CN109777291B - Self-cleaning glass hydrophobing agent - Google Patents
Self-cleaning glass hydrophobing agent Download PDFInfo
- Publication number
- CN109777291B CN109777291B CN201910028067.9A CN201910028067A CN109777291B CN 109777291 B CN109777291 B CN 109777291B CN 201910028067 A CN201910028067 A CN 201910028067A CN 109777291 B CN109777291 B CN 109777291B
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- self
- glass
- cleaning glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000005348 self-cleaning glass Substances 0.000 title claims abstract description 23
- 239000004890 Hydrophobing Agent Substances 0.000 title abstract description 5
- 239000011521 glass Substances 0.000 claims abstract description 32
- 239000004094 surface-active agent Substances 0.000 claims abstract description 28
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 27
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 24
- 239000003054 catalyst Substances 0.000 claims abstract description 24
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 21
- 239000002904 solvent Substances 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 18
- NOKUWSXLHXMAOM-UHFFFAOYSA-N hydroxy(phenyl)silicon Chemical compound O[Si]C1=CC=CC=C1 NOKUWSXLHXMAOM-UHFFFAOYSA-N 0.000 claims abstract description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 14
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 8
- 239000002105 nanoparticle Substances 0.000 claims description 15
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical group [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- IRVZFACCNZRHSJ-UHFFFAOYSA-N 2,4,6,8-tetramethyl-2,4,6,8-tetraphenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si]1(C)C1=CC=CC=C1 IRVZFACCNZRHSJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- VSIKJPJINIDELZ-UHFFFAOYSA-N 2,2,4,4,6,6,8,8-octakis-phenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si]1(C=1C=CC=CC=1)C1=CC=CC=C1 VSIKJPJINIDELZ-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- BPCXHCSZMTWUBW-UHFFFAOYSA-N triethoxy(1,1,2,2,3,3,4,4,5,5,8,8,8-tridecafluorooctyl)silane Chemical compound CCO[Si](OCC)(OCC)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCC(F)(F)F BPCXHCSZMTWUBW-UHFFFAOYSA-N 0.000 claims description 5
- ARVALZZVFLDZSO-UHFFFAOYSA-N triethyl(1,2,2-trifluoroethenyl)silane Chemical compound CC[Si](CC)(CC)C(F)=C(F)F ARVALZZVFLDZSO-UHFFFAOYSA-N 0.000 claims description 5
- BHUMEAJPWLHWPF-UHFFFAOYSA-N 1,1,2,2,3,3,4,4,5,5,6,6,7,7,10,10,10-heptadecafluorodecyl(tripropoxy)silane Chemical compound FC(C(C(C(C(C(C(F)(F)[Si](OCCC)(OCCC)OCCC)(F)F)(F)F)(F)F)(F)F)(F)F)(CCC(F)(F)F)F BHUMEAJPWLHWPF-UHFFFAOYSA-N 0.000 claims description 4
- TYROLSMHVJMZOC-UHFFFAOYSA-N 1,1,2,2,3,3,4,4,5,5,6,6,7,7,10,10,10-heptadecafluorodecyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCC(F)(F)F TYROLSMHVJMZOC-UHFFFAOYSA-N 0.000 claims description 4
- 239000005543 nano-size silicon particle Substances 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 125000003944 tolyl group Chemical group 0.000 claims description 4
- PMQIWLWDLURJOE-UHFFFAOYSA-N triethoxy(1,1,2,2,3,3,4,4,5,5,6,6,7,7,10,10,10-heptadecafluorodecyl)silane Chemical compound CCO[Si](OCC)(OCC)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCC(F)(F)F PMQIWLWDLURJOE-UHFFFAOYSA-N 0.000 claims description 4
- FOAFYQVMBKJRSC-UHFFFAOYSA-N triethoxy-(1,1,2,2,3,3,4,5,5,6,10,10,10-tridecafluoro-4-methyldecyl)silane Chemical compound CC(C(C(C(F)(F)[Si](OCC)(OCC)OCC)(F)F)(F)F)(C(C(CCCC(F)(F)F)F)(F)F)F FOAFYQVMBKJRSC-UHFFFAOYSA-N 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 16
- 238000005096 rolling process Methods 0.000 abstract description 2
- 238000004381 surface treatment Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 description 15
- 229940051841 polyoxyethylene ether Drugs 0.000 description 13
- 229920000056 polyoxyethylene ether Polymers 0.000 description 13
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical group [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- 238000012360 testing method Methods 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 6
- 229910052731 fluorine Inorganic materials 0.000 description 6
- 239000011737 fluorine Substances 0.000 description 6
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 5
- -1 dimethyldiphenylsiloxane Chemical class 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 5
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- IZRJPHXTEXTLHY-UHFFFAOYSA-N triethoxy(2-triethoxysilylethyl)silane Chemical group CCO[Si](OCC)(OCC)CC[Si](OCC)(OCC)OCC IZRJPHXTEXTLHY-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 206010039203 Road traffic accident Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 230000005660 hydrophilic surface Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- JGTNAGYHADQMCM-UHFFFAOYSA-N perfluorobutanesulfonic acid Chemical compound OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F JGTNAGYHADQMCM-UHFFFAOYSA-N 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
The invention belongs to the technical field of glass surface treatment, and particularly relates to a self-cleaning glass hydrophobing agent. The self-cleaning glass hydrophobic agent comprises a component A and a component B, wherein the component A is prepared from the following raw materials in parts by weight: 100 parts of dimethyl cyclosiloxane, 20-50 parts of phenyl siloxane, 5-10 parts of silane coupling agent, 0.1-10 parts of alkaline catalyst, 5-40 parts of surfactant and 10-90 parts of solvent; the component B is prepared from the following raw materials: 80 parts of organic fluoride, 4-15 parts of a silane coupling agent, 10-30 parts of dimethyl cyclosiloxane, 10-20 parts of phenyl siloxane, 0.1-10 parts of an alkaline catalyst, 5-40 parts of a surfactant, 10-90 parts of a solvent and 1-20 parts of nano titanium oxide. After the water drop type automobile glass is used on automobile glass, water drops can form water drops on the surface of the glass, the contact angle of the water drops can reach 125 degrees, automatic rolling can be achieved without leaving traces, and therefore the problem that the sight line is unclear is solved.
Description
Technical Field
The invention belongs to the technical field of glass surface treatment, and particularly relates to a self-cleaning glass hydrophobing agent.
Background
The surface of common glass is a hydrophilic surface, when water drops spread on the glass, the light transmittance of the glass is deteriorated, and the blurs of a windshield, a side windshield and front and rear view mirrors of an automobile are important causes of traffic accidents. In the case of rain or high humidity, the surface of the automobile glass forms attached liquid drops to influence the sight.
Disclosure of Invention
The invention aims to solve the problems and provides a self-cleaning glass hydrophobic agent, water drops can form water drops on the surface of glass, the contact angle of the water drops can reach up to 125 degrees, automatic rolling can be realized without leaving traces, and the problem of unclear sight is solved.
The invention is realized by adopting the following technical scheme:
a self-cleaning glass hydrophobic agent comprises a component A and a component B, and the components are calculated according to parts by weight,
the component A is prepared from the following raw materials: 100 parts of dimethyl cyclosiloxane, 20-50 parts of phenyl siloxane, 5-10 parts of silane coupling agent, 0.1-10 parts of basic catalyst, 5-40 parts of surfactant, 10-90 parts of solvent and 4-20 parts of nano particles;
the component B is prepared from the following raw materials: 80 parts of organic fluoride, 4-15 parts of a silane coupling agent, 10-30 parts of dimethyl cyclosiloxane, 10-20 parts of phenyl siloxane, 0.1-10 parts of an alkaline catalyst, 5-40 parts of a surfactant, 10-90 parts of a solvent and 1-20 parts of nano titanium oxide.
Among the ternary copolymerized siloxane generated by the reaction, the dimethylcyclosiloxane endows the product with better hydrophobicity and weather resistance; the silane coupling agent enables the product and the glass surface to form a bridging effect and be tightly connected, so that the product has the effects of long-term effectiveness, wear resistance and washing resistance; the product has the advantages that the refractive index is improved by the phenyl siloxane, the comprehensive refractive index of the product is about 1.46 and is close to the refractive index of common glass of 1.50, no trace is left on the surface of the glass after the product is used, and the transparency and the attractiveness of the glass are maintained.
Preferably, the dimethyl cyclosiloxane comprises one or more of octamethylcyclotetrasiloxane and dimethyl cyclosiloxane.
In a preferred embodiment, the phenyl-containing siloxane includes one or more of octaphenylcyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane, short-chain dimethyldiphenylsiloxane, and short-chain methylphenylsiloxane.
In a preferred embodiment, the silane coupling agent is N-beta- (aminoethyl) -gamma-aminopropyltrimethoxysilane.
In a preferred embodiment, the basic catalyst is tetramethylammonium hydroxide.
In a preferred scheme, the solvent is one or more of acetonitrile, acetone, methanol, ethanol and isopropanol.
In a preferred embodiment, the organofluoro compound is one or more of tridecafluorooctyltriethoxysilane, 4-methyl-tridecafluorodecyltriethoxysilane, heptadecafluorodecyltriethoxysilane, heptadecafluorodecyltriisopropoxysilane, heptadecafluorodecyltripropoxysilane, triethyl- (trifluorovinyl) silane, nonafluorohexyldimethylchlorosilane.
In a preferable scheme, the particle size of the nano titanium oxide is 20-50 nm.
In a preferred scheme, the nano particles are one or more of nano silicon dioxide and nano zinc oxide.
The invention has the beneficial effects that:
1. the self-cleaning glass hydrophobic agent provided by the invention can form a transparent hydrophobic film on the surface of automobile glass, water drops can form water drops on the surface of the glass, the contact angle can reach up to 125 degrees, automatic rolling-off can be realized without leaving traces, and the problem of unclear sight is solved.
2. The self-cleaning glass hydrophobic agent disclosed by the invention has better hydrophobicity and weather resistance, is effective for a long time after being used, has the advantages of wear resistance, washing resistance and the like, and keeps the attractiveness of glass without influencing the transmittance of the glass.
3. After the component A is sprayed on the surface of the glass, the nano particles can fill up microscopic pores on the surface of the glass, and because the nano particles have high specific surface area and act on the surface of the glass together with the terpolymer, the terpolymer forms a strong bonding effect with the nano particles and the surface of the glass, so that the surface of the glass has a layer of long-term effective, wear-resistant and washing-resistant reference film.
4. The component B forms a transparent hydrophobic film after being used, the nano titanium oxide in the hydrophobic film has a photocatalytic effect, and can decompose organic pollutants attached to the hydrophobic film under the irradiation of sunlight, so that the cleaning performance is obtained, the attachment amount of the organic pollutants is small, and C-F bonds in organic fluorides have high stability and slow decomposition speed, so that the hydrophobic film can keep the hydrophobic effect for a long time, and when the rainy day comes, rainwater can quickly take away inorganic matters on the surface of the hydrophobic film, so that the glass is bright as new.
5. The component B can be used after being diluted by 30-50 times by water as a cleaning agent, because the copolymer exists in the component B, when the component B is cleaned, the water can take away the dust on the surface of the hydrophobic membrane, and when the solvent damages the surface of the hydrophobic membrane, the copolymer, titanium oxide and other substances in the component B can be attached to the surface of the original hydrophobic membrane, and a new hydrophobic layer can be formed on the surface of the hydrophobic membrane after the solvent is volatilized, so that the service life of the hydrophobic membrane is prolonged, and the self-cleaning effect is improved.
Detailed Description
The technical solutions in the examples will be clearly and completely described below. It is to be understood that the described embodiments are merely a few embodiments of the invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments of the present invention without any inventive step, are within the scope of the present invention.
Example 1
A self-cleaning glass hydrophobic agent comprises a component A and a component B;
the substances and the contents of the raw materials in the component A are shown in the table 1, and the unit of the content of each component is g;
the dimethyl cyclosiloxane is octamethylcyclotetrasiloxane;
the phenyl-containing siloxane comprises octaphenylcyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane, short-chain dimethyl diphenyl siloxane and short-chain methyl phenyl siloxane in a weight ratio of 1: 2: 1: 3;
the silane coupling agent is N-beta- (aminoethyl) -gamma-aminopropyltrimethoxysilane;
tetramethyl ammonium hydroxide as basic catalyst;
the surfactant comprises nonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether and isomeric tridecanol polyoxyethylene ether, and the weight ratio is 2: 1: 3;
the solvent is ethanol;
the nano particles are nano silicon dioxide;
the substances and the contents of the raw materials in the component B are shown in Table 2, and the unit of the content of each component is g; the organic fluoride is tridecafluorooctyltriethoxysilane; the types of the silane coupling agent, the dimethyl cyclosiloxane, the phenyl siloxane, the alkaline catalyst and the solvent are consistent with the component A, and the particle size of the nano titanium oxide is 20-50 nm;
the surfactant is F4432 nonionic fluorine-containing compound surfactant.
Example 2
A self-cleaning glass hydrophobic agent comprises a component A and a component B;
the substances and the contents of the raw materials in the component A are shown in the table 1, and the unit of the content of each component is g;
the dimethyl cyclosiloxane comprises octamethylcyclotetrasiloxane and dimethyl cyclosiloxane in a weight ratio of 1: 1;
the phenyl-containing siloxane comprises octaphenylcyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane, short-chain dimethyl diphenyl siloxane and short-chain methyl phenyl siloxane in a weight ratio of 2: 3: 1: 1;
the silane coupling agent is N-beta- (aminoethyl) -gamma-aminopropyltrimethoxysilane;
tetramethyl ammonium hydroxide as basic catalyst;
the surfactant is nonylphenol polyoxyethylene ether;
the solvent is methanol, ethanol and isopropanol, and the weight ratio is 1: 1: 1;
the nano particles are nano zinc oxide;
the substances and the contents of the raw materials in the component B are shown in Table 2, and the unit of the content of each component is g; the organic fluoride is triethyl- (trifluorovinyl) silane; the types of the silane coupling agent, the dimethyl cyclosiloxane, the phenyl siloxane, the alkaline catalyst and the solvent are consistent with the component A, and the particle size of the nano titanium oxide is 20-50 nm;
the surfactant is F4432 nonionic fluorine-containing compound surfactant.
Example 3
A self-cleaning glass hydrophobic agent comprises a component A and a component B;
the substances and the contents of the raw materials in the component A are shown in the table 1, and the unit of the content of each component is g;
the dimethyl cyclosiloxane comprises octamethylcyclotetrasiloxane and dimethyl cyclosiloxane in a weight ratio of 1: 4;
the phenyl-containing siloxane comprises octaphenylcyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane, short-chain dimethyl diphenyl siloxane and short-chain methyl phenyl siloxane, and the weight ratio of the octaphenylcyclotetrasiloxane to the tetramethyltetraphenylcyclotetrasiloxane is 4: 4: 1: 1;
the silane coupling agent is N-beta- (aminoethyl) -gamma-aminopropyltrimethoxysilane;
tetramethyl ammonium hydroxide as basic catalyst;
the surfactant comprises nonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether and isomeric tridecanol polyoxyethylene ether, and the weight ratio is 1: 1: 1;
the solvent comprises acetonitrile and acetone, and the weight ratio is 1: 1;
the nano particles are nano silicon dioxide and nano zinc oxide, and the weight ratio is 1: 1;
the substances and the contents of the raw materials in the component B are shown in Table 2, and the unit of the content of each component is g; the organic fluoride comprises tridecafluorooctyltriethoxysilane, 4-methyl-tridecafluorodecyltriethoxysilane, heptadecafluorodecyltriethoxysilane, heptadecafluorodecyltriisopropoxysilane, heptadecafluorodecyltripropoxysilane, triethyl- (trifluorovinyl) silane, nonafluorohexyldimethylchlorosilane in a weight ratio of 1: 2: 3: 1: 2: 3: 1; the types of the silane coupling agent, the dimethyl cyclosiloxane, the phenyl siloxane, the alkaline catalyst and the solvent are consistent with the component A, and the particle size of the nano titanium oxide is 20-50 nm;
the surfactant is F4432 nonionic fluorine-containing compound surfactant.
Example 4
A self-cleaning glass hydrophobic agent comprises a component A and a component B;
the substances and the contents of the raw materials in the component A are shown in the table 1, and the unit of the content of each component is g;
the dimethyl cyclosiloxane comprises octamethylcyclotetrasiloxane and dimethyl cyclosiloxane in a weight ratio of 3: 1;
the phenyl-containing siloxane is tetramethyl-tetraphenyl cyclotetrasiloxane;
the silane coupling agent is N-beta- (aminoethyl) -gamma-aminopropyltrimethoxysilane;
tetramethyl ammonium hydroxide as basic catalyst;
the surfactant is isomeric tridecanol polyoxyethylene ether;
the solvent is acetone;
the nanoparticles are nanosilica.
The substances and the contents of the raw materials in the component B are shown in Table 2, and the unit of the content of each component is g; the organic fluoride comprises tridecafluorooctyltriethoxysilane, 4-methyl-tridecafluorodecyltriethoxysilane, heptadecafluorodecyltriethoxysilane, heptadecafluorodecyltriisopropoxysilane, heptadecafluorodecyltripropoxysilane, triethyl- (trifluorovinyl) silane, nonafluorohexyldimethylchlorosilane in a weight ratio of 1: 2: 3: 1: 2: 3: 1; the silane coupling agent, dimethyl cyclosiloxane, phenyl siloxane, alkaline catalyst and agent are consistent with the component A, and the particle size of the nano titanium oxide is 20-50 nm;
the surfactant is F4432 nonionic fluorine-containing compound surfactant.
Example 5
A self-cleaning glass hydrophobic agent comprises a component A and a component B;
the substances and the contents of the raw materials in the component A are shown in the table 1, and the unit of the content of each component is g; the difference from example 1 is that:
the silane coupling agent is 1, 2-bis (triethoxysilyl) ethane;
the alkaline catalyst is potassium hydroxide;
the surfactant comprises nonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether and isomeric tridecanol polyoxyethylene ether, and the weight ratio is 1: 2: 1;
no nanoparticles are contained;
the substances and the contents of the raw materials in the component B are shown in Table 2, and the unit of the content of each component is g; the difference from example 1;
the silane coupling agent is 1, 2-bis (triethoxysilyl) ethane;
the alkaline catalyst is potassium hydroxide;
the surfactant is F4432 nonionic fluorine-containing compound surfactant;
the particle size of the nano titanium oxide is 50-100 nm.
Example 6
A self-cleaning glass hydrophobic agent comprises a component A and a component B;
the substances and the contents of the raw materials in the component A are shown in the table 1, and the unit of the content of each component is g; the difference from example 2 is that:
the alkaline catalyst is potassium hydroxide;
the surfactant comprises nonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether and perfluoro-1-butanesulfonic acid, and the weight ratio is 1: 2: 5;
no nanoparticles are contained;
the substances and the contents of the raw materials in the component B are shown in Table 2, and the unit of the content of each component is g; the difference from example 2 is that:
the silane coupling agent is 1, 2-bis (triethoxysilyl) ethane;
the alkaline catalyst is potassium hydroxide;
the surfactant is F4432 nonionic fluorine-containing compound surfactant;
does not contain nano titanium oxide.
The preparation method of examples 1 to 6 is as follows:
s1, preparing the component A, weighing dimethyl cyclosiloxane, phenyl siloxane, a silane coupling agent and nano particles according to a proportion, mixing and stirring uniformly, and heating to 90 ℃ to obtain a hot material; continuously adding an alkaline catalyst into the hot material within 3 hours at the temperature of 140-145 ℃, carrying out polymerization reaction to obtain ternary polymerization siloxane, cooling to room temperature, adding a surfactant, uniformly mixing, adding a solvent for emulsification, and filtering to obtain a component A;
s2, preparing the component B, weighing dimethyl cyclosiloxane, phenyl siloxane and a silane coupling agent according to the proportion, mixing and stirring uniformly, and heating to 90 ℃ to obtain a hot material; continuously adding an alkaline catalyst into the hot material within 3 hours at the temperature of 140-145 ℃, carrying out polymerization reaction to obtain ternary polymerization siloxane, cooling to room temperature, adding a surfactant, uniformly mixing, adding a solvent for emulsification, and filtering to obtain a component B.
TABLE 1 substances and amounts in component A
| Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 | |
| Dimethylcyclosiloxane | 100 | 100 | 100 | 100 | 100 | 100 |
| Containing phenylsiloxane | 21 | 30 | 49 | 25 | 30 | 50 |
| Silane coupling agent | 5 | 7.5 | 10 | 6 | 8 | 9 |
| Basic catalyst | 1 | 0.8 | 0.5 | 1 | 0.3 | 0.1 |
| Surface active agent | 6 | 13 | 20 | 15 | 40 | 30 |
| Solvent(s) | 90 | 30 | 60 | 70 | 10 | 50 |
| Nanoparticles | 10 | 15 | 20 | 5 | 0 | 0 |
Table 2B Components, substances and amounts
| Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 | |
| Organofluoro compounds | 80 | 80 | 80 | 80 | 80 | 80 |
| Silane coupling agent | 15 | 8 | 12 | 10 | 6 | 4 |
| Dimethylcyclosiloxane | 10 | 30 | 13 | 18 | 25 | 20 |
| Containing phenylsiloxane | 20 | 10 | 15 | 12 | 15 | 18 |
| Basic catalyst | 1 | 0.8 | 0.5 | 1 | 0.3 | 0.1 |
| Surface active agent | 6 | 13 | 20 | 15 | 40 | 30 |
| Solvent(s) | 90 | 30 | 60 | 70 | 10 | 50 |
| Nano titanium oxide | 15 | 20 | 5 | 10 | 1 | 0 |
Comparative example 1
The lotus leaf hydrophobing agent is purchased from Taida chemical Co., Ltd, Taida, Librarian ceramic county, and has the model of LC-808.
Comparative example 2
An automobile glass coating agent which is purchased from Henghui nano science and technology Limited and has the model of PV-30000.
Performance testing
The products prepared in examples 1 to 6 and the products of comparative examples 1 to 2 were subjected to the following tests:
experiment 1, contact angle test: glass sheets were prepared into 10 × 10cm standard blocks 1 to 8, which corresponded to example 1, example 2, example 3, example 4, example 5, example 6, comparative example 1 and comparative example 2 in this order, and after washing the glass with 1 part of hydrochloric acid having a mass concentration of 2%, the glass was rinsed with 30 parts of water and dried, and the contact angle before treatment was measured with reference to the GB/T31815-15 standard.
Experiment 2, samples 1 to 6 after the test are sprayed with 20ml of component A corresponding to the components A in examples 1, 2, 3, 4, 5 and 6 in sequence, and after spontaneous combustion drying, the samples 7 to 8 after the test are sprayed with 20ml of component B corresponding to the components B in examples 1, 2, 3, 4, 5 and 6, wherein the products of examples 1 to 6 are diluted by 30 times with water, the products of comparative examples 1 to 2 are sprayed with 40ml of sample blocks 7 to 8 corresponding to the products of comparative examples 1 and 2, and the samples 1 to 8 after the test are dried and then the contact angles after the test are tested according to GB/T31815-15 standard.
Experiment 3, impact 1-8 standard sample blocks with 100g of active clay with 300 meshes from a height of 30cm within 3min, wash with water, dry, and test the friction contact angle.
Experiment 4, samples 1 to 6 after the treatment of experiment 3 were spray-treated corresponding to the component B in examples 1, 2, 3, 4, 5 and 6, with a spray amount of 20ml, and samples 7 to 8 after the treatment of experiment 3 were spray-treated corresponding to examples 1 and 2, with a spray amount of 20ml, and the secondary treatment contact angles were measured with reference to the GB/T31815-15 standard.
Experiment 5, the visible light transmittance was tested with reference to GB/T2680-94 standard.
The test results are shown in table 3.
Table 3 results of performance testing
According to the experimental data, after the product prepared by the invention is used for treating the surface of glass, an effective hydrophobic layer can be formed on the surface of the glass, the contact angle can reach more than 125 degrees, and water drops can naturally fall off without being attached to the glass to influence the sight. The cleaning agent has strong resistance to dust and good dust resistance, can still keep a high contact angle after being washed by dust, can achieve good hydrophobic effect without special treatment after secondary use, can be directly used as a cleaning agent after primary film forming, and does not need special treatment.
Claims (8)
1. A self-cleaning glass hydrophobic agent is characterized by comprising a component A and a component B, wherein the components A and B are calculated according to parts by weight,
the component A is prepared from the following raw materials: 100 parts of dimethyl cyclosiloxane, 20-50 parts of phenyl siloxane, 5-10 parts of silane coupling agent, 0.1-10 parts of basic catalyst, 5-40 parts of surfactant, 10-90 parts of solvent and 4-20 parts of nano particles, wherein the nano particles are one or two of nano silicon dioxide and nano zinc oxide;
the component B is prepared from the following raw materials: 80 parts of organic fluoride, 4-15 parts of a silane coupling agent, 10-30 parts of dimethyl cyclosiloxane, 10-20 parts of phenyl siloxane, 0.1-10 parts of an alkaline catalyst, 5-40 parts of a surfactant, 10-90 parts of a solvent and 1-20 parts of nano titanium oxide;
and spraying the component A on glass, and naturally drying, and then spraying the component B for the second time.
2. The self-cleaning glass hydrophobizing agent of claim 1, wherein: the dimethylcyclosiloxane includes octamethylcyclotetrasiloxane.
3. The self-cleaning glass hydrophobizing agent of claim 1, wherein: the phenyl-containing siloxane comprises one or more of octaphenylcyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane and short-chain methyl phenyl siloxane.
4. The self-cleaning glass hydrophobizing agent of claim 1, wherein: the silane coupling agent is N-beta- (aminoethyl) -gamma-aminopropyltrimethoxysilane.
5. The self-cleaning glass hydrophobizing agent of claim 1, wherein: the alkaline catalyst is tetramethyl ammonium hydroxide.
6. The self-cleaning glass hydrophobizing agent of claim 1, wherein: the solvent is one or more of acetonitrile, acetone, methanol, ethanol and isopropanol.
7. The self-cleaning glass hydrophobizing agent of claim 1, wherein: the organic fluoride is one or more of tridecafluorooctyltriethoxysilane, 4-methyl-tridecafluorodecyltriethoxysilane, heptadecafluorodecyltriethoxysilane, heptadecafluorodecyltriisopropoxysilane, heptadecafluorodecyltripropoxysilane, triethyl- (trifluorovinyl) silane and nonafluorohexyldimethylchlorosilane.
8. The self-cleaning glass hydrophobizing agent of claim 1, wherein: the particle size of the nano titanium oxide is 20-50 nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910028067.9A CN109777291B (en) | 2019-01-11 | 2019-01-11 | Self-cleaning glass hydrophobing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910028067.9A CN109777291B (en) | 2019-01-11 | 2019-01-11 | Self-cleaning glass hydrophobing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109777291A CN109777291A (en) | 2019-05-21 |
| CN109777291B true CN109777291B (en) | 2021-08-10 |
Family
ID=66500343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910028067.9A Active CN109777291B (en) | 2019-01-11 | 2019-01-11 | Self-cleaning glass hydrophobing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109777291B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110387174A (en) * | 2019-07-01 | 2019-10-29 | 深圳华美板材有限公司 | A kind of water-based hydrophobic oleophobic Coil Coating Products and its manufacturing process |
| CN112845334A (en) * | 2020-12-30 | 2021-05-28 | 东莞理工学院 | Surface condensation dust removal method |
| CN113416209B (en) * | 2021-07-07 | 2022-08-09 | 广州市白云化工实业有限公司 | Fluorine-containing cleaning agent and self-cleaning condensed type silane modified polyether adhesive |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101962514A (en) * | 2010-09-27 | 2011-02-02 | 复旦大学 | High-durability super-hydrophobic self-cleaning coating material and preparation method thereof |
| CN104448999A (en) * | 2014-11-18 | 2015-03-25 | 厦门建霖工业有限公司 | Anti-fingerprint surface treating agent and use method thereof |
| CN107201173A (en) * | 2017-06-09 | 2017-09-26 | 广州市白云文物保护工程有限公司 | It is a kind of to can be applied to south of the Five Ridges area iron cultural relic anticorrosion organic/inorganic composite material of high-temperature high humidity climate and preparation method thereof |
-
2019
- 2019-01-11 CN CN201910028067.9A patent/CN109777291B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101962514A (en) * | 2010-09-27 | 2011-02-02 | 复旦大学 | High-durability super-hydrophobic self-cleaning coating material and preparation method thereof |
| CN104448999A (en) * | 2014-11-18 | 2015-03-25 | 厦门建霖工业有限公司 | Anti-fingerprint surface treating agent and use method thereof |
| CN107201173A (en) * | 2017-06-09 | 2017-09-26 | 广州市白云文物保护工程有限公司 | It is a kind of to can be applied to south of the Five Ridges area iron cultural relic anticorrosion organic/inorganic composite material of high-temperature high humidity climate and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109777291A (en) | 2019-05-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109777291B (en) | Self-cleaning glass hydrophobing agent | |
| RU2519258C2 (en) | Silicon dioxide based coating for higher hydrophilicity | |
| CN103635543B (en) | Inorganic hydrophilic coating fluid and, thus obtained by hydrophilic film and use its parts | |
| WO1998055573A1 (en) | Method for surface pretreatment before formation of photocatalytic hydrophilic film, and detergent and undercoat composition for use in the same | |
| CN107892826A (en) | Compound self-cleaning nona coating, inorganic transparent coating and automatically cleaning product | |
| WO2010127034A1 (en) | Ant-reflective and anti-soiling coatings with self-cleaning properties | |
| WO2015141240A1 (en) | Aqueous coating agent, film, film production method, laminate, and solar cell module | |
| CN109678356B (en) | High-light-transmittance glass hydrophobing agent and preparation method thereof | |
| CN110591555A (en) | Preparation method of self-cleaning antifogging astronomical telescope lens | |
| SA517381194B1 (en) | Low-Reflection Coating | |
| CN104497659A (en) | Antifog surface treatment agent for resin optical glasses | |
| CN106519971A (en) | Hydrophilic siliceous coating solution and coating method | |
| JP6805127B2 (en) | Glass plate with coating film and its manufacturing method | |
| CN110746125A (en) | Hydrophobic glass and preparation method thereof | |
| CN109678359B (en) | Preparation method and application of self-cleaning glass hydrophobic agent | |
| WO2021139215A1 (en) | Self-healing or reusable product, preparation method therefor, and application thereof | |
| CN111393926A (en) | Water-based coating liquid | |
| CA3011337A1 (en) | Transparent substrate with non-transparent film | |
| CN114656160B (en) | High-light-transmittance mildew-proof glass and preparation method thereof | |
| CN109762672A (en) | A kind of automobile windscreen cleaning agent | |
| JP2000026756A (en) | Coating composition, coating of base material surface, base material having coated surface | |
| CN108137944B (en) | Room temperature curing highly durable anti-reflective coatings containing nanoparticles | |
| CN111574904B (en) | Oil-water double-hydrophobic coating liquid for automobile glass | |
| CN104098935A (en) | Silicon dioxide coating for improving hydrophilcity/transmissivity | |
| JP2009018946A (en) | Method for forming transparent super-water-repellent film and glass substrate having transparent super-water-repellent film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20211228 Address after: 441047 south of Taoyuan road and west of the fourth West Ring Road, Zaoyang City, Xiangyang City, Hubei Province (Zaoyang Chemical Industrial Park) Patentee after: Hubei Longsheng Sihai New Material Co.,Ltd. Address before: 441000 building 3, group 5, neighborhood committee, Nancheng Wangjiawan community, Zaoyang City, Xiangyang City, Hubei Province Patentee before: HUBEI NEW SIHAI CHEMICAL INDUSTRY CO.,LTD. |
|
| TR01 | Transfer of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A self-cleaning glass hydrophobic agent Granted publication date: 20210810 Pledgee: Bank of China Limited Xiangyang Branch Pledgor: Hubei Longsheng Sihai New Material Co.,Ltd. Registration number: Y2024980006288 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |