CN109758712A - A kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone - Google Patents
A kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone Download PDFInfo
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- CN109758712A CN109758712A CN201811419243.3A CN201811419243A CN109758712A CN 109758712 A CN109758712 A CN 109758712A CN 201811419243 A CN201811419243 A CN 201811419243A CN 109758712 A CN109758712 A CN 109758712A
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- propane
- perfluor
- heptafluoro
- carbon dioxide
- ketone
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Abstract
The invention discloses a kind of mixing extinguishing chemicals using heptafluoro-propane, carbon dioxide and perfluor ketone, mixing extinguishing chemical, ketone forms by heptafluoro-propane, carbon dioxide and perfluor, wherein, heptafluoro-propane accounts for 3% to 50% (by weight) of intermixture, carbon dioxide accounts for 10% to 80% (by weight) of intermixture, and ketone accounts for 10% to 80% (by weight) of intermixture to perfluor.Extinguishing chemical of the invention combines the advantages of heptafluoro-propane, carbon dioxide and perfluor ketone extinguishing chemical fire extinguishing while carrying out physics, chemistry cooling and fire smothering, reaches better fire extinguishing cooling effect.
Description
Technical field
The invention belongs to the technical fields of extinguishing chemical, and in particular to a kind of to have utilized heptafluoro-propane, carbon dioxide and perfluor
The mixing extinguishing chemical of ketone.
Background technique
Since existing new-energy automobile is all using lithium ion battery as dynamical system, and lithium ion battery is transported in vehicle
During row, there are some potential safety problemss, especially in abuse conditions, such as vehicle overcharges during the charging process, over-discharge,
Squeeze, needle thorn, burn etc. when, lithium ion battery be easy to happen smolder, it is on fire in addition explosion safety accident.Therefore,
On-vehicle battery can all be equipped with fire extinguisher.Fire extinguisher is by storage unit, action component, extinguishing chemical composition.
Existing extinguishing chemical, which has, uses carbon dioxide as fire extinguishing material, also has using heptafluoro-propane as fire extinguishing material
, but in the market there is not yet using the mixing extinguishing chemical mixing of heptafluoro-propane+carbon dioxide+perfluor ketone as going out simultaneously
The fire extinguisher of fiery material.It is very sensitive to temperature as the fire extinguisher of fire extinguishing material using pure carbon dioxide, it cannot be heated, still
Carbon-dioxide fire engine sprays speed height, good cooling effect, while carbon dioxide can play good object because its storage pressure is higher
Manage cooling effect, but without chemical cooling function, using pure heptafluoro-propane as material of putting out a fire fire extinguisher then with pure titanium dioxide
Carbon fire extinguisher is on the contrary, up to 700 ° of the decomposition indexing of heptafluoro-propane, and heat-resist, spray speed is low, of less demanding to nozzle, but valence
Lattice are relatively high, and lowering ability is lacking, and are substantially carried out chemical cooling.Perfluor ketone as a kind of fire-extinguishing agent,
Its dominant mechanism of putting out a fire is fire smothering, but the slightly deficiency in several chemical cooling features of Physical temperature-lowering.
Summary of the invention
The shortcomings that in order to overcome above-mentioned existing extinguishing chemical to be used alone, the purpose of the present invention is to provide one kind to combine seven
The advantages of fluoro-propane, carbon dioxide and perfluor ketone extinguishing chemical fire extinguishing, carries out physics, chemistry cooling and fire smothering simultaneously, reaches
To better fire extinguishing cooling effect.
To realize the above-mentioned technical purpose, the technical scheme adopted by the invention is as follows:
A kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone, in which: mixing extinguishing chemical is by seven fluorine third
Ketone forms for alkane, carbon dioxide and perfluor, wherein heptafluoro-propane accounts for 3% to 50% (by weight) of intermixture, and carbon dioxide accounts for
10% to 80% (by weight) of intermixture, ketone accounts for 10% to 80% (by weight) of intermixture to perfluor.
To optimize above-mentioned technical proposal, the concrete measure taken further include:
Heptafluoro-propane, carbon dioxide and perfluor ketone be pre-mixed it is rear canned to storing in extinguishing device.
Three kinds of ingredients of ketone are completely separable for heptafluoro-propane, carbon dioxide and perfluor, independent container filling storage, sprinkling fire extinguishing
Mixing sprinkling is carried out again using preceding.
Heptafluoro-propane and carbon dioxide are pre-mixed rear canned to storing in extinguishing device, perfluor ketone independence container filling
Storage, by perfluor, ketone carries out mixing sprinkling with the intermixture of heptafluoro-propane and carbon dioxide again before for sprinkling fire extinguishing;Or seven
Ketone is pre-mixed rear canned to storing in extinguishing device, carbon dioxide independence container filling storage, sprinkling for fluoro-propane and perfluor
By carbon dioxide and heptafluoro-propane and perfluor, the intermixture of ketone carries out mixing sprinkling using preceding again for fire extinguishing;Or perfluor ketone and two
Carbonoxide is pre-mixed rear canned to storing in extinguishing device, heptafluoro-propane independence container filling storage, before sprinkling fire extinguishing use
By heptafluoro-propane, the intermixture of ketone and carbon dioxide carries out mixing sprinkling with perfluor again.
