CN109732270A - A kind of ray type copper foil maintenance correction technique - Google Patents
A kind of ray type copper foil maintenance correction technique Download PDFInfo
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- CN109732270A CN109732270A CN201910134740.7A CN201910134740A CN109732270A CN 109732270 A CN109732270 A CN 109732270A CN 201910134740 A CN201910134740 A CN 201910134740A CN 109732270 A CN109732270 A CN 109732270A
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Abstract
The invention discloses a kind of ray type copper foils to overhaul correction technique, complementing equipment is overhauled including copper foil, it includes the copper foil conveying mechanism set gradually that copper foil, which overhauls complementing equipment, x-ray defectoscope, the monitoring analysis host being connect with x-ray defectoscope, dust printer and the electrostatic generator that is adsorbed onto copper powder on copper foil of laser cutting machine on copper foil repairing platform, sprinkling N mesh copper powder are set, antistatic floating is scraped, roller press mechanism and receiving mechanism overhaul the technique of correction the following steps are included: conveying copper foil;X-ray defectoscope penetrates copper foil;Monitoring analysis host demarcates copper foil defect;Laser cutting machine cuts copper foil defective locations;The printer that dusts blows powder and fills up copper foil defective locations;Floating is scraped in antistatic floating;Roll-in;Rewinding.After technique repairing of the invention, the quality of copper foil is effectively improved, the roughness of copper foil is controlled, improves the density of copper foil, keeps copper foil surface bright and clean, the uniformity is high, and surface defect is small, guarantees the quality of copper foil.
Description
Technical field
The present invention relates to copper foil repairing fields more particularly to a kind of ray type copper foil to overhaul correction technique.
Background technique
Currently, major part lithium ion battery producer all uses electrolytic copper foil as the negative current collector of lithium battery both at home and abroad,
Copper foil had both served as the carrier of negative electrode active material in lithium battery, and served as collection and the transmission body of cathode electron stream, therefore electricity
Tensile strength, extensibility, compactness, surface roughness, the thickness uniformity and presentation quality of copper foil etc. is solved to lithium ion battery
The chemical property of cathode manufacture craft and lithium ion battery has very big influence.
Since lithium battery copper foil is in aspect of performance, it is desirable that copper foil is few with defect, crystal grain is thin, good in oxidation resistance, folding resistance
Good, the features such as surface roughness is low, tensile strength is high and ductility is high, therefore, lithium battery copper thickness, indicated weight, tensile strength,
The needs such as room temperature elongation percentage, roughness touch the mark.
Electrolytic copper foil accounts for the 5%-8% of lithium battery cost as cathode of lithium battery collector, and copper foil is to produce dynamic lithium battery not
Can or one of scarce critical material, the superiority and inferiority of quality directly influences battery process and performance.6 μm of lithium ion batteries are new energy
Source automobile, using smart phone as the core material of the products batteries such as the 3C industry of representative, laptop, ESS energy-storage system, space flight
Material.But the technology in this field is monopolized by states such as the U.S., Japan, South Korea for a long time, currently, the pursuit of lithium electrolytic copper foil product is lightening
As trend.As the application amount of 6 microns of lithium electrolytic copper foils is increasing increasingly, aluminium foil products are in micron progress from 8 microns to 6
Transformation.The feature of 6 micron copper foils maximum be it is thin, this allows many copper foil manufacturing enterprises to hang back, and can play 6 micron copper foil advantages
Battery enterprise it is very few.
