CN109819987A - A kind of Herbicidal combinations containing diflufenican, pendimethalin and Oxyfluorfen - Google Patents

A kind of Herbicidal combinations containing diflufenican, pendimethalin and Oxyfluorfen Download PDF

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CN109819987A
CN109819987A CN201910218081.5A CN201910218081A CN109819987A CN 109819987 A CN109819987 A CN 109819987A CN 201910218081 A CN201910218081 A CN 201910218081A CN 109819987 A CN109819987 A CN 109819987A
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pendimethalin
oxyfluorfen
diflufenican
grams
herbicidal combinations
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林枫
包来仓
尚铁军
刘继平
侯洁
张艳菊
赵欣雨
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Henan Hansi Crop Protection Co Ltd
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Henan Hansi Crop Protection Co Ltd
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Abstract

The invention patent relates to pesticide herbicide technical fields, disclose a kind of Herbicidal combinations containing diflufenican, pendimethalin and Oxyfluorfen.The Herbicidal combinations active constituent includes diflufenican, pendimethalin and Oxyfluorfen, the mass ratio of the diflufenican, pendimethalin and Oxyfluorfen is 1~10:10~30:1~10, it is also containing auxiliary agent usually used in pesticidal preparations, the preferred dosage form of the Herbicidal combinations are as follows: missible oil, wettable powder, water dispersible granules, suspending agent, aqueous emulsion.Relative to traditional single dose or binary built Herbicidal combinations, the active ingredient combinations of three kinds of diflufenican, pendimethalin and Oxyfluorfen different role mechanism are used in compounding by Herbicidal combinations provided by the invention, so that the Herbicidal combinations have apparent synergistic function, not only effectively reduce the generation of herbicide resistance, expand degrass spectrum, and it is at low cost, drug effect plays rapidly, and the lasting period is long.

Description

A kind of Herbicidal combinations containing diflufenican, pendimethalin and Oxyfluorfen
Technical field
The invention patent relates to pesticide herbicide technical field, it is especially a kind of containing diflufenican, pendimethalin and The Herbicidal combinations of Oxyfluorfen.
Background technique
Diflufenican (diflufenican), chemical name N- (2,4 difluorobenzene base) -2- [(3- trifluoromethyl) benzene oxygen Base] -3- pyridine anilide, it is a kind of herxheimer-liked reaction inhibitor, belongs to amine herbicide, weeds plant is absorbing Carotenoid content can be gradually reduced after medicament, and so as to cause Destruction of Chlorophyll and cell rupture, it is de- that weeds show as young shoot Color or white, until it is dead to wilt.It is mainly used for preventing and treating a variety of annual gramineous weeds such as corn and soybean and wheatland and certain A little broadleaf weeds, it is especially obvious to clearvers, Veronica removal effect.
Pendimethalin (pendimethalin), chemical name N- (1- ethyl propyl) -2,6- dinitro -3,4- dimethyl Aniline, before being a kind of selective bud, upland field soil handles herbicide after bud.The weed bud that it can sprouted absorbs, and makes Obtain medicament causes weeds dead with tubulin binding after entering plant to inhibit the mitosis of plant cell, It has been widely used in the various crops such as corn and soybean, peanut, cotton, direct-seeding dry rice, potato, tobacco, vegetables, Neng Gouyou Effect prevention and treatment annual gramineous weed, part broadleaf weeds, such as nutgrass flatsedge, barnyard grass, herba digitariae, herba setariae viridis, semen euphorbiae, herba eleusines indicae, horse Bitterroot, amaranth, Chenopodiaceae, piemarker, black nightshade, cyperus iria, anisotropic nutgrass flatsedge etc..
Oxyfluorfen is a kind of contact killing type herbicide, its activity of weeding is usually played in the case where there is light, main logical Cross plumule, mesocotyl enters in plant, less through root absorption, only denier is transported up by root into leaf Portion, before being widely used in cotton, round onions, peanut, soybean, beet, fruit tree and vegetable fields bud, weeding after bud, to barnyard grass, sesbania, Downy brome, herba setariae viridis, datura, quackgrass, artemisiifolia, secondary chrysanthemum twirl, piemarker, charlock unifacial leaf and broadleaf weeds have significantly Control efficiency, while its very anti-leaching can be made into missible oil use.
Currently, common herbicide is mostly single dose in agricultural production, often effect is single, such as closes herbicide only to not going out The weeds of soil are effective, then invalid to unearthed weeds, thus in order to reach different herbicidal effects, it is often necessary to repeatedly divide Not Shi Yong a variety of special purposes herbicide, not only considerably increase medicine frequency and recruitment cost in this way, but also can be to work Object and Environmental security threaten, and are used for a long time, are also easy to that weeds is made to develop drug resistance.Therefore suitable herbicide is screened to carry out Compounding, which is used in mixed way, can not only effectively improve herbicidal effect, reduce dosage, reduce cost, and be conducive to delay weeds anti- The generation of pharmacological property is of great practical significance simultaneously for complicated and diversified weed species are prevented and treated.
Summary of the invention
For the problems of the prior art, the purpose of the present invention is to provide a kind of component is reasonable, drug cost is low, is not easy The Herbicidal combinations containing diflufenican, pendimethalin and Oxyfluorfen to develop drug resistance, not only to various grass Section weeds and broadleaf weeds and wait different careless phase weeds have preferable control efficiency, and slowing down Weed Resistance, reducing drug Dosage etc. also has positive effect.
In order to achieve the above object, the technical scheme is that
A kind of Herbicidal combinations containing diflufenican, pendimethalin and Oxyfluorfen comprising active constituent pyrrole Fluorine acyl grass amine, pendimethalin and Oxyfluorfen, the mass ratio of the diflufenican, pendimethalin and Oxyfluorfen are 1 ~10:10~30:1~10.
Herbicidal combinations of the present invention are also containing auxiliary agent usually used in pesticidal preparations to be prepared into suitable agriculture The various suitable dosage forms that industry uses.
Specifically, the auxiliary agent include solvent, emulsifier, dispersing agent, wetting agent, disintegrating agent, thickener, stabilizer, One or more of antifreezing agent, defoaming agent, filler.
Specifically, the solvent is selected from aromatic solvent naphtha, toluene, dimethylbenzene, cyclohexanone, pyrrolidones, solvent naphtha, two Methylformamide, N-methyl pyrrolidones, fatty acid distribution of coconut oil methyl esters, methyl oleate, methylated vegetable oil, ethyl acetate, adjacent benzene One or more of dicarboxylic acid methyl ester, dibutyl phthalate.
Specifically, the emulsifier is selected from agriculture breast 500#, agriculture breast 600#, Nongru-700 #, castor oil polyoxyethylene ether, rouge Fat acid polyoxyethylene ether, polyoxyethylene aliphatic alcohol ether, alkyl phenol polyoxyethylene ether, ethoxy castor oil, polymethyl acrylate, rouge One or more of fat acid polyethylene glycol ester, trilaurin polyoxyethylene ether.
Specifically, the dispersing agent is selected from sodium lignin sulfonate, calcium lignosulfonate, Sodium Polyacrylate, di-2-ethylhexylphosphine oxide Naphthalene sulfonate, alkyl amine group taurate, sodium methylene bis-naphthalene sulfonate formaldehyde condensation products, carboxymethyl cellulose, alkyl naphthalene sulfonic acid One or more of salt condensation polymer.
Specifically, the wetting agent is selected from lauryl sodium sulfate, neopelex, dodecyl benzene sulfonic acid Calcium, Negel, fatty alcohol polyglycol ether sulfate, fat alcohol polyethylene ether, nonylphenol polyoxyethylene ether, dehydration mountain One or more of pears polyol fatty acid ester APEO, Nekal BX, wetting and penetrating agent F, spaonin powder, spaonin powder.
Specifically, the disintegrating agent is selected from one of bentonite, urea, ammonium sulfate or a variety of.
Specifically, the thickener be selected from one of xanthan gum, polyvinyl alcohol, sodium alginate, aluminum magnesium silicate or It is a variety of.
Specifically, the stabilizer is selected from BH-2,6- di-t-butyl -4-4 methylphenol, butylated hydroxy anisole, ring One or more of oxygen chloropropane.
Specifically, the antifreezing agent is selected from one or more of ethylene glycol, propylene glycol, glycerine, polyethylene glycol.
Specifically, the defoaming agent is selected from silicone oil, silicone compound, C10-20 saturated fat acid compounds, C8- One or more of 10 fatty alcohols compounds.
Specifically, the filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon black, starch, lightweight carbon One or more of sour calcium.
Preferably, the suitable dosage forms of Herbicidal combinations of the present invention be missible oil, wettable powder, water dispersible granules, suspending agent, Aqueous emulsion.
Compared with prior art, the invention has the advantages that
1. Herbicidal combinations provided by the invention are by three kinds of diflufenican, pendimethalin and Oxyfluorfen different roles The active ingredient combinations of mechanism use, and give full play to the advantage of three, can effectively reduce the generation of herbicide resistance, expand and kill Grass spectrum has widened prevention and treatment using the time, and primary application can reach the purpose for preventing and kill off a variety of weeds, miscellaneous suitable for preventing and kill off grass family The weeds of the different growing stages such as grass, broadleaf weeds, different careless phases, overcome the defect and deficiency that existing herbicide uses.
2. relative to traditional single dose or binary built Herbicidal combinations, three kinds of work of Herbicidal combinations provided by the invention It is had obvious synergistic function between property ingredient, weeds in field control efficiency is significant, not only greatly reduces active constituent Dosage and times for spraying, and environmental pollution very little, have no adverse effects to crop safety.
3. Herbicidal combinations provided by the invention, drug effect is played rapidly, and the lasting period is long, at low cost, easy to use, time saving province Power, easy to spread and large-scale application have huge economic benefit and social value, meet the demand of sustainable development.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described. Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all Belong to the scope of protection of the invention.
1 50% diflufenican pendimethalin oxyfluorfen EC of embodiment
10 grams of diflufenican, 30 grams of pendimethalin, 10 grams of Oxyfluorfen, 10 grams of castor oil polyoxyethylene ether are taken, it is molten Agent oil complements to 100 grams, and above-mentioned each component is sufficiently mixed uniformly, and is sanded, is sheared, and missible oil is prepared into.
2 32% diflufenican pendimethalin oxyfluorfen EC of embodiment
1 gram of diflufenican, 30 grams of pendimethalin, 1 gram of Oxyfluorfen, 500#10 grams of agriculture breast are taken, solvent naphtha complements to 100 grams, above-mentioned each component is sufficiently mixed uniformly, and is sanded, is sheared, is prepared into missible oil.
3 26% diflufenican pendimethalin oxyfluorfen EC of embodiment
Take 5 grams of diflufenican, 20 grams of pendimethalin, 1 gram of Oxyfluorfen, 10 grams of aliphatic acid polyethenoxy ether, hexamethylene Ketone complements to 100 grams, and above-mentioned each component is sufficiently mixed uniformly, and is sanded, is sheared, and missible oil is prepared into.
4 19% diflufenican pendimethalin oxyfluorfen EC of embodiment
Take 8 grams of diflufenican, 10 grams of pendimethalin, 1 gram of Oxyfluorfen, 8 grams of aliphatic acid polyethenoxy ether, acetic acid second Ester complements to 100 grams, and above-mentioned each component is sufficiently mixed uniformly, and is sanded, is sheared, and missible oil is prepared into.
5 22% diflufenican pendimethalin oxyfluorfen EC of embodiment
Take 10 grams of diflufenican, 10 grams of pendimethalin, 2 grams of Oxyfluorfen, 10 grams of alkyl phenol polyoxyethylene ether, adjacent benzene Dicarboxylic acid methyl ester complements to 100 grams, and above-mentioned each component is sufficiently mixed uniformly, and is sanded, is sheared, and missible oil is prepared into.
6 41% diflufenican pendimethalin oxyfluorfen EC of embodiment
Take 10 grams of diflufenican, 30 grams of pendimethalin, 1 gram of Oxyfluorfen, 15 grams of ethoxy castor oil, ethyl acetate 100 grams are complemented to, above-mentioned each component is sufficiently mixed uniformly, and is sanded, sheared, missible oil is prepared into.
7 22% diflufenican pendimethalin Oxyfluorfen wettable powder of embodiment
Take 1 gram of diflufenican, 20 grams of pendimethalin, 1 gram of Oxyfluorfen, 5 grams of sodium lignin sulfonate, dodecyl sulphur 6 grams of sour sodium, kaolin complements to 100 grams, and above-mentioned each component is uniformly mixed, again through air-flow crushing to get can after mechanical crushing Wet powder.
8 16% diflufenican pendimethalin Oxyfluorfen wettable powder of embodiment
Take 5 grams of diflufenican, 10 grams of pendimethalin, 1 gram of Oxyfluorfen, 5 grams of calcium lignosulfonate, detergent alkylate 6 grams of sodium sulfonate, diatomite complements to 100 grams, and above-mentioned each component is uniformly mixed, after mechanical crushing again through air-flow crushing to get Wettable powder.
9 20% diflufenican pendimethalin Oxyfluorfen wettable powder of embodiment
Take 8 grams of diflufenican, 10 grams of pendimethalin, 2 grams of Oxyfluorfen, 5 grams of Sodium Polyacrylate, poly alkyl alcohol second two 6 grams of ether alcohol sulfate, white carbon black complements to 100 grams, and above-mentioned each component is uniformly mixed, again through air-flow crushing after mechanical crushing, Up to wettable powder.
10 25% diflufenican pendimethalin Oxyfluorfen wettable powder of embodiment
Take 10 grams of diflufenican, 10 grams of pendimethalin, 5 grams of Oxyfluorfen, 5 grams of calcium lignosulfonate, dodecyl 6 grams of benzene sulfonic acid sodium salt, diatomite complement to 100 grams, and above-mentioned each component is uniformly mixed, again through air-flow crushing after mechanical crushing, i.e., Obtain wettable powder.
11 12% diflufenican pendimethalin Oxyfluorfen wettable powder of embodiment
1 gram of diflufenican, 10 grams of pendimethalin, 1 gram of Oxyfluorfen, 5 grams of carboxymethyl cellulose, 5 grams of spaonin powder are taken, Precipitated calcium carbonate complements to 100 grams, and above-mentioned each component is uniformly mixed, again through air-flow crushing to get wettable after mechanical crushing Pulvis.
12 13% diflufenican pendimethalin Oxyfluorfen water dispersible granules of embodiment
Take 1 gram of diflufenican, 10 grams of pendimethalin, 2 grams of Oxyfluorfen, 5 grams of sodium lignin sulfonate, dodecyl sulphur 5 grams of sour sodium, 2 grams of bentonite, kaolin supplies 100 grams, a small amount of water extrusion granulation will be added after above-mentioned each component co-grinding, dried It is dry to obtain water dispersible granules.
13 17% diflufenican pendimethalin Oxyfluorfen water dispersible granules of embodiment take diflufenican 5 Gram, 10 grams of pendimethalin, 2 grams of Oxyfluorfen, 5 grams of Sodium Polyacrylate, 5 grams of Negel, 2 grams of urea, diatomite mend 100 grams of foot.A small amount of water extrusion granulation will be added after above-mentioned each component co-grinding, drying obtains water dispersible granules.
14 23% diflufenican pendimethalin Oxyfluorfen water dispersible granules of embodiment
It takes 8 grams of diflufenican, 10 grams of pendimethalin, 5 grams of Oxyfluorfen, 10 grams of alkyl amino taurate, pull open BX5 grams of powder, 2 grams of bentonite, white carbon black supplies 100 grams, a small amount of water extrusion granulation will be added after above-mentioned each component co-grinding, dried It is dry to obtain water dispersible granules.
15 30% diflufenican pendimethalin Oxyfluorfen water dispersible granules of embodiment
Take 10 grams of diflufenican, 10 grams of pendimethalin, 10 grams of Oxyfluorfen, 10 grams of di-2-ethylhexylphosphine oxide naphthalene sulfonate, profit F8 grams of wet bleeding agent, 3 grams of ammonium sulfate, starch supplies 100 grams, and a small amount of water extruding will be added to make after above-mentioned each component co-grinding Grain, drying obtain water dispersible granules.
16 36% diflufenican pendimethalin Oxyfluorfen water dispersible granules of embodiment
Take 5 grams of diflufenican, 30 grams of pendimethalin, 1 gram of Oxyfluorfen, 10 grams of carboxymethyl cellulose, spaonin powder 5 Gram, 2 grams of bentonite, precipitated calcium carbonate supplies 100 grams, will dry after above-mentioned each component co-grinding plus a small amount of water extrusion granulation It is dry to obtain water dispersible granules.
17 16% diflufenican pendimethalin Oxyfluorfen suspending agent of embodiment
Take 1 gram of diflufenican, 10 grams of pendimethalin, 5 grams of Oxyfluorfen, 3 grams of lauryl sodium sulfate, sulfomethylated lignin 3 grams of sour sodium, 1 gram of xanthan gum, water complements to 100 grams, and above-mentioned each component is sufficiently mixed uniformly, and is sanded, suspension is prepared into Agent.
18 20% diflufenican pendimethalin Oxyfluorfen suspending agent of embodiment
Take 5 grams of diflufenican, 10 grams of pendimethalin, 5 grams of Oxyfluorfen, 3 grams of neopelex, lignin 3 grams of sulfoacid calcium, 1 gram of xanthan gum, water complements to 100 grams, and above-mentioned each component is sufficiently mixed uniformly, and is sanded, is prepared into outstanding Floating agent.
19 28% diflufenican pendimethalin Oxyfluorfen suspending agent of embodiment
Take 8 grams of diflufenican, 10 grams of pendimethalin, 10 grams of Oxyfluorfen, 5 grams of Negel, sulfomethylated lignin 3 grams of sour sodium, 1 gram of xanthan gum, water complements to 100 grams, and above-mentioned each component is sufficiently mixed uniformly, and is sanded, suspension is prepared into Agent.
20 39% diflufenican pendimethalin Oxyfluorfen suspending agent of embodiment
Take 8 grams of diflufenican, 30 grams of pendimethalin, 1 gram of Oxyfluorfen, 8 grams of Nekal BX, alkyl amine group taurine 6 grams of salt, 1 gram of xanthan gum, water complements to 100 grams, and above-mentioned each component is sufficiently mixed uniformly, and is sanded, suspending agent is prepared into.
21 31% diflufenican pendimethalin Oxyfluorfen suspending agent of embodiment
Take 10 grams of diflufenican, 20 grams of pendimethalin, 1 gram of Oxyfluorfen, 8 grams of spaonin powder, carboxymethyl cellulose 5 Gram, 1 gram of xanthan gum, water complements to 100 grams, and above-mentioned each component is sufficiently mixed uniformly, and is sanded, suspending agent is prepared into.
22 21% diflufenican pendimethalin oxyfluorfen water emulsion of embodiment
Take 1 gram of diflufenican, 10 grams of pendimethalin, 10 grams of Oxyfluorfen, 500#5 grams of agriculture breast, dimethylformamide 10 grams, 3 grams of ethylene glycol, 1 gram of silicone oil, 1 gram of xanthan gum, deionized water complements to 100 grams, is added after above-mentioned oil phase component is mixed In water phase, aqueous emulsion is obtained.
23 25% diflufenican pendimethalin oxyfluorfen water emulsion of embodiment
Take 5 grams of diflufenican, 10 grams of pendimethalin, 10 grams of Oxyfluorfen, 5 grams of castor oil polyoxyethylene ether, pyrroles 10 grams of alkanone, 1 gram of silicone compound, 1 gram of polyvinyl alcohol, 3 grams of propylene glycol, deionized water complements to 100 grams, by above-mentioned oily phase It is added in water phase after component mixing, obtains aqueous emulsion.
24 29% diflufenican pendimethalin oxyfluorfen water emulsion of embodiment
Take 8 grams of diflufenican, 20 grams of pendimethalin, 1 gram of Oxyfluorfen, 5 grams of aliphatic acid polyethenoxy ether, acetic acid second 10 grams of ester, 1 gram of C10-20 saturated fat acid compounds, 1 gram of aluminum magnesium silicate, 3 grams of propylene glycol, deionized water complements to 100 grams, It is added in water phase after above-mentioned oil phase component is mixed, obtains aqueous emulsion.
25 21% diflufenican pendimethalin oxyfluorfen water emulsion of embodiment
Take 10 grams of diflufenican, 10 grams of pendimethalin, 1 gram of Oxyfluorfen, 5 grams of polymethyl acrylate, O-phthalic 10 grams of sour methyl esters, 1 gram of silicone oil, 1 gram of aluminum magnesium silicate, 3 grams of propylene glycol, deionized water complements to 100 grams, and above-mentioned oil phase component is mixed It is added in water phase after conjunction, obtains aqueous emulsion.
The pharmacodynamic test of 26 garlic field weeding composition pharmaceutical preparation of embodiment
The Herbicidal combinations medicament that Example 1 to embodiment 25 prepares carries out pharmacodynamic test, with 50% pyrrole fluorine acyl Careless amine wettable powder 1,330 grams per liter pendimethalin missible oil, 2,240 grams per liter Oxyfluorfen as a control group as a control group Missible oil as a control group 3, clear water is as blank control group.
(1) synergy effect of each group drug to be measured to weeds:
Co-toxicity coefficient method is used to evaluate the synergistic effect of Herbicidal combinations medicament provided by the invention: dense with composition medicament The natural logrithm of degree (X) is asked with growth inhibition percent or fresh weight suppression percentage (Y) of the composition medicament to target weeds Regression equation, and composition medicament is calculated to the EC of weeds50Value or EC90Value, then acquires co-toxicity coefficient.With co-toxicity coefficient Complex composition medicament is evaluated to the synergy effect of weeds, co-toxicity coefficient > 120 are expressed as synergistic effect, and co-toxicity coefficient exists Summation action is expressed as between 80~120, co-toxicity coefficient < 80 are expressed as antagonism.
The co-toxicity coefficient calculation formula used in the present embodiment is as follows:
Co-toxicity coefficient (CTC)=100/ (ECIt is mixed×PDiflufenican/ECDiflufenican+ECIt is mixed×PPendimethalin/ECPendimethalin+ECIt is mixed× POxyfluorfen/ECOxyfluorfen)
In formula: ECIt is mixedFor the EC of composition medicament50It is worth (to clearvers, shepherd's purse, herba digitariae, herba setariae viridis, similarly hereinafter);PDiflufenicanFor Diflufenican shared mass ratio in composition medicament effective component;PPendimethalinIt is effective in composition medicament for pendimethalin Shared mass ratio in ingredient;POxyfluorfenFor Oxyfluorfen in composition medicament effective component shared mass ratio; ECDiflufenicanFor the EC of diflufenican50Value;ECPendimethalinFor the EC of pendimethalin50Value, ECOxyfluorfenFor the EC of Oxyfluorfen50 Value.Each group of other EC50Value and co-toxicity coefficient are shown in Table 1.
The EC of 1 each group of table other drug to be measured50Value and co-toxicity coefficient
By 1 experimental result of table it is found that diflufenican provided by the invention, pendimethalin, Oxyfluorfen compounding after institute Herbicidal combinations, diflufenican, pendimethalin, Oxyfluorfen mass ratio in 1~10:10~30:1~10, Co-toxicity coefficient is all far more than 120, illustrates that diflufenican, pendimethalin, Oxyfluorfen after compounding, produce apparent increasing Effect effect.
(2) cauline leaf process control efficiency of each group drug to be measured to various weeds
It tests and is carried out in Henan Zhongmou County garlic field, each group handles 4 repetitions, and processing area is 20m2;Implement Example 1 is another that (the 34% pendimethalin Oxyfluorfen of control group 4 is arranged to embodiment 25, control group 1, control group 2, control group 3 Missible oil).Application method: soil sprays before seedling after garlic is broadcast for embodiment 1 to embodiment 25, control group 2, control group 3, control group 4 Mist processing, control group 1 is 15 days after weeds 1-2 leaf phase spraying treatment, medicine, 30 days statistics prevent and treat result.Test process, formulation rate And control efficiency is shown in Table 2.
Preventive effect calculation formula are as follows: strain preventive effect (%)=(check plot weeds strain number-treatment region weeds strain number)/check plot weeds Strain number × 100
The each group of 2 garlic field weed of table processing medication administration amount to be measured and control efficiency
By 2 test result of table it is found that diflufenican, pendimethalin or Oxyfluorfen and 34% 2 compared to single agent The clever oxyfluorfen EC of first penta, gained removes after diflufenican provided by the invention, pendimethalin, Oxyfluorfen compounding The herbicidal effect of careless composition will be apparently higher than four control groups, and significant difference (P < 0.05), synergistic function is obvious, simultaneously Degrass spectrum has also been enlarged.
In conclusion Herbicidal combinations provided by the invention compound diflufenican, pendimethalin, Oxyfluorfen Afterwards, reach cooperative synergism effect, expand degrass spectrum, the confrontation stronger weeds of pharmacological property can also effectively prevent, environmentally safe It has no adverse effects, can be used for preventing and treating weeds in field.
The foregoing description of the disclosed embodiments can be realized those skilled in the art or using the present invention.To this A variety of modifications of a little embodiments will be apparent for a person skilled in the art, and the general principles defined herein can Without departing from the spirit or scope of the present invention, to realize in other embodiments.Therefore, the present invention will not be limited It is formed on the embodiments shown herein, and is to fit to consistent with the principles and novel features disclosed in this article widest Range.

Claims (4)

1. a kind of Herbicidal combinations containing diflufenican, pendimethalin and Oxyfluorfen, it is characterised in that: including activity Ingredient diflufenican, pendimethalin and Oxyfluorfen, the quality of the diflufenican, pendimethalin and Oxyfluorfen Than for 1~10:10~30:1~10.
2. the Herbicidal combinations as described in claim 1 containing diflufenican, pendimethalin and Oxyfluorfen, feature It is: also containing auxiliary agent usually used in pesticidal preparations to be prepared into various doses of suitable agricultural use in Herbicidal combinations Type.
3. the Herbicidal combinations as claimed in claim 2 containing diflufenican, pendimethalin and Oxyfluorfen, feature Be: the auxiliary agent includes solvent, emulsifier, dispersing agent, wetting agent, disintegrating agent, thickener, stabilizer, antifreezing agent, defoaming One or more of agent, filler.
4. the Herbicidal combinations as claimed in claim 2 containing diflufenican, pendimethalin and Oxyfluorfen, feature Be: the dosage form of Herbicidal combinations preparation is missible oil, wettable powder, water dispersible granules, suspending agent, aqueous emulsion.
CN201910218081.5A 2019-03-21 2019-03-21 A kind of Herbicidal combinations containing diflufenican, pendimethalin and Oxyfluorfen Pending CN109819987A (en)

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CN102599163A (en) * 2011-12-20 2012-07-25 青岛瀚生生物科技股份有限公司 Compound herbicide
CN103918649A (en) * 2013-10-15 2014-07-16 孙雪梅 Herbicide prepared by binary complex formulation of pendimetalin and oxyfluorfen
CN104798785A (en) * 2015-04-09 2015-07-29 山东华阳农药化工集团有限公司 Herbicide formed by mixing pendimethalin with pyrithiobac-sodium and oxyfluorfen

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