Ketone at least one is not pre-mixed for heptafluoro-propane, carbon dioxide and perfluor, and extinguishing chemical ingredient passes through respective spray
It spills device and is separately sprayed onto the same area, mixing fire extinguishing is carried out outside extinguishing device.
Ketone as fire extinguishing material, heptafluoro-propane is extinguishing chemical of the invention using heptafluoro-propane and carbon dioxide and perfluor
One kind having the clean coal power system of physics fire extinguishing effect concurrently based on inhibition;Storage space is small, and critical-temperature is high, faces
Boundary's pressure is low, and carbon dioxide is physically to put out a fire, and when carbon dioxide is changed into gaseous state from liquid, can absorb big calorimetric, rises
It being acted on to huge Physical temperature-lowering fire extinguishing, ketone is as Novel clean extinguishing chemical for perfluor, by remarkable result in fire smothering, and
Have both certain cooling effect.The present invention combines the object of the above heptafluoro-propane and carbon dioxide and perfluor three kinds of extinguishing chemicals of ketone
Reason, inhibition advantage, have taken into account physics and inhibition principle.This combined dose the advantages of combining three kinds of extinguishing chemicals,
On-vehicle battery is particularly suitable for put out a fire this occasion for needing sharply to cool down with inhibition, but not limited to this occasion, especially
It is needing to reduce under the quadratic loss occasion of protection target, had better effect with such extinguishing chemical.
Specific embodiment
The embodiment of the present invention is described in further detail below.
Embodiment one:
A kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone, in which: mixing extinguishing chemical is by seven fluorine third
Ketone forms for alkane, carbon dioxide and perfluor, wherein heptafluoro-propane accounts for 3% (by weight) of intermixture, and carbon dioxide accounts for mixing
17% (by weight) of agent, ketone accounts for 80% (by weight) of intermixture to perfluor.
The storage state for mixing extinguishing chemical is pressurized storage.
Heptafluoro-propane, carbon dioxide and perfluor ketone be pre-mixed it is rear canned to storing in extinguishing device.
Embodiment two:
A kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone, in which: mixing extinguishing chemical is by seven fluorine third
Ketone forms for alkane, carbon dioxide and perfluor, wherein heptafluoro-propane accounts for 50% (by weight) of intermixture, and carbon dioxide accounts for mixing
40% (by weight) of agent, ketone accounts for 10% (by weight) of intermixture to perfluor.
The storage state for mixing extinguishing chemical is normal temperature pressurized storage.
Three kinds of ingredients of ketone are completely separable for heptafluoro-propane, carbon dioxide and perfluor, independent container filling storage, sprinkling fire extinguishing
Mixing sprinkling is carried out again using preceding.
Embodiment three:
A kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone, in which: mixing extinguishing chemical is by seven fluorine third
Ketone forms for alkane, carbon dioxide and perfluor, wherein heptafluoro-propane accounts for 25% (by weight) of intermixture, and carbon dioxide accounts for mixing
50% (by weight) of agent, ketone accounts for 25% (by weight) of intermixture to perfluor.
The storage state for mixing extinguishing chemical is room temperature, pressurized storage.
Heptafluoro-propane and carbon dioxide are pre-mixed rear canned to storing in extinguishing device, perfluor ketone independence container filling
Storage, by perfluor, ketone carries out mixing sprinkling with the intermixture of heptafluoro-propane and carbon dioxide again before for sprinkling fire extinguishing.
Example IV:
A kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone, in which: mixing extinguishing chemical is by seven fluorine third
Ketone forms for alkane, carbon dioxide and perfluor, wherein heptafluoro-propane accounts for 25% (by weight) of intermixture, and carbon dioxide accounts for mixing
50% (by weight) of agent, ketone accounts for 25% (by weight) of intermixture to perfluor.
The storage state for mixing extinguishing chemical is room temperature and pressurized storage.
Ketone is not pre-mixed for heptafluoro-propane, carbon dioxide and perfluor, and extinguishing chemical ingredient passes through respective flusher point
It opens and is sprayed onto the same area, mixing fire extinguishing is carried out outside extinguishing device.
Embodiment five:
A kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone, in which: mixing extinguishing chemical is by seven fluorine third
Ketone forms for alkane, carbon dioxide and perfluor, wherein heptafluoro-propane accounts for 30% (by weight) of intermixture, and carbon dioxide accounts for mixing
40% (by weight) of agent, ketone accounts for 30% (by weight) of intermixture to perfluor.
The storage state for mixing extinguishing chemical is room temperature pressurized storage.
Ketone is pre-mixed rear canned to extinguishing device/device memory storage for heptafluoro-propane and perfluor, and carbon dioxide independently fills
Packaging container storage, by carbon dioxide and heptafluoro-propane and perfluor, the intermixture of ketone carries out mixing spray using preceding again for sprinkling fire extinguishing
It spills.
