CN109820004B - Moso bamboo extract water suspending agent and preparation method and application thereof - Google Patents
Moso bamboo extract water suspending agent and preparation method and application thereof Download PDFInfo
- Publication number
- CN109820004B CN109820004B CN201910177089.1A CN201910177089A CN109820004B CN 109820004 B CN109820004 B CN 109820004B CN 201910177089 A CN201910177089 A CN 201910177089A CN 109820004 B CN109820004 B CN 109820004B
- Authority
- CN
- China
- Prior art keywords
- moso bamboo
- bamboo extract
- extract
- parts
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 244000302661 Phyllostachys pubescens Species 0.000 title claims abstract description 98
- 235000003570 Phyllostachys pubescens Nutrition 0.000 title claims abstract description 98
- 239000000284 extract Substances 0.000 title claims abstract description 91
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000000375 suspending agent Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 21
- 241001330002 Bambuseae Species 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 7
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 7
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 7
- 239000011425 bamboo Substances 0.000 claims abstract description 7
- 239000007900 aqueous suspension Substances 0.000 claims description 35
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 241000607479 Yersinia pestis Species 0.000 claims description 12
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 11
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 10
- 241000721621 Myzus persicae Species 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 4
- 235000019438 castor oil Nutrition 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
- 239000000230 xanthan gum Substances 0.000 claims description 4
- 229920001285 xanthan gum Polymers 0.000 claims description 4
- 229940082509 xanthan gum Drugs 0.000 claims description 4
- 235000010493 xanthan gum Nutrition 0.000 claims description 4
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 claims description 3
- 239000011324 bead Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 2
- 238000007865 diluting Methods 0.000 claims 1
- 239000004546 suspension concentrate Substances 0.000 claims 1
- 239000000575 pesticide Substances 0.000 abstract description 15
- 239000003995 emulsifying agent Substances 0.000 abstract description 13
- 239000002270 dispersing agent Substances 0.000 abstract description 11
- 239000002562 thickening agent Substances 0.000 abstract description 11
- 239000000080 wetting agent Substances 0.000 abstract description 11
- 230000002528 anti-freeze Effects 0.000 abstract description 7
- 238000012545 processing Methods 0.000 abstract description 5
- 239000002671 adjuvant Substances 0.000 abstract description 3
- 239000003607 modifier Substances 0.000 abstract description 2
- 244000144972 livestock Species 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000000295 complement effect Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000003223 protective agent Substances 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 240000003553 Leptospermum scoparium Species 0.000 description 3
- 235000015459 Lycium barbarum Nutrition 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- -1 polyoxyethylene Polymers 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000012154 double-distilled water Substances 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000000361 pesticidal effect Effects 0.000 description 2
- 239000000447 pesticide residue Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 229940047670 sodium acrylate Drugs 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000256593 Brachycaudus schwartzi Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- RRDQTXGFURAKDI-UHFFFAOYSA-N formaldehyde;naphthalene-2-sulfonic acid Chemical compound O=C.C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 RRDQTXGFURAKDI-UHFFFAOYSA-N 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229940070721 polyacrylate Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000011067 sorbitan monolaureate Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a moso bamboo extract water suspending agent, a preparation method and application thereof. The moso bamboo extract water suspending agent provided by the invention is mainly prepared from the following raw materials: bamboo extract, adjuvant, and water; wherein the auxiliary agent comprises: at least one of an emulsifier, a dispersant, a wetting agent, an antifreeze, a thickener, a structure modifier, and a protectant. The moso bamboo extract water suspending agent has the characteristics of simple processing, easily obtained raw materials, convenient use, lower cost, safety to human, livestock and ecological environment and the like, and is an environment-friendly and safe botanical pesticide preparation.
Description
Technical Field
The invention relates to the field of pesticides, and particularly relates to a moso bamboo extract water suspending agent, and a preparation method and application thereof.
Background
Agricultural pests such as green peach aphids and the like seriously damage crops, and the current main control mode is chemical pesticide control. Pesticide residues, environmental pollution and food safety problems caused by long-term, large and unreasonable use of chemical pesticides have seriously affected people's lives. For the control of agricultural pests, the development of novel environment-friendly pesticides with high efficiency, low toxicity and low residue is urgently needed.