It is broken out the driving power battery market demand by new-energy automobile to increase, lithium electrolytic copper foil production capacity is well sold and in short supply, from technical standpoint
For, power battery enterprise is to meet downstream course continuation mileage demand, cost efficiency, to the demand trend of the slimming of lithium electrolytic copper foil
It grows in intensity, compared to 8 μm lithium electrolytic copper foils, 6 μm of product is the hot spot that power battery enterprise competitively chases instantly, but from reality
From the point of view of applicable cases, 6 μm of lithium electrolytic copper foils do not reach expected but in the application of power battery enterprise, first is that the country can be steady
It is few quantitatively to produce 6 μm of copper foil enterprise;Second is that encounter disconnected foil, cross cutting copper powder etc. in importing process more for power battery enterprise
A technical problem needs to solve.Currently, the stage of 6 μm of lithium electrolytic copper foil positive values " that thing which is rare is dear ", but in fact, up to the present
It can stably produce and 6 μm of lithium electrolytic copper foil enterprises for meeting the performance requirements such as power battery enterprise high flexibility, high resistance to compression count on one's fingers
Denumerable, production capacity supply in market is limited.In addition to this, power battery enterprise import 6 μm of process be also far from the industry it is expected that
Fast, the thickness of 6 μm of lithium electrolytic copper foils understands from copper foil enterprise and battery enterprise just like 1/10th of a piece hair of the mankind
It arrives, power battery enterprise from so frivolous copper foil was not used, all meets with before this in links such as coating, cross cutting, cold pressing, bakings
Not small challenge.For example currently, cutting away copper powder is exactly a difficult problem for enabling power battery enterprise headache the most.
Copper foil in lithium battery will cause very big influence: 1. rough surface big electrolytic copper foil and stone to lithium battery performance
The contact of the negative electrode active materials such as ink is poor, is also easy to produce falling off for coating active material, directly affects battery life;2, work as copper foil
When tensile strength is higher, copper foil is harder, and during will carry out roll containing the cathode of graphite active material, copper foil is without enough
To adapt to active material surface characteristic, the contact performance of the two is deteriorated for deformation;On the contrary, easily making electrode size when tensile strength is lower
Stability and planarization are deteriorated, and are also easy to produce copper foil fracture.These will lead to negative electrode material decrease in yield, influence battery capacity,
Internal resistance and service life;3, the copper foil of high-performance lithium battery must have enough elongation percentage, if elongation percentage is low, the copper in roll process
Foil will generate internal stress, divide, and influence battery capacity etc.;4, must be clean, smooth for the copper foil appearance of lithium battery, no
Allow to there is any striped, surface indentation, spot and machinery to pull, copper foil adhesive force is otherwise easy to cause to decline, coating is leaked
Foil point, two sides coating weight differ;5, the thickness uniformity has a direct impact negative electrode active material coating weight.
Because defective copper foil is used on lithium ion battery, lithium ion battery is easy breakdown, can generate explosion danger,
The danger of generation can be greatly reduced in repairing copper foil defect, during cell electrochemical reaction, because of the surface evenness of copper foil
It is relatively high, it is not easy to generate the excessive situation of local corrosion.
Based on the above situation, it is necessary to which the technique for studying a kind of copper foil repairing correction guarantees the quality of copper foil.
Summary of the invention
It is an object of the invention to overcome problem above of the existing technology, a kind of ray type copper foil maintenance correction is provided
Technique, simple process effectively improve the quality of copper foil, control the roughness of copper foil, improve after technique repairing of the invention
The density of copper foil keeps copper foil surface bright and clean, and the uniformity is high, and surface defect is small.
To realize above-mentioned technical purpose and the technique effect, the invention is realized by the following technical scheme:
A kind of ray type copper foil maintenance correction technique, including copper foil overhaul complementing equipment, and the copper foil maintenance complementing equipment includes
The copper foil conveying mechanism set gradually, x-ray defectoscope, the monitoring analysis host connecting with x-ray defectoscope, setting exist
Laser cutting machine, dusting for sprinkling N mesh copper powder on copper foil repairing platform and make copper powder be adsorbed onto the electrostatic on copper foil at printer
Generator, antistatic floating scrape, roller press mechanism and receiving mechanism, overhaul correction technique the following steps are included:
Step 1: conveying copper foil;Copper foil production equipment produces copper foil, conveys copper foil by copper foil conveying mechanism, the copper foil is defeated
The linear velocity for sending mechanism to run is 3~15 ms/min;
Step 2:X light ray defectoscope penetrates copper foil;X-ray defectoscope is with 6 meters of speed per minute by X-ray to copper foil
It is penetrated;
Step 3: monitoring analysis host demarcates copper foil defect;The copper foil analysis software being arranged in monitoring analysis host is according to setting
Copper foil defect is analyzed and judged in copper foil defect kind, shape, position, and copper foil defect is carried out to the calibration of shape and position;
Step 4: laser cutting machine cuts copper foil defective locations;According to copper foil defective locations and size, laser cutting machine cuts copper
Foil defective locations;
Step 5: the printer that dusts blows powder and fills up copper foil defective locations;Open electrostatic generator |, meanwhile, the printer that dusts blows copper
Powder fills the thickness setting that copper powder is blown to copper foil cutting position in 0.3-1.5um;
Step 6: floating is scraped in antistatic floating;It is smoothed out by antistatic and scrapes the copper powder for smoothing out filling, the copper foil after making repairing is kept
It is smooth and bright and clean;
Step 7: roll-in;The region repaired by roller press mechanism rolled copper foil and copper foil, passes through a roll-in and multiple roll-in
Make its roll-in to copper foil target thickness 6um-8um, the pressure of the roll-in is set as 0.2~0.8MPa, the roughness after rolling
Ra≤0.1~0.4 is set;
Step 8: rewinding;Roll-in is completed, and carries out coiled strip by receiving mechanism guidance copper foil.
