CN109775785A - A kind of high-salt wastewater burns desalting system and its processing method - Google Patents

A kind of high-salt wastewater burns desalting system and its processing method Download PDF

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Publication number
CN109775785A
CN109775785A CN201711127008.4A CN201711127008A CN109775785A CN 109775785 A CN109775785 A CN 109775785A CN 201711127008 A CN201711127008 A CN 201711127008A CN 109775785 A CN109775785 A CN 109775785A
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China
Prior art keywords
vertical cylinder
air
air inlet
salt wastewater
flue gas
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CN201711127008.4A
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Chinese (zh)
Inventor
孙明华
尚文君
王兆民
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JIANGSU JINNIU ENVIRONMENTAL ENGINEERING EQUIPMENT Co Ltd
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JIANGSU JINNIU ENVIRONMENTAL ENGINEERING EQUIPMENT Co Ltd
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Priority to CN201711127008.4A priority Critical patent/CN109775785A/en
Publication of CN109775785A publication Critical patent/CN109775785A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/30Technologies for a more efficient combustion or heat usage

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  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

A kind of high-salt wastewater burns desalting system and its processing method, including dry reactor, demineralizer, secondary combustion chamber, waste-heat recovery device and purification tapping equipment, dry reactor air outlet pipeline connects demineralizer, demineralizer air outlet pipeline connects secondary combustion chamber, secondary combustion chamber air outlet pipeline connects waste-heat recovery device, purifying tapping equipment includes smoke exhaust fan, dry reactor includes vertical cylinder, it is opened in the high-salt wastewater import on vertical cylinder top, pressurised atomised device is provided in import, the high-temperature flue gas air inlet being opened in vertical cylinder, the salt outlet of vertical cylinder bottom end, it is opened in the organic gas outlet of the nearly bottom end side wall of vertical cylinder, high-temperature flue gas air inlet is tangentially opened up along vertical cylinder, high-temperature flue gas is set to form the downward flow-disturbing of helical form along vertical cylinder inner wall, high-temperature flue gas air inlet Heating furnace and natural gas combustion engine are connected, is provided with oxygenating air inlet on heating furnace.

