CN109749707B - Anti-splash preparation and toilet trap sewage anti-splash method - Google Patents
Anti-splash preparation and toilet trap sewage anti-splash method Download PDFInfo
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- CN109749707B CN109749707B CN201910024405.1A CN201910024405A CN109749707B CN 109749707 B CN109749707 B CN 109749707B CN 201910024405 A CN201910024405 A CN 201910024405A CN 109749707 B CN109749707 B CN 109749707B
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Abstract
The embodiment of the invention discloses an anti-splash preparation and a toilet trap sewage anti-splash method. The anti-splash preparation comprises 30-45 parts by weight of acid salt, 30-45 parts by weight of bicarbonate or/and carbonate, 8-15 parts by weight of surfactant and 8-15 parts by weight of mineral. The anti-splash preparation has higher foam height, and the foam height is maintained for a long time, so that sewage splashing can be effectively avoided; and the cost is low, and the fluidity is good.
Description
Technical Field
The invention relates to the technical field of bathroom products, in particular to a splash-proof preparation and a toilet trap sewage splash-proof method.
Background
When the toilet is used, sewage in the toilet (or the urinal) is easy to splash to skin and clothes. Therefore, people throw toilet paper into the closestool during defecation, but the splashing prevention effect is influenced by the quantity of the toilet paper thrown in, the throwing angle and the difference of the water seal area of the closestool. The throwing amount is large, so that the toilet is easy to block; the throwing amount is small, and the anti-splash effect cannot be achieved.
In order to solve the problem of splashing of toilet sewage, various toilet sewage splash-proof products appear on the market. For example: the closestool with the function of preventing splash and foam, the external hanging device of the closestool, the foam generating device, the splash-proof film, the splash-proof floater of the closestool, the splash-proof foam filled with compressed gas and other splash-proof appliances. These splash guards have various advantages and disadvantages, as follows:
the price of the closestool with the anti-splash foam function is from ten thousand yuan to tens of thousands yuan, and the foaming preparation is continuously purchased from a closestool manufacturer and added into the closestool in the later period. The price of the closestool and the later use cost are high, so that the closestool is difficult to popularize.
The external hanging device of the closestool can generate anti-splash foam, but needs to be additionally provided with a power supply, and has larger potential safety hazard when being used in a humid environment. In addition, because the external hanging device is arranged in the closestool, dirt remained on the external hanging device is difficult to clean, the generated foam and viscosity are low, the foam attenuation height is reduced quickly, and the anti-splash effect is poor.
The foam generating device is an independent device for generating splash-proof foam, occupies the space of a toilet due to large volume, and is poor in user experience because foam needs to be generated and put in one minute in advance.
The splash-proof film needs to stretch hands into the toilet bowl and lay the hands on the water cover, and the hands easily touch the inner wall of the toilet bowl, so that the use sanitary condition is poor. And the splash-proof film has higher degradation speed in water, and the splash-proof effect is not as good as that of toilet paper.
Although the splash-proof floater can be used for multiple times, dirt is easy to stay on the surface of the splash-proof floater, and the dirt is difficult to clean. In addition, splash floats are prone to toilet blockage.
The anti-splash foam filled in the compressed gas tank is sprayed into the closestool by the compressed gas in the tank body. Because the foam is sprayed with great force, the sound of the foam sprayed into water is great, and local upward airflow is generated to bring bacteria, so that the use sense and sanitary conditions are not good enough.
In summary, the anti-splash device has many problems and cannot be carried. To this end, chinese patent 201620125536.0 provides an anti-spattering formulation comprising a solid acid, a carbonate and/or bicarbonate salt, a foam booster and/or foam stabilizer. When the anti-splash preparation is used for a closestool with small water seal area, the anti-splash effect is obvious if the minimum water seal surface size of GB/T6952-. But the height and viscosity of the foam are reduced quickly, and the anti-splash performance is obviously attenuated. When the product is used for a closestool with a slightly large water seal area, if the product reaches 1.9 times of the requirement of the minimum water seal surface size of 100mm multiplied by 85mm of the national standard GB/T6952-2015, the generated foam is thin and low in viscosity, and the phenomenon of sewage splashing still exists. In addition, the anti-spattering agent is not sufficiently contacted with water to foam due to the gel barrier occurring at the time of use, thereby causing the anti-spattering agent to foam highly unstably. In addition, the splash-proof preparation can only be packaged by a heat-sealed plastic bag, and is not easy to be unsealed and torn by hands when in use in a toilet, so that the use is very inconvenient.
Disclosure of Invention
The embodiment of the invention aims to provide a splash-proof agent and a toilet trap sewage splash-proof method, which are used for solving the problems of thin foam, low viscosity, unstable foaming height and high attenuation speed of the existing splash-proof agent.