Preferably, the x-ray defectoscope includes X-ray transmitter and X-ray receiver, the X-ray transmitter passes through X
Ray penetrates copper foil, and the image and film transport that the X-ray receiver detects X-ray transmitter give monitoring analysis host, by supervising
Copper foil defect analysis software in control analysis host analyzes the copper produced according to the copper foil defect kind of setting, shape, position
Foil defect, and calibrate shape and the position of copper foil defect.
Preferably, the step 1 carries out in order to step 8.
Preferably, the copper foil conveying mechanism includes guide roller and conveying roller, copper foil is delivered to copper foil repairing platform;Institute
Stating copper foil receiving mechanism includes guide roller and material receiving roller, and copper foil is directed to coiled strip roller by guide roller and carries out coiled strip.
Preferably, the step 4, when laser cutting machine cuts copper foil defective locations, the range of cutting is greater than copper foil
Indicated range 1mm-1cm.
Preferably, the copper powder that the printer that dusts blows 80-200 mesh fills up copper foil defective locations.
Preferably, the overall thickness of the copper foil is arranged in 6um-8um.
Preferably, being additionally provided with photoelectric sensor and gap sensor in the roller press mechanism for ensuring the thickness of copper foil
Degree.
The beneficial effects of the present invention are:
1. the defect occurred in discovery copper foil production process, not only saves manpower, reduce the labor intensity of operator, contract
Casual labourer's sequence improves working efficiency, and checks that repairing accuracy is high, and timeliness is strong, highly reliable;
2. finding defect by x-ray defectoscope and repairing defect, simple process has after technique repairing of the invention
Effect improves the quality of copper foil, controls the roughness of copper foil, improves the density of copper foil, keeps copper foil surface bright and clean, and the uniformity is high, surface
Defect is small, improves the surface quality of copper foil;
3. copper foil is avoided the bad phenomenons such as different thickness, corrugation and cracking occur, the performance of copper foil is improved on the whole, is conducive to
Application in lithium battery manufacture.
The above description is only an overview of the technical scheme of the present invention, in order to better understand the technical means of the present invention,
And can be implemented in accordance with the contents of the specification, with presently preferred embodiments of the present invention and attached drawing is cooperated to be described in detail below.This hair
Bright specific embodiment is shown in detail by following embodiment and its attached drawing.
Detailed description of the invention
The drawings described herein are used to provide a further understanding of the present invention, constitutes part of this application, this hair
Bright illustrative embodiments and their description are used to explain the present invention, and are not constituted improper limitations of the present invention.In the accompanying drawings:
Fig. 1 is process flow chart of the present invention;
Fig. 2 is that copper foil of the present invention overhauls 1 structural schematic diagram of complementing equipment;
Figure label explanation: copper foil overhauls complementing equipment 1, copper foil 11, copper foil conveying mechanism 2, x-ray defectoscope 3, monitoring
Host 4 is analyzed, copper foil repairs platform 5, and laser cutting machine 6, dust printer 7, electrostatic generator 8, and antistatic floating scrapes 9, roll-in
Mechanism 10, receiving mechanism 11, copper foil production equipment 12.
Specific embodiment
In order to which the technical features, objects and effects of invention are more clearly understood, the Detailed description of the invention present invention is now compareed
Specific embodiment, identical label indicates identical part in the various figures.
Herein, " schematic " expression " serving as examplea, instances, or illustrations " should not will be described herein as " showing
Any diagram, the embodiment of meaning property " are construed to technical solution that is a kind of preferred or more having advantages:
Referring to figs. 1 to shown in Fig. 2, a kind of ray type copper foil maintenance correction technique, including copper foil overhaul complementing equipment 1, the copper
Foil maintenance complementing equipment 1 includes the copper foil conveying mechanism 2 set gradually, and x-ray defectoscope 3 connects with x-ray defectoscope 3
The monitoring analysis host 4 connect, be arranged in copper foil repairing platform 5 on laser cutting machine 6, sprinkling N mesh copper powder dust printer 7 with
And the electrostatic generator 8 for being adsorbed onto copper powder on copper foil, antistatic floating scrape 9, roller press mechanism 10 and receiving mechanism 11, inspection
Repair positive technique the following steps are included:
Step 1: conveying copper foil;Copper foil production equipment 12 produces copper foil, conveys copper foil, the copper by copper foil conveying mechanism 2
The linear velocity that foil conveying mechanism 2 is run is 3~15 ms/min;
Copper foil conveying mechanism 2 includes guide roller and conveying roller in the present invention, and copper foil is delivered to copper foil by guide roller and conveying roller
Platform is repaired, the speed of conveying operation is 3~15 ms/min.
Step 2:X light ray defectoscope 3 penetrates copper foil;X-ray defectoscope 3 passes through X-ray with 6 meters of speed per minute
Copper foil is penetrated;
In the present invention, x-ray defectoscope 3 penetrates copper foil using X-ray, the absorption and scattering process due to copper foil to ray
Different degrees of difference the different image of blackness is then formed on egative film to keep light reaching the film different, from film and
The internal flaw that copper foil is showed in imaging is lacked image transmission to monitoring analysis host 4 by the copper foil in monitoring analysis host 4
Analysis software is fallen into according to the copper foil defect kind of setting, shape, position, analyzes lacking for the copper foil that copper foil production equipment 12 is produced
It falls into, and calibrates shape and the position of copper foil defect.
Step 3: monitoring analysis host 4 demarcates copper foil defect;The copper foil analysis software being arranged in monitoring analysis host 4 according to
The copper foil defect kind of setting, shape, position, analyze and judge copper foil defect, and copper foil defect is carried out shape and position
Calibration;
In the present invention, the defect kind of copper foil includes crackle, shrinkage cavity, stomata, slag inclusion, finish, roughness, out-of-flatness, item
Line, surface indentation, spot, machinery is pulled, density is low, burr, bending, the target thickness of copper foil and leakage foil point etc., and is determined
Defective locations and size.
In the present invention, the defect of copper foil includes the type more than being not limited to, and further includes the copper foil defect of other discoveries.
Step 4: laser cutting machine 6 cuts copper foil defective locations;According to copper foil defective locations and size, it is cut by laser machine-cut
6 cut copper foil defective locations;
In the present invention, after monitoring analysis host 4 has demarcated position and the size of copper foil defect, 6 basis of laser cutting machine
The position of the position of copper foil defect and size cutting copper foil defect.
Step 5: the printer 7 that dusts blows powder and fills up copper foil defective locations;Electrostatic generator 8 is opened, meanwhile, dust printer
7, which blow copper powder, fills the thickness setting that copper powder is blown to copper foil cutting position in 0.3-1.5um;
Cutting finishes, and user fills up defective locations by the copper powder that the printer 7 that dusts blows 80-200 mesh, while blowing copper powder,
Electrostatic generator 8 is opened, copper powder is allowed to be adsorbed on copper foil, because copper powder is thinner, copper powder passes through the method blown, it is easy to float everywhere
It dissipates, so the present invention facilitates copper powder to be adsorbed on defective locations using electrostatic generator.
Step 6: 9 floatings are scraped in antistatic floating;The copper powder for scraping 9 floatings filling is smoothed out by antistatic, the copper after making repairing
Foil keeps smooth and bright and clean;
Step 7: roll-in;The region repaired by 10 rolled copper foil of roller press mechanism and copper foil, passes through a roll-in and multiple roller
Pressure makes its roll-in to copper foil target thickness 6um-8um, and the pressure of the roll-in is set as 0.2~0.8MPa, coarse after rolling
Degree setting Ra≤0.1~0.4;
Step 8: rewinding;Roll-in is completed, and guides copper foil to carry out coiled strip by receiving mechanism 11.
In embodiments of the present invention, x-ray defectoscope 3 includes X-ray transmitter and X-ray receiver, the X-ray transmitter
Copper foil is penetrated by X-ray, the image and film transport that the X-ray receiver detects X-ray transmitter give monitoring analysis host
4, by the copper foil defect analysis software in monitoring analysis host 4 according to the copper foil defect kind of setting, shape, position, analysis life
The copper foil defect of output, and calibrate shape and the position of copper foil defect.
In embodiments of the present invention, the step 1 carries out in order to step 8.
In embodiments of the present invention, the copper foil receiving mechanism 11 includes guide roller and material receiving roller, by guide roller by copper foil
It is directed to coiled strip roller and carries out coiled strip.
In embodiments of the present invention, the step 4 is when laser cutting machine 6 cuts copper foil defective locations, the model of cutting
It encloses and is greater than copper foil indicated range 1mm-1cm.
In embodiments of the present invention, the overall thickness of copper foil is arranged in 6um-8um.
In embodiments of the present invention, photoelectric sensor and gap sensor are additionally provided in roller press mechanism 10 for ensuring copper
The thickness of foil.
Specific embodiment:
In actual use, copper foil production equipment 12 produces copper foil, conveys copper foil by copper foil conveying mechanism 2, in conveying copper
While foil, x-ray defectoscope 3 penetrates copper foil using X-ray, by image transmission to monitoring analysis host 4, by monitoring analysis
Copper foil defect analysis software in host 4 analyzes copper foil production equipment 12 according to the copper foil defect kind of setting, shape, position
The defect for the copper foil produced, and calibrate shape and the position of copper foil defect, laser cutting machine 6 according to copper foil defective locations and
Size is cut by laser copper foil defective locations, defective locations is cut off, cutting finishes, and the printer 7 that dusts blows copper powder and fills to copper foil
Cutting position, while electrostatic generator 8 is opened, facilitate copper powder to be adsorbed on defective locations, then scrapes 9 floatings using antistatic floating
The copper powder of filling, the copper foil after making repairing keep smooth and bright and clean, are repaired by 10 rolled copper foil of roller press mechanism and copper foil
Region makes its roll-in to copper foil target thickness 6um-8um, finally, roll-in is completed, by rewinding by a roll-in and multiple roll-in
Mechanism 11 guides copper foil to carry out coiled strip.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain
Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.
Claims (8)
1. a kind of ray type copper foil overhauls correction technique, it is characterised in that: overhaul complementing equipment (1) including copper foil, the copper foil
Maintenance complementing equipment (1) includes the copper foil conveying mechanism (2) set gradually, and x-ray defectoscope (3) is detected a flaw with x-ray
The monitoring analysis host (4) of instrument (3) connection, the laser cutting machine (6) being arranged in copper foil repairing platform (5) spray N mesh copper powder
Dust printer (7) and the electrostatic generator (8) that is adsorbed onto copper powder on copper foil, and (9), roller press mechanism are scraped in antistatic floating
(10) and receiving mechanism (11), overhaul the technique of correction the following steps are included:
Convey copper foil;Copper foil production equipment (12) produces copper foil, conveys copper foil, the copper foil by copper foil conveying mechanism (2)
The linear velocity of conveying mechanism (2) operation is 3~15 ms/min;
X-ray defectoscope (3) penetrates copper foil;X-ray defectoscope (3) is with 6 meters of speed per minute by X-ray to copper foil
It is penetrated;
Monitoring analysis host (4) demarcates copper foil defect;The copper foil analysis software being arranged in monitoring analysis host (4) is according to setting
Copper foil defect is analyzed and judged in copper foil defect kind, shape, position, and copper foil defect is carried out to the calibration of shape and position;
Laser cutting machine (6) cuts copper foil defective locations;According to copper foil defective locations and size, it is cut by laser machine-cut (6) and cuts copper
Foil defective locations;
The printer (7) that dusts blows powder and fills up copper foil defective locations;Open electrostatic generator | (8), meanwhile, the printer that dusts (7) is blown
Copper powder fills the thickness setting that copper powder is blown to copper foil cutting position in 0.3-1.5um;
(9) floating is scraped in antistatic floating;The copper powder scraped (9) and smooth out filling is smoothed out by antistatic, the copper foil after making repairing is kept
It is smooth and bright and clean;
Roll-in;The region repaired by roller press mechanism (10) rolled copper foil and copper foil, is made by a roll-in and multiple roll-in
Its roll-in is to copper foil target thickness 6um-8um, and the pressure of the roll-in is set as 0.2~0.8MPa, and the roughness after rolling is set
Set Ra≤0.1~0.4;
Rewinding;Roll-in is completed, and carries out coiled strip by receiving mechanism (11) guidance copper foil.