Description

A kind of high-salt wastewater burns desalting system and its processing method
Technical field
The present invention relates to high-salt wastewater process fields more particularly to incineration method to handle high-salt wastewater.
Background technique
A large amount of high slat-containing wastewater can inevitably be generated in the industrial production at present, traditional technique is generally contained using burning height Salt method for waste water is handled, and is had problems in that: 1. brine wastes must be carried out cold after burning using quick cooling method But, traditional method is all that combination cooling is carried out using a large amount of water, and the water after chilling also needs to drain into sewage treatment plant's progress Subsequent processing, significantly waste water resource and subsequent treatment process are complicated, and cost of investment is higher;2. during the burning process, burning Temperature is excessively high to will lead to salt fusing, and the salt of molten can penetrate into the refractory material of incinerator, lead to one layer one of refractory material Layer delamination damage, shortens the service life of refractory material significantly;3. the thermal energy after burning cannot recycle, energy consumption is high;4. fuse salt and Other substances can generate insoluble matter in high temperature incineration, can occluding device and system;5. the salt after chilling will become floating dust to periphery Environment brings serious pollution.Have much room for improvement.
Chinese patent notification number CN2893438Y discloses a kind of organic waste liquid containing salt burning system, belongs to liquid waste processing and section Energy equipment, including incinerator, deduster, waste heat recovery apparatus, an incinerator furnace roof are equipped with waste liquid import, outlet at bottom pipeline Cyclone dust collectors are connected, house-bag duster for high temperature is connected in gas outlet at the top of cyclone dust collectors, and the top of house-bag duster for high temperature goes out Mouth connection secondary incinerator, the gas outlet pipeline of secondary incinerator connect waste heat recovery apparatus, and the salt fines of this incineration system are no longer Into in the liquid of purification system, reduce the difficulty of purification wastewater treatment, recycles high-temperature flue gas using waste heat recovery apparatus In heat, substantially increase the thermal efficiency of incinerator.Its technical solution removes a large amount of precipitation salt by once burning, and then leads to Dust-extraction unit removal saliferous dust is crossed, is burned again subsequently into secondary incinerator, system concept is correct, but it can not be right The temperature of the high-temperature flue gas of entrance is controlled, and the oxygen concentration in flue gas is also unable to control, and is caused it that salt is precipitated and is easy shape At molten, cannot be introduced into subsequent cleaner at all and be dusted, and its incinerator burn after flue gas its analysis Salt is dusted together with organic gas into dust-extraction unit out, dust-extraction unit at all can not load so big salt content, contain The dust particles of salt can not be separated and be discharged, and cause secondary incinerator still to generate problem of the prior art, have much room for improvement.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of system is simple, but solid-state can be precipitated in high efficiency early period Simultaneously the subsequent burning difficulty of reduction is discharged in salt, and solid salt eduction rate is up to 99%, greatly prolongs the service life of equipment, is suitble to industry The high-salt wastewater for changing application burns desalting system and its processing method.
Purpose to realize the present invention provides a kind of following technical scheme: 1. high-salt wastewater burning desalting systems, including dry Dry reactor, demineralizer, secondary combustion chamber, waste-heat recovery device and purification tapping equipment, dry reactor air outlet pipe Road connects demineralizer, and demineralizer air outlet pipeline connects secondary combustion chamber, and secondary combustion chamber air outlet pipeline connects waste heat Recyclable device, whole system are sealing structure, and purification tapping equipment includes smoke exhaust fan, and whole system is evacuated negative pressure shape State, it is characterised in that dry reactor includes vertical cylinder, the high-salt wastewater import for being opened in vertical cylinder top, is set in import It is equipped with pressurised atomised device, the salt outlet of the high-temperature flue gas air inlet, vertical cylinder bottom end that are opened in vertical cylinder is opened in The organic gas of the nearly bottom end side wall of vertical cylinder exports, and high-temperature flue gas air inlet connects heating furnace and natural gas combustion engine, heating Oxygenating air inlet is provided on furnace;Waste-heat recovery device includes the air heat exchanger connecting with secondary combustion chamber air outlet pipeline, Air heat exchanger air intlet connects oxygenating blower, and air heat exchanger air outlet slit connects oxygenating pipeline, and the connection of oxygenating pipeline adds Oxygenating air inlet in hot stove.