In order to achieve the above object, an anti-spattering agent according to an embodiment of the present invention comprises 30 to 45 parts by weight of an acid salt, 30 to 45 parts by weight of a bicarbonate or/and carbonate, 8 to 15 parts by weight of a surfactant, and 8 to 15 parts by weight of a mineral.
Preferably, the anti-spattering agent comprises 35-45 parts by weight of an acid salt, 35-45 parts by weight of a bicarbonate or/and carbonate, 8-10 parts by weight of a surfactant, and 8-10 parts by weight of a mineral.
Preferably, the acidic salt is a salt whose aqueous solution hydrogen ion concentration index is less than 7.
Wherein the acid salt is one or more of aluminum potassium sulfate, aluminum sulfate, copper sulfate, silver nitrate, ferric chloride, aluminum chloride, copper chloride, ferrous sulfate, sodium dihydrogen phosphate and ammonium salt.
Wherein, the bicarbonate is one or more of sodium bicarbonate, potassium bicarbonate and calcium bicarbonate; the carbonate is one or more of sodium carbonate, potassium carbonate and calcium carbonate.
The surfactant is one or more of dodecyl sulfate, protein, polyvinyl alcohol, lignosulfonate, heavy alkylbenzene sulfonate, cocoyl glycine, sodium stearyl glutamate, lauroyl glutamic acid, lauryl polyether sulfate, cocamidopropyl betaine, fatty alcohol-polyoxyethylene ether sodium sulfate and fatty alcohol-polyoxyethylene ether ammonium sulfate.
Wherein the mineral is one or more of talc, quartz, marble and limestone.
Preferably, the mineral is a powder or granules with a particle size of 6 to 400 mesh.
The splash-proof preparation is packaged in a paper tube, a paper bag, a laminating paper packaging bag and a plastic bottle.
In addition, the invention also provides a sewage anti-splashing method for the toilet trap, and anti-splashing agent is put in the toilet trap and adopts the anti-splashing agent provided by the invention.
The embodiment of the invention has the following advantages:
according to the splash-proof preparation provided by the embodiment of the invention, the foaming height is improved by utilizing the gas generated by the reaction of the acid salt and the bicarbonate or carbonate, the surfactant is more dispersed by the doped minerals, and the effect of a gel barrier in the using process is reduced, so that the foaming height of the splash-proof preparation is more stable, and the splash-proof performance is more stable; and the density of the splash-proof agent can be improved, the splash-proof agent can be favorably and completely sunk into the water seal, the splash-proof agent can completely react in water, and the foaming height is ensured. In addition, the mineral can increase the fluidity of the anti-splash preparation, is beneficial to the filling of products and has better manufacturability. In addition, the minerals can be natural or artificially synthesized, and have rich colors, so that the splash-proof foam has richer colors and good sensory effect. In anti-splash formulations, surfactants are used to increase the viscosity of the foam, prolonging the bubble collapse time. While the aluminum sulfate in the acid salt reacts with the bicarbonate/carbonate to generate gas, the aluminum hydroxide flocculus can also generate gel-like aluminum hydroxide flocculus which can adsorb and precipitate bacteria, colloid and other suspended matters, is favorable for improving the viscosity of foam, relieving the attenuation of the foam, maintaining the height of the foam and is favorable for environmental protection. In addition, the acid salt can also react with bicarbonate/carbonate to generate corresponding flocculent hydroxide gel, which is beneficial to improving the viscosity of the foam, prolonging the breaking time of the bubbles and relieving the attenuation of the foam.
The raw material of the splash-proof preparation provided by the embodiment of the invention is a widely-applied large-scale production raw material, and is environment-friendly, easy to obtain and low in cost.
Detailed Description
The following description of the embodiments of the present invention is provided for illustrative purposes, and other advantages and effects of the present invention will become apparent to those skilled in the art from the present disclosure.
Example 1
This example provides an anti-spattering formulation comprising an acid salt, a bicarbonate or/and carbonate salt, a surfactant and a mineral.
Among them, the acidic salt is preferably a salt whose hydrogen ion concentration index in an aqueous solution is less than 7. Such as one or more of aluminum potassium sulfate, aluminum sulfate, copper sulfate, silver nitrate, ferric chloride, aluminum chloride, cupric chloride, ferrous sulfate, sodium dihydrogen phosphate and ammonium salt.
The bicarbonate is sodium bicarbonate, potassium bicarbonate or calcium bicarbonate, and the carbonate is one or more selected from sodium carbonate, potassium carbonate and calcium carbonate.
