CN109794180A - A kind of household hydrogen-rich water dispenser - Google Patents
A kind of household hydrogen-rich water dispenser Download PDFInfo
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- CN109794180A CN109794180A CN201811616320.4A CN201811616320A CN109794180A CN 109794180 A CN109794180 A CN 109794180A CN 201811616320 A CN201811616320 A CN 201811616320A CN 109794180 A CN109794180 A CN 109794180A
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- hydrogen
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Abstract
The present invention relates to a kind of household hydrogen-rich water dispensers, belong to an electro-technical field, including drinking water filling apparatus, water receiver, hydrogenation unit and hydrogen activation unit, installation having heaters and refrigerator in the water receiver；The present invention prepares hydrogen-rich water by hydrogen source of hydrogen storing unit, can flexible modulation add hydrogen amount to obtain required hydrogen content and inoxidizability, and it will not influence the water quality indicators such as the content of mineral substances in water, pH value, it is more convenient to use, safe and efficient, utilize hydrogen activation unit, the molecular hydrogen in water can be cracked into the stronger atomic hydrogen of activity on hydrogen catalysis cracking material surface, and form H (H with the associated water molecules of surrounding2O) n cluster obtains higher reproducibility and stability.
Description
Technical field
The present invention relates to family's electro-technical field, specifically a kind of household hydrogen-rich water dispenser.
Background technique
Medical research shows that " oxidative damage " is the most basic pathophysiological mechanism of human diseases.Hydrogen has strong also
Originality can generate harmless water, not only to diabetes, cardiovascular and cerebrovascular disease, brain in conjunction with the intracorporal pernicious active oxygen of people
Disease, tumour and various inflammation have obvious curative effects, can also play the role of preventing disease and anti-aging.Human body utilizes hydrogen
A kind of approach easily and effectively of gas is intake hydrogen-rich water, and the hydrogen of reproducibility is delivered to each organ of human body for carrier by water
And cell, play antioxidation.
The preparation method of hydrogen-rich water mainly has hydrogen-rich magnesium bar method, electrolysis method, physical mixed method at present, these three methods are deposited
Certain insufficient.Hydrogen-rich magnesium bar method needs to heat mostly, inconvenient for use, and the hydrogen-rich water hydrogen content produced is lower, in addition magnesium ion into
Entering not only influences mouthfeel in water, also will affect the health (such as calculus patient) of part population.Electrolysis method is that current application is most
Method, especially on household hydrogen-rich water machine.Electrolysis method produces hydrogen-rich water, in addition to cathode generate hydrogen-rich water other than, can also be in anode
Impotable acid water is generated, causes to waste, and cathode can increase during producing hydrogen with the pH of dampening, when pH is higher than
Mouthfeel can obviously be deteriorated when 7.8, and pH is higher than 8.5 and exceeds drinking water standard.Therefore, the hydrogen-rich water hydrogen content that electrolysis method is produced is not
It is preferably excessively high.Physical mixed method packaging hydrogen-rich water suitable for mass production, but it is not suitable for household hydrogen-rich water dispenser, and consider health peace
Quan Xing, physical mixed method can only produce hydrogen-rich water by raw water of pure water, excessively drink and will cause minerals missing.In addition to above-mentioned
Problem, existing hydrogen-rich water preparation method are exactly that hydrogen exists completely with molecular conformation in water there is also a common feature,
Solubility and reduction activation are lower, and stability is poor, are easy escape, are unfavorable for the promotion and holding of anti-oxidation efficacy.
Summary of the invention
The purpose of the present invention is to provide a kind of household hydrogen-rich water dispensers, to solve the problems mentioned in the above background technology.
To achieve the above object, the invention provides the following technical scheme:
A kind of household hydrogen-rich water dispenser, including drinking water filling apparatus, water receiver, hydrogenation unit and hydrogen activation unit；It is described to drink
Water filling apparatus is for drinking water to be added in water receiver；The water receiver is for storing drinking water and sending drinking water to rear
Procedure；The hydrogen storing unit and water receiver outlet connect, and contain for injecting hydrogen generation into the drinking water that water receiver is released
Hydrogen water；The hydrogen activation unit is used to be mixed in hydrogeneous water, catalytic activation is at hydrogen-rich water.
As further technical solution of the present invention: the hydrogen storing unit is the container with hydrogen storage funtion part, described
Hydrogen storage funtion part is hydrogeneous solid solution, hydrogen-absorbing material or hollow micro-nano container.
As further technical solution of the invention: the hydrogen activation unit includes gas-liquid mixed part and hydrogen activation function
Energy part, the gas-liquid mixed part are pipeline mixer, gas-liquid mixing pump, ejector, microfluid mixer or fixed bed
At least one of；Hydrogen mobilizing function part is made of the nanometer hydrogen activated material with hydrogen catalytic cracking ability.
As further technical solution of the invention: the nanometer hydrogen activated material be noble metal or its oxide, it is dilute
Soil or its oxide, nickel, cobalt, copper, molybdenum, tungsten or its oxide, at least one of metal-organic framework materials.
As further technical solution of the invention: the noble metal is preferably platinum, gold, palladium, ruthenium；The rare earth is preferred
For lanthanum, cerium, neodymium.
As further technical solution of the invention: the hydrogen-rich water water yield is 0.5-5 liters/min, and hydrogen content is
0.5-2.5 mg/litre.
As further technical solution of the invention: be equipped in the hydrogen storing unit for controlling hydrogen storage and releasing
The temperature-adjusting device and pressure-regulating device put.
As further technical solution of the invention: the hydrogen activation unit is to be filled with consolidating for nanometer hydrogen activated material
Fixed bed；The nanometer Hydrogen activation material volume is 20-400 milliliters；The fixed bed draw ratio is 2-10:1, gas-liquid volume ratio
For 1:10-100.
As further technical solution of the invention: installation having heaters and refrigerator inside the water receiver.
Compared with prior art, the beneficial effects of the present invention are:
1, the present invention uses hydrogen storing unit to produce hydrogen-rich water for hydrogen source, can get higher hydrogen content and stronger reproducibility, and
And water quality is not influenced, and acid anode water is not generated, it is safer, efficient；
2, hydrogen storing unit can be mass, and is easily changed and regenerates, easy to use, economical；
3, the molecular hydrogen in water can be cracked into active stronger, more stable atomic hydrogen, obtained hydrogen-rich water by hydrogen activation unit
Inoxidizability is stronger, and effective time is longer.
4, the household hydrogen-rich water machine in the present invention has heating, refrigeration and heat insulation function, adapts to a variety of different raw waters,
Such as pure water, mineral water, tap water, warm water, cold water, ice water etc., can satisfy more crowds personal preference and
Health demand.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of household hydrogen-rich water dispenser；
Fig. 2 is the structural schematic diagram of water receiver in household hydrogen-rich water dispenser；
Fig. 3 is the nuclear magnetic resoance spectrum comparison diagram of hydrogen-rich water prepared by embodiment 1 and raw water.
In figure: 1- drinking water filling apparatus, 2- water receiver, 3- hydrogenation unit, 4- hydrogen activation unit, 5- heater, 6- system
Cooler.
Specific embodiment
In the description of the present invention, it is to be understood that, term " center ", " longitudinal direction ", " transverse direction ", " length ", " width ",
" thickness ", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom" "inner", "outside", " up time
The orientation or positional relationship of the instructions such as needle ", " counterclockwise ", " axial direction ", " radial direction ", " circumferential direction " be orientation based on the figure or
Positional relationship is merely for convenience of description of the present invention and simplification of the description, rather than the device or element of indication or suggestion meaning must
There must be specific orientation, be constructed and operated in a specific orientation, therefore be not considered as limiting the invention.
In addition, term " first ", " second " are used for descriptive purposes only and cannot be understood as indicating or suggesting relative importance
Or implicitly indicate the quantity of indicated technical characteristic.Define " first " as a result, the feature of " second " can be expressed or
Implicitly include one or more of the features.In the description of the present invention, the meaning of " plurality " is two or more,
Unless otherwise specifically defined.
In the present invention unless specifically defined or limited otherwise, term " installation ", " connected ", " connection ", " fixation " etc.
Term shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or integral；It can be mechanical connect
It connects, is also possible to be electrically connected；It can be directly connected, can also can be in two elements indirectly connected through an intermediary
The interaction relationship of the connection in portion or two elements.It for the ordinary skill in the art, can be according to specific feelings
Condition understands the concrete meaning of above-mentioned term in the present invention.
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description.
Embodiment 1
Household hydrogen-rich water dispenser as shown in Figure 1, including drinking water filling apparatus 1, water receiver 2, hydrogenation unit 3 and hydrogen activation unit
4；The drinking water filling apparatus 1 is for drinking water to be added in water receiver 2；The water receiver 2 is for storing drinking water simultaneously
Drinking water is sent to later process；The hydrogen storing unit 3 is connected with the outlet of water receiver 2, the drinking water for releasing to water receiver 2
Middle injection hydrogen generates hydrogeneous water；The hydrogen activation unit 4 is used to be mixed in hydrogeneous water, catalytic activation is at hydrogen-rich water.
The hydrogen storing unit 3 is the container with hydrogen storage funtion part, and the hydrogen storage funtion part is hydrogeneous solid solution, hydrogen
Adsorbent material or hollow micro-nano container.
The hydrogen activation unit 4 includes gas-liquid mixed part and hydrogen mobilizing function part, and the gas-liquid mixed part is pipe
At least one of road formula mixer, gas-liquid mixing pump, ejector, microfluid mixer or fixed bed；The hydrogen mobilizing function
Part is made of the nanometer hydrogen activated material with hydrogen catalytic cracking ability, and the nanometer hydrogen with hydrogen catalytic cracking ability is living
Change material working principle are as follows: hydrogen adsorption activated material surface and with the active site bonding on activated material surface, generate
New activated hydrogen species are broken original H-H key, and activated hydrogen species dynamically dissociate hydrogen atom and and associated water molecules
Form H (H2O) n cluster, H (H2O) n cluster, which enters, forms hydrogen-rich water in water；The nanometer hydrogen activated material be noble metal or its
Oxide, rare earth or its oxide, nickel, cobalt, copper, molybdenum, tungsten or its oxide, at least one of metal-organic framework materials；
The noble metal is preferably platinum, gold, palladium, ruthenium；The rare earth is preferably lanthanum, cerium, neodymium.
The hydrogen-rich water water yield is 0.5-5 liters/min, and hydrogen content is 0.5-2.5 mg/litre.
Temperature and pressure regulating device is installed in the hydrogen storing unit 3, is adjusted by temperature and pressure and realizes hydrogen
Storage and controlled release；It can be supplemented when hydrogen consumption is to critical state, hydrogen storing unit is used for multiple times；The hydrogen storing unit 3
Single effectively for 0.5-5 grams of hydrogen amount, can meet the hydrogen demand of 300-3000L hydrogen-rich water.
The hydrogen activation unit 4 is to be filled with a nanometer fixed bed for hydrogen activated material, and hydrogen and water pass through preposition gas-liquid
Mixing portion enters fixed bed after mixing and is activated, and water outlet is hydrogen-rich water；Nanometer Hydrogen activation material volume is 20-400
Milliliter, fixed bed draw ratio are 2-10:1, gas-liquid volume ratio 1:10-100.
Pure water is added in water receiver 2 by drinking water filling apparatus 1 when use, then opens going out for water receiver 2
The gas outlet at the mouth of a river and hydrogen storing unit 3, in hydrogen injection pure water, will obtain hydrogeneous water, and hydrogeneous water is living by hydrogen activation unit 4
After change, as hydrogen-rich water.The hydrogen-rich water can be drunk immediately, can also be sealed.In the present embodiment, water temperature is 13 DEG C, hydrogen-rich
Water water yield is 2 liters/min, and Hydrogen activation material volume is 100 milliliters, and fixed bed draw ratio is 3:1, gas liquid ratio 1:10
(volume ratio), the hydrogen content for the hydrogen-rich water produced are 1.7ppm, and oxidation-reduction potential is -690mV.Using nuclear magnetic resonance-hydrogen
Spectrum detects raw water and hydrogen-rich water, it is found that the water peak of hydrogen-rich water is significantly broadened and ABSORPTION EDGE (Fig. 3) occur, this is because hydrogen
Molecular dissociation is with hydrone dynamic bind to form H (H after hydrogen atom2O) n cluster makes environment locating for water clusters and hydrogen
Qi occurs to become, causes resonance frequency range broadening.
Embodiment 2
As shown in Fig. 2, the present embodiment advanced optimizes on the basis of embodiment 1, having heaters is installed inside the water receiver 2
5 and refrigerator 6, facilitate user to heat, freeze or protect to drinking water as needed by setting heater 5 and refrigerator 6
Temperature.
Tap water is added in water receiver 2 using by drinking water filling apparatus 1, and with heater 5 in water receiver 2
Water is heated its is boiled, and then boiled water imported into another water receiver 2 is cooling and heat preservation, obtain warm water.Open temperature
Hydrogen injection warm water is obtained hydrogeneous water by the water outlet of boiled water water receiver 2 and the gas outlet of hydrogen storing unit 3, and hydrogeneous water passes through
After hydrogen activation unit 4 activates, as hydrogen-rich water.The hydrogen-rich water can be drunk immediately, can also be sealed.In the present embodiment, water
Temperature is 30 DEG C, and hydrogen-rich water water yield is 1 liter/min, and Hydrogen activation material volume is 200 milliliters, and fixed bed draw ratio is 5:1,
Gas liquid ratio is 1:12(volume ratio), the hydrogen-rich water hydrogen content produced is 1.3ppm, and oxidation-reduction potential is -550mV.
In order to investigate the storage stability of prepared hydrogen-rich water, by the hydrogen-rich water and physical mixed preparation in the present embodiment
Hydrogen-rich water is attached separately in PET plastic bottle, and is stored under 25 DEG C of non-illuminated conditions, separately sampled test oxidation after 3 days and 7 days
Reduction potential.The result shows that oxidation-reduction potential from -650mV rises to 103mV after hydrogen-rich water 3 days of physical mixed preparation, 7 days
After rise to 250mV, oxidation-reduction potential rises to -245mV from -690mV behind hydrogen-rich water 3 days in the present embodiment, risen to after 7 days -
70mV.It can be seen that the hydrogen-rich water that the method in the present invention is produced, has higher storage stability.
Working principle is as follows: drinking water is added in water receiver 2, then according to need by starting drinking water filling apparatus 1 first
The water in water receiver 2 is heated, freezed or kept the temperature with heater 5 or refrigerator 6, finally opens the water outlet of water receiver 2
The gas outlet of mouth and hydrogen storing unit 3 exports hydrogeneous water, and hydrogeneous water is after hydrogen activation unit 4 carries out mixing and catalytic activation, system
Obtain hydrogen-rich water.By adjusting the running parameter of hydrogen-rich water, the hydrogen-rich with different reproducibilities, hydrogen content and water temperature can be obtained
Water, relevant parameter and range are shown in Table 1.
The running parameter and hydrogen-rich water parameter of 1 household hydrogen-rich water dispenser of table
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, and do not carrying on the back
In the case where from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter from
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that the institute that will be fallen within the meaning and scope of the equivalent elements of the claims
It changes and is included within the present invention.Any reference signs in the claims should not be construed as limiting the involved claims.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (9)
1. a kind of household hydrogen-rich water dispenser, it is characterised in that: including drinking water filling apparatus (1), water receiver (2), hydrogenation unit (3)
With hydrogen activation unit (4)；
The drinking water filling apparatus (1) is for drinking water to be added in water receiver (2)；
The water receiver (2) is for storing drinking water and sending drinking water to later process；
The hydrogen storing unit (3) and water receiver (2) outlet connect, and inject hydrogen in the drinking water for releasing to water receiver (2)
Generate hydrogeneous water；
The hydrogen activation unit (4) is used to be mixed in hydrogeneous water, catalytic activation is at hydrogen-rich water.
2. household hydrogen-rich water dispenser according to claim 1, it is characterised in that: the hydrogen storing unit (3) is with hydrogen storage function
The container of energy part, the hydrogen storage funtion part are hydrogeneous solid solution, hydrogen-absorbing material or hollow micro-nano container.
3. household hydrogen-rich water dispenser according to claim 1, it is characterised in that: the hydrogen activation unit (4) includes that gas-liquid is mixed
Part and hydrogen mobilizing function part are closed, the gas-liquid mixed part is pipeline mixer, gas-liquid mixing pump, ejector, miniflow
At least one of body mixer or fixed bed；Hydrogen mobilizing function part is by the nanometer hydrogen with hydrogen catalytic cracking ability
Activated material composition.
4. household hydrogen-rich water dispenser according to claim 3, it is characterised in that: the nanometer hydrogen activated material be noble metal or
Its oxide, rare earth or its oxide, nickel, cobalt, copper, molybdenum, tungsten or its oxide, at least one in metal-organic framework materials
Kind.
5. household hydrogen-rich water dispenser according to claim 4, it is characterised in that: the noble metal include but is not limited to platinum, gold,
Palladium, ruthenium；The rare earth includes but is not limited to lanthanum, cerium, neodymium.
6. household hydrogen-rich water dispenser according to claim 1, it is characterised in that: the hydrogen-rich water water yield is 0.5-5 liters/min
Clock, hydrogen content are 0.5-2.5 mg/litre.
7. household hydrogen-rich water dispenser according to claim 1 or 2, it is characterised in that: installation is useful in the hydrogen storing unit (3)
In the temperature-adjusting device and pressure-regulating device of control hydrogen storage and release.
8. household hydrogen-rich water dispenser according to claim 1 or 3, it is characterised in that: the hydrogen activation unit (4) is to be filled with
The fixed bed of nanometer hydrogen activated material；The nanometer Hydrogen activation material volume is 20-400 milliliters；The fixed bed draw ratio
For 2-10:1, gas-liquid volume ratio 1:10-100.
9. household hydrogen-rich water dispenser according to claim 1, it is characterised in that: be equipped with heating inside the water receiver (2)
Device (5) and refrigerator (6).
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811616320.4A CN109794180A (en) | 2018-12-28 | 2018-12-28 | A kind of household hydrogen-rich water dispenser |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811616320.4A CN109794180A (en) | 2018-12-28 | 2018-12-28 | A kind of household hydrogen-rich water dispenser |
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| CN109794180A true CN109794180A (en) | 2019-05-24 |
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| CN201811616320.4A Pending CN109794180A (en) | 2018-12-28 | 2018-12-28 | A kind of household hydrogen-rich water dispenser |
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| CN102317214A (en) * | 2009-02-10 | 2012-01-11 | 株式会社志贺机能水研究所 | Method for producing active hydrogen-dissolved water and apparatus for producing active hydrogen-dissolved water |
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Application publication date: 20190524 |