CN109762428A - A kind of water-repellent paint and its construction method for garden path - Google Patents
A kind of water-repellent paint and its construction method for garden path Download PDFInfo
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Abstract
The invention discloses a kind of water-repellent paint for garden path, including liquid material and powder, the mass ratio of the liquid material and powder is (0.8-1.2): 1；The liquid material includes the component of following parts by weight: 80-85 parts of water-proof emulsion, 0.5-0.8 parts of defoaming agent, 1-2 parts of dispersing agent, 6-8 parts of coalescing agent, 2-3 parts of levelling agent, 20-25 parts of water, 0.4-0.6 parts of preservative；The powder includes the component of following parts by weight: 40-50 parts of cement, 15-20 parts of silica flour, 15-20 parts of diamond dust, 3-7 parts of organo montmorillonite, 6-8 parts of tourmaline powder.Water-repellent paint has many advantages, such as adhesion strength height, weatherability height, good waterproof performance, easily constructs, is nontoxic.Film layer has waterproof but ventilative characteristic simultaneously, therefore tourmaline powder can contact with air and discharge anion largely beneficial to human health, anion in conjunction with the pollutant in air after can be degraded, and then improvement air quality is good for the environment.
Description
Technical field
The present invention relates to gardens bridge deck water-proof, in particular to a kind of water-repellent paint and its construction party for garden path
Method.
Background technique
Garden path is to be built in garden landscape and the road and bridge current for people, bridge include wooden bridge, stone bridge,
Reinforced concrete bridge etc..Wherein wooden bridge and reinforced concrete bridge are required to carry out water-proofing treatment after the completion of building, and avoid timber rotten
The trouble that rotten, reinforcing bar gets rusty improves the service life of bridge, and brushing water-repellent paint is a kind of water-proofing treatment mode.
Notification number is that the Chinese patent of CN106634603B discloses a kind of bridge floor waterproofing paint, by weight, including
Following components: the drift-sand of 3~20 parts by weight, the 90# asphalt of 5~16 parts by weight, 5~10 parts by weight nanometer titanium dioxide
Titanium, the boccaro of 5~10 parts by weight, the precipitated calcium carbonate of 5~10 parts by weight, the KH-560 of 1~5 parts by weight, 1~5 parts by weight
KH-550, the epoxy-capped polyetheramine of 5~10 parts by weight, 8~10 parts by weight beta-cyclodextrin modified amido block sulfonated polyphenyl
And the 1,4,5,8 naphthalenetetracarboxylic acid acid anhydride of imidazoles, 4~6 parts by weight, the 8- naphthylamines -1- sulfonic acid of 1~4 parts by weight, 3~5 parts by weight
1,5- naphthalenedisulfonic acid, the dodecanedioic acid of 5~10 parts by weight, the dimethyl sulfoxide of 20~50 parts by weight and 50~100 weight
The deionized water of part.
Above-mentioned water-repellent paint can be used for carrying out bridge deck water-proof processing, but its main water-repellent substance pitch has certain poison
Property, benzene class toxic gas can be released, air pollution is caused, and is easy to influence green plant growth, is not suitable for needing with fresh air
Gardens, have much room for improvement.
Summary of the invention
In view of the above technical defects, the object of the present invention is to provide a kind of water-repellent paint for garden path, environmentally friendly nothings
Pollution and good water-proof effect.
To achieve the above object, the present invention provides the following technical scheme that
The mass ratio of a kind of water-repellent paint for garden path, including liquid material and powder, the liquid material and powder is (0.8-
1.2):1；
The liquid material includes the component of following parts by weight:
80-85 parts of water-proof emulsion
0.5-0.8 parts of defoaming agent
1-2 parts of dispersing agent
6-8 parts of coalescing agent
2-3 parts of levelling agent
20-25 parts of water
0.4-0.6 parts of preservative；
The powder includes the component of following parts by weight:
40-50 parts of cement
15-20 parts of silica flour
15-20 parts of diamond dust
3-7 parts of organo montmorillonite
6-8 parts of tourmaline powder；
The water-proof emulsion the preparation method is as follows:
Step 1, by perfluor alkyl ethyl acrylate, methacrylic acid octadecyl, hydroxypropyl acrylate, to chloromethylbenzene
Ethylene is mixed and stirred for uniformly, obtaining mixed liquor by equal mass ratioes；
5-7 parts of emulsifiers and 30-40 parts of water are mixed by weight, are heated to 75-80 DEG C and keep the temperature, led to by step 2
Nitrogen protection 10-20min adds 40-50 portions of mixed liquors, 0.8-1 parts of ammonium persulfates, reacts 1-2h；
Step 3, while 40-50 portions of mixed liquors, 0.8-1 parts of ammonium persulfates are added dropwise, charging is completed in control in 2-3h, is finally existed
75-85 DEG C of heat preservation is lower to react 3-4h, and cooling discharging obtains water-proof emulsion.
By using above-mentioned technical proposal, powder is used for rigid waterproofing, stronger with being tightly combined property of concrete structure, durable
Property is good；Liquid material is used for flexible water, and waterproof performance is good.Be coated on bridge floor after the two mixing, hydration reaction through cement and
The advantages of moisture evaporation of lotion forms one layer of uniform and flexible film, has both the two has adhesion strength high, resistance to
Hou Xinggao, good waterproof performance, easy the advantages that constructing, is nontoxic.
Contain a large amount of benzene ring structures, fluorine and chlorine in water-proof emulsion structural molecule, after it forms film layer, fluorine element migration
Surface water repellency is improved to film surface, and then improves waterproof performance, chlorine element is distributed in substrate surface, and then improves film
Bond strength between layer and base.Film layer has waterproof but ventilative characteristic simultaneously, therefore tourmaline powder can connect with air
Touching and discharge the largely anion beneficial to human health, anion in conjunction with the pollutant in air after can be degraded,
And then improve air quality, it is good for the environment.
Organo montmorillonite can be such that the waterproof performance of coating improves because of its laminated structure；Tourmaline powder is in addition to that can discharge
Outside environmentally friendly anion, moreover it is possible to improve film layer compactness as ultra-fine filling material, and then improve waterproof performance.
The present invention is further arranged to: the emulsifier includes OBS, SDS, OP-10, the matter of described OBS, SDS, OP-10
Amount is than being 2:1:2.
By using above-mentioned technical proposal, there are synergistic functions between three, and emulsifying effectiveness is good, the anti-water and milk of generation
Liquid is stable, solid content is high, waterproof performance is good.
The present invention is further arranged to: the powder further includes 8-10 parts of nano-titanium dioxides.
By using above-mentioned technical proposal, nano-titanium dioxide on the one hand can promote tourmaline powder release more bear from
On the other hand son is used as filler, can be improved the performances such as drying time, ageing-resistant, corrosion-resistant, waterproof, the bond strength of film layer,
And with water-proof emulsion it is compound after, using bionics principle, what the hydrophobic group and nano-titanium dioxide of film surface were formed
Binary coarse structure makes it have excellent waterproof performance and self-cleaning performance.
The present invention is further arranged to: the defoaming agent is dimethyl silicone polymer.
By using above-mentioned technical proposal, dimethyl silicone polymer is good to the defoaming effect of water-proof emulsion, and then is conducive to
Improve the adhesion strength of film layer.
The present invention is further arranged to: the dispersing agent is Sodium Polyacrylate.
By using above-mentioned technical proposal, Sodium Polyacrylate is good to the dispersion effect of powder, helps to improve waterproof effect
And anion burst size.
The present invention is further arranged to: the dipropylene glycol methyl ether and dipropylene glycol that the coalescing agent is 1:1 by mass ratio
Butyl ether compounds.
By using above-mentioned technical proposal, film layer synthesis speed is improved and Forming Quality is good.
The present invention is further arranged to: the powder further includes 3-5 parts of active hollow carbon fibers.
By using above-mentioned technical proposal, on the one hand active hollow carbon fiber is used as filler, improves the mechanical performance of film layer；
On the other hand it can adsorb polluter and cooperate anion degradation treatment with adsorptivity, while its hollow structure is advantageous
In improving the gas permeability of film layer without will affect waterproofness, and then improve tourmaline powder anion burst size.
It is a further object of the present invention to provide a kind of construction methods of water-repellent paint for garden path.
A kind of construction method of the water-repellent paint for garden path, includes the following steps:
The preparation of S1 liquid material: it after liquid material each component is weighed by deal needed for being formulated, is mixed and stirred for uniformly；
The preparation of S2 powder: it after powder each component is weighed by deal needed for being formulated, is mixed and stirred for uniformly；
S3 coating preparation: liquid material and powder are mixed and stirred for uniformly；
S4 is brushed: being brushed in three times after base treatment, makes coating dry film with a thickness of 1.8-2.0mm.
