CN109763326B - Antioxidant antistatic spinning oil - Google Patents
Antioxidant antistatic spinning oil Download PDFInfo
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- CN109763326B CN109763326B CN201910028968.8A CN201910028968A CN109763326B CN 109763326 B CN109763326 B CN 109763326B CN 201910028968 A CN201910028968 A CN 201910028968A CN 109763326 B CN109763326 B CN 109763326B
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- 238000009987 spinning Methods 0.000 title claims abstract description 85
- 239000003963 antioxidant agent Substances 0.000 title claims abstract description 62
- 230000003078 antioxidant effect Effects 0.000 title claims abstract description 62
- 239000003921 oil Substances 0.000 claims abstract description 124
- 239000000835 fiber Substances 0.000 claims abstract description 35
- 239000000654 additive Substances 0.000 claims abstract description 21
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 15
- -1 alcohol ether compound Chemical class 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims description 93
- 239000013543 active substance Substances 0.000 claims description 87
- 238000003756 stirring Methods 0.000 claims description 74
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 72
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 54
- 238000001816 cooling Methods 0.000 claims description 48
- 239000002994 raw material Substances 0.000 claims description 43
- 239000000203 mixture Substances 0.000 claims description 42
- 238000002360 preparation method Methods 0.000 claims description 40
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 27
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 claims description 26
- 235000019441 ethanol Nutrition 0.000 claims description 24
- 238000009499 grossing Methods 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 24
- 230000000996 additive effect Effects 0.000 claims description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims description 18
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 14
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 claims description 14
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 14
- CHPZKNULDCNCBW-UHFFFAOYSA-N gallium nitrate Chemical compound [Ga+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CHPZKNULDCNCBW-UHFFFAOYSA-N 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 12
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- 239000000706 filtrate Substances 0.000 claims description 12
- 238000001914 filtration Methods 0.000 claims description 12
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 claims description 12
- 238000000967 suction filtration Methods 0.000 claims description 12
- 235000002906 tartaric acid Nutrition 0.000 claims description 12
- 239000011975 tartaric acid Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 10
- NPKKFQUHBHQTSH-UHFFFAOYSA-N 2-(decoxymethyl)oxirane Chemical compound CCCCCCCCCCOCC1CO1 NPKKFQUHBHQTSH-UHFFFAOYSA-N 0.000 claims description 7
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 239000005639 Lauric acid Substances 0.000 claims description 7
- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 claims description 7
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 7
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 claims description 7
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 claims description 7
- 229910001981 cobalt nitrate Inorganic materials 0.000 claims description 7
- 238000004821 distillation Methods 0.000 claims description 7
- 229940044658 gallium nitrate Drugs 0.000 claims description 7
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 claims description 6
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 6
- 229920006197 POE laurate Polymers 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- 229920013822 aminosilicone Polymers 0.000 claims description 6
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 claims description 6
- 238000001354 calcination Methods 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000004359 castor oil Substances 0.000 claims description 6
- 235000019438 castor oil Nutrition 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 6
- 238000006297 dehydration reaction Methods 0.000 claims description 6
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 6
- 229940095098 glycol oleate Drugs 0.000 claims description 6
- 239000002480 mineral oil Substances 0.000 claims description 6
- 235000010446 mineral oil Nutrition 0.000 claims description 6
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 6
- 235000006408 oxalic acid Nutrition 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- 239000005053 propyltrichlorosilane Substances 0.000 claims description 6
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 6
- DOEHJNBEOVLHGL-UHFFFAOYSA-N trichloro(propyl)silane Chemical compound CCC[Si](Cl)(Cl)Cl DOEHJNBEOVLHGL-UHFFFAOYSA-N 0.000 claims description 6
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 5
- 229930091371 Fructose Natural products 0.000 claims description 5
- 239000005715 Fructose Substances 0.000 claims description 5
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 5
- 229930195725 Mannitol Natural products 0.000 claims description 5
- 235000021255 galacto-oligosaccharides Nutrition 0.000 claims description 5
- 150000003271 galactooligosaccharides Chemical class 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000000594 mannitol Substances 0.000 claims description 5
- 235000010355 mannitol Nutrition 0.000 claims description 5
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 4
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 4
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 claims description 4
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 4
- 239000012190 activator Substances 0.000 claims description 4
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 4
- 239000008101 lactose Substances 0.000 claims description 4
- 239000000600 sorbitol Substances 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 26
- 238000004804 winding Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003063 flame retardant Substances 0.000 abstract description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 3
- 229920002994 synthetic fiber Polymers 0.000 abstract description 3
- 239000012209 synthetic fiber Substances 0.000 abstract description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract description 2
- 238000004939 coking Methods 0.000 abstract description 2
- 239000004744 fabric Substances 0.000 abstract description 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 2
- 239000011574 phosphorus Substances 0.000 abstract description 2
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 abstract description 2
- 238000006366 phosphorylation reaction Methods 0.000 abstract description 2
- 229920000570 polyether Polymers 0.000 abstract description 2
- 229910052710 silicon Inorganic materials 0.000 abstract description 2
- 239000010703 silicon Substances 0.000 abstract description 2
- 230000009977 dual effect Effects 0.000 abstract 1
- 239000002585 base Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 239000012258 stirred mixture Substances 0.000 description 8
- 229920001778 nylon Polymers 0.000 description 6
- 230000003068 static effect Effects 0.000 description 6
- 239000004677 Nylon Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002216 antistatic agent Substances 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 239000008041 oiling agent Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- OISVCGZHLKNMSJ-UHFFFAOYSA-N 2,6-Lutidine Substances CC1=CC=CC(C)=N1 OISVCGZHLKNMSJ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229920006052 Chinlon® Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001263 acyl chlorides Chemical class 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009435 amidation Effects 0.000 description 1
- 238000007112 amidation reaction Methods 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000007760 free radical scavenging Effects 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
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- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
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- 238000007142 ring opening reaction Methods 0.000 description 1
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- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Lubricants (AREA)
Abstract
The invention discloses an antioxidant antistatic spinning oil, and belongs to the technical field of synthetic fiber additives. According to the invention, on one hand, silicon and phosphorus dual flame-retardant elements are introduced into the spinning oil to form flame-retardant protection on the fiber surface after the spinning oil is oiled, and on the other hand, phosphorus trichloride and an alcohol ether compound are used for carrying out phosphorylation reaction, so that the antistatic effect is improved. The introduction of the epoxypropane chain link improves the heat resistance of the spinning oil, greatly reduces the coking phenomenon on the spinning surface, and improves the phenomena of broken filaments and broken filaments of the fibers. And a continuous oil film is formed by chain link arrangement of polyether molecular chains for spinning protection. The introduced amido bond has better polarity and stability, and the branched chain structure of the skeleton structure is utilized to uniformly disperse the antioxidant in the oil agent, thereby improving the performance of the spinning oil. The invention solves the problems that the spinning oil has poor antistatic performance, winding and broken ends occur, and the spinning oil is easy to oxidize, so that the fabric is easy to turn yellow.