Preferably, high-temperature flue gas air inlet is tangentially opened up along vertical cylinder, make high-temperature flue gas along vertical cylinder inner wall shape Spiral downward flow-disturbing,
Preferably, demineralizer includes cyclone dust collectors, high temperature too cotton deduster.
Preferably, vertical cylinder is set as the gradually smaller multistage of diameter, height is offered on the barrel of every section of cylinder Warm smoke air inlet.Most preferably, high-temperature flue gas air inlet is around the vertical cylinder center of circle at least provided with one.
Preferably, organic gas outlet connection escape pipe, escape pipe connecting pin are protruded into vertical cylinder, port is close to vertical Formula body centre.
Preferably, height of the pressurised atomised the bottom of the device apart from nearest high-temperature flue gas air inlet is 300mm ~ 600mm.
Preferably, the height of size diameter section and the range of diameter and between proportionate relationship be 3 to 2.
Purpose to realize the present invention provides a kind of processing method of high-salt wastewater burning desalting system, it is characterised in that The following steps are included: natural gas combustion engine heats the oxygen-containing air in heating furnace, the oxygen content in air passes through oxygenating Pipeline carries out oxygenating, makes its oxygen content 28%, and by oxygenating pipeline come oxygen-containing hot wind, make the temperature of its oxygen-containing air At 650 DEG C ~ 720 DEG C, oxygen-containing air enters being sprayed for dry reactor and high-salt wastewater by high-temperature flue gas air inlet for degree control After mixing, temperature is controlled at 650 DEG C ~ 720 DEG C, electrodeless to salt out, and is discharged from dry reactor bottom end, and organic gas, which enters, to be removed Salt device carries out desalination again, and the organic gas after desalination enters secondary combustion chamber and burns, and removes organic matter, removes organic Gas after matter enters subsequent waste-heat recovery device and purification tapping equipment carries out waste heat recycling and discharge.
Preferably, the oxygen-containing air that the air heat exchanger in waste-heat recovery device is pumped into oxygenating blower preheats, Preheating temperature is 160 DEG C ~ 200 DEG C.
Fuse salt is led to the problem of burning of the existing technology the invention has the advantages that: the present invention to improve, Make to be substantially free of inorganic salts into the gas of secondary burning room, electrodeless salt is largely precipitated in dry reactor, passes through control Temperature and the method for improving oxygenating amount, greatly improve the eduction rate of inorganic salts, and it is made not generate fuse salt, whole system work Skill is simple, is convenient for industrial application.
Detailed description of the invention
Fig. 1 is the schematic diagram of the embodiment of the present invention 1.
Fig. 2 is the schematic diagram of the embodiment of the present invention 2.
Fig. 3 is the schematic diagram of the embodiment of the present invention 3.
Specific embodiment
Embodiment 1: a kind of high-salt wastewater burning desalting system, including dry reactor 1, demineralizer 2, secondary combustion chamber 3, waste-heat recovery device 4 and purification tapping equipment 5,1 air outlet pipeline of dry reactor connect demineralizer 2, demineralizer 2 Air outlet pipeline connects secondary combustion chamber 3, and 3 air outlet pipeline of secondary combustion chamber connects waste-heat recovery device 4, and whole system is close Seal structure, purification tapping equipment 5 include smoke exhaust fan 6, whole system are evacuated negative pressure state, dry reactor 1 includes Vertical cylinder 1.1, the high-salt wastewater import 1.2 for being opened in 1.1 top of vertical cylinder are provided with increasing in high-salt wastewater import 1.2 Atomising device 1.3 is pressed, the salt outlet of high-temperature flue gas air inlet 1.4 in vertical cylinder 1.1,1.1 bottom end of vertical cylinder is opened in 1.5, it is opened in the organic gas outlet 1.6 of the nearly bottom end side wall of vertical cylinder 1.1, high-temperature flue gas air inlet 1.4 connects heating furnace 1.7 and natural gas combustion engine 1.8, oxygenating air inlet 1.7.1 is provided on heating furnace 1.7;Waste-heat recovery device 4 include with it is secondary The air heat exchanger 10 of 3 air outlet pipeline of combustion chamber connection, 10 air intlet of air heat exchanger connect oxygenating blower 7, and air changes Hot 10 air outlet slit of device connects oxygenating pipeline 8, and oxygenating pipeline 8 connects the oxygenating air inlet 1.7.1 on heating furnace 1.7.It is pressurized mist Makeup sets 1.3 as twin device.Natural gas line 11 connects natural gas combustion engine 1.8, and high-salt wastewater pipeline 12 connects High-salt wastewater import 1.2.
Embodiment 2: referring to embodiment 1, other structures are constant, 1.4 edge of high-temperature flue gas air inlet of the dry reactor 1 Vertical cylinder 1 tangentially opens up, and high-temperature flue gas is made to form the downward flow-disturbing of helical form along 1.1 inner wall of vertical cylinder, and demineralizer 2 wraps Cyclone dust collectors 2.1, high temperature too cotton deduster 2.2 are included, waste-heat recovery device 4 includes air heat exchanger 10, air heat exchanger 10 It is anxious that air intlet connects oxygenating blower 7, the heat recovery steam generator 4.1 connecting with 10 exhanst gas outlet of air heat exchanger, half dry type Cold tower 4.2;Purify tapping equipment 5 include mixing reactor 5.1, bag filter 5.2, neutralize scrubbing tower 5.3, smoke exhaust fan 6, Exhaust tube 5.4 etc..
Embodiment 3, referring to embodiment 2, other structures are constant, and upper section enlarged diameter section 1.1.1 is arranged under in vertical cylinder 1.1 Section reduced diameter section 1.1.2, offers high-temperature flue gas air inlet 1.4, the high-temperature flue gas air inlet on the barrel of every section of cylinder 1.4 are provided with one around every section of 1.1 center of circle of vertical cylinder, and organic gas outlet 1.6 connects escape pipe 9,9 connecting pin of escape pipe It protrudes into vertical cylinder 1.1, port is close to 1.1 center of vertical cylinder.Pressurised atomised 1.3 bottom end of device is apart from nearest high temperature cigarette The height of gas air inlet 1.4 is 300mm ~ 600mm.The height of size diameter section (1.1.1,1.1.2) and the range of diameter and Between proportionate relationship 3 to 2.
Embodiment 4: a kind of high-salt wastewater burns the processing method of desalting system, comprising the following steps: natural gas combustion engine Oxygen-containing air in 1.8 pairs of heating furnaces 1.7 heats, and the oxygen content in air carries out oxygenating by oxygenating pipeline 8, makes its oxygen Content is 28%, and by oxygenating pipeline 8 conveying come oxygen-containing hot wind, make its oxygen-containing air temperature control 650 DEG C ~ 720 DEG C, oxygen-containing air by high-temperature flue gas air inlet 1.4 enter dry reactor 1 and high-salt wastewater it is spraying mix after, temperature control System is electrodeless to salt out at 650 DEG C ~ 720 DEG C, is discharged from 1 bottom end of dry reactor, and organic gas, which enters demineralizer 2, to carry out again Secondary desalination, the organic gas after desalination enter secondary combustion chamber 3 and burn, and remove organic matter, the gas after removing organic matter Waste heat recycling and discharge are carried out into subsequent waste-heat recovery device 4 and purification tapping equipment 5, the sky in waste-heat recovery device 4 The oxygen-containing air that gas heat exchanger 6 is pumped into oxygenating blower 7 preheats, and preheating temperature is 160 DEG C ~ 200 DEG C.
Rotary kiln can be separately added, dry reactor 1 is heated by the organic exhaust gas generated after rotary kiln incineration, Kiln temperature controls between 500 to 700 DEG C, decomposes the organic matter in solid.Inorganic salts go out from 1 bottom end of dry reactor Salt mouth 1.5 is discharged, and 1 bottom end salt outlet 1.5 of dry reactor connects out salt device, and high temperature organic exhaust gas is mentioned to dry reactor 1 For thermal energy.
Dry reactor 1 has the high-temperature flue gas of heating furnace offer and the brine waste after atomization sufficiently to disturb and reach critical point Dry reaction, organic salt resolve into carbon monoxide, water, inorganic dust salt.Demineralizer 2 in systems the effect of it is most important. High temperature too cotton deduster 2.2 is used for the filtering of high-temperature gas, and 1200 DEG C of heatproof, acid-alkali-corrosive-resisting, high temperature strength is high, can mistake Filter is greater than 1 micron of dust, removal rate >=99.99%.
3 incineration temperature of secondary combustion chamber is controlled at 1150 DEG C, is decomposed organic matter completely, is destroyed removal rate >=99.99% by fire. (residence time is 2.5 seconds)
1000 DEG C of the flue gas that secondary combustion chamber 3 generates enters heat recovery steam generator 4.3, and heat is for heating soft water generation The saturated vapor of 1.0Mpa.Flue gas is cooled to 509 DEG C and enters spray quenchers, and flue gas instantaneous cooling is to 190 in quencher DEG C or so come out, sodium bicarbonate and calcium hydroxide is added using dry type reactor, dioxin is completely removed by bag filter, cigarette Gas passes through scrubbing tower qualified discharge.Quencher is jacket type, and centre walks flue gas, walks recirculated water in collet, 7% is sprayed in flue gas The lye of left and right neutralizes flue gas.
The outlet of dual firing chamber is arranged in air preheater, is heated to 160 DEG C of oxygenating air, into dry reactor and returns Rotary kiln.
Flue gas emission presses GB18484-2001 " dangerous waste incineration contamination control standard ":

Claims (9)

1. a kind of high-salt wastewater burns desalting system, including dry reactor, demineralizer, secondary combustion chamber, waste heat recycling dress Tapping equipment is set and purifies, dry reactor air outlet pipeline connects demineralizer, demineralizer air outlet pipeline connection two Secondary combustion chamber, secondary combustion chamber air outlet pipeline connect waste-heat recovery device, and whole system is sealing structure, purify tapping equipment Including smoke exhaust fan, whole system is evacuated negative pressure state, it is characterised in that dry reactor includes vertical cylinder, opens up High-salt wastewater import in vertical cylinder top is provided with pressurised atomised device in import, the high temperature being opened in vertical cylinder Smoke air inlet, vertical cylinder bottom end salt outlet, be opened in the nearly bottom end side wall of vertical cylinder organic gas outlet, high temperature cigarette Gas air inlet connects heating furnace and natural gas combustion engine, is provided with oxygenating air inlet on heating furnace;Waste-heat recovery device include with The air heat exchanger of secondary combustion chamber air outlet pipeline connection, air heat exchanger air intlet connect oxygenating blower, air heat-exchange Device air outlet slit connects oxygenating pipeline, and oxygenating pipeline connects the oxygenating air inlet on heating furnace.
2. a kind of high-salt wastewater according to claim 1 burns desalting system, it is characterised in that high-temperature flue gas air inlet edge Vertical cylinder tangentially opens up, and high-temperature flue gas is made to form the downward flow-disturbing of helical form along vertical cylinder inner wall,
A kind of high-salt wastewater according to claim 1 burns desalting system, it is characterised in that demineralizer includes that whirlwind removes Dirt device, high temperature too cotton deduster.
3. a kind of high-salt wastewater according to claim 1 burns desalting system, it is characterised in that vertical cylinder is set as straight The gradually smaller multistage of diameter offers high-temperature flue gas air inlet on the barrel of every section of cylinder.
4. a kind of high-salt wastewater according to claim 4 burns desalting system, it is characterised in that high-temperature flue gas air inlet encloses Around the vertical cylinder center of circle at least provided with one.
5. a kind of high-salt wastewater according to claim 1 burns desalting system, it is characterised in that organic gas outlet connection Escape pipe, escape pipe connecting pin are protruded into vertical cylinder, and port is close to vertical cylinder center.
6. a kind of high-salt wastewater according to claim 1 burns desalting system, it is characterised in that pressurised atomised the bottom of the device Height apart from nearest high-temperature flue gas air inlet is 300mm ~ 600mm.
7. a kind of high-salt wastewater according to claim 4 burns desalting system, it is characterised in that adjacent size diameter section Height is than being 3:2.
8. the processing method that a kind of high-salt wastewater as described in claim 1 burns desalting system, it is characterised in that including following Step: natural gas combustion engine heats the oxygen-containing air in heating furnace, and the oxygen content in air is carried out by oxygenating pipeline Oxygenating, makes its oxygen content 28%, and by oxygenating pipeline come oxygen-containing hot wind, control the temperature of its oxygen-containing air and exist 650 DEG C ~ 720 DEG C, oxygen-containing air by high-temperature flue gas air inlet enter dry reactor and high-salt wastewater it is spraying mix after, Temperature control at 650 DEG C ~ 720 DEG C, it is electrodeless to salt out, from dry reactor bottom end be discharged, organic gas enter demineralizer into Row desalination again, the organic gas after desalination enter secondary combustion chamber and burn, and remove organic matter, the gas after removing organic matter Body enters subsequent waste-heat recovery device and purification tapping equipment carries out waste heat recycling and discharge.
9. the processing method that a kind of high-salt wastewater as described in claim 1 burns desalting system, it is characterised in that waste heat recycling The oxygen-containing air that air heat exchanger in device is pumped into oxygenating blower preheats, and preheating temperature is 160 DEG C ~ 200 DEG C.
CN201711127008.4A 2017-11-15 2017-11-15 A kind of high-salt wastewater burns desalting system and its processing method Pending CN109775785A (en)

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CN110631032A (en) * 2019-09-28 2019-12-31 江苏朗誉环保设备有限公司 High-salt organic waste liquid incineration treatment system and method
CN113757693A (en) * 2021-08-09 2021-12-07 江苏金牛环保工程设备有限公司 Dry salt secondary heating incineration system for solid-liquid treatment and use method thereof
WO2021253865A1 (en) * 2021-01-15 2021-12-23 江苏宏牛环保集团有限公司 Domestic waste percolate concentrated-solution pyrolysis treatment system
CN113979507A (en) * 2021-11-22 2022-01-28 江苏中圣高科技产业有限公司 Harmless recycling treatment process and system for high-salt and high-concentration organic wastewater

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WO2021253865A1 (en) * 2021-01-15 2021-12-23 江苏宏牛环保集团有限公司 Domestic waste percolate concentrated-solution pyrolysis treatment system
CN113757693A (en) * 2021-08-09 2021-12-07 江苏金牛环保工程设备有限公司 Dry salt secondary heating incineration system for solid-liquid treatment and use method thereof
CN113979507A (en) * 2021-11-22 2022-01-28 江苏中圣高科技产业有限公司 Harmless recycling treatment process and system for high-salt and high-concentration organic wastewater
CN113979507B (en) * 2021-11-22 2024-03-22 江苏中圣高科技产业有限公司 Harmless recycling treatment process and system for high-salt-content high-concentration organic wastewater

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Application publication date: 20190521