In conclusion the invention has the following advantages:
1. water-repellent paint has many advantages, such as adhesion strength height, weatherability height, good waterproof performance, easily constructs, is nontoxic；
2. there is more excellent waterproof for water-proof emulsion is compared to silicone acrylic emulsion more popular on the market, styrene-acrylic emulsion
Performance simultaneously has both certain air permeability energy；
3. the compounding of active hollow carbon fiber and tourmaline powder, can release a large amount of anions, so that the pollutant in air
It can be removed, be conducive to environmental protection and human health.
Detailed description of the invention
Fig. 1 is the flow diagram of embodiment one to three.
Specific embodiment
Below in conjunction with attached drawing, invention is further described in detail.
Embodiment one:
A kind of water-repellent paint for garden path, the concrete structure bridge suitable for gardens are matched by liquid material and powder mixing
It makes, the mass ratio of liquid material and powder is 0.8:1.
Liquid material includes the component of following parts by weight:
80 parts of water-proof emulsion；
0.5 part of dimethyl silicone polymer；
1 part of Sodium Polyacrylate；
6 parts of coalescing agent, coalescing agent is compounded by the dipropylene glycol methyl ether that mass ratio is 1:1 and dipropylene；
It 2 parts of levelling agent, model BYK-333, buys from Bi Ke chemical company, Germany；
20 parts of water；
It 0.4 part of preservative, model ZB-101, buys from Jinan Zhong Bei Fine Chemical Co., Ltd.
Powder includes the component of following parts by weight:
40 parts of portland cement 42.5R；
15 parts of silica flour；
15 parts of diamond dust；
It 3 parts of organo montmorillonite, buys from Lingshou County Xin Bin mineral products processing factory；
6 parts of tourmaline powder, 1250 mesh；
8 parts of nano-titanium dioxide, partial size 20nm；
It 3 parts, i.e. ACHF of active hollow carbon fiber, buys from toray.
Water-proof emulsion the preparation method is as follows:
Step 1, by perfluor alkyl ethyl acrylate, methacrylic acid octadecyl, hydroxypropyl acrylate, to chloromethylbenzene
Ethylene is mixed and stirred for uniformly, obtaining mixed liquor by equal mass ratioes；
5 parts of emulsifiers and 30 parts of water are mixed by weight, are heated to 75 DEG C and keep the temperature, lead to nitrogen protection by step 2
10min adds 40 portions of mixed liquors, 0.8 part of ammonium persulfate, reacts 1h；
Step 3, while 40 portions of mixed liquors, 0.8 part of ammonium persulfate are added dropwise, charging is completed in control in 2h, is finally kept the temperature at 75 DEG C
Lower reaction 3h, cooling discharging obtain water-proof emulsion.
Emulsifier includes OBS, SDS, OP-10, and the mass ratio of OBS, SDS, OP-10 are 2:1:2.OBS, that is, perfluorinated nonene oxygen
Base benzene sulfonic acid sodium salt；SDS, that is, lauryl sodium sulfate；OP-10, that is, alkyl phenol polyoxyethylene ether.
A kind of construction method of the water-repellent paint for garden path, as shown in Figure 1, including the following steps:
The preparation of S1 liquid material: after liquid material each component is weighed by deal needed for being formulated, dispersion stirring multiple purpose aeroplane is poured into, is mixed and stirred for
Uniformly；
The preparation of S2 powder: after powder each component is weighed by deal needed for being formulated, concrete mixer is poured into, is mixed and stirred for
It is even；
S3 coating preparation: by formula definite quality ratio, powder is poured into liquid material, is mixed and stirred for uniformly up to no agglomeration；
S4 is brushed: it first carries out base treatment and is brushed up to foreign matters such as no rubble, dusts, then in three times, per pass curing of coating
Brush afterwards it is lower together and brush direction with it is upper perpendicular together, make coating dry film overall thickness 1.8-2.0mm.
Embodiment two:
A kind of water-repellent paint for garden path, the concrete structure bridge suitable for gardens are matched by liquid material and powder mixing
It makes, the mass ratio of liquid material and powder is 1.2:1.
Liquid material includes the component of following parts by weight:
85 parts of water-proof emulsion；
0.8 part of dimethyl silicone polymer；
2 parts of Sodium Polyacrylate；
8 parts of coalescing agent, coalescing agent is compounded by the dipropylene glycol methyl ether that mass ratio is 1:1 and dipropylene；
It 3 parts of levelling agent, model BYK-333, buys from Bi Ke chemical company, Germany；
25 parts of water；
It 0.6 part of preservative, model ZB-101, buys from Jinan Zhong Bei Fine Chemical Co., Ltd.
Powder includes the component of following parts by weight:
50 parts of portland cement 42.5R；
20 parts of silica flour；
20 parts of diamond dust；
It 7 parts of organo montmorillonite, buys from Lingshou County Xin Bin mineral products processing factory；
8 parts of tourmaline powder, 1250 mesh；
10 parts of nano-titanium dioxide, partial size 20nm；
It 5 parts, i.e. ACHF of active hollow carbon fiber, buys from toray.
Water-proof emulsion the preparation method is as follows:
Step 1, by perfluor alkyl ethyl acrylate, methacrylic acid octadecyl, hydroxypropyl acrylate, to chloromethylbenzene
Ethylene is mixed and stirred for uniformly, obtaining mixed liquor by equal mass ratioes；
7 parts of emulsifiers and 40 parts of water are mixed by weight, are heated to 80 DEG C and keep the temperature, lead to nitrogen protection by step 2
20min adds 50 portions of mixed liquors, 1 part of ammonium persulfate, reacts 2h；
Step 3, while 50 portions of mixed liquors, 1 part of ammonium persulfate are added dropwise, charging is completed in control in 3h, finally under 85 DEG C of heat preservations
4h is reacted, cooling discharging obtains water-proof emulsion.
Emulsifier includes OBS, SDS, OP-10, and the mass ratio of OBS, SDS, OP-10 are 2:1:2.OBS, that is, perfluorinated nonene oxygen
Base benzene sulfonic acid sodium salt；SDS, that is, lauryl sodium sulfate；OP-10, that is, alkyl phenol polyoxyethylene ether.
A kind of construction method of the water-repellent paint for garden path, as shown in Figure 1, including the following steps:
The preparation of S1 liquid material: after liquid material each component is weighed by deal needed for being formulated, dispersion stirring multiple purpose aeroplane is poured into, is mixed and stirred for
Uniformly；
The preparation of S2 powder: after powder each component is weighed by deal needed for being formulated, concrete mixer is poured into, is mixed and stirred for
It is even；
S3 coating preparation: by formula definite quality ratio, powder is poured into liquid material, is mixed and stirred for uniformly up to no agglomeration；
S4 is brushed: it first carries out base treatment and is brushed up to foreign matters such as no rubble, dusts, then in three times, per pass curing of coating
Brush afterwards it is lower together and brush direction with it is upper perpendicular together, make coating dry film overall thickness 1.8-2.0mm.
Embodiment three:
A kind of water-repellent paint for garden path, the concrete structure bridge suitable for gardens are matched by liquid material and powder mixing
It makes, the mass ratio of liquid material and powder is 1:1.
Liquid material includes the component of following parts by weight:
82 parts of water-proof emulsion；
0.6 part of dimethyl silicone polymer；
1.5 parts of Sodium Polyacrylate；
7 parts of coalescing agent, coalescing agent is compounded by the dipropylene glycol methyl ether that mass ratio is 1:1 and dipropylene；
It 2.5 parts of levelling agent, model BYK-333, buys from Bi Ke chemical company, Germany；
22 parts of water；
It 0.5 part of preservative, model ZB-101, buys from Jinan Zhong Bei Fine Chemical Co., Ltd.
Powder includes the component of following parts by weight:
45 parts of portland cement 42.5R；
18 parts of silica flour；
18 parts of diamond dust；
It 5 parts of organo montmorillonite, buys from Lingshou County Xin Bin mineral products processing factory；
7 parts of tourmaline powder, 1250 mesh；
9 parts of nano-titanium dioxide, partial size 20nm；
It 4 parts, i.e. ACHF of active hollow carbon fiber, buys from toray.
Water-proof emulsion the preparation method is as follows:
Step 1, by perfluor alkyl ethyl acrylate, methacrylic acid octadecyl, hydroxypropyl acrylate, to chloromethylbenzene
Ethylene is mixed and stirred for uniformly, obtaining mixed liquor by equal mass ratioes；
6 parts of emulsifiers and 35 parts of water are mixed by weight, are heated to 78 DEG C and keep the temperature, lead to nitrogen protection by step 2
15min adds 45 portions of mixed liquors, 0.9 part of ammonium persulfate, reacts 1.5h；
Step 3, while 45 portions of mixed liquors, 0.9 part of ammonium persulfate are added dropwise, charging is completed in control in 2.5h, is finally protected at 80 DEG C
Temperature is lower to react 3.5h, and cooling discharging obtains water-proof emulsion.
Emulsifier includes OBS, SDS, OP-10, and the mass ratio of OBS, SDS, OP-10 are 2:1:2.OBS, that is, perfluorinated nonene oxygen
Base benzene sulfonic acid sodium salt；SDS, that is, lauryl sodium sulfate；OP-10, that is, alkyl phenol polyoxyethylene ether.
A kind of construction method of the water-repellent paint for garden path, as shown in Figure 1, including the following steps:
The preparation of S1 liquid material: after liquid material each component is weighed by deal needed for being formulated, dispersion stirring multiple purpose aeroplane is poured into, is mixed and stirred for
Uniformly；
The preparation of S2 powder: after powder each component is weighed by deal needed for being formulated, concrete mixer is poured into, is mixed and stirred for
It is even；
S3 coating preparation: by formula definite quality ratio, powder is poured into liquid material, is mixed and stirred for uniformly up to no agglomeration；
S4 is brushed: it first carries out base treatment and is brushed up to foreign matters such as no rubble, dusts, then in three times, per pass curing of coating
Brush afterwards it is lower together and brush direction with it is upper perpendicular together, make coating dry film overall thickness 1.8-2.0mm.
Example IV:
Difference with embodiment three is: powder does not include active hollow carbon fiber, remaining is all the same.
Embodiment five:
Difference with embodiment three is: dispersing agent is calgon, remaining is all the same.
Embodiment six；
Difference with embodiment three is: defoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether, remaining is all the same.
Embodiment seven:
Difference with embodiment three is: powder does not include nano-titanium dioxide, remaining is all the same.
Embodiment eight:
Difference with embodiment three is: emulsifier AEO-9, remaining is all the same.
Comparative example one:
Difference with embodiment three is: powder does not include organo montmorillonite, remaining is all the same.
Comparative example two:
Difference with embodiment three is: powder does not include tourmaline powder, remaining is all the same.
Comparative example three:
Difference with embodiment three is: water-proof emulsion is silicone acrylic emulsion, remaining is all the same.
Comparative example four:
Difference with embodiment three is: water-proof emulsion is silicone acrylic emulsion, and powder does not include organo montmorillonite, tourmaline powder, work
Property hollow carbon fiber, nano-titanium dioxide, remaining is all the same.
Water-repellent paint performance test:
The water-repellent paint of embodiment one to embodiment three is all satisfied national standard " JCT 975-2005 bridge water-repellent paint "
Regulation.
Using the method recorded in national sector standard " GB/T 16777-2008 Test methods for building waterproof coatings ", survey
The adhesion strength for trying film, is as a result recorded in table 1.
Using the method recorded in chemical industry standard " HG/T 3344-2012 paint film water absorption rate measuring method ", test is applied
As a result the water absorption rate of film is recorded in table 1.
Using the method recorded in national sector standard " GB/T 18809-2002 ", DLY-7 type air ion measurement is used
Instrument, tests film coated surface anion concentration, is as a result recorded in table 1.
The water-repellent paint the performance test results record sheet of 1 embodiment one to eight of table, comparative example one to four
| Adhesion strength (MPa) | Water absorption rate (%) | Anion concentration (a/cm3) | |
| Embodiment one | 2.53 | 2.8 | 895 |
| Embodiment two | 2.59 | 2.8 | 872 |
| Embodiment three | 2.56 | 2.9 | 885 |
| Example IV | 2.52 | 3.7 | 742 |
| Embodiment five | 2.47 | 3.4 | 801 |
| Embodiment six | 2.21 | 3.5 | 882 |
| Embodiment seven | 2.41 | 5.7 | 764 |
| Embodiment eight | 2.37 | 4.2 | 853 |
| Comparative example one | 2.51 | 4.8 | 879 |
| Comparative example two | 2.44 | 3.2 | 73 |
| Comparative example three | 1.36 | 10.6 | 218 |
| Comparative example four | 0.93 | 14.7 | 70 |
This specific embodiment is only explanation of the invention, is not limitation of the present invention, and those skilled in the art exist
It can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as in the present invention
Scope of the claims in all by the protection of Patent Law.
Claims (8)
1. a kind of water-repellent paint for garden path, it is characterised in that: including liquid material and powder, the matter of the liquid material and powder
The ratio between amount is (0.8-1.2): 1；
The liquid material includes the component of following parts by weight:
80-85 parts of water-proof emulsion
0.5-0.8 parts of defoaming agent
1-2 parts of dispersing agent
6-8 parts of coalescing agent
2-3 parts of levelling agent
20-25 parts of water
0.4-0.6 parts of preservative；
The powder includes the component of following parts by weight:
40-50 parts of cement
15-20 parts of silica flour
15-20 parts of diamond dust
3-7 parts of organo montmorillonite
6-8 parts of tourmaline powder；
The water-proof emulsion the preparation method is as follows:
Step 1, by perfluor alkyl ethyl acrylate, methacrylic acid octadecyl, hydroxypropyl acrylate, to chloromethylbenzene
Ethylene is mixed and stirred for uniformly, obtaining mixed liquor by equal mass ratioes；
5-7 parts of emulsifiers and 30-40 parts of water are mixed by weight, are heated to 75-80 DEG C and keep the temperature, led to by step 2
Nitrogen protection 10-20min adds 40-50 portions of mixed liquors, 0.8-1 parts of ammonium persulfates, reacts 1-2h；
Step 3, while 40-50 portions of mixed liquors, 0.8-1 parts of ammonium persulfates are added dropwise, charging is completed in control in 2-3h, is finally existed
75-85 DEG C of heat preservation is lower to react 3-4h, and cooling discharging obtains water-proof emulsion.
2. a kind of water-repellent paint for garden path according to claim 1, it is characterised in that: the emulsifier packet
OBS, SDS, OP-10 are included, the mass ratio of described OBS, SDS, OP-10 are 2:1:2.
3. a kind of water-repellent paint for garden path according to claim 1, it is characterised in that: the powder further includes
8-10 parts of nano-titanium dioxides.
4. a kind of water-repellent paint for garden path according to claim 1, it is characterised in that: the defoaming agent is poly-
Dimethyl siloxane.
5. a kind of water-repellent paint for garden path according to claim 1, it is characterised in that: the dispersing agent is poly-
Sodium acrylate.
6. a kind of water-repellent paint for garden path according to claim 1, it is characterised in that: the coalescing agent by
Mass ratio is that the dipropylene glycol methyl ether of 1:1 and dipropylene compound.
7. a kind of water-repellent paint for garden path according to claim 1, it is characterised in that: the powder further includes
3-5 parts of active hollow carbon fibers.
8. a kind of construction method of the water-repellent paint described in claim 1 for garden path, which is characterized in that including as follows
Step:
The preparation of S1 liquid material: it after liquid material each component is weighed by deal needed for being formulated, is mixed and stirred for uniformly；
The preparation of S2 powder: it after powder each component is weighed by deal needed for being formulated, is mixed and stirred for uniformly；
S3 coating preparation: liquid material and powder are mixed and stirred for uniformly；
S4 is brushed: being brushed in three times after base treatment, makes coating dry film with a thickness of 1.8-2.0mm.
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| CN201910108192.0A CN109762428B (en) | 2019-01-18 | 2019-01-18 | Waterproof coating for garden roads and construction method thereof |
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| CN201910108192.0A CN109762428B (en) | 2019-01-18 | 2019-01-18 | Waterproof coating for garden roads and construction method thereof |
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| CN112662243A (en) * | 2020-12-29 | 2021-04-16 | 山西中涂交通科技股份有限公司 | Cement-based water-based marking paint |
| CN115322604A (en) * | 2022-08-16 | 2022-11-11 | 老顽固(上海)新材料科技有限公司 | High-wear-resistance interior wall cement paint and preparation method thereof |
| CN115322604B (en) * | 2022-08-16 | 2023-05-30 | 老顽固(上海)新材料科技有限公司 | High-wear-resistance interior wall cement paint and preparation method thereof |
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