Description
Technical Field
The invention belongs to the technical field of synthetic fiber additives, and particularly relates to antioxidant antistatic spinning oil.
Background
Synthetic fibers do not have special adhesion on the surface of natural fibers, so that chemical fiber oiling agents are indispensable to be used in the fiber spinning process. The friction characteristic of the fiber can be adjusted by using the oil agent, the static accumulation is prevented or eliminated, the cohesive force among tows is controlled, the fiber is endowed with good convergence, smoothness and fiber separation, and the smooth performance of chemical fiber spinning is ensured. The oil agent on the surface of the fiber is firstly contacted with production equipment, and the configuration of the oil agent has obvious influence on the production cost, the production efficiency and the product quality under the conditions determined by raw materials and production process equipment. The prior oiling agent for chemical fibers mainly comprises a smoothing agent, a bundling agent, an antistatic agent, an emulsifier, a balance regulator and the like; however, due to the difference of the components, the phenomena of broken filaments, broken ends and the like are easy to occur in the spinning process, so that the winding forming is poor, the high-quality product rate is low, the corrosion phenomenon is serious, and the requirements of the spinning process are difficult to adapt.
In the production and post-processing of chemical fiber, in order to have better spinnability, the static electricity of the protofilament must be eliminated, the friction coefficient must be adjusted, the fiber must be smooth and soft, and the fiber must pass through the processes of spinning, drafting, winding, twisting, spooling, weaving and the like, so that proper spinning oil must be added. The components of the commonly used chemical fiber oil agent can be divided into two categories: the first main group comprises components of a smoothing agent, an antistatic agent and an emulsifier, and the second main group comprises auxiliary components of a wetting agent, a softening agent, a cohesive agent, an antioxidant, a fiber separating agent, a penetrating agent, a pH regulator, a viscosity modifier, a stabilizer, an antifoaming agent, an antimicrobial agent, a preservative, a balance regulator and the like. The conventional oil agent consists of more than 90 percent of main components and less than 10 percent of auxiliary components, and is used for adjusting the friction performance of chemical fibers together, preventing or eliminating static accumulation and endowing the fibers with the performances of smoothness, bundling, static resistance, softness and the like.
The silk oil agent can adjust the friction coefficient between fibers and between metals, reduce static electricity generated by friction, enable the fibers to have good bundling property, smoothness and fiber separation property, and meet the requirements of relevant procedures of fiber post-processing. In general, a chinlon spinning oil agent mainly comprises a wetting agent, a bundling agent, a smoothing agent, an emulsifier, an antistatic agent and the like. The common filament oiling agent has the main functions of smoothly winding oiled fibers, forming a filament tube well, reducing broken filaments and broken ends in a drawing process and ensuring normal drawing. Therefore, the oil agent is required to have good antistatic properties, moderate wettability, fiber cohesion, smoothness, high temperature resistance, and low volatility. In recent years, with the high-speed spinning of the nylon industry, the development of fine denier, functionalization and greenization of fibers, higher performance requirements are put forward on the performance of nylon spinning oil.
However, most of the existing nylon spinning oil agents in the current market have the following defects, including: some cotton spinning oil agents have poor heat resistance, oxidation resistance and oxidation resistance, and are easy to yellow nylon fibers, so that great loss is caused; the emulsifier in some nylon spinning oil contains APEO (ammonium polyoxyethylene ether), and APEO is an environmental hormone substance, which causes difficulty in product export of downstream printing and dyeing enterprises and causes environmental pollution and ecological hazard; in addition, some nylon spinning oil agents in the current market have poor emulsibility, so that the oil agents on the yarns are not easy to clean, and further, the subsequent dyeing is influenced. Particularly, the antistatic property of the cotton spinning oil agent needs to be further improved, phosphate ester is generally adopted as an antistatic agent in the market, which can only ensure that the oil agent has good antistatic property under high humidity, but under the condition of low humidity, the antistatic effect is greatly reduced, so that the phenomena of winding and end breakage caused by poor antistatic property often occur in dry seasons or northern areas.
Disclosure of Invention
The technical problems to be solved by the invention are as follows: aiming at the problems that winding and broken ends occur due to poor antistatic performance of the existing spinning oil and the fabric is easy to yellow due to easy oxidation of the oil agent, the antioxidant antistatic spinning oil is provided.
In order to solve the technical problems, the invention adopts the following technical scheme:
an antioxidant antistatic spinning oil comprises the following components of 100-150 parts of a spinning oil base material, 1-3 parts of polyoxyethylene laurate, 1-3 parts of polyethylene glycol oleate, 5-15 parts of an antistatic active agent, 3-9 parts of a spinning oil smoothing active agent and 2-5 parts of an oil antioxidant active agent;
the preparation method of the antistatic active agent comprises the following steps: taking phosphorus oxychloride according to a mass ratio of 3-6: 1-5: 10-20, adding propyl trichlorosilane and an alcohol additive, stirring and mixing at 40-50 ℃ to obtain a mixture a, and mixing the mixture a according to a mass ratio of 3-7: 10-20, adding diethylene glycol dimethyl ether, stirring and mixing at 100-110 ℃, cooling to room temperature to obtain a cooling material, and taking the cooling material according to a mass ratio of 2-5: 10-15, adding absolute ethyl alcohol, standing, distilling the precipitate under reduced pressure, and drying to obtain the antistatic active agent.
The preparation method of the alcohol additive comprises the following steps: taking active raw materials according to a mass ratio of 2-6: 5-8: adding 50-70 parts of n-decyl glycidyl ether and deionized water, adding a catalyst accounting for 5-10% of the mass of the active raw materials, stirring and mixing, introducing hydrogen for reaction, keeping the reaction at the temperature of 150-200 ℃ under 8MPa for 4-7 hours, cooling to room temperature, filtering, and taking the filtrate to obtain the alcohol additive.
The active raw materials are as follows: mixing one or more of sorbitol, fructose, mannitol, galacto-oligosaccharide, maltose and lactose at any mass ratio.
The preparation method of the catalyst comprises the following steps: according to the mass parts, 10-15 parts of cerium nitrate, 3-7 parts of cobalt nitrate, 5-9 parts of gallium nitrate and 80-100 parts of deionized water are stirred and mixed at 40-50 ℃ to obtain a mixture, and the mixture is taken according to the mass ratio of 20-50: and 3-5, adding tartaric acid, heating to 70-80 ℃, stirring and mixing, adding ethylene glycol accounting for 20-30% of the weight of the tartaric acid, stirring and mixing at 80-90 ℃, performing suction filtration, drying suction filtration residues, calcining at 600-700 ℃, and cooling to room temperature to obtain the catalyst.
The preparation method of the spinning oil smoothing active agent comprises the following steps: taking an initial active agent according to the mass ratio of 5-9: 1-4, adding pyridine, introducing nitrogen for dehydration for 20-30 min to obtain a dehydrate, and taking propylene oxide according to a mass ratio of 3-7: 2-5, adding butylene oxide, adding dehydrate accounting for 2-9% of the mass of propylene oxide, introducing nitrogen for protection, heating to 120-130 ℃, preserving heat, cooling to room temperature to obtain a cooling object a, and taking the cooling object a according to the mass ratio of 40-50: and 2-5, adding oxalic acid, mixing, decoloring by using active carbon, filtering, and taking the filtrate to obtain the spinning oil smoothing activator.
The starting active agents are: mixing 5-10 parts of myristamine, 3-7 parts of lauric acid, 1-4 parts of octyldodecanol, 20-40 parts of propylene glycol and 1-3 parts of nonyl phenol according to parts by weight.
The preparation method of the oil antioxidant active agent comprises the following steps: according to the mass parts, 20-30 parts of nuclear molecule active agent, 5-8 parts of triethylamine, 1-4 parts of 4-dimethylpyridine and 40-60 parts of N, N-dimethylformamide are stirred and mixed at 20-25 ℃ to obtain a stirring mixture, and the stirring mixture is taken according to the mass ratio of 40-50: 5-9, adding an antioxidant raw material, stirring and mixing at 0-4 ℃, stirring and mixing at 20-25 ℃, and distilling under reduced pressure to obtain the antioxidant active agent of the oil.
The preparation method of the nuclear molecule active agent comprises the following steps: taking 1, 4-butanediamine according to a mass ratio of 2-5: 10-20 adding methanol, then adding methyl acrylate accounting for 20-30% of the mass of the methanol, stirring and mixing at 20-25 ℃, carrying out reduced pressure distillation to obtain a reduced pressure distillate, and taking the reduced pressure distillate according to the mass ratio of 2-6: and (3) adding methanol into the mixture 10-15, adding 1, 4-butanediamine with the mass 2-4 times that of the methanol, stirring and mixing the mixture at the temperature of 20-25 ℃, and distilling the mixture under reduced pressure to obtain the nuclear molecule active agent.
The preparation method of the antioxidant raw material comprises the following steps: taking beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid according to a mass ratio of 2-5: adding 10-20 parts of N, N-dimethylformamide, stirring and mixing at 30-40 ℃, adding 10-15% by mass of benzoyl chloride of the N, N-dimethylformamide, introducing nitrogen for protection, stirring and mixing at 30-40 ℃, and distilling under reduced pressure to obtain the antioxidant raw material.
The spinning oil base material comprises: according to the mass parts, 5-10 parts of mineral oil, 1-3 parts of amino silicone oil, 2-5 parts of castor oil and 5-10 parts of chemical fiber oil are mixed to obtain the oil.
Compared with other methods, the method has the beneficial technical effects that:
(1) the antistatic active agent prepared by the invention takes an alcohol additive as a main raw material, mainly uses acid complex gallium which is carried out by cerium nitrate, cobalt nitrate, gallium nitrate and the like as an active component to absorb CO molecules in a non-dissociative way, has the functions of CO insertion and C-C chain growth, ensures that cobalt ions and gallium ions in a crystal lattice structure of perovskite can be uniformly dispersed at the atomic level in the catalytic process, has better catalytic activity, carries out catalytic hydrogenation on fructose, mannitol, galacto-oligosaccharide and the like to improve alcohol conversion, takes the polyhydroxy compound as the raw material to introduce polyhydroxy compound, and adds n-decyl glycidyl ether to carry out dissociation of the alcohol active agent to obtain alcohol anions under the alkali catalytic condition to attack an epoxy compound to carry out ring opening to generate an alcohol ether compound, on the one hand, introduces double flame-retardant elements of silicon and phosphorus into spinning oil to form flame-retardant protection on the surface of fibers after the spinning oil is oiled, on the other hand, phosphorus trichloride and an alcohol ether compound are subjected to phosphorylation reaction, and oxygen anions in the obtained product have good hygroscopicity and hydrophilicity, so that charges generated on the surface of the fiber can be better dissipated, and the antistatic effect is improved;
(2) the spinning oil smoothing activator prepared by the invention takes myristamine, lauric acid and the like as the raw materials of the initiator, propylene oxide, butylene oxide and the like are added for reaction, the propylene oxide chain link is introduced to improve the heat resistance of the spinning oil, the initiator with short carbon chain is introduced to reduce the decomposition residue of the spinning oil, so that the coking phenomenon on the spinning surface is greatly reduced, thereby improving the phenomena of broken filaments and broken filaments of the fiber, on the other hand, introducing the starting agent raw material with larger viscosity, so that the steric hindrance between molecules of the smoothing active agent is reduced, the mutual entanglement between flexible macromolecular chains is increased, the cohesive force and the wear resistance of an oil film formed when the spinning oil is used are improved by improving the viscosity of the spinning oil, the spinning oil is well adhered to fibers, and the surface tension when the spinning oil is spread is reduced by chain link arrangement of a polyether molecular chain, so that the spinning oil is tightly arranged to form a continuous oil film for spinning protection;
(3) the antioxidant raw material prepared by the invention is prepared by taking beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid as a raw material, adding benzoyl chloride for acyl chlorination reaction, adding a nuclear molecule formed by 1, 4-butanediamine and methyl acrylate as a skeleton structure of a grafted antioxidant active agent, and carrying out amidation condensation reaction on an obtained acyl chloride product and a terminal amino group of the skeleton, on one hand, hindered phenol and tertiary amine active groups with free radical scavenging function are introduced into spinning oil to play a long-acting protection on the antioxidant performance of an oil base, on the other hand, the introduced amido bond has better polarity and stability, the antioxidant active agent is connected to keep antioxidant stability in the heating process of the spinning oil, and the antioxidant is uniformly dispersed in the oil agent by using a branched chain structure of the skeleton structure, improving the performance of the spinning oil.
Detailed Description
The preparation method of the catalyst comprises the following steps: taking 10-15 parts of cerium nitrate, 3-7 parts of cobalt nitrate, 5-9 parts of gallium nitrate and 80-100 parts of deionized water by weight, stirring and mixing at 40-50 ℃ for 20-40 min to obtain a mixture, and taking the mixture according to the mass ratio of 20-50: 3-5, adding tartaric acid, heating to 70-80 ℃, stirring and mixing for 30-60 min, adding ethylene glycol with the mass of 20-30% of that of the tartaric acid, stirring and mixing for 3-6 h at 80-90 ℃, performing suction filtration, drying suction filtration residues, calcining for 3-5 h at 600-700 ℃, and cooling to room temperature to obtain the catalyst.
The active raw materials are as follows: mixing one or more of sorbitol, fructose, mannitol, galacto-oligosaccharide, maltose and lactose at any mass ratio.
The preparation method of the alcohol additive comprises the following steps: taking active raw materials according to a mass ratio of 2-6: 5-8: adding 50-70 parts of n-decyl glycidyl ether and deionized water, adding a catalyst accounting for 5-10% of the mass of the active raw material, stirring and mixing at 800r/min for 20-40 min, introducing hydrogen for reaction, keeping at 150-200 ℃ for 4-7 h under 8MPa, cooling to room temperature, filtering, and taking the filtrate to obtain the alcohol additive.
The preparation method of the antistatic active agent comprises the following steps: taking phosphorus oxychloride according to a mass ratio of 3-6: 1-5: 10-20, adding propyl trichlorosilane and an alcohol additive, stirring and mixing at 40-50 ℃ for 1-3 hours to obtain a mixture a, and mixing the mixture a according to a mass ratio of 3-7: 10-20, adding diethylene glycol dimethyl ether, stirring and mixing at 100-110 ℃ for 3-5 h, cooling to room temperature to obtain a cooling material, and taking the cooling material according to a mass ratio of 2-5: 10-15, adding absolute ethyl alcohol, standing for 30-50 min, distilling the precipitate under reduced pressure, and drying to obtain the antistatic active agent.
The starting active agents were: mixing 5-10 parts of myristamine, 3-7 parts of lauric acid, 1-4 parts of octyldodecanol, 20-40 parts of propylene glycol and 1-3 parts of nonyl phenol according to parts by weight.
The preparation method of the spinning oil smoothing active agent comprises the following steps: taking an initial active agent according to the mass ratio of 5-9: 1-4, adding pyridine, introducing nitrogen for dehydration for 20-30 min to obtain a dehydrate, and taking propylene oxide according to a mass ratio of 3-7: 2-5, adding butylene oxide, adding dehydrate accounting for 2-9% of the mass of propylene oxide, introducing nitrogen for protection, heating to 120-130 ℃, preserving heat for 20-30 min, cooling to room temperature to obtain a cooling object a, and taking the cooling object a according to the mass ratio of 40-50: and 2-5, adding oxalic acid, mixing, decoloring by using active carbon, filtering, and taking the filtrate to obtain the spinning oil smoothing activator.
The preparation method of the nuclear molecule active agent comprises the following steps: taking 1, 4-butanediamine according to a mass ratio of 2-5: 10-20 adding methanol, then adding methyl acrylate accounting for 20-30% of the mass of the methanol, stirring and mixing at 20-25 ℃ for 18-24 h, carrying out reduced pressure distillation to obtain a reduced pressure distillate, and taking the reduced pressure distillate according to the mass ratio of 2-6: and (2) adding methanol into the mixture 10-15, adding 1, 4-butanediamine with the mass 2-4 times that of the methanol, stirring and mixing the mixture at the temperature of 20-25 ℃ for 20-24 hours, and distilling the mixture under reduced pressure to obtain the nuclear molecule active agent.
The preparation method of the antioxidant raw material comprises the following steps: taking beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid according to a mass ratio of 2-5: adding N, N-dimethylformamide into the mixture 10-20, stirring and mixing the mixture at the temperature of 30-40 ℃ for 20-40 min, adding benzoyl chloride accounting for 10-15% of the mass of the N, N-dimethylformamide, introducing nitrogen for protection, stirring and mixing the mixture at the temperature of 30-40 ℃ for 3-7 h, and distilling the mixture under reduced pressure to obtain the antioxidant raw material.
The preparation method of the oil antioxidant active agent comprises the following steps: according to the mass parts, 20-30 parts of nuclear molecule active agent, 5-8 parts of triethylamine, 1-4 parts of 4-lutidine and 40-60 parts of N, N-dimethylformamide are stirred and mixed for 40-50 min at 20-25 ℃ to obtain a stirred mixture, and the stirred mixture is taken according to the mass ratio of 40-50: 5-9, adding an antioxidant raw material, stirring and mixing at 0-4 ℃ for 30-50 min, stirring and mixing at 20-25 ℃ for 10-12 h, and distilling under reduced pressure to obtain the antioxidant active agent of the oil.
The spinning oil base material comprises: according to the mass parts, 5-10 parts of mineral oil, 1-3 parts of amino silicone oil, 2-5 parts of castor oil and 5-10 parts of chemical fiber oil are mixed to obtain the oil.
The antioxidant antistatic spinning oil comprises, by mass, 100-150 parts of a spinning oil base material, 1-3 parts of polyoxyethylene laurate, 1-3 parts of polyethylene glycol oleate, 5-15 parts of an antistatic active agent, 3-9 parts of a spinning oil smoothing active agent and 2-5 parts of an oil antioxidant active agent.
The preparation method of the catalyst comprises the following steps: taking 10 parts of cerium nitrate, 3 parts of cobalt nitrate, 5 parts of gallium nitrate and 80 parts of deionized water, stirring and mixing at 40 ℃ for 20min to obtain a mixture, and taking the mixture according to a mass ratio of 20: 3, adding tartaric acid, heating to 70 ℃, stirring and mixing for 30min, adding ethylene glycol accounting for 20% of the weight of the tartaric acid, stirring and mixing for 3h at 80 ℃, performing suction filtration, drying suction filtration residues, calcining for 3h at 600 ℃, and cooling to room temperature to obtain the catalyst.
The active raw materials are as follows: mixing sorbitol and fructose according to any mass ratio to obtain the product.
The preparation method of the alcohol additive comprises the following steps: taking active raw materials according to the mass ratio of 2: 5: adding n-decyl glycidyl ether and deionized water into 50, adding a catalyst with the mass of 5% of that of the active raw material, stirring and mixing at 800r/min for 20min, introducing hydrogen for reaction, keeping at 150 ℃ under 8MPa for 4h, cooling to room temperature, filtering, and taking the filtrate to obtain the alcohol additive.
The preparation method of the antistatic active agent comprises the following steps: taking phosphorus oxychloride according to a mass ratio of 3: 1: 10, adding propyl trichlorosilane and an alcohol additive, stirring and mixing for 1h at 40 ℃ to obtain a mixture a, and mixing the mixture a according to a mass ratio of 3: 10, adding diethylene glycol dimethyl ether, stirring and mixing for 3 hours at 100 ℃, cooling to room temperature to obtain a cooling material, and taking the cooling material according to a mass ratio of 2: 10 adding absolute ethyl alcohol, standing for 30min, taking the precipitate, distilling under reduced pressure, and drying to obtain the antistatic active agent.
The starting active agents were: mixing 5 parts of myristamine, 3 parts of lauric acid, 1 part of octyldodecanol, 20 parts of propylene glycol and 1 part of nonyl phenol according to parts by weight to obtain the composition.
The preparation method of the spinning oil smoothing active agent comprises the following steps: taking an initial active agent according to the mass ratio of 5: 1, adding pyridine, introducing nitrogen for dehydration for 20min to obtain a dehydrate, and taking propylene oxide according to a mass ratio of 3: 2, adding butylene oxide, adding dehydrate accounting for 2% of the mass of propylene oxide, introducing nitrogen for protection, heating to 120 ℃, preserving the heat for 20min, cooling to room temperature to obtain a cooling object a, and taking the cooling object a according to a mass ratio of 40: 2, adding oxalic acid, mixing, decoloring by active carbon, filtering, and taking the filtrate to obtain the spinning oil smoothing active agent.
The preparation method of the nuclear molecule active agent comprises the following steps: taking 1, 4-butanediamine according to a mass ratio of 2: 10, adding methanol, adding methyl acrylate accounting for 20% of the mass of the methanol, stirring and mixing for 18 hours at 20 ℃, carrying out reduced pressure distillation to obtain a reduced pressure distillate, and taking the reduced pressure distillate according to the mass ratio of 2: 10 adding methanol, adding 1, 4-butanediamine 2 times of the mass of the methanol, stirring and mixing for 20 hours at the temperature of 20 ℃, and distilling under reduced pressure to obtain the nuclear molecule active agent.
The preparation method of the antioxidant raw material comprises the following steps: taking beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid according to the mass ratio of 2: 10 adding N, N-dimethylformamide, stirring and mixing for 20min at 30 ℃, adding 10 mass percent of benzoyl chloride of the N, N-dimethylformamide, introducing nitrogen for protection, stirring and mixing for 3h at 30 ℃, and distilling under reduced pressure to obtain the antioxidant raw material.
The preparation method of the oil antioxidant active agent comprises the following steps: according to the mass parts, 20 parts of nuclear molecule active agent, 5 parts of triethylamine, 1 part of 4-dimethylpyridine and 40 parts of N, N-dimethylformamide are stirred and mixed for 40min at 20 ℃ to obtain a stirred mixture, and the stirred mixture is taken according to the mass ratio of 40: 5 adding antioxidant raw materials, stirring and mixing at 0 deg.C for 30min, stirring and mixing at 20 deg.C for 10 hr, and distilling under reduced pressure to obtain antioxidant active agent.
The spinning oil base material comprises: according to the mass parts, 5 parts of mineral oil, 1 part of amino silicone oil, 2 parts of castor oil and 5 parts of chemical fiber oil are mixed to obtain the oil.
The antioxidant antistatic spinning oil comprises, by mass, 100 parts of a spinning oil base material, 1 part of polyoxyethylene laurate, 1 part of polyethylene glycol oleate, 5 parts of an antistatic active agent, 3 parts of a spinning oil smoothing active agent and 2 parts of an oil antioxidant active agent.
The preparation method of the catalyst comprises the following steps: taking 12 parts of cerium nitrate, 5 parts of cobalt nitrate, 7 parts of gallium nitrate and 90 parts of deionized water in parts by mass, stirring and mixing at 45 ℃ for 30min to obtain a mixture, and taking the mixture according to a mass ratio of 35: 4, adding tartaric acid, heating to 75 ℃, stirring and mixing for 45min, adding ethylene glycol accounting for 25% of the weight of the tartaric acid, stirring and mixing for 5h at 85 ℃, performing suction filtration, drying suction filtration residues, calcining for 4h at 650 ℃, and cooling to room temperature to obtain the catalyst.
The active raw materials are as follows: mixing mannitol and galacto-oligosaccharide at any mass ratio.
The preparation method of the alcohol additive comprises the following steps: taking active raw materials according to a mass ratio of 4: 6: 60 adding n-decyl glycidyl ether and deionized water, adding a catalyst accounting for 8% of the mass of the active raw material, stirring and mixing at 800r/min for 30min, introducing hydrogen for reaction, keeping at 175 ℃ under 8MPa for 5h, cooling to room temperature, filtering, and taking the filtrate to obtain the alcohol additive.
The preparation method of the antistatic active agent comprises the following steps: taking phosphorus oxychloride according to a mass ratio of 5: 3: 15, adding propyl trichlorosilane and an alcohol additive, stirring and mixing for 2 hours at 45 ℃ to obtain a mixture a, and mixing the mixture a according to a mass ratio of 5: adding diethylene glycol dimethyl ether 15, stirring and mixing at 105 ℃ for 4 hours, cooling to room temperature to obtain a cooling material, and taking the cooling material according to a mass ratio of 4: 12 adding absolute ethyl alcohol, standing for 40min, distilling the precipitate under reduced pressure, and drying to obtain the antistatic active agent.
The starting active agents were: according to the mass parts, 8 parts of myristamine, 5 parts of lauric acid, 3 parts of octyldodecanol, 30 parts of propylene glycol and 2 parts of nonyl phenol are mixed to obtain the composition.
The preparation method of the spinning oil smoothing active agent comprises the following steps: taking an initial active agent according to the mass ratio of 7: 3, adding pyridine, introducing nitrogen for dehydration for 25min to obtain a dehydrate, and taking propylene oxide according to a mass ratio of 5: 3, adding butylene oxide, adding dehydrate accounting for 5% of the mass of propylene oxide, introducing nitrogen for protection, heating to 125 ℃, preserving the heat for 25min, cooling to room temperature to obtain a cooling object a, and taking the cooling object a according to a mass ratio of 45: 3, adding oxalic acid, mixing, decoloring by active carbon, filtering, and taking the filtrate to obtain the spinning oil smoothing active agent.
The preparation method of the nuclear molecule active agent comprises the following steps: taking 1, 4-butanediamine according to a mass ratio of 4: 15, adding methanol, adding methyl acrylate accounting for 25% of the mass of the methanol, stirring and mixing for 21 hours at 22 ℃, carrying out reduced pressure distillation to obtain a reduced pressure distillate, and taking the reduced pressure distillate according to a mass ratio of 4: 12 adding methanol, adding 1, 4-butanediamine with the mass of 3 times of that of the methanol, stirring and mixing for 22 hours at the temperature of 22 ℃, and distilling under reduced pressure to obtain the nuclear molecule active agent.
The preparation method of the antioxidant raw material comprises the following steps: taking beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid according to a mass ratio of 4: 15 adding N, N-dimethylformamide, stirring and mixing at 35 ℃ for 30min, adding benzoyl chloride accounting for 12% of the mass of the N, N-dimethylformamide, introducing nitrogen for protection, stirring and mixing at 35 ℃ for 5h, and distilling under reduced pressure to obtain the antioxidant raw material.
The preparation method of the oil antioxidant active agent comprises the following steps: according to the mass parts, 25 parts of nuclear molecule active agent, 6 parts of triethylamine, 3 parts of 4-dimethylpyridine and 50 parts of N, N-dimethylformamide are stirred and mixed for 45min at 23 ℃ to obtain a stirred mixture, and the stirred mixture is taken according to the mass ratio of 45: 7 adding antioxidant raw materials, stirring and mixing at 2 deg.C for 40min, stirring and mixing at 23 deg.C for 11h, and distilling under reduced pressure to obtain antioxidant active agent.
The spinning oil base material comprises: according to the mass portion, 7 portions of mineral oil, 2 portions of amino silicone oil, 4 portions of castor oil and 8 portions of chemical fiber oil are mixed to obtain the product.
An antioxidant antistatic spinning oil comprises, by mass, 125 parts of a spinning oil base material, 2 parts of polyoxyethylene laurate, 2 parts of polyethylene glycol oleate, 10 parts of an antistatic active agent, 6 parts of a spinning oil smoothing active agent and 4 parts of an oil antioxidant active agent.
The preparation method of the catalyst comprises the following steps: taking 15 parts of cerium nitrate, 7 parts of cobalt nitrate, 9 parts of gallium nitrate and 100 parts of deionized water in parts by mass, stirring and mixing at 50 ℃ for 40min to obtain a mixture, and taking the mixture according to a mass ratio of 50: and 5, adding tartaric acid, heating to 80 ℃, stirring and mixing for 60min, adding ethylene glycol accounting for 30% of the weight of the tartaric acid, stirring and mixing for 6h at 90 ℃, performing suction filtration, drying suction filtration residues, calcining for 5h at 700 ℃, and cooling to room temperature to obtain the catalyst.
The active raw materials are as follows: mixing maltose and lactose at any mass ratio.
The preparation method of the alcohol additive comprises the following steps: taking active raw materials according to the mass ratio of 6: 8: adding 70 n-decyl glycidyl ether and deionized water, adding 10% of catalyst by mass of active raw material, stirring and mixing at 800r/min for 40min, introducing hydrogen gas for reaction, keeping at 200 ℃ under 8MPa for 7h, cooling to room temperature, filtering, and collecting filtrate to obtain the alcohol additive.
The preparation method of the antistatic active agent comprises the following steps: taking phosphorus oxychloride according to a mass ratio of 6: 5: 20, adding propyl trichlorosilane and an alcohol additive, stirring and mixing for 3 hours at 50 ℃ to obtain a mixture a, and mixing the mixture a according to a mass ratio of 7: 20 adding diethylene glycol dimethyl ether, stirring and mixing for 5 hours at 110 ℃, cooling to room temperature to obtain a cooling material, and taking the cooling material according to the mass ratio of 5: 15 adding absolute ethyl alcohol, standing for 50min, taking the precipitate, distilling under reduced pressure, and drying to obtain the antistatic active agent.
The starting active agents were: according to the mass parts, 10 parts of myristamine, 7 parts of lauric acid, 4 parts of octyldodecanol, 40 parts of propylene glycol and 3 parts of nonyl phenol are mixed to obtain the composition.
The preparation method of the spinning oil smoothing active agent comprises the following steps: taking an initial active agent according to the mass ratio of 9: 4, adding pyridine, introducing nitrogen for dehydration for 30min to obtain a dehydrate, and taking propylene oxide according to a mass ratio of 7: and 5, adding butylene oxide, adding dehydrate accounting for 9% of the mass of propylene oxide, introducing nitrogen for protection, heating to 130 ℃, preserving the heat for 30min, cooling to room temperature to obtain a cooling object a, and taking the cooling object a according to the mass ratio of 50: and 5, adding oxalic acid, mixing, decoloring by using active carbon, filtering, and taking filtrate to obtain the spinning oil smoothing active agent.
The preparation method of the nuclear molecule active agent comprises the following steps: taking 1, 4-butanediamine according to a mass ratio of 5: 20, adding methanol, adding methyl acrylate accounting for 30% of the mass of the methanol, stirring and mixing for 24 hours at 25 ℃, carrying out reduced pressure distillation to obtain a reduced pressure distillate, and taking the reduced pressure distillate according to the mass ratio of 6: adding methanol 15, adding 1, 4-butanediamine 4 times of methanol, stirring and mixing at 25 deg.C for 24 hr, and distilling under reduced pressure to obtain nuclear molecule active agent.
The preparation method of the antioxidant raw material comprises the following steps: taking beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid according to the mass ratio of 5: 20 adding N, N-dimethylformamide, stirring and mixing at 40 deg.C for 40min, adding benzoyl chloride 15% of the mass of N, N-dimethylformamide, introducing nitrogen for protection, stirring and mixing at 40 deg.C for 7h, and distilling under reduced pressure to obtain antioxidant raw material.
The preparation method of the oil antioxidant active agent comprises the following steps: according to the mass parts, 30 parts of nuclear molecule active agent, 8 parts of triethylamine, 4 parts of 4-dimethylpyridine and 60 parts of N, N-dimethylformamide are stirred and mixed for 50min at 25 ℃ to obtain a stirred mixture, and the stirred mixture is taken according to the mass ratio of 50: 9 adding antioxidant raw materials, stirring and mixing at 4 deg.C for 50min, stirring and mixing at 25 deg.C for 12 hr, and distilling under reduced pressure to obtain antioxidant active agent.
The spinning oil base material comprises: according to the mass parts, 10 parts of mineral oil, 3 parts of amino silicone oil, 5 parts of castor oil and 10 parts of chemical fiber oil are mixed to obtain the oil.
An antioxidant antistatic spinning oil comprises, by mass, 150 parts of a spinning oil base material, 3 parts of polyoxyethylene laurate, 3 parts of polyethylene glycol oleate, 15 parts of an antistatic active agent, 9 parts of a spinning oil smoothing active agent and 5 parts of an oil antioxidant active agent.
Comparative example 1: essentially the same procedure as in example 1 was followed, except that the antistatic active agent was absent.
Comparative example 2: essentially the same procedure as in example 1 except that spin oil smoothing actives were absent.
Comparative example 3: essentially the same procedure as in example 1, except that the oil antioxidant active was absent.
Comparative example 4: an antioxidant antistatic spinning oil produced by a certain company in Nanjing.
The antioxidant antistatic spinning oils obtained in the examples and comparative examples were tested according to GB/T14342-1993, and the test results are shown in Table 1:
table 1:
| test items | Example 1 | Example 2 | Example 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 |
| Surface static electricity (kv) | 0.07 | 0.08 | 0.12 | 0.10 | 0.18 | 0.20 | 0.28 |
| Oil application Rate (%) | 1.20 | 1.15 | 1.19 | 1.02 | 1.07 | 1.12 | 0.89 |
| Breaking strength (g) | 53.1 | 52.5 | 51.6 | 52.9 | 51.9 | 52.3 | 48.6 |
| Oxidation resistance | Is preferably used | Is preferably used | Is preferably used | Is preferably used | In general | In general | Is poor |
In conclusion, the antioxidant antistatic spinning oil obtained by the invention has good antistatic property and uniform oiling, has better effect compared with a commercially available product, and is worthy of great popularization.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, but rather as the subject matter of the invention is to be construed in all aspects and as broadly as possible, and all changes, equivalents and modifications that fall within the true spirit and scope of the invention are therefore intended to be embraced therein.
Claims (4)
1. An antioxidant antistatic spinning oil comprises, by mass, 100-150 parts of a spinning oil base material, 1-3 parts of polyoxyethylene laurate and 1-3 parts of polyethylene glycol oleate, and is characterized by further comprising 5-15 parts of an antistatic active agent, 3-9 parts of a spinning oil smoothing active agent and 2-5 parts of an oil antioxidant active agent;
the spinning oil base material comprises: mixing 5-10 parts of mineral oil, 1-3 parts of amino silicone oil, 2-5 parts of castor oil and 5-10 parts of chemical fiber oil according to parts by weight to obtain the composite material;
the preparation method of the antistatic active agent comprises the following steps: taking phosphorus oxychloride according to a mass ratio of 3-6: 1-5: 10-20, adding propyl trichlorosilane and an alcohol additive, stirring and mixing at 40-50 ℃ to obtain a mixture a, and mixing the mixture a according to a mass ratio of 3-7: 10-20, adding diethylene glycol dimethyl ether, stirring and mixing at 100-110 ℃, cooling to room temperature to obtain a cooling material, and taking the cooling material according to a mass ratio of 2-5: 10-15, adding absolute ethyl alcohol, standing, distilling the precipitate under reduced pressure, and drying to obtain the antistatic active agent;
the preparation method of the spinning oil smoothing active agent comprises the following steps: taking an initial active agent according to the mass ratio of 5-9: 1-4, adding pyridine, introducing nitrogen for dehydration for 20-30 min to obtain a dehydrate, and taking propylene oxide according to a mass ratio of 3-7: 2-5, adding butylene oxide, adding dehydrate accounting for 2-9% of the mass of propylene oxide, introducing nitrogen for protection, heating to 120-130 ℃, preserving heat, cooling to room temperature to obtain a cooling object a, and taking the cooling object a according to the mass ratio of 40-50: 2-5, adding oxalic acid, mixing, decoloring by active carbon, filtering, and taking the filtrate to obtain a spinning oil smoothing activator; the starting active agents are: mixing 5-10 parts of myristamine, 3-7 parts of lauric acid, 1-4 parts of octyldodecanol, 20-40 parts of propylene glycol and 1-3 parts of nonyl phenol according to parts by weight to obtain the composition;
the preparation method of the oil antioxidant active agent comprises the following steps: according to the mass parts, 20-30 parts of nuclear molecule active agent, 5-8 parts of triethylamine, 1-4 parts of 4-dimethylpyridine and 40-60 parts of N, N-dimethylformamide are stirred and mixed at 20-25 ℃ to obtain a stirring mixture, and the stirring mixture is taken according to the mass ratio of 40-50: 5-9, adding an antioxidant raw material, stirring and mixing at 0-4 ℃, stirring and mixing at 20-25 ℃, and distilling under reduced pressure to obtain an oil antioxidant active agent; the preparation method of the nuclear molecule active agent comprises the following steps: taking 1, 4-butanediamine according to a mass ratio of 2-5: 10-20 adding methanol, then adding methyl acrylate accounting for 20-30% of the mass of the methanol, stirring and mixing at 20-25 ℃, carrying out reduced pressure distillation to obtain a reduced pressure distillate, and taking the reduced pressure distillate according to the mass ratio of 2-6: adding 10-15 times of methanol, adding 1, 4-butanediamine 2-4 times of the mass of the methanol, stirring and mixing at 20-25 ℃, and carrying out reduced pressure distillation to obtain a nuclear molecule active agent; the preparation method of the antioxidant raw material comprises the following steps: taking beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid according to a mass ratio of 2-5: adding 10-20 parts of N, N-dimethylformamide, stirring and mixing at 30-40 ℃, adding 10-15% by mass of benzoyl chloride of the N, N-dimethylformamide, introducing nitrogen for protection, stirring and mixing at 30-40 ℃, and distilling under reduced pressure to obtain the antioxidant raw material.
2. The antioxidant antistatic spinning oil of claim 1, wherein the alcohol additive is prepared by the following method: taking active raw materials according to a mass ratio of 2-6: 5-8: adding 50-70 parts of n-decyl glycidyl ether and deionized water, adding a catalyst accounting for 5-10% of the mass of the active raw materials, stirring and mixing, introducing hydrogen for reaction, keeping the reaction at the temperature of 150-200 ℃ under 8MPa for 4-7 hours, cooling to room temperature, filtering, and taking the filtrate to obtain the alcohol additive.
3. The antioxidant antistatic spinning oil of claim 2, wherein the active raw materials are: mixing one or more of sorbitol, fructose, mannitol, galacto-oligosaccharide, maltose and lactose at any mass ratio.
4. The antioxidant antistatic spinning oil as claimed in claim 2, wherein the catalyst is prepared by the following method: according to the mass parts, 10-15 parts of cerium nitrate, 3-7 parts of cobalt nitrate, 5-9 parts of gallium nitrate and 80-100 parts of deionized water are stirred and mixed at 40-50 ℃ to obtain a mixture, and the mixture is taken according to the mass ratio of 20-50: and 3-5, adding tartaric acid, heating to 70-80 ℃, stirring and mixing, adding ethylene glycol accounting for 20-30% of the weight of the tartaric acid, stirring and mixing at 80-90 ℃, performing suction filtration, drying suction filtration residues, calcining at 600-700 ℃, and cooling to room temperature to obtain the catalyst.
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| CN115701843B (en) * | 2022-11-21 | 2023-12-15 | 上海丰泽源科技有限公司 | Ultraviolet-resistant special environment-friendly spinning oil for ATY fibers and preparation method thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0268370A (en) * | 1988-08-29 | 1990-03-07 | Sanyo Chem Ind Ltd | Aqueous emulsion-type spinning lubricant and usage therefor |
| JPH03213576A (en) * | 1990-01-17 | 1991-09-18 | Toray Ind Inc | Treating lubricant for synthetic fiber intended for fluid jet processing |
| CN101139425A (en) * | 2006-09-05 | 2008-03-12 | 中国石油天然气集团公司 | Method for synthesizing polyvinyl chloride modifier |
| CN103147168A (en) * | 2013-03-06 | 2013-06-12 | 常州市灵达化学品有限公司 | Spinning finish and preparation method thereof |
| CN104179005A (en) * | 2014-08-15 | 2014-12-03 | 上海中孚特种油品有限公司 | Fiber fully drawn yarn (FDY) spinning oil and preparation method thereof |
| CN104725668A (en) * | 2015-03-10 | 2015-06-24 | 三峡大学 | Fluorophenyl and phosphate structure-containing novel phosphorus-silicon flame retardant and preparation method and application thereof |
| CN105064019A (en) * | 2015-07-31 | 2015-11-18 | 浙江皇马科技股份有限公司 | Nylon 6 short fiber spinning oil agent, preparation method and application thereof |
| BE1023475B1 (en) * | 2016-06-09 | 2017-04-03 | Vertexco Nv | METHOD FOR MANUFACTURING A SPIN OIL |
| CN107674745A (en) * | 2017-10-18 | 2018-02-09 | 上海都伟光伏科技有限公司 | A kind of diamond wire metalworking coolant and application |
| CN108671960A (en) * | 2018-05-02 | 2018-10-19 | 中山大学 | A kind of high hydrothermal stability MOFs catalyst, the method for preparing and preparing chemicals for cellulose conversion |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140154457A1 (en) * | 2012-12-05 | 2014-06-05 | Arrowstar Llc | Lubricant compositions useful in the production of synthetic fibers |
-
2019
- 2019-01-12 CN CN201910028968.8A patent/CN109763326B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0268370A (en) * | 1988-08-29 | 1990-03-07 | Sanyo Chem Ind Ltd | Aqueous emulsion-type spinning lubricant and usage therefor |
| JPH03213576A (en) * | 1990-01-17 | 1991-09-18 | Toray Ind Inc | Treating lubricant for synthetic fiber intended for fluid jet processing |
| CN101139425A (en) * | 2006-09-05 | 2008-03-12 | 中国石油天然气集团公司 | Method for synthesizing polyvinyl chloride modifier |
| CN103147168A (en) * | 2013-03-06 | 2013-06-12 | 常州市灵达化学品有限公司 | Spinning finish and preparation method thereof |
| CN104179005A (en) * | 2014-08-15 | 2014-12-03 | 上海中孚特种油品有限公司 | Fiber fully drawn yarn (FDY) spinning oil and preparation method thereof |
| CN104725668A (en) * | 2015-03-10 | 2015-06-24 | 三峡大学 | Fluorophenyl and phosphate structure-containing novel phosphorus-silicon flame retardant and preparation method and application thereof |
| CN105064019A (en) * | 2015-07-31 | 2015-11-18 | 浙江皇马科技股份有限公司 | Nylon 6 short fiber spinning oil agent, preparation method and application thereof |
| BE1023475B1 (en) * | 2016-06-09 | 2017-04-03 | Vertexco Nv | METHOD FOR MANUFACTURING A SPIN OIL |
| CN107674745A (en) * | 2017-10-18 | 2018-02-09 | 上海都伟光伏科技有限公司 | A kind of diamond wire metalworking coolant and application |
| CN108671960A (en) * | 2018-05-02 | 2018-10-19 | 中山大学 | A kind of high hydrothermal stability MOFs catalyst, the method for preparing and preparing chemicals for cellulose conversion |
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