2. a kind of ray type copper foil according to claim 1 overhauls correction technique, it is characterised in that: the x-ray is visited
Hurting instrument (3) includes X-ray transmitter and X-ray receiver, and the X-ray transmitter penetrates copper foil, the X-ray receiver by X-ray
The image and film transport that X-ray transmitter is detected give monitoring analysis host (4), are lacked by the copper foil in monitoring analysis host (4)
Analysis software is fallen into according to the copper foil defect kind of setting, shape, position, analyzes the copper that the copper foil production equipment (12) is produced
Foil defect, and calibrate the shape and position and size of copper foil defect.
3. a kind of ray type copper foil according to claim 1 overhauls correction technique, it is characterised in that: the step 1 to step
Rapid 8 carry out in order.
4. a kind of ray type copper foil according to claim 1 overhauls correction technique, it is characterised in that: the copper foil conveyer
Structure (2) includes guide roller and conveying roller, copper foil is directed to conveying roller by guide roller, copper foil is delivered to copper foil repairing platform;It is described
Copper foil receiving mechanism (11) includes guide roller and material receiving roller, and copper foil is directed to coiled strip roller by guide roller and carries out coiled strip.
5. a kind of ray type copper foil according to claim 1 overhauls correction technique, it is characterised in that: the step 4 is swashing
When light cutting machine (6) cuts copper foil defective locations, the range of cutting is greater than copper foil indicated range 1mm-1cm.
6. a kind of ray type copper foil according to claim 1 overhauls correction technique, it is characterised in that: the printer that dusts
(7) copper powder for blowing 80-200 mesh fills up copper foil defective locations.
7. a kind of ray type copper foil according to claim 1 overhauls correction technique, it is characterised in that: the total thickness of the copper foil
Degree is arranged in 6um-8um.
8. a kind of ray type copper foil according to claim 1 overhauls correction technique, it is characterised in that: the roller press mechanism
(10) it is additionally provided with photoelectric sensor on and gap sensor is used to ensure the thickness of copper foil.
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CN103499585A (en) * | 2013-10-22 | 2014-01-08 | 常州工学院 | Non-continuity lithium battery thin film defect detection method and device based on machine vision |
CN204855404U (en) * | 2015-06-29 | 2015-12-09 | 南通蒂龙针织制衣有限公司 | Electrolytic capacitor foil strips defect detecting system |
CN105478477A (en) * | 2016-01-01 | 2016-04-13 | 杭州巨力绝缘材料有限公司 | Aluminum foil air gap filling production line and filling method |
CN105677970A (en) * | 2016-01-07 | 2016-06-15 | 浪潮集团有限公司 | Copper-deficiency automatic supplementing method with no need of repeatedly avoiding copper |
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US4690721A (en) * | 1983-07-06 | 1987-09-01 | Santrade Ltd. | Apparatus and process for the production of multilayer laminated plates |
CN102175701A (en) * | 2011-02-11 | 2011-09-07 | 王慧斌 | System and method for online flaw detection of industrial X-ray machine |
CN103499585A (en) * | 2013-10-22 | 2014-01-08 | 常州工学院 | Non-continuity lithium battery thin film defect detection method and device based on machine vision |
CN204855404U (en) * | 2015-06-29 | 2015-12-09 | 南通蒂龙针织制衣有限公司 | Electrolytic capacitor foil strips defect detecting system |
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