CN109722930A - A kind of the anti-inflammatory paper and its method of the preparation of prescriptions worth thousand gold dregs of a decoction resource regeneration - Google Patents
A kind of the anti-inflammatory paper and its method of the preparation of prescriptions worth thousand gold dregs of a decoction resource regeneration Download PDFInfo
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Abstract
The present invention relates to the anti-inflammatory paper and its method of a kind of preparation of prescriptions worth thousand gold dregs of a decoction resource regeneration, the technique for disclosing prescriptions worth thousand gold dregs of a decoction papermaking includes the Microwave Pretreatment of the dregs of a decoction, ethanol pulping, papermaking, extracts effective component in black liquor and the techniques such as paper is modified.The present invention is using the prescriptions worth thousand gold dregs of a decoction as preparation staple fiber, and in conjunction with the long fibre characteristic of cotton fiber, the anti-inflammatory of preparation has extraordinary tensile property with paper, while being applied by plasm-glue-blending and surface, has significant wet strength.The present invention does not introduce harmful chemicals using ethanol pulping whole process, it is ensured that the hygienic characteristic of paper.The effect of pharmacological property ingredient mixes upper prescriptions worth thousand gold ingredient is also extracted in initiative slave black liquor of pulp making, and u is applied to paper itself, has good anti-inflammatory, antibiotic effect, can prevent microorganism infection, there is cleaning, comfortable, health-care effect when use, be suitble to the application of anti-inflammatory articles.
Description
Technical field
The invention belongs to dregs of a decoction resource regeneration technical fields, and in particular, to a kind of prescriptions worth thousand gold dregs of a decoction resource regeneration
Utilize the anti-inflammatory paper and its method of preparation.
Background technique
Dregs of a decoction resource regeneration is the important proposition of the field of Chinese medicines.Chinese medicine slag is both medical processing enterprise's production Chinese herbal medicine
The discarded object of power boiler discharge generated in the process, while being also the distinctive plant fiber resource of China, it is the weight of pulp and paper industry
Want raw material.The Chinese medicine slag residue that be Chinese medicine remaining after water or organic solvent extraction, ingredient be mainly cellulose,
Hemicellulose and lignin are limited since Chinese medicine is generally herbaceous plant by chemical pulping process and equipment, Chinese medicine slag ingredient
Diversity and complexity and Chinese medicine slag institute fibre-bearing is short and small, influence of the heteroproteose cell mostly with pigment weight so that using Chinese medicine slag into
Row chemical pulping is by a degree of obstruction.
The Organosolv Pulping to grow up in recent years can provide better delignification method, the wood of degradation
There are more response function groups in element, hemicellulose, and easier can recycle, purify from solvent medium.?
Under certain condition, organic solvent can be with the lignin in degrading plant raw material, so that it is efficient to reach lignin, cellulose, hemicellulose
Isolated purpose, and organic solvent can be recovered by distillation, the basic non-wastewater discharge of whole process, be to realize pollution-free green
The effective technical way of environmentally friendly papermaking.
Wherein, ethanol pulping is pulping process the most typical in organic solvent pulping, including self-catalysis, base catalysis
With acid catalysis ethanol pulping technology.Auto-catalyzed ethanol pulping is since high with pulping yield, pulping process is simple, byproduct can have
Effect such as utilizes at the advantages, and becomes research hotspot.But there are lignin macromolecule structures to remove difficulty for traditional Auto-catalyzed Ethanol Pulping
Greatly, the defects of Kappa number is high eventually leads to pulping yield and the low problem of fiber fineness.
In addition, naturally containing pharmacological property ingredient in Chinese medicine slag, how to retain during resource recycling and utilize it
Pharmacological property ingredient provides the surcharge of product, realizes that high price value utilizes, exactly realizes the difficulty of dregs of a decoction resource recycling
Topic.
Summary of the invention
The technical problem to be solved by the present invention is to the prescriptions worth thousand gold dregs of a decoction to prepare fibre technology deficiency, provide a kind of prescriptions worth thousand gold dregs of a decoction
The method of resource regeneration preparation anti-inflammatory paper.The method is not only able to effectively solve lignin macromolecule structure removing difficulty
Big problem, fiber yield is high, and performance is good；The pharmacological property ingredient of pulping raw material can also be made full use of, is made with medicinal function
Anti-inflammatory paper provides thinking for the reasonable resource regeneration of Chinese medicine slag.
Another object of the present invention is to provide a kind of anti-inflammatory paper of prescriptions worth thousand gold dregs of a decoction resource regeneration preparation.
