3Indicate the real time temperature of mixed liquor；T30Table
Show preset temperature value, temperature value is 60 DEG C；f30It indicates phase III preset vibration frequency, is 30kHz；
The mixed liquor of phase III is placed in 55 DEG C of hot bath by step d, and remaining three ethyl alcohol is added thereto
Amine and petroleum sodium sulfonate, sodium phosphate, allyl polyethenoxy ether, polyethyleneglycol ether stir 15-20min；
Wherein, remaining triethanolamine and petroleum sodium sulfonate, sodium phosphate, allyl polyethenoxy is added in fourth stage
Ether, polyethyleneglycol ether, stirring rate are as follows:
In formula, v is indicated4Remaining triethanolamine and petroleum sodium sulfonate, sodium phosphate, allyl polyoxy is added in fourth stage
The real-time mixing speed of vinethene, polyethyleneglycol ether；v40It indicates the preset mixing speed of fourth stage, is 200r/min,；
g4It indicates that remaining triethanolamine and petroleum sodium sulfonate, sodium phosphate, allyl polyethenoxy ether, polyethyleneglycol ether is added
Quality, G4Indicate the gross mass of fourth stage mixed liquor, c1Indicate the specific heat capacity of triethanolamine；
Modified rosin is added into the mixed liquor of fourth stage in step e, and 240 DEG C are warming up under the protection of nitrogen, is added
Surfactant, microwave vibrations 40-90min；
Wherein, the microwave vibrations frequency after modified rosin and surfactant was added in the 5th stage are as follows:
In formula, f5Microwave vibrations frequency after indicating the 5th stage addition modified rosin and surfactant；f50Indicate the
Five stages preset vibration frequency, is 25kHz；g5Indicate that the quality of modified rosin, G was added in the 5th stage5Indicated for the 5th stage
The gross mass of mixed liquor, c2Indicate the specific heat capacity of modified rosin, c3Indicate the specific heat capacity of Tea Saponin solution.
Above-mentioned hydraulic support oil emulsion is in preservation it should be noted that the following:
(1) it should be stored in dry, shady and cool ventilation storehouse；
(2) solarization should be avoided in transporting procedures, drench with rain；
(3) 5~35 DEG C of storage temperature；
(4) in the case of normal shelf, the shelf-life is 1 year.
Wherein, it when the heating of first stage described in embodiment of the present invention rosin, is electrically heated using rosin size cooking kettle.
In the preparation method of above-mentioned hydraulic support oil emulsion, the paraffin is semi-refined paraffin wax.
In the preparation method of above-mentioned hydraulic support oil emulsion, the Tea Saponin is glycosylation to extract in tea tree seed
Close object.
In the preparation method of above-mentioned hydraulic support oil emulsion, the bark soak is the oil trees such as pine tree, cypress
Skin impregnates resulting extracting solution through polar organic solvent, and the polar organic solvent can be methanol/ethanol acetone etc..
In the preparation method of above-mentioned hydraulic support oil emulsion, the emulsifier is polyacrylamide amine emulsifier.
In the preparation method of above-mentioned hydraulic support oil emulsion, the surfactant is nonionic surfactant, can
To be alkyl glucoside, fatty glyceride, fatty acid sorbitan, one or more of polysorbate.
Embodiment one
Hydraulic support oil emulsion in the present embodiment, comprises the following components in parts by weight: 15 parts of paraffin, 4 parts of Tea Saponin,
10 parts of n-butanol, 8 parts of bark soak, 10 parts of emulsifier, 35 parts of triethanolamine, 40 parts of boric acid, 15 parts of petroleum sodium sulfonate, phosphoric acid
15 parts of sodium, 10 parts of allyl polyethenoxy ether, 10 parts of polyethyleneglycol ether, 15 parts of rosin, 10 parts of surfactant.
Embodiment two
Hydraulic support oil emulsion in the present embodiment, comprises the following components in parts by weight: 18 parts of paraffin, 5 parts of Tea Saponin,
12 parts of n-butanol, 9 parts of bark soak, 12 parts of emulsifier, 40 parts of triethanolamine, 45 parts of boric acid, 17 parts of petroleum sodium sulfonate, phosphoric acid
15 parts of sodium, 13 parts of allyl polyethenoxy ether, 15 parts of polyethyleneglycol ether, 20 parts of rosin, 12 parts of surfactant.
Embodiment three
Hydraulic support oil emulsion in the present embodiment, comprises the following components in parts by weight: 16 parts of paraffin, 6 parts of Tea Saponin,
11 parts of n-butanol, 10 parts of bark soak, 11 parts of emulsifier, 38 parts of triethanolamine, 43 parts of boric acid, 19 parts of petroleum sodium sulfonate, phosphorus
16 parts of sour sodium, 13 parts of allyl polyethenoxy ether, 16 parts of polyethyleneglycol ether, 22 parts of rosin, 16 parts of surfactant.
Example IV
Hydraulic support oil emulsion in the present embodiment, comprises the following components in parts by weight: 25 parts of paraffin, 7 parts of Tea Saponin,
13 parts of n-butanol, 11 parts of bark soak, 14 parts of emulsifier, 44 parts of triethanolamine, 57 parts of boric acid, 23 parts of petroleum sodium sulfonate, phosphorus
18 parts of sour sodium, 14 parts of allyl polyethenoxy ether, 19 parts of polyethyleneglycol ether, 27 parts of rosin, 18 parts of surfactant.
Embodiment five
Hydraulic support oil emulsion in the present embodiment, comprises the following components in parts by weight: 30 parts of paraffin, 9 parts of Tea Saponin,
15 parts of n-butanol, 12 parts of bark soak, 15 parts of emulsifier, 50 parts of triethanolamine, 60 parts of boric acid, 25 parts of petroleum sodium sulfonate, phosphorus
20 parts of sour sodium, 15 parts of allyl polyethenoxy ether, 20 parts of polyethyleneglycol ether, 30 parts of rosin, 20 parts of surfactant.
In the various embodiments described above, hydraulic support oil emulsion the preparation method comprises the following steps:
Step a, heating rosin melt it and are gradually warmed to 230 DEG C, then in three second that 20%-30% is wherein added
Hydramine stirs 45-70min to get modified rosin is arrived, and is kept for 190 DEG C of constant temperature save backup；
Tea Saponin is dissolved in n-butanol by step b, and bark soak is added and stirs evenly obtained Tea Saponin solution for standby；
Step c, by heating paraffin to 47-62 DEG C make its melt and insulated and stirred 20-30min, add boric acid and emulsification
Agent recycles microwave reactor microwave return stirring to react 30-60min；
The mixed liquor of phase III is placed in 55 DEG C of hot bath by step d, and remaining three ethyl alcohol is added thereto
Amine and petroleum sodium sulfonate, sodium phosphate, allyl polyethenoxy ether, polyethyleneglycol ether stir 15-20min；
Modified rosin is added into the mixed liquor of fourth stage in step e, and 240 DEG C are warming up under the protection of nitrogen, is added
Surfactant, microwave vibrations 40-90min；
To the hydraulic support oil emulsion of the above various embodiments preparation, its HLB is detected respectively under same standard conditions
Value, using the nitrogen content of waste liquid after 5 days, pH value, thermal stability (oil soap precipitation amount) and fat content using waste liquid after 5 days,
Testing result is as shown in the table:
Obviously, hydraulic support oil emulsion provided by the invention effectively reduces the nitrogen content in waste liquid, and meets ring
Border requirement for bearing capacity will not pollute water quality, and HLB value is in the state of relative equilibrium, so that oil emulsion effect pole
It is good, do not occur the phenomenon that oil soap precipitation in each embodiment, thermal stability is strong, and the fat content in waste liquid is far below standard
Index substantially reduces the negative effect to environment.
Obviously, various changes and modifications can be made to the invention without departing from essence of the invention by those skilled in the art
Mind and range.In this way, if these modifications and changes of the present invention belongs to the range of the claims in the present invention and its equivalent technologies
Within, then the present invention is also intended to include these modifications and variations.
Claims (9)
1. a kind of hydraulic support oil emulsion, which is characterized in that comprise the following components in parts by weight: 15-30 parts of paraffin, Tea Saponin
4-9 parts, 10-15 parts of n-butanol, 8-12 parts of bark soak, 10-15 parts of emulsifier, 35-50 parts of triethanolamine, boric acid 40-60
Part, 15-25 parts of petroleum sodium sulfonate, 15-20 parts of sodium phosphate, 10-15 parts of allyl polyethenoxy ether, polyethyleneglycol ether 10-
20 parts, 15-30 parts of rosin, 10-20 parts of surfactant.
2. hydraulic support oil emulsion according to claim 1, which is characterized in that comprise the following components in parts by weight: stone
20 parts of wax, 6 parts of Tea Saponin, 12 parts of n-butanol, 9 parts of bark soak, 13 parts of emulsifier, 44 parts of triethanolamine, 42 parts of boric acid, stone
19 parts of oily sodium sulfonate, 17 parts of sodium phosphate, 13 parts of allyl polyethenoxy ether, 15 parts of polyethyleneglycol ether, 20 parts of rosin, surface
15 parts of activating agent.
3. a kind of preparation method of hydraulic support oil emulsion, which is characterized in that its step are as follows:
Step a, heating rosin melt it and are gradually warmed to 230 DEG C, then in three ethyl alcohol that 20%-30% is wherein added
Amine stirs 45-70min to get modified rosin is arrived, and is kept for 190 DEG C of constant temperature save backup；
Wherein first stage mixing speed meets following relationship:
In formula, v1Indicate rosin and to the mixed real-time mixing speed of triethanolamine；T1Indicate mixeding liquid temperature；T10Indicate pre-
If temperature value, temperature value is 225 DEG C；g1Indicate that the quality of rosin, G is added in the first stage10The gross mass of current mixed liquor；C table
Show the specific heat capacity of rosin；v10It indicates preset mixing speed, is 330r/min；
Tea Saponin is dissolved in n-butanol by step b, and bark soak is added and stirs evenly obtained Tea Saponin solution for standby；
Step c, by heating paraffin to 47-62 DEG C make its melt and insulated and stirred 20-30min, add boric acid and emulsifier, then
30-60min is reacted using microwave reactor microwave return stirring；
Wherein second stage heating paraffin mixing speed meets following relationship:
In formula, v2Indicate the real-time mixing speed of heating paraffin wax；T2Indicate paraffin real time temperature；T20Indicate preset temperature value, temperature
Value is 55 DEG C；t2Indicate the real-time mixing time of paraffin；t20It indicates default mixing time, is 12 minutes；v20It indicates preset to stir
Speed is mixed, is 800r/min；
After boric acid and emulsifier is added in phase III, mixed liquor microwave vibrations frequency is f3:
In formula, f3Indicate the microwave vibrations frequency that boric acid and emulsifier is added；T3Indicate the real time temperature of mixed liquor；T30Indicate pre-
If temperature value, temperature value is 60 DEG C；f30It indicates phase III preset vibration frequency, is 30kHz；
The mixed liquor of phase III is placed in 55 DEG C of hot bath by step d, and be added thereto remaining triethanolamine with
And petroleum sodium sulfonate, sodium phosphate, allyl polyethenoxy ether, polyethyleneglycol ether, stir 15-20min；
Wherein, fourth stage is added remaining triethanolamine and petroleum sodium sulfonate, sodium phosphate, allyl polyethenoxy ether, gathers
Ethylene glycol monoethyl ether, stirring rate are as follows:
In formula, v is indicated4Remaining triethanolamine and petroleum sodium sulfonate, sodium phosphate, allyl polyethenoxy is added in fourth stage
The real-time mixing speed of ether, polyethyleneglycol ether；v40It indicates the preset mixing speed of fourth stage, is 200r/min,；g4Table
Show the matter that remaining triethanolamine and petroleum sodium sulfonate, sodium phosphate, allyl polyethenoxy ether, polyethyleneglycol ether is added
Amount, G4Indicate the gross mass of fourth stage mixed liquor, c1Indicate the specific heat capacity of triethanolamine；
Modified rosin is added into the mixed liquor of fourth stage in step e, and 240 DEG C are warming up under the protection of nitrogen, and surface is added
Activating agent, microwave vibrations 40-90min；
Wherein, the microwave vibrations frequency after modified rosin and surfactant was added in the 5th stage are as follows:
In formula, f5Microwave vibrations frequency after indicating the 5th stage addition modified rosin and surfactant；f50Indicate the 5th rank
The preset vibration frequency of section, is 25kHz；g5Indicate that the quality of modified rosin, G was added in the 5th stage5Indicate that the 5th stage mixed
The gross mass of liquid, c2Indicate the specific heat capacity of modified rosin, c3Indicate the specific heat capacity of Tea Saponin solution.
4. the preparation method of hydraulic support oil emulsion according to claim 3, which is characterized in that in the step a, add
When hot rosin, it is electrically heated using rosin size cooking kettle.
5. the preparation method of hydraulic support oil emulsion according to claim 3, which is characterized in that the paraffin is half essence
Refine paraffin.
6. the preparation method of hydraulic support oil emulsion according to claim 3, which is characterized in that the Tea Saponin is tea
The glycoside compounds extracted in tree species.
7. the preparation method of hydraulic support oil emulsion according to claim 3, which is characterized in that the bark soak
Impregnate resulting extracting solution through polar organic solvent for the oil bark such as pine tree, cypress, the polar organic solvent be methanol,
One or more of ethyl alcohol, acetone.
8. the preparation method of hydraulic support oil emulsion according to claim 3, which is characterized in that the emulsifier is poly-
Acrylamide emulsifier.
9. the preparation method of hydraulic support oil emulsion according to claim 3, which is characterized in that the surfactant
For nonionic surfactant, alkyl glucoside can be, fatty glyceride, fatty acid sorbitan, one in polysorbate
Kind is several.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103305327A (en) * | 2013-07-10 | 2013-09-18 | 哈尔滨紫杉油脂有限责任公司 | Preparation method of emulsified oil for hydraulic support |
| CN106867634A (en) * | 2016-12-25 | 2017-06-20 | 常州梦泰照明科技有限公司 | A kind of preparation method of environmentally friendly antiwear hydraulic oil |
| CN108485772A (en) * | 2018-05-25 | 2018-09-04 | 富地润滑科技股份有限公司 | A kind of environmentally protective mine hydraulic support fluid |
| CN109181838A (en) * | 2018-10-09 | 2019-01-11 | 中国石油化工股份有限公司 | Hydraulic support oil emulsion and application thereof |
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2019
- 2019-03-26 CN CN201910234365.3A patent/CN109825356B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103305327A (en) * | 2013-07-10 | 2013-09-18 | 哈尔滨紫杉油脂有限责任公司 | Preparation method of emulsified oil for hydraulic support |
| CN106867634A (en) * | 2016-12-25 | 2017-06-20 | 常州梦泰照明科技有限公司 | A kind of preparation method of environmentally friendly antiwear hydraulic oil |
| CN108485772A (en) * | 2018-05-25 | 2018-09-04 | 富地润滑科技股份有限公司 | A kind of environmentally protective mine hydraulic support fluid |
| CN109181838A (en) * | 2018-10-09 | 2019-01-11 | 中国石油化工股份有限公司 | Hydraulic support oil emulsion and application thereof |
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