The surfactant is one or more of dodecyl sulfate, protein, polyvinyl alcohol, lignosulfonate, heavy alkylbenzene sulfonate, cocoyl glycine, sodium stearyl glutamate, lauroyl glutamic acid, laureth sulfate, cocamidopropyl betaine, fatty alcohol-polyoxyethylene ether sodium sulfate and fatty alcohol-polyoxyethylene ether ammonium sulfate.
The mineral is one or more of pulvis Talci, Quartz, Marble, and limestone. In addition, the mineral is powder or granules, and the granularity is 6 meshes to 400 meshes.
In this example, the splash guard preparation includes 40 parts by weight of aluminum sulfate, 40 parts by weight of sodium bicarbonate, 10 parts by weight of sodium lauryl sulfate, and 10 parts by weight of quartz.
Example 2
The splash-proof preparation comprises 30 parts of aluminum sulfate, 40 parts of sodium bicarbonate, 8 parts of lauroyl glutamic acid and 10 parts of quartz by weight.
Example 3
The splash-proof preparation comprises, by weight, 35 parts of aluminum sulfate, 30 parts of sodium bicarbonate, 8 parts of polyvinyl alcohol and 12 parts of quartz.
Example 4
The splash-proof preparation comprises, by weight, 45 parts of aluminum sulfate, 45 parts of sodium bicarbonate, 15 parts of polyvinyl alcohol and 15 parts of quartz.
Example 5
The splash-proof preparation comprises, by weight, 45 parts of aluminum sulfate, 45 parts of potassium bicarbonate, 10 parts of lignosulfonate and 15 parts of talc.
Comparative example 1
The splash-proof preparation comprises, by weight, 30 parts of citric acid, 30 parts of sodium bicarbonate and 10 parts of polyvinyl alcohol.
Comparative example 2
The splash-proof preparation comprises, by weight, 40 parts of tartaric acid, 40 parts of calcium bicarbonate and 15 parts of polyvinyl alcohol.
27 g of the splash-proof preparations of examples 1 to 5 and comparative examples 1 to 2 were put into a toilet bowl and tested, and the water seal area of the toilet bowl for testing was 100X 85mm and the minimum depth was 55 mm, and the test results are shown in Table 1. Wherein the height of the foam is measured by an electronic height gauge, the height is the height of the foam at the highest position, the duration is the time taken for the height of the foam to fall from the highest position to a half,
| foam height (centimeter) | Duration (minutes) | |
| Example 1 | 5 | 7 |
| Example 2 | 6 | 9 |
| Example 3 | 8 | 12 |
| Example 4 | 11 | 17 |
| Example 5 | 7 | 8 |
| Comparative example 1 | 2.5 | 4 |
| Comparative example 2 | 3 | 5 |
The anti-splash preparation provided by the embodiment utilizes the reaction of the acid salt and the bicarbonate or carbonate to generate gas, and the acid salt can generate more gas compared with the reaction of the solid acid and the bicarbonate or carbonate, so that the foaming height is favorably improved. The mixed minerals not only enable the surfactant to be more dispersed, but also reduce the effect of a gel barrier in the using process, so as to ensure that the foaming height of the splash-proof agent is more stable and the splash-proof performance is more stable; and the density of the splash-proof agent can be improved, the splash-proof agent can be favorably and completely sunk into the water seal, the splash-proof agent can completely react in water, and the foaming height is ensured. In addition, the mineral can increase the fluidity of the anti-splash preparation, is beneficial to the filling of products and has better manufacturability. In addition, the minerals can be natural or artificially synthesized, and have rich colors, so that the splash-proof foam has richer colors and good sensory effect. In the splash-proof preparation, the surfactant (such as sodium sulfonate, polyvinyl alcohol, lauroyl glutamic acid and the like) can increase the viscosity of the splash-proof preparation, and the viscosity is increased along with the increase of the use ratio; while the aluminum sulfate in the acid salt reacts with the bicarbonate/carbonate to generate gas, the aluminum hydroxide flocculus can also generate gel-like aluminum hydroxide flocculus which can adsorb and precipitate bacteria, colloid and other suspended matters, is favorable for improving the viscosity of foam, relieving the attenuation of the foam, maintaining the height of the foam and is favorable for environmental protection.
The splash-proof preparation provided by each embodiment has good fluidity, can be filled in a paper tube plastic bottle and also can be packaged in a paper bag, so that different requirements of different users are facilitated, and meanwhile, the packaging cost is reduced.
Example 6
The embodiment provides a sewage anti-splashing method for a toilet trap, and the anti-splashing method is to put an anti-splashing agent into the toilet trap. The anti-spattering agent is the anti-spattering agent provided in the above examples 1 to 5, and thus the specific components of the anti-spattering agent will not be described herein.
The splash-proof method provided by the embodiment can effectively avoid splashing of sewage in the toilet trap during toilet, so that personal hygiene is improved, and the toilet cannot be blocked.
Although the invention has been described in detail above with reference to a general description and specific examples, it will be apparent to one skilled in the art that modifications or improvements may be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.
Claims (9)
1. An anti-splash preparation is characterized in that the anti-splash preparation comprises 30-45 parts by weight of acid salt, 30-45 parts by weight of bicarbonate or/and carbonate, 8-15 parts by weight of surfactant and 8-15 parts by weight of mineral;
the acid salt is one or more of potassium aluminum sulfate, copper sulfate, silver nitrate, ferric chloride, aluminum chloride, copper chloride, ferrous sulfate, sodium dihydrogen phosphate and ammonium salt.
2. The anti-spattering formulation according to claim 1, wherein the components of the anti-spattering formulation comprise 35-45 parts by weight of the acid salt, 35-45 parts by weight of the bicarbonate or/and carbonate salt, 8-10 parts by weight of the surfactant and 8-10 parts by weight of the mineral.
3. The anti-spattering formulation according to claim 1, wherein said acid salt is a salt having a hydrogen ion concentration index of less than 7 in an aqueous solution.
4. The anti-splash preparation according to claim 1, wherein the bicarbonate is one or more of sodium bicarbonate, potassium bicarbonate, calcium bicarbonate; the carbonate is one or more of sodium carbonate, potassium carbonate and calcium carbonate.
5. The anti-splash formulation according to claim 1, wherein the surfactant is one or more of dodecyl sulfate, protein, polyvinyl alcohol, lignosulfonate, heavy alkylbenzene sulfonate, cocoyl glycine, sodium stearyl glutamate, lauroyl glutamic acid, laureth sulfate, cocamidopropyl betaine, sodium fatty alcohol-polyoxyethylene ether sulfate, and ammonium fatty alcohol-polyoxyethylene ether sulfate.
6. The anti-splash preparation according to claim 1, wherein the minerals are one or more selected from talc, quartz, marble and limestone.
7. The anti-spattering formulation according to claim 6, wherein said mineral is in the form of powder or granule having a particle size of 6 to 400 mesh.
8. The anti-splash preparation according to any of claims 1 to 7, wherein the anti-splash preparation is packaged in paper cartridges, paper bags and plastic bottles.
9. A method for preventing sewage in a toilet trap from splashing, which puts splash-proof agent in the toilet trap, characterized in that the splash-proof agent is the splash-proof agent according to any one of claims 1 to 7.
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| CN201910024405.1A CN109749707B (en) | 2019-01-10 | 2019-01-10 | Anti-splash preparation and toilet trap sewage anti-splash method |
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| CN109749707B true CN109749707B (en) | 2021-11-09 |
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| JP2001241085A (en) * | 2000-02-25 | 2001-09-04 | Lion Corp | Splash preventing product for western-style toilet |
| CN102367399A (en) * | 2011-05-25 | 2012-03-07 | 王国松 | Sanitation bubbles |
| CN104559921A (en) * | 2014-06-17 | 2015-04-29 | 李震 | Splash-proof agent and preparation method thereof |
| CN104629688A (en) * | 2015-03-05 | 2015-05-20 | 李震 | Closestool splash-proof foam aerosol and preparation method thereof |
| CN105779144A (en) * | 2014-12-15 | 2016-07-20 | 上海家化联合股份有限公司 | Composition capable of rapidly forming splash-proof buffering film on surface of water seal of closestool |
| CN105885785A (en) * | 2016-05-16 | 2016-08-24 | 盛毅 | Splash-proof preparation |
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Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001241085A (en) * | 2000-02-25 | 2001-09-04 | Lion Corp | Splash preventing product for western-style toilet |
| CN102367399A (en) * | 2011-05-25 | 2012-03-07 | 王国松 | Sanitation bubbles |
| CN102703230A (en) * | 2011-05-25 | 2012-10-03 | 王国松 | Spray-proof, olid-resistant, anti-sticking automatic foaming powder when wets for toilets |
| CN104559921A (en) * | 2014-06-17 | 2015-04-29 | 李震 | Splash-proof agent and preparation method thereof |
| CN105779144A (en) * | 2014-12-15 | 2016-07-20 | 上海家化联合股份有限公司 | Composition capable of rapidly forming splash-proof buffering film on surface of water seal of closestool |
| CN104629688A (en) * | 2015-03-05 | 2015-05-20 | 李震 | Closestool splash-proof foam aerosol and preparation method thereof |
| CN105885785A (en) * | 2016-05-16 | 2016-08-24 | 盛毅 | Splash-proof preparation |
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