Embodiment six:
A kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone, in which: mixing extinguishing chemical is by seven fluorine third
Ketone forms for alkane, carbon dioxide and perfluor, wherein heptafluoro-propane accounts for 25% (by weight) of intermixture, and carbon dioxide accounts for mixing
50% (by weight) of agent, ketone accounts for 25% (by weight) of intermixture to perfluor.
The storage state for mixing extinguishing chemical is normal temperature pressurized storage.
Ketone and carbon dioxide are pre-mixed rear canned to the storage of extinguishing device/device memory perfluor, and heptafluoro-propane independently fills
Packaging container storage, by heptafluoro-propane, the intermixture of ketone and carbon dioxide carries out mixing spray with perfluor again before for sprinkling fire extinguishing
It spills.
To sum up, the mixing extinguishing chemical of the invention using heptafluoro-propane+carbon dioxide+perfluor ketone, three kinds of ingredients press one
Fixed ratio is mixed, while acting on kindling protection zone, is including but not limited to carried out against the mode that ignition point sprays
Fire extinguishing, cooling.Wherein, mark temperature and the carbon dioxide of mark pressure are gaseous state, and ketone is liquid for heptafluoro-propane and perfluor;In pressure shape
Under state, three kinds of ingredients are liquid or supercriticality;After environment temperature rising, ketone is gaseous state to perfluor.Heptafluoro-propane, two
Ketone accounts for the ratio of intermixture according to different fire extinguishing conditions and requires respectively to optimize adjustment for carbonoxide and perfluor.Storage side
Formula also there are many: be summarized as follows:
1, three kinds of ingredients independently store, and storage mode in specific proportions, in fire extinguishing, is not monitored by external sense and carried out
Three kinds of ingredients are algorithmically shown that the ratio of obtaining sprays, can advanced in flusher by certain algorithm operation, final control extinguishing device
Row mixing can also carry out mixing in protection zone after flusher and realize fire extinguishing.
2, three kinds of ingredients are mixed in a certain ratio storage according to particular requirement in advance but are not limited in same container, are putting out a fire
When, protection zone sprinkling is delivered to by extinguishing device movement and realizes fire extinguishing.
3, in three kinds of ingredients any two kinds be mixed in a certain ratio in advance, the third ingredient separate storage.It is logical in fire extinguishing
Certain proportion algorithm is crossed, mixing realization is carried out after mixing or spray before flusher by a certain percentage in protection zone and goes out
Fire.
The above is only the preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-described embodiment,
All technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art
For those of ordinary skill, several improvements and modifications without departing from the principles of the present invention should be regarded as protection of the invention
Range.
Claims (5)
1. a kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone, it is characterized in that: mixing extinguishing chemical is by seven
Ketone forms for fluoro-propane, carbon dioxide and perfluor, wherein heptafluoro-propane accounts for 3% to 80% (by weight) of intermixture, titanium dioxide
Carbon accounts for 10% to 80% (by weight) of intermixture, and ketone accounts for 10% to 80% (by weight) of intermixture to perfluor.
2. a kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone according to claim 1, special
Sign is: heptafluoro-propane, carbon dioxide and perfluor ketone be pre-mixed it is rear canned to storing in extinguishing device.
3. a kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone according to claim 1, special
Sign is: three kinds of ingredients of ketone are completely separable for heptafluoro-propane, carbon dioxide and perfluor, and independent container filling storage, sprinkling fire extinguishing makes
Mixing sprinkling is carried out again with preceding.
4. a kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone according to claim 1, special
Sign is: heptafluoro-propane and carbon dioxide are pre-mixed rear canned to storing in extinguishing device, and perfluor store up by ketone independence container filling
It deposits, by perfluor, ketone carries out mixing sprinkling with the intermixture of heptafluoro-propane and carbon dioxide again before for sprinkling fire extinguishing;Or seven fluorine
Ketone is pre-mixed rear canned to storing in extinguishing device for propane and perfluor, and carbon dioxide independence container filling storage, sprinkling is gone out
By carbon dioxide and heptafluoro-propane and perfluor, the intermixture of ketone carries out mixing sprinkling fire using preceding again;Or perfluor ketone and dioxy
Mdi prepolymer is canned to storing in extinguishing device after first mixing, the storage of heptafluoro-propane independence container filling, sprinkling fire extinguishing using it is preceding again
By heptafluoro-propane, the intermixture of ketone and carbon dioxide carries out mixing sprinkling with perfluor.
5. a kind of mixing extinguishing chemical using heptafluoro-propane, carbon dioxide and perfluor ketone according to claim 1, special
Sign is: ketone at least one is not pre-mixed for heptafluoro-propane, carbon dioxide and perfluor, and extinguishing chemical ingredient is filled by respective sprinkling
It sets and is separately sprayed onto the same area, mixing fire extinguishing is carried out outside extinguishing device.
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Cited By (1)
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CN115591173A (en) * | 2022-10-09 | 2023-01-13 | 广东电网有限责任公司(Cn) | Composite fire extinguishing agent, preparation method thereof, fire extinguishing device comprising composite fire extinguishing agent and application of composite fire extinguishing agent |
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Cited By (1)
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Application publication date: 20190517 |