The present invention is achieved by the following technical solutions:
A kind of method of prescriptions worth thousand gold dregs of a decoction resource regeneration preparation anti-inflammatory paper, comprising the following steps:
S1. it pre-processes: the prescriptions worth thousand gold dregs of a decoction that water content is 25%~45% is subjected to Micro-wave pretreatment, microwave power
For 900~1500W, microwave irradiation time is 5~10min, for use；
S2. boiling: the prescriptions worth thousand gold dregs of a decoction that step S1 is obtained are placed in boiling vessel, and the second that concentration is 40%~60% is added
After alcoholic solution, liquor ratio is 1:4~5, is rapidly heated to 120~140 DEG C, and blowing after 100~120min of insulation reaction is slightly starched
Material and black liquor；
S3. it washs: the obtained coarse particles of step S2 is placed in displacement washing device, the ethyl alcohol for being 55%~70% with concentration
Solution carries out multistage displacement washing, and cleaning solution ratio is 1:7~8, and wash temperature is 40~60 DEG C；Then it is washed with water completely, obtains
To dreg fibers；
S4. the extraction of effective component: concentration is evaporated to the black liquor in S2, is obtained after recycling of condensed steam ethyl alcohol water-soluble
Liquid is concentrated, and obtaining has effective component solution；
S5. papermaking: dreg fibers made from S3 are mixed with cotton pulp, filler are added, internal sizing agent is manufactured paper with pulp, progress
Body paper is obtained after top sizing；The dreg fibers and the usage ratio of cotton pulp are 70~80:20~30；
S6. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
Effective component solution in basic medical fluid and S4 is mixed to get medical fluid；
By the body paper surface of medicine liquid spray and S5, the anti-inflammatory paper with pharmacological property is obtained after dry.
Preferably, the prescriptions worth thousand gold dregs of a decoction are very heavy group, cherokee rose root, Caulis Spatholobi, single side needle, leatherleaf mahonia, Herba Andrographitis, Radix Angelicae Sinensis
With residue mixing of the Radix Codonopsis after water or ethyl alcohol extract.
Preferably, the preparation method of the prescriptions worth thousand gold dregs of a decoction is prepared with reference to the method for following patent notes: (1)
ZL99115682.X, a kind of manufacture craft of ' Qianjin ' capsule to treat ganopathy；(2) a kind of manufacture of ' Qianjin ' capsule to treat ganopathy of ZL99115683.8
Method；(3) preparation method of ZL98112696.0 compound Chinese medicinal preparation FUKE QIANJIN PIAN.
Preferably, the partial size of the prescriptions worth thousand gold dregs of a decoction is less than 3cm.
Preferably, the water content of the prescriptions worth thousand gold dregs of a decoction is 30%~35% in step S1, and microwave power is 1000~1200W,
Microwave irradiation time is 7~8min.
Preferably, in step S2, after the ethanol solution that concentration is 53% is added, liquor ratio 1:4.5 is rapidly heated to 130
DEG C, blowing after insulation reaction 110min obtains coarse particles and black liquor.
Preferably, 3 sections of displacement washings are carried out with the ethanol solution that concentration is 60% in step S3, cleaning solution ratio for 1:7~
8, wash temperature is 50 DEG C.
Preferably, the water content of the body paper is 91%~93%.
Preferably, the temperature that black liquor vaporizing is concentrated in step S4 is 110~120 DEG C, described to have in effective component solution
Concentration of alcohol is 20%~25%.
Preferably, dreg fibers made from S3 are beaten in step S5, beating degree is 37~47oSR；The cotton pulp
Beating degree be 25~30oSR；Using starch as Cypres；Preferably, Cypres concentration is 8%~10%,
Coating weight is 0.7~1g/m2.The present invention, as sizing agent, can be improved the physical property of paper, also remain paper using starch
The health opened avoids chemicals bring from endangering.
Preferably, the dreg fibers and the usage ratio of cotton pulp are 70:25；Preferably, the filler be calcium carbonate or
Talcum powder；The internal sizing agent is starch, polyacrylamide or modified rosin；Preferably, the dosage of the internal sizing agent
It is the 0.7%~0.9% of over dry slurry weight.
Preferably, in step S6, by the body paper surface of medicine liquid spray and S5, the anti-inflammatory paper with pharmacological property is obtained after dry
Fountain height with effective component solution is the 20%~30% of original paper quality, and obtaining after dry at 60~65 DEG C has pharmacological property
Anti-inflammatory paper.
A kind of anti-inflammatory paper of the method preparation by above-mentioned prescriptions worth thousand gold dregs of a decoction resource regeneration preparation anti-inflammatory paper.This disappears
Inflammation paper is preparing the application in amenities or medical supplies.
The present invention pre-processes the prescriptions worth thousand gold dregs of a decoction using microwave irradiation, and plant cell wall tissue is made to generate micropore knot
Structure is more advantageous to the chemical reaction of subsequent delignification, and the lignin components being very beneficial in the dregs of a decoction are separated, and solves in a creative way
Lignin macromolecule structure of having determined removes the big problem of difficulty, to obtain the fiber of high-purity.Meanwhile using microwave irradiation pair
The dregs of a decoction are pre-processed, moreover it is possible to generate the substance with bonding or glue blending function, these substances play the work of reinforcing fibre crosslinking
With so that the physical property at paper is reinforced.
The present invention using the prescriptions worth thousand gold dregs of a decoction as the raw material for preparing fiber, due to the prescriptions worth thousand gold dregs of a decoction exist simultaneously herbaceous plant and
Shrub raw material, acetyl content is higher and lignin in based on the strong p-hydroxyphenyl type lignin building unit of activity, raw material mix
Loose, cooperation uses microwave irradiation and Ethanol Method, and scientific control prepares liquor ratio during fiber, temperature and time, so that
A large amount of existing acetyl group hydrolysis generate acetic acid in the dregs of a decoction, acidity needed for obtaining ethanol pulping system, using this law slurrying
Paper pulp yield is high, is not necessarily to boiling and washing at high temperature under high pressure, can be obtained the slurry that residual lignin content is few, Kappa number is low.
Compared with prior art, the invention has the following advantages:
The present invention utilizes microwave irradiation technology for the first time, fiber is prepared using the prescriptions worth thousand gold dregs of a decoction as raw material, according to the prescriptions worth thousand gold dregs of a decoction
Herbaceous plant and shrub raw material this characteristic are existed simultaneously, isolates lignin components from the dregs of a decoction with the use of microwave technology, is promoted
Into the decomposition of lignin macromolecule structure and the fracture of chemical bond, it is more advantageous to the chemical reaction of subsequent delignification, it can be better
Lignin in paper pulp is dissolved out, the lower slurry of Kappa number is obtained.
The method that prescriptions worth thousand gold dregs of a decoction resource regeneration provided by the invention prepares fiber, simple process, ethyl alcohol can lead to
It crosses distillation recovery to recycle, to supplement ethyl alcohol for subsequent processing steps, whole preparation process is environmentally protective, has wide hair
Exhibition prospect.
In conclusion using microwave irradiation technology in conjunction with Ethanol Method, it is residual using the fiber that the prescriptions worth thousand gold dregs of a decoction are prepared as raw material
Stay lignin content low, and pulp preparing process is simple, easy to operate, the time is short.Using the coarse particles tool of the method for the present invention preparation
Have the characteristics that Kappa number is low, intensity is good, fiber yield is greater than 75%, and Kappa number is 30% or so.The paper performance of anti-inflammatory paper
Good, in view of the property of raw material of the prescriptions worth thousand gold dregs of a decoction, the features such as staple fiber and more heteroproteose cell, the dry tensile index of paper reaches 50N.m/
G or more, wet tensile index reach 13N.m/g or more.
The present invention uses ethanol pulping, and using solvent identical with pharmacy procedure, pulping process does not introduce harmful
Product, it is ensured that the hygienic characteristic of fiber.
Extract pharmacological property ingredient in the also initiative slave black liquor of pulp making of the present invention, and be applied to body paper itself, anti-inflammatory obtained
There is good anti-inflammatory, antibiotic effect with paper, there is high functional characteristic and added value.
Specific embodiment
The present invention is further illustrated combined with specific embodiments below.Unless stated otherwise, it is used in the embodiment of the present invention
Raw material and method are the raw material of this field regular market purchase and conventional use of method, used equipment are that this field is routinely set
It is standby.
The preparation method of basic medical fluid:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
First by Herba Andrographitis and the Radix Angelicae Sinensis effective ingredient that with 85% concentration the heated circumfluence method of ethyl alcohol both is extracted, filter
The filtrate that ethyl alcohol is solvent is obtained after de- slag, recovered ethyl alcohol obtains filtrate.
Secondly respectively by leatherleaf mahonia, single side needle and very heavy group, cherokee rose root, Caulis Spatholobi, Radix Codonopsis distinguish boiling, it is extracted,
It filters de- slag and obtains corresponding filtrate；It will wherein leave after very heavy group, cherokee rose root, Caulis Spatholobi, Radix Codonopsis boiling and extracted again；It should
Extracting solution merges with first time extracting solution.
Embodiment 1
A kind of method that prescriptions worth thousand gold dregs of a decoction resource regeneration prepares fiber, comprising the following steps:
S1. it pre-processes: the prescriptions worth thousand gold dregs of a decoction that water content is 25% being subjected to Micro-wave pretreatment, microwave power is
900W, microwave irradiation time 5min, for use；
S2. boiling: the prescriptions worth thousand gold dregs of a decoction that step S1 is obtained are placed in boiling vessel, and the ethanol solution that concentration is 40% is added
Afterwards, liquor ratio 1:4 is rapidly heated to 120 DEG C, and blowing after insulation reaction 100min obtains coarse particles and black liquor；
S3. wash: the obtained coarse particles of step S2 are placed in displacement washing device, with concentration be 55% ethanol solution into
3 sections of displacement washings of row, cleaning solution ratio are 1:7, and wash temperature is 40 DEG C；Then it is washed with water completely, obtains dreg fibers；
S4. the extraction of effective component: concentration is evaporated to the black liquor in S2, is obtained after recycling of condensed steam ethyl alcohol water-soluble
Liquid is concentrated, and obtaining has effective component solution；The temperature of black liquor vaporizing concentration is 110 DEG C, described to have effective component molten
Concentration of alcohol is 20% in liquid.
S5. papermaking:
Dreg fibers made from S3 are beaten, beating degree 37oSR；The beating degree of cotton pulp is 25oSR；Dreg fibers
Usage ratio with cotton pulp is 70:30.Filler is calcium carbonate, and amount of filler 5%, internal sizing agent is starch, plasm-glue-blending
The dosage of agent is the 0.7% of over dry slurry weight.Then it manufactures paper with pulp, using starch as Cypres, Cypres are dense
Degree is 8%, coating weight 0.7g/m2, body paper is obtained after drying.The water content of body paper is 91%.
S6. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
Effective component solution in basic medical fluid and S4 is mixed to get medical fluid；
By the body paper surface of medicine liquid spray and S5, the anti-inflammatory paper with pharmacological property is obtained after dry.In step S6, by medical fluid
The body paper surface of sprinkling and S5, it is body paper that the anti-inflammatory with pharmacological property is obtained after dry to have the fountain height of effective component solution with paper
The 20% of quality obtains the fiber with pharmacological property after dry at 60 DEG C.
The preparation method of the prescriptions worth thousand gold dregs of a decoction is referred to patent ZL99115682.X, a kind of production work of ' Qianjin ' capsule to treat ganopathy
Skill, the prescriptions worth thousand gold dregs of a decoction are very heavy group, cherokee rose root, Caulis Spatholobi, single side needle, leatherleaf mahonia, Herba Andrographitis, Radix Angelicae Sinensis and Radix Codonopsis pass through water or second
Residue mixing after alcohol extracting.The partial size of the prescriptions worth thousand gold dregs of a decoction is less than 3cm.
Embodiment 2
A kind of method that prescriptions worth thousand gold dregs of a decoction resource regeneration prepares fiber, comprising the following steps:
S1. it pre-processes: the prescriptions worth thousand gold dregs of a decoction that water content is 45% being subjected to Micro-wave pretreatment, microwave power is
1500W, microwave irradiation time 10min, for use；
S2. boiling: the prescriptions worth thousand gold dregs of a decoction that step S1 is obtained are placed in boiling vessel, and the ethanol solution that concentration is 60% is added
Afterwards, liquor ratio 1:5 is rapidly heated to 140 DEG C, and blowing after insulation reaction 120min obtains coarse particles and black liquor；
S3. wash: the obtained coarse particles of step S2 are placed in displacement washing device, with concentration be 70% ethanol solution into
3 sections of displacement washings of row, cleaning solution ratio are 1:8, and wash temperature is 60 DEG C；Then it is washed with water completely, obtains dreg fibers；
S4. the extraction of effective component: concentration is evaporated to the black liquor in S2, is obtained after recycling of condensed steam ethyl alcohol water-soluble
Liquid is concentrated, and obtaining has effective component solution；The temperature of black liquor vaporizing concentration is 120 DEG C, described to have effective component molten
Concentration of alcohol is 25% in liquid.
S5. papermaking:
Dreg fibers made from S3 are beaten, beating degree 47oSR；The beating degree of cotton pulp is 30oSR；Dreg fibers
Usage ratio with cotton pulp is 80:20.Filler is calcium carbonate, and amount of filler 8%, internal sizing agent is polyacrylamide, slurry
The dosage of sizing agent is the 0.9% of over dry slurry weight.Then it manufactures paper with pulp, using starch as Cypres, surface is applied
Jelly concentration is 10%, coating weight 1g/m2, body paper is obtained after drying.The water content of body paper is 93%.
S6. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
Effective component solution in basic medical fluid and S4 is mixed to get medical fluid；
By the body paper surface of medicine liquid spray and S5, the anti-inflammatory paper with pharmacological property is obtained after dry.In step S6, by medical fluid
The body paper surface of sprinkling and S5, it is body paper that the anti-inflammatory with pharmacological property is obtained after dry to have the fountain height of effective component solution with paper
The 30% of quality obtains the fiber with pharmacological property after dry at 65 DEG C.
The preparation method of the prescriptions worth thousand gold dregs of a decoction is referred to a kind of manufacturing method of ' Qianjin ' capsule to treat ganopathy of patent ZL99115683.8,
The prescriptions worth thousand gold dregs of a decoction are very heavy group, cherokee rose root, Caulis Spatholobi, single side needle, leatherleaf mahonia, Herba Andrographitis, Radix Angelicae Sinensis and Radix Codonopsis pass through water or ethyl alcohol
Residue mixing after extraction.The partial size of the prescriptions worth thousand gold dregs of a decoction is less than 2cm.
Embodiment 3
A kind of method that prescriptions worth thousand gold dregs of a decoction resource regeneration prepares fiber, comprising the following steps:
S1. it pre-processes: the prescriptions worth thousand gold dregs of a decoction that water content is 30% being subjected to Micro-wave pretreatment, microwave power is
1000W, microwave irradiation time 7min, for use；
S2. boiling: the prescriptions worth thousand gold dregs of a decoction that step S1 is obtained are placed in boiling vessel, and the ethanol solution that concentration is 53% is added
Afterwards, liquor ratio 1:4.5 is rapidly heated to 130 DEG C, and blowing after insulation reaction 110min obtains coarse particles and black liquor；
S3. wash: the obtained coarse particles of step S2 are placed in displacement washing device, with concentration be 60% ethanol solution into
3 sections of displacement washings of row, cleaning solution ratio are 1:7, and wash temperature is 50 DEG C；Then it is washed with water completely, obtains dreg fibers.
S4. the extraction of effective component: concentration is evaporated to the black liquor in S2, is obtained after recycling of condensed steam ethyl alcohol water-soluble
Liquid is concentrated, and obtaining has effective component solution；The temperature that black liquor vaporizing is concentrated in step S4 is 110 DEG C, described to have medicine
Imitating concentration of alcohol in ingredient solution is 20%.
S5. papermaking:
Dreg fibers made from S3 are beaten, beating degree 40oSR；The beating degree of cotton pulp is 26oSR；Dreg fibers
Usage ratio with cotton pulp is 75:25.Filler is talcum powder, and amount of filler 6%, internal sizing agent is polyacrylamide, slurry
The dosage of sizing agent is the 0.8% of over dry slurry weight.Then it manufactures paper with pulp, using starch as Cypres, surface is applied
Jelly concentration is 9%, coating weight 0.8g/m2, body paper is obtained after drying.The water content of body paper is 92%.
S6. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
Effective component solution in basic medical fluid and S4 is mixed to get medical fluid；
By the body paper surface of medicine liquid spray and S5, the anti-inflammatory paper with pharmacological property is obtained after dry.In step S6, by medical fluid
The body paper surface of sprinkling and S5, it is body paper that the anti-inflammatory with pharmacological property is obtained after dry to have the fountain height of effective component solution with paper
The 25% of quality obtains the fiber with pharmacological property after dry at 63 DEG C.
The preparation method of the prescriptions worth thousand gold dregs of a decoction refers to matching with patent ZL98112696.0 compound Chinese medicinal preparation FUKE QIANJIN PIAN
Method processed, the prescriptions worth thousand gold dregs of a decoction are very heavy group, cherokee rose root, Caulis Spatholobi, single side needle, leatherleaf mahonia, Herba Andrographitis, Radix Angelicae Sinensis and Radix Codonopsis pass through water
Or the residue mixing after ethyl alcohol extraction.
Embodiment 4
A kind of method that prescriptions worth thousand gold dregs of a decoction resource regeneration prepares fiber, comprising the following steps:
S1. it pre-processes: the prescriptions worth thousand gold dregs of a decoction that water content is 35% being subjected to Micro-wave pretreatment, microwave power is
1200W, microwave irradiation time 8min, for use；
S2. boiling: the prescriptions worth thousand gold dregs of a decoction that step S1 is obtained are placed in boiling vessel, and the ethanol solution that concentration is 53% is added
Afterwards, liquor ratio 1:4.5 is rapidly heated to 130 DEG C, and blowing after insulation reaction 110min obtains coarse particles and black liquor；
S3. wash: the obtained coarse particles of step S2 are placed in displacement washing device, with concentration be 60% ethanol solution into
3 sections of displacement washings of row, cleaning solution ratio are 1:7, and wash temperature is 50 DEG C；Then it is washed with water completely, obtains dreg fibers.
S4. the extraction of effective component: concentration is evaporated to the black liquor in S2, is obtained after recycling of condensed steam ethyl alcohol water-soluble
Liquid is concentrated, and obtaining has effective component solution；The temperature that black liquor vaporizing is concentrated in step S4 is 120 DEG C, described to have medicine
Imitating concentration of alcohol in ingredient solution is 25%.
S5. papermaking:
Fiber made from S3 is beaten, beating degree is 43 ° of SR；The beating degree of cotton pulp is 28 ° of SR；Dreg fibers and cotton
The usage ratio of slurry is 76:24.Filler is calcium carbonate, and amount of filler 7%, internal sizing agent is modified rosin, plasm-glue-blending
The dosage of agent is the 0.9% of over dry slurry weight.Then it manufactures paper with pulp, using starch as Cypres, Cypres are dense
Degree is 8%, coating weight 0.9g/m2, body paper is obtained after drying.The water content of body paper is 93%.
S6. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
Effective component solution in basic medical fluid and S4 is mixed to get medical fluid；
By the body paper surface of medicine liquid spray and S5, the anti-inflammatory paper with pharmacological property is obtained after dry.In step S6, by medical fluid
The body paper surface of sprinkling and S5, it is body paper that the anti-inflammatory with pharmacological property is obtained after dry to have the fountain height of effective component solution with paper
The 25% of quality obtains the fiber with pharmacological property after dry at 62 DEG C.
The preparation method of the prescriptions worth thousand gold dregs of a decoction is referred to patent ZL99115682.X, a kind of production work of ' Qianjin ' capsule to treat ganopathy
Skill, the prescriptions worth thousand gold dregs of a decoction are very heavy group, cherokee rose root, Caulis Spatholobi, single side needle, leatherleaf mahonia, Herba Andrographitis, Radix Angelicae Sinensis and Radix Codonopsis pass through water or second
Residue mixing after alcohol extracting.
Comparative example 1 (does not have Microwave Pretreatment)
A kind of method that prescriptions worth thousand gold dregs of a decoction resource regeneration prepares fiber, comprising the following steps:
S1. boiling: the prescriptions worth thousand gold dregs of a decoction that water content is 30% are placed in boiling vessel, and it is molten that the ethyl alcohol that concentration is 53% is added
After liquid, liquor ratio 1:4.5 is rapidly heated to 130 DEG C, and blowing after insulation reaction 110min obtains coarse particles and black liquor；
S2. wash: the obtained coarse particles of step S1 are placed in displacement washing device, with concentration be 60% ethanol solution into
3 sections of displacement washings of row, cleaning solution ratio are 1:7, and wash temperature is 50 DEG C；Then it is washed with water completely, obtains dreg fibers.
S3. the extraction of effective component: concentration is evaporated to the black liquor in S1, is obtained after recycling of condensed steam ethyl alcohol water-soluble
Liquid is concentrated, and obtaining has effective component solution；The temperature that black liquor vaporizing is concentrated in step S3 is 110 DEG C, described to have medicine
Imitating concentration of alcohol in ingredient solution is 20%.
S4. papermaking: fiber made from S2 is beaten, and beating degree is 40 ° of SR, is then manufactured paper with pulp, is made using starch
For Cypres, body paper is obtained after dry.The water content of body paper is 92%.Cypres concentration is 9%, and coating weight is
0.8g/m2。
Dreg fibers made from S2 are beaten, beating degree is 40 ° of SR；The beating degree of cotton pulp is 26 ° of SR；Dreg fibers
Usage ratio with cotton pulp is 75:25.Filler is talcum powder, and amount of filler 6%, internal sizing agent is polyacrylamide, slurry
The dosage of sizing agent is the 0.8% of over dry slurry weight.Then it manufactures paper with pulp, using starch as Cypres, surface is applied
Jelly concentration is 9%, coating weight 0.8g/m2, body paper is obtained after drying.The water content of body paper is 92%.
S5. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: the incorporation of Radix Angelicae Sinensis, Radix Codonopsis, Herba Andrographitis and single side needle
Amount is respectively the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；
Effective component solution in basic medical fluid and S4 is mixed to get medical fluid；
By the body paper surface of medicine liquid spray and S4, the anti-inflammatory paper with pharmacological property is obtained after dry.In step S5, by medical fluid
The body paper surface of sprinkling and S4, it is body paper that the anti-inflammatory with pharmacological property is obtained after dry to have the fountain height of effective component solution with paper
The 25% of quality obtains the fiber with pharmacological property after dry at 63 DEG C.
Comparative example 2 (does not apply medical fluid)
A kind of method that prescriptions worth thousand gold dregs of a decoction resource regeneration prepares fiber, comprising the following steps:
S1. it pre-processes: the prescriptions worth thousand gold dregs of a decoction that water content is 30% being subjected to Micro-wave pretreatment, microwave power is
1000W, microwave irradiation time 7min, for use；
S2. boiling: the prescriptions worth thousand gold dregs of a decoction that step S1 is obtained are placed in boiling vessel, and the ethanol solution that concentration is 53% is added
Afterwards, liquor ratio 1:4.5 is rapidly heated to 130 DEG C, and blowing after insulation reaction 110min obtains coarse particles and black liquor；
S3. wash: the obtained coarse particles of step S2 are placed in displacement washing device, with concentration be 60% ethanol solution into
3 sections of displacement washings of row, cleaning solution ratio are 1:7, and wash temperature is 50 DEG C；Then it is washed with water completely, obtains fiber after dry.
S4. papermaking: dreg fibers made from S3 are beaten, and beating degree is 40 ° of SR；The beating degree of cotton pulp is 26 ° of SR；
Dreg fibers and the usage ratio of cotton pulp are 75:25.Filler is talcum powder, and amount of filler 6%, internal sizing agent is polypropylene
Amide, the dosage of internal sizing agent are the 0.8% of over dry slurry weight.Then it manufactures paper with pulp, using starch as Cypres,
Cypres concentration is 9%, coating weight 0.8g/m2, body paper is obtained after drying.The water content of body paper is 92%.
Comparative example 3~6 (microwave treatment condition is poor)
The process conditions of comparative example 3~6 are similar to Example 3, the difference is that following technique is respectively adopted in step S1
Condition:
| Prescriptions worth thousand gold dregs of a decoction water content, % | Microwave power, w | Microwave time, min | |
| Comparative example 3 | 24 | 850 | 10 |
| Comparative example 4 | 24 | 1000 | 7 |
| Comparative example 5 | 46 | 1550 | 5 |
| Comparative example 6 | 30 | 850 | 10 |
Comparative example 7~12 (digesting technoloy is poor)
The process conditions of comparative example 7~12 are similar to Example 3, the difference is that following technique is respectively adopted in step S2
Condition:
Comparative example 13~15 (effective component)
The process conditions of comparative example 13~15 are similar to Example 3, the difference is that following work is respectively adopted in step S4
Skill condition:
| The temperature of concentration, DEG C | Concentration of alcohol, % | |
| Comparative example 13 | 105 | 20 |
| Comparative example 14 | 125 | 25 |
| Comparative example 15 | 110 | 18 |
Comparative example 16~18 (spray processing)
The process conditions of comparative example 16~18 are similar to Example 3, the difference is that following work is respectively adopted in step S6
Skill condition:
| Fountain height, % | Drying temperature, DEG C | |
| Comparative example 16 | 32 | 63 |
| Comparative example 17 | 18 | 63 |
| Comparative example 18 | 25 | 67 |
Comparative example 19~21
The process conditions of comparative example 19~21 are similar to Example 3, the difference is that following work is respectively adopted in step S5
Skill condition:
Kappa number measurement and pulping yield are carried out to the fiber that the preparation method of Examples 1 to 4 and comparative example 1~21 obtains
It calculates, wherein Kappa number is measured according to standard GB/T/T 1546-2004, and to paper strength, Pharmaceutical Compositions content
(being reference with the content of the Berberine hydrochloride in fiber) is measured.It the results are shown in Table 1.
Table 1
It is found that the present invention is using the dregs of a decoction as plant material, using microwave irradiation to prescriptions worth thousand gold compared with comparative example 1 and 3~6
The dregs of a decoction are pre-processed, and the lignin components being very beneficial in the dregs of a decoction are separated, and plant cell wall tissue is made to generate micropore knot
Structure is more advantageous to the chemical reaction of subsequent delignification, is prepared using bioanalysis dregs of a decoction pulping process provided by the invention
Paper pulp, residual lignin content is low, and Kappa number is only 30 or so, and cellulose yield can reach 78% or more.
It is found that the present invention solves existing ethanol pulping from the angle of environmental protection in a creative way compared with comparative example 7~12
There are lignin macromolecule structure removing difficulty it is big, the high problem of Kappa number, make up it is existing using Chinese medicine slag progress ethanol pulping
Technological gap.Meanwhile having many advantages, such as hygienic environment-protecting using ethanol pulping, do not introduce harmful chemicals.
It is found that extracting effective component in the slave black liquor of present invention initiative compared with comparative example 2, and it is applied to fiber
On, effectively raise medical value.
It is found that influence of the technique to effective component for extracting effective component in black liquor is very big compared with comparative example 13~15,
Especially influence of the temperature to the viscosity of black liquor etc., so that the volatility of effective component is changed.
It is found that the spray processing of effective component can be in the Adsorption Effect drug effect to effective component compared with comparative example 16~18
Ingredient volatilization and the drying and adsorption capacity of fiber.
It is found that being resisted using its beating degree of fiber made of the dregs of a decoction and coating process to paper compared with comparative example 19~21
The features such as extensional can have a significant impact, and dreg fibers are short more with heteroproteose cell there are this fibre length.
Detailed process equipment and processing step of the invention that the present invention is explained by the above embodiments, those skilled in the art
Member is not it should be appreciated that the present invention is limited by above-described embodiment, and the above embodiments and description only describe the present invention
Principle, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, this is to this field
It is it will be apparent that these changes and improvements all fall within the protetion scope of the claimed invention for technical staff.
Claims (10)
1. a kind of method of prescriptions worth thousand gold dregs of a decoction resource regeneration preparation anti-inflammatory paper, which comprises the following steps:
S1. pre-process: by water content be 25% ~ 45% the prescriptions worth thousand gold dregs of a decoction carry out Micro-wave pretreatment, microwave power be 900 ~
1500W, microwave irradiation time are 5 ~ 10 min, for use；
S2. boiling: the prescriptions worth thousand gold dregs of a decoction that step S1 is obtained are placed in boiling vessel, and the ethanol solution that concentration is 40% ~ 60% is added
Afterwards, liquor ratio is 1:4 ~ 5, is rapidly heated to 120 ~ 140 DEG C, blowing after 100 ~ 120 min of insulation reaction, obtains coarse particles and black
Liquid；
S3. wash: the obtained coarse particles of step S2 are placed in displacement washing device, with concentration be 55% ~ 70% ethanol solution into
Row multistage displacement washing, cleaning solution ratio are 1:7 ~ 8, and wash temperature is 40 ~ 60 DEG C；Then it is washed with water completely, obtains dregs of a decoction fibre
Dimension；
S4. the extraction of effective component: being evaporated concentration to the black liquor in S2, obtained after recycling of condensed steam ethyl alcohol aqueous solution into
Row concentration, obtaining has effective component solution；
S5. papermaking: dreg fibers made from S3 are mixed with cotton pulp, filler are added, internal sizing agent is manufactured paper with pulp, progress surface
Body paper is obtained after sizing；The dreg fibers and the usage ratio of cotton pulp are 70 ~ 80:20 ~ 30；
S6. medical fluid preparation and coating:
Basic medical fluid includes the active component extract of following parts by weight: Radix Angelicae Sinensis, Radix Codonopsis, the incorporation of Herba Andrographitis and single side needle are each
It is the 9% of medicinal material total weight；Cherokee rose root, Caulis Spatholobi, leatherleaf mahonia and philippine flemingia root incorporation be respectively the 16% of medicinal material total amount；By base
Effective component solution in plinth medical fluid and S4 is mixed to get medical fluid；
By the body paper surface of medicine liquid spray and S5, the anti-inflammatory paper with pharmacological property is obtained after dry.
2. the method for prescriptions worth thousand gold dregs of a decoction resource regeneration preparation anti-inflammatory paper according to claim 1, which is characterized in that institute
Stating the prescriptions worth thousand gold dregs of a decoction is very heavy group, cherokee rose root, Caulis Spatholobi, single side needle, leatherleaf mahonia, Herba Andrographitis, Radix Angelicae Sinensis and Radix Codonopsis by water or second
Residue mixing after alcohol extracting.
3. the method for prescriptions worth thousand gold dregs of a decoction resource regeneration preparation anti-inflammatory paper according to claim 1, which is characterized in that step
The water content of the prescriptions worth thousand gold dregs of a decoction is 30% ~ 35% in rapid S1, and microwave power is 1000 ~ 1200W, and microwave irradiation time is 7 ~ 8min.
4. the method for prescriptions worth thousand gold dregs of a decoction resource regeneration preparation anti-inflammatory paper according to claim 1, which is characterized in that step
In rapid S2, after the ethanol solution that concentration is 53% is added, liquor ratio 1:4.5 is rapidly heated to 130 DEG C, 110 min of insulation reaction
Blowing afterwards obtains coarse particles and black liquor.
5. the method for prescriptions worth thousand gold dregs of a decoction resource regeneration preparation anti-inflammatory paper according to claim 1, which is characterized in that step
3 sections of displacement washings are carried out with the ethanol solution that concentration is 60% in rapid S3, cleaning solution ratio is 1:7 ~ 8, and wash temperature is 50 DEG C.
6. the method for prescriptions worth thousand gold dregs of a decoction resource regeneration preparation anti-inflammatory paper according to claim 1, which is characterized in that step
The temperature of black liquor vaporizing concentration is 110 ~ 120 DEG C in rapid S4, and described to have concentration of alcohol in effective component solution be 20% ~ 25%.
7. the method for prescriptions worth thousand gold dregs of a decoction resource regeneration preparation anti-inflammatory paper according to claim 1, which is characterized in that step
Dreg fibers made from S3 are beaten in rapid S5, beating degree is 37 ~ 47oSR；The beating degree of the cotton pulp is 25 ~ 30 oSR；
Using starch as Cypres；Preferably, Cypres concentration is 8% ~ 10%, and coating weight is 0.7 ~ 1g/m2.
8. the method for prescriptions worth thousand gold dregs of a decoction resource regeneration preparation anti-inflammatory paper according to claim 1, which is characterized in that institute
The usage ratio for stating dreg fibers and cotton pulp is 70:25；Preferably, the filler is calcium carbonate or talcum powder；It is applied in the slurry
Jelly is starch, polyacrylamide or modified rosin；Preferably, the dosage of the internal sizing agent is the 0.7% of over dry slurry weight
~0.9%。
9. the method for prescriptions worth thousand gold dregs of a decoction resource regeneration preparation anti-inflammatory paper according to claim 1, which is characterized in that step
In rapid S6, by the body paper surface of medicine liquid spray and S5, the anti-inflammatory with pharmacological property is obtained after dry has effective component solution with paper
Fountain height be the 20% ~ 30% of original paper quality, obtain the anti-inflammatory paper with pharmacological property after dry at 60 ~ 65 DEG C.
10. a kind of anti-inflammatory paper of the prescriptions worth thousand gold dregs of a decoction resource regeneration preparation by the preparation of claim 1 ~ 9 the method.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099827A (en) * | 1994-07-01 | 1995-03-08 | 黄庆文 | Toilet paper with traditional Chinese medicine and making method |
| CN1281074A (en) * | 1999-07-19 | 2001-01-24 | 西北轻工业学院 | Diwei self-catalyzing alcohol process for pulping |
| CN103669058A (en) * | 2013-11-13 | 2014-03-26 | 华南理工大学 | Method for utilizing traditional Chinese medicine residue resources |
| CN105484083A (en) * | 2015-11-22 | 2016-04-13 | 北京化工大学 | Green separating process for components of lignocellulose |
-
2017
- 2017-10-31 CN CN201711053394.7A patent/CN109722930A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099827A (en) * | 1994-07-01 | 1995-03-08 | 黄庆文 | Toilet paper with traditional Chinese medicine and making method |
| CN1281074A (en) * | 1999-07-19 | 2001-01-24 | 西北轻工业学院 | Diwei self-catalyzing alcohol process for pulping |
| CN103669058A (en) * | 2013-11-13 | 2014-03-26 | 华南理工大学 | Method for utilizing traditional Chinese medicine residue resources |
| CN105484083A (en) * | 2015-11-22 | 2016-04-13 | 北京化工大学 | Green separating process for components of lignocellulose |
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Application publication date: 20190507 |