The plant source pesticide has the advantages of safety to the environment, wide plant resources, safety to non-target organisms, specific action mode and the like which cannot be compared favorably with chemical agents. However, at present, the botanical pesticide mostly uses organic substances as solvents, which also can cause harm to human bodies and environment, and is not beneficial to popularization and application of the botanical pesticide.
The moso bamboo is one of the bamboo species with the longest cultivation history, the widest planting area and the highest economic value in China. In the felling/processing process of the moso bamboos, a large amount of residues are generated, and the development and the effective utilization of the moso bamboo residues are also the technical problems to be solved at present.
In view of the above, the present invention is particularly proposed.
Disclosure of Invention
The invention aims to provide a moso bamboo extract water suspending agent, which takes a moso bamboo extract which is easily obtained as a raw material as an effective component, provides a safe and environment-friendly botanical pesticide water-based preparation, and not only can solve the deep processing and utilization problem of moso bamboo, but also can solve the safety problem of the botanical pesticide preparation.
The second purpose of the invention is to provide a preparation method of the moso bamboo extract water suspending agent, which has simple steps and is suitable for large-scale production.
The third purpose of the invention is to provide the application of the moso bamboo extract water suspending agent in agricultural pest control.
In order to achieve the above purpose of the present invention, the following technical solutions are adopted:
the moso bamboo extract aqueous suspending agent is mainly prepared from the following raw materials: bamboo extract, adjuvant, and water;
wherein the auxiliary agent comprises: at least one of an emulsifier, a dispersant, a wetting agent, an antifreeze, a thickener, a structure modifier, and a protectant.
Meanwhile, the invention also provides a preparation method of the moso bamboo extract water suspending agent, which comprises the following steps: and (3) uniformly mixing water and the auxiliary agent, adding the moso bamboo extract, continuously and uniformly mixing, and sanding to obtain the moso bamboo extract water suspending agent.
Further, the invention also provides application of the moso bamboo extract water suspending agent in agricultural pest control.
Compared with the prior art, the invention has the beneficial effects that:
in the invention, the moso bamboo extract which is simple and easy to obtain is taken as an effective substance, so that the full utilization of moso bamboo resources is realized.
Meanwhile, the prepared moso bamboo extract aqueous suspending agent does not contain organic solvents, and the dosage of the auxiliary agents such as raw material emulsifiers is reduced compared with that of the conventional pesticide, so that the environment pollution can be reduced, and the moso bamboo extract aqueous suspending agent is a plant source pesticide with harmonious environment.
Furthermore, the moso bamboo extract aqueous suspension agent has good agricultural pest control effect and good control effect on agricultural pests such as green peach aphids.
Detailed Description
Embodiments of the present invention will be described in detail below with reference to examples, but it will be understood by those skilled in the art that the following examples are only illustrative of the present invention and should not be construed as limiting the scope of the present invention. The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.
The moso bamboo extract water suspending agent provided by the invention is a novel botanical pesticide, can replace the traditional chemical pesticide, is beneficial to controlling the pesticide residue of agricultural products from the source, and can avoid pollution and potential hazard caused by the use of organic solvent.
Specifically, the moso bamboo extract water suspension provided by the invention is prepared from the following raw materials: bamboo extract, adjuvant, and water. Specifically, the method comprises the following steps:
(a) phyllostachys pubescens extract
In the invention, the moso bamboo extract used as an efficacy raw material is obtained by extracting moso bamboo leaves used as a raw material, and the specific extraction method can be referred to as follows:
cleaning and drying the moso bamboo leaves, crushing, and then screening to obtain moso bamboo leaf powder; extracting folium Bambusae powder with organic solvent (such as ethanol), collecting extractive solution, and concentrating to obtain extract, or further drying to obtain powder.
In the process of cutting and processing the moso bamboo, a large amount of moso bamboo leaf waste is generated, and in the invention, the original waste moso bamboo leaves are used as basic raw materials, so that the raw materials are wide in source, low in price and easy to obtain, deep processing and utilization of moso bamboo resources can be realized, and the application value of the moso bamboo resources is improved.
(b) Auxiliary agent
In the invention, the raw material auxiliary agents are an emulsifier, a dispersant, a wetting agent, an antifreezing agent, a thickening agent, a structure regulator and a protective agent;
wherein the emulsifier is selected from: one or more of calcium dodecyl benzene sulfonate, castor oil polyoxyethylene ether and styryl phenyl polyoxyethylene ether;
the dispersant is selected from: at least one of sodium salt of 2-naphthalenesulfonic acid-formaldehyde polymer (NNO), polyethylene glycol, and glyceryl monostearate;
the wetting agent is selected from: at least one of polyoxyethylene alkylphenol ether, fatty alcohol-polyoxyethylene ether, alkyl sulfate (e.g., sodium dodecyl sulfate, etc.), and sulfonate (e.g., sodium dodecyl sulfate, etc.);
the anti-freezing agent is selected from: at least one of ethylene glycol, propylene glycol, and glycerol;
the thickening agent is selected from: at least one of polyacrylate, carboxymethyl cellulose, xanthan gum, and sodium acrylate;
the structure-modifying agent is selected from: at least one of magnesium aluminum silicate, bentonite and white carbon black;
the protective agent is selected from: s-20 (span-20), s-40 (span-40) and s-60 (span-60).
In the invention, all the assistants are nontoxic/low-toxicity assistants, so that the moso bamboo extract water suspending agent is safer and more environment-friendly, and is beneficial to further popularization and application.
(c) Water (W)
In the present invention, distilled water, double distilled water, deionized water, or double distilled water, etc. may be used as the raw material.
Further, in the aqueous suspension of phyllostachys pubescens extract according to the present invention, the amount of each raw material is as follows:
10-30 parts of moso bamboo extract, such as but not limited to 12, 15, 17, 20, 22, 25, 27 parts and the like; 1-5 parts of emulsifier, such as but not limited to 2, 3, or 4 parts; 0.5-5 parts of dispersant, such as but not limited to 1, 2, or 4 parts; 0.5-2 parts of wetting agent, such as but not limited to 1, or 1.5 parts; 2-5 parts of antifreeze agent, such as but not limited to 3, or 4 parts; thickener 0.1-2 parts, such as but not limited to 0.3, 0.5, 1, 1.2, or 1.5 parts, etc.; 1-4 parts of structure regulator, such as but not limited to 2, or 3 parts, etc.; 0.3-2 parts of protective agent, such as but not limited to 0.5, 1, or 1.5 parts; and 40-90 parts of water, such as but not limited to 45, 50, 55, 60, 65, 70, 75, 80, or 85 parts, etc.;
the condition is that the sum of the using amount of all the raw materials is 100 parts.
Further, the aqueous suspension of bamboo extract of the present invention having the above raw material composition can be prepared by conventional mixing and grinding methods, and the specific steps can be referred to as follows:
firstly, mixing an emulsifier, a dispersant, a wetting agent, an antifreezing agent, a thickening agent, a structure regulator, a protective agent and water according to the formula ratio, and then uniformly shearing and mixing at a high speed;
then, adding the moso bamboo extract with the formula amount into the mixed solution, and continuously and uniformly mixing to obtain a uniform mixed phase;
and finally, adding the mixed phase into a storage tank, sanding by using glass beads as abrasive materials, and uniformly stirring to obtain the product phyllostachys pubescens extract water suspension.
The moso bamboo extract aqueous suspension prepared by the method is uniform dark green liquid, does not contain organic solvent, reduces the types and the dosage of the used emulsifying agents, reduces the pollution to the environment, and is a botanical pesticide which is harmonious to the environment.
On the basis of the previous research on the sterilization of the moso bamboo extract (see, for example, CN104970053A, CN104970054A and the like), the inventors further found that the moso bamboo extract has a strong insecticidal effect, so that the moso bamboo extract aqueous suspension provided by the invention can be further used as an agricultural pest control agent and used for controlling agricultural pests such as green peach aphids and the like.
Specifically, the phyllostachys pubescens extract aqueous suspension prepared as above can be diluted by 10-200 times with water, and then used for controlling agricultural pests such as green peach aphids.
Example 1
Cleaning and placing moso bamboo leaves, drying in the air, crushing by an electric crusher, sieving by a 40-mesh sieve to obtain moso bamboo leaf powder, weighing 500g of moso bamboo leaf powder, placing the moso bamboo leaf powder in an extraction tank of an extraction and concentration machine set, adding 95% ethanol (10L) according to a ratio of 20:1 (extraction solvent/sample, ml/g), extracting at the temperature of 30 ℃ for 24h, repeating for 2 times, concentrating the extracting solution to be extractum to obtain a moso bamboo extract, and storing at the temperature of 4 ℃.
The 20% moso bamboo extract aqueous suspension is prepared according to the formula shown in table 1, and the specific steps are as follows:
(1) mixing the auxiliary agents in proportion, and uniformly mixing the mixture through high-speed shearing;
(2) adding the moso bamboo extract into the uniform mixed phase obtained in the step (1) in proportion;
(3) and (3) adding the mixed phase obtained in the step (2) into a storage tank, uniformly stirring the mixed phase with a sand mill assisted with glass beads, and grinding the mixed phase for 30 minutes at the rotating speed of 3200rpm to obtain the aqueous suspension of the example 1.
Formula of water suspension agent containing moso bamboo extract with content of 120% in table
| Raw materials | Weight (gram) |
| Phyllostachys pubescens extract (extract) | 20 |
| NNO (dispersant) | 3 |
| Castor oil polyoxyethylene ether (emulsifier) | 2 |
| Fatty alcohol polyoxyethylene ether (wetting agent) | 1.5 |
| Xanthan gum (thickener) | 0.15 |
| Ethylene glycol (antifreeze) | 4 |
| Magnesium aluminium silicate (Structure regulator) | 2 |
| s-20 (protectant) | 0.5 |
| Deionized water | Complement 100 |
Example 2
A phyllostachys pubescens extract was obtained according to the method of example 1, and then, a 10% aqueous suspension of the phyllostachys pubescens extract was prepared according to the formulation as shown in table 2 below.
Formula of moso bamboo extract aqueous suspension agent with content of 210% in table
| Raw materials | Weight (gram) |
| Phyllostachys pubescens extract (extract) | 10 |
| Polyethylene glycol (dispersant) | 1 |
| Calcium dodecylbenzene sulfonate (emulsifier) | 1.5 |
| Sodium dodecyl sulfate (wetting agent) | 1 |
| Carboxymethyl cellulose (thickener) | 0.1 |
| Propylene glycol (antifreeze) | 2 |
| Bentonite (Structure regulator) | 1 |
| s-40 (protectant) | 0.3 |
| Deionized water | Complement 100 |
Then, referring to the method of example 1, a 10% aqueous suspension of moso bamboo extract was obtained.
Example 3
A phyllostachys pubescens extract was obtained according to the method of example 1, and then, a 15% aqueous phyllostachys pubescens extract suspension was prepared according to the formulation as shown in table 3 below.
TABLE 315% Moso bamboo extract aqueous suspension formulation
| Raw materials | Weight (gram) |
| Phyllostachys pubescens extract (extract) | 15 |
| Stearic acid monoglyceride (dispersant) | 2 |
| Styryl phenyl polyoxyethylene ether (emulsifier) | 2 |
| Sodium dodecyl sulfate (wetting agent) | 1.5 |
| Sodium acrylate (thickener) | 0.2 |
| Glycerol (antifreeze) | 3 |
| White carbon black (Structure regulator) | 2 |
| s-60 (protectant) | 0.5 |
| Deionized water | Complement 100 |
Then, referring to the method of example 1, a 15% aqueous suspension of moso bamboo extract was obtained.
Example 4
A moso bamboo extract was obtained according to the method of example 1, and then, a 25% moso bamboo extract aqueous suspension was prepared according to the formulation as in table 4 below.
Formula of water suspension agent containing moso bamboo extract with surface 425 percent
| Raw materials | Weight (gram) |
| Phyllostachys pubescens extract (extract) | 25 |
| Polyethylene glycol (dispersant) | 3 |
| Castor oil polyoxyethylene ether (emulsifier) | 3 |
| Fatty alcohol polyoxyethylene ether (wetting agent) | 2 |
| Carboxymethyl cellulose (thickener) | 0.5 |
| Propylene glycol (antifreeze) | 4 |
| Magnesium aluminum silicate (Structure regulator) | 3 |
| s-40 (protectant) | 1 |
| Deionized water | Complement 100 |
Then, referring to the method of example 1, a 25% aqueous suspension of moso bamboo extract was obtained.
Example 5
A phyllostachys pubescens extract was obtained according to the method of example 1, and then a 30% aqueous suspension of the phyllostachys pubescens extract was prepared according to the formulation as shown in table 5 below.
TABLE 530% Moso bamboo extract aqueous suspension formulation
| Raw materials | Weight (gram) |
| Phyllostachys pubescens extract (extract) | 30 |
| Stearic acid monoglyceride (dispersant) | 4 |
| Styryl phenyl polyoxyethylene ether (emulsifier) | 4 |
| Polyoxyethylene alkylphenol ether (wetting agent) | 2 |
| Xanthan gum (thickener) | 1 |
| Ethylene glycol (antifreeze) | 4 |
| White carbon black (Structure regulator) | 4 |
| s-20 (protectant) | 1.5 |
| Deionized water | Complement 100 |
Then, referring to the method of example 1, a 25% aqueous suspension of moso bamboo extract was obtained.
Experimental example physical and chemical properties of 120% Phyllostachys Pubescens extract aqueous suspension agent
The stability of the aqueous suspension of bamboo extract of the present invention was tested by taking the 20% aqueous suspension of bamboo extract prepared in example 1 as an example, and the results are shown in table 6 below:
TABLE 620% stability of aqueous suspensions of Phyllostachys pubescens extract
| Index name | Index (I) |
| Appearance of the product | Greenish black suspension |
| Phyllostachys pubescens extract | 20％ |
| Dilution stability (Dilute 200 times) | Rapidly self-dispersing |
| Freeze thaw stability | No precipitation and no oil separation |
| Stability in Heat storage | Qualified (resolution ratio 1.55%) |
| Stability in Cold storage | Qualified (resolution ratio 1.01%) |
| Pourability | Qualified |
| Long-lasting foamability | Qualified |
The results in table 6 show that the technical indexes of the moso bamboo extract aqueous suspension provided by the invention meet the quality control requirements of the preparation.
Experimental example field pesticide effect of 220% moso bamboo extract water suspension agent for preventing and controlling myzus persicae
The aqueous emulsion containing the phyllostachys pubescens extract prepared in example 1 is used as an experimental agent to perform a field efficacy test, and meanwhile, 33% tea tree essential oil missible oil is used as a control agent, and clear water is used as a blank control.
The specific test steps are as follows: the 20% aqueous suspension containing the phyllostachys pubescens extract prepared in example 1 was diluted with water by 10, 50, and 200 times, respectively, and used for controlling myzus persicae. The test results are shown in Table 7.
Results of field pesticide effect test of using phyllostachys pubescens extract aqueous suspension agent with content shown in table 720% to control peach aphids
As can be seen from the control test results in table 7, when the dilution ratio is 10 times, the control effects of the 20% phyllostachys pubescens extract aqueous suspension for 24 hours and 48 hours are 68.05% and 65.94%, respectively, and the control effects are close to those of the control group of 33% tea tree essential oil emulsifiable concentrate, calculated according to the content of the effective components.
Similarly, when the dilution times are 50 and 200 times, the control effect of the 20% moso bamboo extract water suspending agent can also reach the equivalent level of the control group of 33% tea tree essential oil missible oil according to the content calculation of the active ingredients.
Therefore, the 20% moso bamboo extract aqueous suspension prepared in the embodiment 1 of the invention has a good control effect on myzus persicae.
While particular embodiments of the present invention have been illustrated and described, it would be obvious that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
Claims (4)
1. The moso bamboo extract water suspending agent is characterized by being prepared from the following raw materials: according to the weight parts, the bamboo extract comprises 20 parts of moso bamboo extract, 3 parts of NNO, 2 parts of castor oil polyoxyethylene ether, 1.5 parts of fatty alcohol polyoxyethylene ether, 0.15 part of xanthan gum, 4 parts of ethylene glycol, 2 parts of magnesium aluminum silicate, s-200.5 parts of deionized water and 66.85 parts of deionized water;
the preparation method of the moso bamboo extract comprises the following steps: cleaning and drying the moso bamboo leaves, crushing, and then screening to obtain moso bamboo leaf powder; then extracting the moso bamboo leaf powder with ethanol, collecting the extracting solution and concentrating to obtain the moso bamboo extract.
2. The method for preparing a phyllostachys pubescens extract aqueous suspension agent as set forth in claim 1, comprising:
and (3) uniformly mixing water and the auxiliary agent, adding the moso bamboo extract, continuously and uniformly mixing, and grinding to obtain the moso bamboo extract water suspending agent.
3. The method of claim 2, wherein the grinding comprises grinding with glass beads as an abrasive.
4. The use of the aqueous phyllostachys pubescens extract suspension concentrate of claim 1 for agricultural pest control, comprising: diluting the moso bamboo extract aqueous suspension agent by 10-200 times with water, and using the aqueous suspension agent for preventing and controlling agricultural pests, wherein the agricultural pests comprise green peach aphids.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910177089.1A CN109820004B (en) | 2019-03-08 | 2019-03-08 | Moso bamboo extract water suspending agent and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910177089.1A CN109820004B (en) | 2019-03-08 | 2019-03-08 | Moso bamboo extract water suspending agent and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109820004A CN109820004A (en) | 2019-05-31 |
| CN109820004B true CN109820004B (en) | 2020-08-07 |
Family
ID=66865762
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910177089.1A Active CN109820004B (en) | 2019-03-08 | 2019-03-08 | Moso bamboo extract water suspending agent and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109820004B (en) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104970054B (en) * | 2015-04-14 | 2018-05-18 | 安徽农业大学 | A kind of bactericide compounded preparation of the extract containing mao bamboon and preparation method thereof |
| CN104970053B (en) * | 2015-04-14 | 2018-05-01 | 安徽农业大学 | A kind of mao bamboon extract aqueous emulsion and preparation method thereof |
-
2019
- 2019-03-08 CN CN201910177089.1A patent/CN109820004B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN109820004A (en) | 2019-05-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105690519B (en) | Environmentally friendly wood preservative | |
| CN102342307B (en) | Pollution-free biopesticide | |
| CN102018266B (en) | All-natural plant composite preservative and preparation method and use method thereof | |
| CN103317566A (en) | Micro-emulsion-type wood and bamboo mould-proof agent, as well as preparation method and application thereof | |
| CN101647437A (en) | Methyl sulcotrione oil suspension concentrate combination | |
| CN109321363B (en) | Method for extracting juniper essential oil and phytoncide at low temperature under negative pressure | |
| CA2920061C (en) | Biopesticide compositions comprising water soluble polyols | |
| CN113767916B (en) | Composition for resisting plant virus diseases and preparation method and application thereof | |
| CN109820004B (en) | Moso bamboo extract water suspending agent and preparation method and application thereof | |
| CN105901681A (en) | Preparation methods for extract liquid, fermentation extracellular liquid and fermentation intracellular liquid of dictyophora, and application thereof | |
| CN111165479A (en) | Abamectin and lufenuron synergistic suspending agent and preparation method thereof | |
| CN105961414A (en) | Water-based plant-source pesticide with diosgenin and method for preparing water-based plant-source pesticide | |
| CN107410351B (en) | Regulating agent for grapes | |
| CN106386796B (en) | Bispyribac-sodium cyhalofop-butyl suspension emulsion and preparation method thereof | |
| CN113545361B (en) | Seed treatment suspending agent containing difenoconazole and imidacloprid | |
| CN101218922A (en) | High-efficiency and low-toxin seed-treating agent | |
| CN102887911A (en) | Azadirachtin extraction method | |
| CN112314596B (en) | Animal-derived acaricide 20-30% amitraz acid water emulsion and preparation method and application thereof | |
| CN112500930A (en) | Preparation method and application of compound essential oil of vitex rotundifolia | |
| CN102258019A (en) | Mixed fatty acid preparation for biochemical pesticides and application thereof | |
| CN106942302A (en) | A kind of biological pesticide for preventing and treating tea tree tea lesser leafhopper | |
| CN106720282B (en) | Composite preservative film based on plant source extracting agent | |
| CN115590038B (en) | Tobacco mosaic virus nucleic acid interferon dispersible oil suspending agent and application thereof | |
| CN101322503A (en) | Method for preparing agent for preventing and treating red spider of Chinese chestnut using extract from vervain family flowers | |
| CN107156195B (en) | Botanical pesticide for preventing and treating plant pests and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |