CN109796541A - A kind of meat products specific complex alginates cleanly production technique - Google Patents
A kind of meat products specific complex alginates cleanly production technique Download PDFInfo
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- CN109796541A CN109796541A CN201811609148.XA CN201811609148A CN109796541A CN 109796541 A CN109796541 A CN 109796541A CN 201811609148 A CN201811609148 A CN 201811609148A CN 109796541 A CN109796541 A CN 109796541A
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- meat products
- alginates
- calcium alginate
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Abstract
The present invention provides a kind of meat products specific complex alginates cleanly production techniques, including the immersion of dry brown alga, compound biological enzyme enzymatic hydrolysis, calcification, squeezing, reverse washing, squeezing, ion exchange, granulation, drying and other steps.The production technology uses ion exchange technique, carries out solid-state ion exchange with composite phosphate and calcium alginate fibre, is eventually converted into compound alginate.Meanwhile using whole fibrosis production method, eliminates the huge digestion of water consumption in traditional handicraft and rush dilute step, water resource is greatly saved, reduces production cost.Using reverse washing process, industrial water has been saved again.
Description
Technical field
The invention belongs to marine chemical industry product preparation technical fields, and in particular to a kind of meat products specific complex alginates are clear
Clean production technology.
Background technique
Since commercially producing since the nineteen twenty-nine sodium alginate, countries in the world production sodium alginate is substantially all made of pure
Alkali digestion technique makes the alginate in seaweed be converted into sol form sodium alginate and is dissolved in the water, then uses calcium with lye
Salt purifies seaweed acid group, is acidified again later as alginic acid, finally in alcohol in caustic soda and obtaining the alginic acid of high-purity
Sodium.This traditional handicraft process is many and diverse, and soda ash digestion process will consume a large amount of alkali, it is subsequent closely follow rush dilute technique can expend and
A large amount of water.100-150 times that dilute process water consumption is about dry brown alga is rushed, the water consumption for producing 1 ton of sodium alginate finished product is caused
Amount is about 700 tons, and water consumption is huge.Process modification how to be carried out to achieve the purpose that water conservation, becomes the industry urgently
It solves the problems, such as.
Sodium alginate mainly plays thickening, emulsification and gelatification as natural edible colloid, in food every profession and trade extensively
It uses.Sodium alginate is applied mainly utilizes its thickening property and gel water-retaining property in meat products.In recent years, it is with Russia markets
Leading, the trend of globalization is presented in application of the sodium alginate in meat products direction.Since sodium alginate is calcium ion responsive type colloid,
It can not independent gel, it is necessary to suitable calcium salt and phosphate is added, is made into composite buffering gel rubber system, can just form uniform gel,
Therefore compounding alginate formulations come into being.It is normal to compound alginates (based on sodium alginate, adding suitable calcium salt and phosphate)
By as meat products tumbling agent, injection and fat subsitutes product etc., it is widely used in high and low temperature meat products.
But common compound alginate formulations product is realized by simple mixing procedure, sodium alginate in the method,
Phosphate cannot be merged with calcium salt well, and the too fast problem of gel local reaction easily occurs after dissolution, leads to product structure not
Uniform, texture and water retention property are deteriorated.
Summary of the invention
The present invention is directed to state of the art, provides a kind of meat products specific complex alginates cleanly production technique,
Including the step such as the immersion of dry brown alga, compound biological enzyme enzymatic hydrolysis, calcification, squeezing, reverse washing, squeezing, ion exchange, granulation, drying
Suddenly.The production technology uses ion exchange technique, carries out solid-state ion exchange with composite phosphate and calcium alginate fibre,
It is eventually converted into compound alginate.Meanwhile using whole fibrosis production method, it is huge to eliminate water consumption in traditional handicraft
Digestion rush dilute step, water resource is greatly saved, reduces production cost.Using reverse washing process, life has been saved again
Fisheries water.
The present invention is the high-valued development and utilization to alginic acid technology of threonates, simplifies production process, from technique
On realize the production of the alginates with specific application area.
For achieving the above object, the present invention, which adopts the following technical solutions, is achieved:
A kind of meat products specific complex alginates cleanly production technique, comprising the following steps:
(1) dry brown alga is impregnated: brown alga being put into abundant rehydration in enzymatic vessel, amount of water is about 8-10 times, when rehydration
Between: 2-8h；
(2) complex enzyme zymohydrolysis: enzymatic vessel temperature is adjusted to 40-55 DEG C, pH 4.5-5.5, and complex enzyme (cellulose is added
Enzyme: pectase=1:1.2-1.5), additional amount is dry brown alga weight 1-3%, enzyme digestion reaction 3-5h, it is therefore an objective to by fruit in brown alga
Glue, cellulose etc. decompose completely；
(3) calcification: calcium chloride being added into enzymatic vessel, until calcium chloride concentration is 5% or so, fills seaweed acid group therein
Divide calcification, is converted into fibrous calcium alginate；
(4) reverse washing: with being in 30 ° of angles with ground, length is that calcium alginate fibre is risen to a high position by 8 meters of conveyer belt,
Multiple water jets are accessed at the rear (at 4-4.5 rice) of conveyer belt, spraying-rinsing processing repeatedly is carried out to calcium alginate on a small quantity.With
Water washes the impurity such as the pectin digested and fiber, and filtered cleaning solution can be used as impregnating the soak of dry brown alga, residue
For making alga fertilizer；
(5) it squeezes: calcium alginate fibre being subjected to press dewatering with twin rollers；
(6) ion exchange: dewatered calcium alginate fibre is put into neutralizing tank, with composite phosphate (sodium pyrophosphate:
Sodium tripolyphosphate: sodium polyphosphate=1:2-4:1-3) solid-state ion exchange is carried out, sentenced with universal indicator chromogenic reaction
Disconnected reaction end, wherein calcium alginate: phosphate (in terms of phosphate radical)=2.5-4.5:1；
(7) it is granulated: being granulated with pelletizer；
(8) it crushes, obtain meat products specific complex alginate after drying.
In the step (2), complex enzyme is protease, cellulase and pectase, wherein protease: cellulase: fruit
Glue enzyme=1:1:1.2-1.5；
In the step (4), reverse washing transports calcium alginate fibre using conveyer belt, and conveyer belt parameter is that length is 7-
8 meters, it is in 30 ° of angles with ground, can facilitates and calcium alginate fibre is risen into a high position, is accessed at the rear (at 3.5-4 rice) of conveyer belt
Multiple water jets repeatedly carry out spraying-rinsing processing to calcium alginate on a small quantity.This mode is conducive to improve flush efficiency and water-saving.
In the step (6), phosphatic type is sodium pyrophosphate, sodium tripolyphosphate and sodium polyphosphate.
In the step (6), mass ratio=2.5-4.5:1 of calcium alginate and phosphate (in terms of phosphate radical).
In the step (8), compound alginate because its with dissolubility and it is sequestering can also be used in dairy products, daily use chemicals,
In beverage, makees thickener, stabilizer, emulsifier and coagulator and use.
The present invention improves in terms of having following six compared with current sodium alginate production technology:
1) complex enzyme zymohydrolysis brown alga removes the other structures ingredient other than algal polysaccharide by complex enzyme hydrolysis mode, improves
Reaction efficiency, saves the reaction time, has saved water consumption；
2) direct calcification after digesting, and process (sol form process) is digested without tradition, realize full technical process
Fibrosis production, simplifies production process, reduces the dosage of chemicals, protect polysaccharide structures from the root, ensure that
The high viscosity of sodium alginate；
3) reverse washing process is used, a small amount of repeatedly washing is significantly more efficient to remove the impurity taken off in calcification process, protects
Product purity is demonstrate,proved；
4) dilute technical process is rushed without tradition, substantially reduces water consumption, and water scouring water is Ke Xunhuanliyong after calcification, it is real
The production of high-efficiency cleaning metaplasia is showed；
5) method for using ion exchange, allows alkaline phosphate and calcium alginate that solid phase neutralization reaction directly occurs, saves
Traditional decalcification technique, simplifies the technological process of production；
6) compound alginates prepared by the present invention are embedded with sodium, calcium ion using algal polysaccharides segment as main chain simultaneously on segment,
And there are electrostatic interactions with phosphate radical.Will not occur topical gel reaction, excellent aqueous solubility, and in conjunction with meat albumen after
Uniform gel is formed, meat products texture can be significantly improved, reduces cooking loss, improves meat products water-retaining property.
Detailed description of the invention
Fig. 1 is process flow chart of the invention.
Specific embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1
(1) dry brown alga is impregnated: brown alga being put into abundant rehydration in enzymatic vessel, amount of water is about 8-10 times, when rehydration
Between: 2-8h；
(2) complex enzyme zymohydrolysis: enzymatic vessel temperature is adjusted to 40-55 DEG C, pH 4.5-5.5, and complex enzyme (cellulose is added
Enzyme: pectase=1:1.2-1.5), additional amount is dry brown alga weight 1-3%, enzyme digestion reaction 3-5h, it is therefore an objective to by fruit in brown alga
Glue, cellulose etc. decompose completely；
(3) calcification: calcium chloride being added into enzymatic vessel, until calcium chloride concentration is 5% or so, fills seaweed acid group therein
Divide calcification, is converted into fibrous calcium alginate；
(4) reverse washing: with being in 30 ° of angles with ground, length is that calcium alginate fibre is risen to a high position by 8 meters of conveyer belt,
Multiple water jets are accessed at the rear (at 4-4.5 rice) of conveyer belt, spraying-rinsing processing repeatedly is carried out to calcium alginate on a small quantity.With
Water washes the impurity such as the pectin digested and fiber, and filtered cleaning solution can be used as impregnating the soak of dry brown alga, residue
For making alga fertilizer；
(5) it squeezes: calcium alginate fibre being subjected to press dewatering with twin rollers；
(6) ion exchange: dewatered calcium alginate fibre is put into neutralizing tank, with composite phosphate (sodium pyrophosphate:
Sodium tripolyphosphate: sodium polyphosphate=1:4:1) solid-state ion exchange is carried out, it is anti-with the judgement of universal indicator chromogenic reaction
Answer terminal, wherein calcium alginate: phosphate (in terms of phosphate radical)=2.5:1；
(7) it is granulated: being granulated with pelletizer；
(8) it crushes, obtain meat products specific complex alginate after drying.
After compound alginates are dissolved in water, transparence is presented in solution, and 1% solution viscosity is 30mpa.s.Meat products injection volume is
When 0.3%, the digester yield and water-retaining property of meat products can be significantly improved, the yield of sausage product is increased to 123% by 103%.
Embodiment 2
(1) dry brown alga is impregnated: brown alga being put into abundant rehydration in enzymatic vessel, amount of water is about 8-10 times, when rehydration
Between: 2-8h；
(2) complex enzyme zymohydrolysis: enzymatic vessel temperature is adjusted to 40-55 DEG C, pH 4.5-5.5, and complex enzyme (cellulose is added
Enzyme: pectase=1:1.2-1.5), additional amount is dry brown alga weight 1-3%, enzyme digestion reaction 3-5h, it is therefore an objective to by fruit in brown alga
Glue, cellulose etc. decompose completely；
(3) calcification: calcium chloride being added into enzymatic vessel, until calcium chloride concentration is 5% or so, fills seaweed acid group therein
Divide calcification, is converted into fibrous calcium alginate；
(4) reverse washing: with being in 30 ° of angles with ground, length is that calcium alginate fibre is risen to a high position by 8 meters of conveyer belt,
Multiple water jets are accessed at the rear (at 4-4.5 rice) of conveyer belt, spraying-rinsing processing repeatedly is carried out to calcium alginate on a small quantity.With
Water washes the impurity such as the pectin digested and fiber, and filtered cleaning solution can be used as impregnating the soak of dry brown alga, residue
For making alga fertilizer；
(5) it squeezes: calcium alginate fibre being subjected to press dewatering with twin rollers；
(6) ion exchange: dewatered calcium alginate fibre is put into neutralizing tank, with composite phosphate (sodium pyrophosphate:
Sodium tripolyphosphate: sodium polyphosphate=1:3:2) solid-state ion exchange is carried out, it is anti-with the judgement of universal indicator chromogenic reaction
Answer terminal, wherein calcium alginate: phosphate (in terms of phosphate radical)=3:1；
(7) it is granulated: being granulated with pelletizer；
(8) it crushes, obtain meat products specific complex alginate after drying.
After compound alginates are dissolved in water, transparence is presented in solution, and 1% solution viscosity is 80mpa.s.As meat products tumbling
Agent, can significantly improve the digester yield and water-retaining property of meat products, and the yield of sausage product is increased to 127% by 108%.
Embodiment 3
(1) dry brown alga is impregnated: brown alga being put into abundant rehydration in enzymatic vessel, amount of water is about 8-10 times, when rehydration
Between: 2-8h；
(2) complex enzyme zymohydrolysis: enzymatic vessel temperature is adjusted to 40-55 DEG C, pH 4.5-5.5, and complex enzyme (cellulose is added
Enzyme: pectase=1:1.2-1.5), additional amount is dry brown alga weight 1-3%, enzyme digestion reaction 3-5h, it is therefore an objective to by fruit in brown alga
Glue, cellulose etc. decompose completely；
(3) calcification: calcium chloride being added into enzymatic vessel, until calcium chloride concentration is 5% or so, fills seaweed acid group therein
Divide calcification, is converted into fibrous calcium alginate；
(4) reverse washing: with being in 30 ° of angles with ground, length is that calcium alginate fibre is risen to a high position by 8 meters of conveyer belt,
Multiple water jets are accessed at the rear (at 4-4.5 rice) of conveyer belt, spraying-rinsing processing repeatedly is carried out to calcium alginate on a small quantity.With
Water washes the impurity such as the pectin digested and fiber, and filtered cleaning solution can be used as impregnating the soak of dry brown alga, residue
For making alga fertilizer；
(5) it squeezes: calcium alginate fibre being subjected to press dewatering with twin rollers；
(6) ion exchange: dewatered calcium alginate fibre is put into neutralizing tank, with composite phosphate (sodium pyrophosphate:
Sodium tripolyphosphate: sodium polyphosphate=1:2:3) solid-state ion exchange is carried out, it is anti-with the judgement of universal indicator chromogenic reaction
Answer terminal, wherein calcium alginate: phosphate (in terms of phosphate radical)=4.5:1；
(7) it is granulated: being granulated with pelletizer；
(8) it crushes, obtain meat products specific complex alginate after drying.
After compound alginates are dissolved in water, transparence is presented in solution, and 1% solution viscosity is 30mpa.s.Meat products injection volume is
When 0.3%, it can significantly improve,
After compound alginates are dissolved in water, transparence is presented in solution, and 1% solution viscosity is 600mpa.s.It cuts and mixes in meat products
Shi Tianjia can significantly improve the digester yield and water-retaining property of meat products, improve products'texture, sausage product hardness is by 823.12g
It is increased to 1213.25g.
Claims (7)
1. a kind of meat products specific complex alginates cleanly production technique, comprising the following steps:
(1) dry brown alga is impregnated: brown alga being put into abundant rehydration in enzymatic vessel, amount of water is about 8-10 times, rehydration time: 2-
8h；
(2) complex enzyme zymohydrolysis: enzymatic vessel temperature is adjusted to 40-55 DEG C, pH 4.5-5.5, addition complex enzyme (cellulase:
Pectase=1:1.2-1.5), additional amount is dry brown alga weight 1-3%, enzyme digestion reaction 3-5h, it is therefore an objective to by pectin, fibre in brown alga
Element etc. is tieed up to decompose completely；
(3) calcification: calcium chloride being added into enzymatic vessel, until calcium chloride concentration is 5% or so, makes the abundant calcium of seaweed acid group therein
Change, is converted into fibrous calcium alginate；
(4) reverse washing: with being in 30 ° of angles with ground, length is that calcium alginate fibre is risen to a high position by 8 meters of conveyer belt, is being passed
It send the rear (at 4-4.5 meters) of band to access multiple water jets, spraying-rinsing processing repeatedly is carried out to calcium alginate on a small quantity.It is clear with water
The impurity such as the pectin digested and fiber are washed off, filtered cleaning solution can be used as impregnating the soak of dry brown alga, and residue is used for
Make alga fertilizer；
(5) it squeezes: calcium alginate fibre being subjected to press dewatering with twin rollers；
(6) ion exchange: dewatered calcium alginate fibre is put into neutralizing tank, with phosphate (sodium pyrophosphate: tripolyphosphate
Sodium: sodium polyphosphate=1:2-4:1-3) solid-state ion exchange is carried out, judge reaction eventually with universal indicator chromogenic reaction
Point, wherein calcium alginate: phosphate (in terms of phosphate radical)=2.5-4.5:1；
(7) it is granulated: being granulated with pelletizer；
(8) it crushes, obtain meat products specific complex alginate after drying.
2. a kind of meat products specific complex alginates cleanly production technique according to claim 1, it is characterised in that: institute
It states in step (2), complex enzyme is protease, cellulase and pectase, wherein protease: cellulase: pectase=1:1:
1.2-1.5。
3. a kind of meat products specific complex alginates cleanly production technique according to claim 1, it is characterised in that: institute
It states in step (4), reverse washing transports calcium alginate fibre using conveyer belt, and conveyer belt parameter is that length is 7-8 meters, with ground
In 30 ° of angles, it can facilitate and calcium alginate fibre is risen into a high position, access multiple water jets at the rear (at 3.5-4 rice) of conveyer belt,
Spraying-rinsing processing repeatedly is carried out to calcium alginate on a small quantity.
4. a kind of meat products specific complex alginates cleanly production technique according to claim 1, it is characterised in that: institute
It states in step (6), phosphatic type is sodium pyrophosphate, sodium tripolyphosphate and sodium polyphosphate.
5. a kind of meat products specific complex alginates cleanly production technique according to claim 1, it is characterised in that: institute
It states in step (6), mass ratio=2.5-4.5:1 of calcium alginate and phosphate (in terms of phosphate radical).
6. a kind of meat products specific complex alginates cleanly production technique according to claim 1, it is characterised in that: institute
It states in step (8), compound alginate with dissolubility and sequestering can also be used in dairy products, daily use chemicals, in beverage, make to increase because of it
Thick dose, stabilizer and emulsifier use.
7. a kind of meat products specific complex alginates cleanly production technique according to claim 1, it is characterised in that: whole
A production process product realizes whole fibrosis, and no glue state existence form belongs to realization and cleans water-saving production
New method.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111938138A (en) * | 2020-08-24 | 2020-11-17 | 青岛泓源食品科技有限公司 | Chitin-containing calcium alginate-based phosphate compound and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0345886A2 (en) * | 1988-06-10 | 1989-12-13 | Kelco International Limited | Alginate gels |
| CN102492053A (en) * | 2011-12-28 | 2012-06-13 | 青岛明月海洋科技有限公司 | Preparation method of high-viscosity alginate |
| CN103172761A (en) * | 2013-04-22 | 2013-06-26 | 青岛贝尔特生物科技有限公司 | Energy-saving and emission-reducing production method of high-quality sodium alginate |
| CN103351440A (en) * | 2013-07-31 | 2013-10-16 | 青岛海之林生物科技开发有限公司 | Production technology of pharmaceutical grade sodium alginate |
| CN104292361A (en) * | 2014-09-27 | 2015-01-21 | 山东黄河三角洲纺织科技研究院有限公司 | Method for recycling sodium alginate from reactive dye printing wastewater by virtue of calcium coagulation-chelating agent process |
| CN104341536A (en) * | 2013-08-08 | 2015-02-11 | 青岛博研达工业技术研究所(普通合伙) | Method for high-efficiency extraction of nutrient substances in seaweed |
| CN104804109A (en) * | 2014-01-25 | 2015-07-29 | 青岛海之林生物科技开发有限公司 | Preparation method and application of dissolving injectable calcium alginate base |
| CN105440154A (en) * | 2015-12-09 | 2016-03-30 | 江苏明月海洋科技有限公司 | Method for extracting alginate in brown algae |
| CN106496351A (en) * | 2016-11-27 | 2017-03-15 | 威海蓝印海洋生物科技有限公司 | A kind of method of nutrient substance in high efficiency extraction Sargassum |
-
2018
- 2018-12-27 CN CN201811609148.XA patent/CN109796541A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0345886A2 (en) * | 1988-06-10 | 1989-12-13 | Kelco International Limited | Alginate gels |
| CN102492053A (en) * | 2011-12-28 | 2012-06-13 | 青岛明月海洋科技有限公司 | Preparation method of high-viscosity alginate |
| CN103172761A (en) * | 2013-04-22 | 2013-06-26 | 青岛贝尔特生物科技有限公司 | Energy-saving and emission-reducing production method of high-quality sodium alginate |
| CN103351440A (en) * | 2013-07-31 | 2013-10-16 | 青岛海之林生物科技开发有限公司 | Production technology of pharmaceutical grade sodium alginate |
| CN104341536A (en) * | 2013-08-08 | 2015-02-11 | 青岛博研达工业技术研究所(普通合伙) | Method for high-efficiency extraction of nutrient substances in seaweed |
| CN104804109A (en) * | 2014-01-25 | 2015-07-29 | 青岛海之林生物科技开发有限公司 | Preparation method and application of dissolving injectable calcium alginate base |
| CN104292361A (en) * | 2014-09-27 | 2015-01-21 | 山东黄河三角洲纺织科技研究院有限公司 | Method for recycling sodium alginate from reactive dye printing wastewater by virtue of calcium coagulation-chelating agent process |
| CN105440154A (en) * | 2015-12-09 | 2016-03-30 | 江苏明月海洋科技有限公司 | Method for extracting alginate in brown algae |
| CN106496351A (en) * | 2016-11-27 | 2017-03-15 | 威海蓝印海洋生物科技有限公司 | A kind of method of nutrient substance in high efficiency extraction Sargassum |
Non-Patent Citations (9)
| Title |
|---|
| 上海纺织工学院编著: "《腈纶生产工艺及其原理》", 31 July 1976, 上海人民出版社 * |
| 李德茂等: ""褐藻胶的酶法提取研究"", 《中国酿造》 * |
| 杨琴等: ""海藻酸钠的复配及在低温肉制品中应用研究"", 《中国食品添加剂》 * |
| 王卫主编: "《现代肉制品加工实用技术手册》", 31 July 2002, 科学技术文献出版社 * |
| 王素娟主编: "《中国经济海藻超微结构研究》", 31 January 1991, 浙江科学技术出版社 * |
| 田洪芸等: ""复合酶法提取褐藻酸钠的工艺研究"", 《世界科技研究与发展》 * |
| 胡坤等: ""多糖与磷酸盐对草鱼鱼糜凝胶特性影响的研究"", 《肉类工业》 * |
| 詹益兴主编: "《绿色精细化工-天然产品制造法 第4集》", 28 February 2009, 科学技术文献出版社 * |
| 顾其胜主编: "《海藻酸盐基生物医用材料与临床医学》", 30 April 2015, 上海科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111938138A (en) * | 2020-08-24 | 2020-11-17 | 青岛泓源食品科技有限公司 | Chitin-containing calcium alginate-based phosphate compound and preparation method thereof |
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Application publication date: 20190524 |