CN109706538A - One kind is dust-proof to take polyester fabric and preparation method thereof - Google Patents

One kind is dust-proof to take polyester fabric and preparation method thereof Download PDF

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Publication number
CN109706538A
CN109706538A CN201811492490.6A CN201811492490A CN109706538A CN 109706538 A CN109706538 A CN 109706538A CN 201811492490 A CN201811492490 A CN 201811492490A CN 109706538 A CN109706538 A CN 109706538A
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CN
China
Prior art keywords
proof
dust
polyester
ultra
copper wire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811492490.6A
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Chinese (zh)
Inventor
潘金江
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan Shuanglin Jinhui Shipbuilding Co Ltd
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Hunan Shuanglin Jinhui Shipbuilding Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by Hunan Shuanglin Jinhui Shipbuilding Co Ltd filed Critical Hunan Shuanglin Jinhui Shipbuilding Co Ltd
Priority to CN201811492490.6A priority Critical patent/CN109706538A/en
Publication of CN109706538A publication Critical patent/CN109706538A/en
Pending legal-status Critical Current

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Abstract

The present invention provides it is a kind of it is dust-proof take polyester fabric, using dust-proof antistatic polyester fiber as raw material, which includes following raw material: anti-static electricity modifying agent, dust-proof inorganic agent, molybdenum disulfide and polyester slice.By the way that ultra-fine copper wire is added in fibrous inside, the effect of antistatic not only can achieve, and compared to conventional fiber blend mode, additional amount is less than 1%;It is mixed using calcined shell powder with ultra-fine copper wire, dispersing agent can not only be played the role of, and since the main component of conch meal is calcium carbonate, using can continuous oligodynamical after the cleaning of faintly acid detergent, after can guaranteeing long-time service, anti-static effect does not weaken;Graphene, which is added, can be significantly reduced the additional amount of ultra-fine copper wire;Molybdenum dioxide, which is added, can promote the dispersion effect of anti-static electricity modifying agent, reduce its additional amount;Using the dust-proof inorganic agent of special inorganic+organic+catalyst combination form, extraordinary dust-proof effect can achieve.

Description

One kind is dust-proof to take polyester fabric and preparation method thereof
Technical field
The present invention relates to functional form garment material fields, take polyester fabric and its preparation side more particularly to one kind is dust-proof Method.
Background technique
Polyester fiber is as most widely used chemical fibre, with good fibre-forming performance and mechanical performance, intensity High, fast light, heat-resisting and resistance to acid and alkali is good, has good processability and Yi Fangxing, pure can spin, blended and intertexture.Polyester fabric Washable and wearable, ironing and anti-crease, clothes, home textile, decoration and product with etc. fields be widely used.However, polyester fiber is also deposited Hygroscopicity is poor, absorbing sweat, dress do not have the shortcomings that feeling of oppression and heat, dirt exclusion capabilities difference and easily stain dust fabric, therefore restrict significantly The application and development of polyester fiber.For the snugness of fit for improving polyester fiber, the application added value of polyester fiber is improved, is led to It is often to be improved to the improvement in terms of polyester fiber progress chemically or physically, and then the higher moisture absorbing and sweat releasing property of endowing terylene fiber Dacron wearing comfort.
Garment for clean room is to protect the protective garment for endangering body skin from dust pollution in relation to operating personnel, be applied to mine, building materials, The industries such as chemical industry, metallurgy, food, medicine, military project.Since the use environment of garment for clean room is generally also required to antistatic, thus it is of the invention One kind is provided using dust-proof antistatic polyester fiber as polyester fabric made of raw material.
Summary of the invention
In view of this, dust-proof taking polyester fabric and preparation method thereof the object of the present invention is to provide a kind of.
One kind is dust-proof to take polyester fabric, using dust-proof antistatic polyester fiber as raw material, the dustproof static-proof electricity terylene Fiber includes the raw material of following weight percent:
Anti-static electricity modifying agent 1-2%
Dust-proof inorganic agent 0.2-0.5%
Molybdenum disulfide 2-3%
Polyester slice surplus.
Preferably, in the anti-static electricity modifying agent, the weight percent of each raw material are as follows:
Ultra-fine copper wire 10-15%
Graphene 0.05-0.2%
Calcined shell powder 50-60%
Gelatin surplus.
Preferably, the diameter of the ultra-fine copper wire is 0.012-0.015mm.
Preferably, the partial size of the calcined shell powder is 10-50 μm.
Preferably, in the dust-proof inorganic agent, the weight percent of each raw material are as follows:
Nano-titanium dioxide 1-3%
Polystyrene 8-12%
Lanthana 0.02-0.05%
Ethyl acetate surplus.
A kind of dust-proof preparation method for taking polyester fabric carries out as steps described below:
A, after shell being milled and being cleaned with dilute hydrochloric acid, water is dried under the conditions of 100-120 DEG C, 350-400 DEG C of roasting is cold But, calcined shell powder is obtained;And mix calcined shell powder with ultra-fine copper wire and graphene, it dry grinds, obtains mixture;
B, use gelatin to coat mixture as softgel shell, form microcapsules, as anti-static electricity modifying agent;
C, microcapsules and molybdenum disulfide are added in the polyester slice of molten condition, after mixing, by polyester slice in spinning High speed spinning is made as-spun fibre on machine, and in spinning process, using air-jet device, from up and down, four direction is simultaneously to fibre Spray dust-proof inorganic agent in dimension table face;Specific spinning process condition are as follows: 280-300 DEG C of spinning temperature, spinning speed 1200- 1300m/min obtains terylene as-spun fibre;
D, as-spun fibre is carried out shaping using parallel drafting machine, dustproof static-proof electricity polyester fiber can be obtained;
E, dustproof static-proof electricity polyester fiber obtains dust-proof taking polyester fabric by woven fabric, arrangement, sizing, coating, drying.
The dust-proof preparation method for taking polyester fabric of one kind provided by the present invention, has the advantages that
1, by the way that ultra-fine copper wire is added in fibrous inside, it not only can achieve the effect of antistatic, and compared to conventional fiber Blended mode, additional amount is less than 1%.
2, it is mixed using calcined shell powder with ultra-fine copper wire, can not only play the role of dispersing agent, and due to shell The main component of powder is calcium carbonate, using can continuous oligodynamical after the cleaning of faintly acid detergent, it is ensured that is used for a long time Afterwards, anti-static effect does not weaken.
3, graphene is added can be significantly reduced the additional amount of ultra-fine copper wire.
4, the dispersion effect of anti-static electricity modifying agent can be promoted by molybdenum dioxide being added, and reduce its additional amount.
5, it using the dust-proof inorganic agent of special inorganic+organic+catalyst combination form, can achieve extraordinary dust-proof Effect.
Specific embodiment
Embodiment 1
One kind is dust-proof to take polyester fabric, using dust-proof antistatic polyester fiber as raw material, the dustproof static-proof electricity polyester fiber Raw material including following weight percent:
Anti-static electricity modifying agent 1.7%
Dust-proof inorganic agent 0.35%
Molybdenum disulfide 2.2%
Polyester slice surplus.
In the anti-static electricity modifying agent, the weight percent of each raw material are as follows:
Ultra-fine copper wire 12.5%
Graphene 0.15%
Calcined shell powder 55%
Gelatin surplus.
The diameter of the ultra-fine copper wire is 0.012-0.015mm.
The partial size of the calcined shell powder is 10-50 μm.
In the dust-proof inorganic agent, the weight percent of each raw material are as follows:
Nano-titanium dioxide 1.8%
Polystyrene 10.5%
Lanthana 0.025%
Ethyl acetate surplus.
A kind of dust-proof preparation method for taking polyester fabric carries out as steps described below:
A, after shell being milled and being cleaned with dilute hydrochloric acid, water is dried under the conditions of 105 DEG C, 375 DEG C of roastings are cooling, forged Burn conch meal;And mix calcined shell powder with ultra-fine copper wire and graphene, it dry grinds, obtains mixture;
B, use gelatin to coat mixture as softgel shell, form microcapsules, as anti-static electricity modifying agent;
C, microcapsules and molybdenum disulfide are added in the polyester slice of molten condition, after mixing, by polyester slice in spinning High speed spinning is made as-spun fibre on machine, and in spinning process, using air-jet device, from up and down, four direction is simultaneously to fibre Spray dust-proof inorganic agent in dimension table face;Specific spinning process condition are as follows: 295 DEG C of spinning temperature, spinning speed 1250m/min is obtained To terylene as-spun fibre;
D, as-spun fibre is carried out shaping using parallel drafting machine, dustproof static-proof electricity polyester fiber can be obtained;
E, dustproof static-proof electricity polyester fiber obtains dust-proof taking polyester fabric by woven fabric, arrangement, sizing, coating, drying.
Embodiment 2
One kind is dust-proof to take polyester fabric, using dust-proof antistatic polyester fiber as raw material, the dustproof static-proof electricity polyester fiber Raw material including following weight percent:
Anti-static electricity modifying agent 1%
Dust-proof inorganic agent 0.2%
Molybdenum disulfide 3%
Polyester slice surplus.
In the anti-static electricity modifying agent, the weight percent of each raw material are as follows:
Ultra-fine copper wire 10%
Graphene 0.05%
Calcined shell powder 50%
Gelatin surplus.
The diameter of the ultra-fine copper wire is 0.012-0.015mm.
The partial size of the calcined shell powder is 10-50 μm.
In the dust-proof inorganic agent, the weight percent of each raw material are as follows:
Nano-titanium dioxide 1%
Polystyrene 12%
Lanthana 0.02%
Ethyl acetate surplus.
A kind of dust-proof preparation method for taking polyester fabric carries out as steps described below:
A, after shell being milled and being cleaned with dilute hydrochloric acid, water is dried under the conditions of 100 DEG C, 400 DEG C of roastings are cooling, forged Burn conch meal;And mix calcined shell powder with ultra-fine copper wire and graphene, it dry grinds, obtains mixture;
B, use gelatin to coat mixture as softgel shell, form microcapsules, as anti-static electricity modifying agent;
C, microcapsules and molybdenum disulfide are added in the polyester slice of molten condition, after mixing, by polyester slice in spinning High speed spinning is made as-spun fibre on machine, and in spinning process, using air-jet device, from up and down, four direction is simultaneously to fibre Spray dust-proof inorganic agent in dimension table face;Specific spinning process condition are as follows: 300 DEG C of spinning temperature, spinning speed 1200m/min is obtained To terylene as-spun fibre;
D, as-spun fibre is carried out shaping using parallel drafting machine, dustproof static-proof electricity polyester fiber can be obtained;
E, dustproof static-proof electricity polyester fiber obtains dust-proof taking polyester fabric by woven fabric, arrangement, sizing, coating, drying.
Embodiment 3
One kind is dust-proof to take polyester fabric, using dust-proof antistatic polyester fiber as raw material, the dustproof static-proof electricity polyester fiber Raw material including following weight percent:
Anti-static electricity modifying agent 2%
Dust-proof inorganic agent 0.5%
Molybdenum disulfide 2%
Polyester slice surplus.
In the anti-static electricity modifying agent, the weight percent of each raw material are as follows:
Ultra-fine copper wire 15%
Graphene 0.2%
Calcined shell powder 60%
Gelatin surplus.
The diameter of the ultra-fine copper wire is 0.012-0.015mm.
The partial size of the calcined shell powder is 10-50 μm.
In the dust-proof inorganic agent, the weight percent of each raw material are as follows:
Nano-titanium dioxide 3%
Polystyrene 8%
Lanthana 0.05%
Ethyl acetate surplus.
A kind of dust-proof preparation method for taking polyester fabric carries out as steps described below:
A, after shell being milled and being cleaned with dilute hydrochloric acid, water is dried under the conditions of 120 DEG C, 350 DEG C of roastings are cooling, forged Burn conch meal;And mix calcined shell powder with ultra-fine copper wire and graphene, it dry grinds, obtains mixture;
B, use gelatin to coat mixture as softgel shell, form microcapsules, as anti-static electricity modifying agent;
C, microcapsules and molybdenum disulfide are added in the polyester slice of molten condition, after mixing, by polyester slice in spinning High speed spinning is made as-spun fibre on machine, and in spinning process, using air-jet device, from up and down, four direction is simultaneously to fibre Spray dust-proof inorganic agent in dimension table face;Specific spinning process condition are as follows: 280 DEG C of spinning temperature, spinning speed 1300m/min is obtained To terylene as-spun fibre;
D, as-spun fibre is carried out shaping using parallel drafting machine, dustproof static-proof electricity polyester fiber can be obtained;
E, dustproof static-proof electricity polyester fiber obtains dust-proof taking polyester fabric by woven fabric, arrangement, sizing, coating, drying.
Comparative example 1
Calcined shell powder is removed, remaining preparation condition is same as Example 1.
Comparative example 2
Graphene is removed, remaining preparation condition is same as Example 1.
Comparative example 3
Titanium dioxide is removed, remaining preparation condition is same as Example 1.
Comparative example 4
Polystyrene is removed, remaining preparation condition is same as Example 1.
Comparative example 5
Lanthana is removed, remaining preparation condition is same as Example 1.
Sample is detected below:
The antistatic standard that anti-static effect still can achieve GB/T12014-2009 after the sample of embodiment 1-3 is taken 3 years is wanted It asks.
The long-term anti-static effect of the sample of comparative example 1 is very poor, and dress was just unable to reach antistatic standard using 3 months later Requirement.
The sample anti-static effect of comparative example 2 is very poor, is unable to reach the effect of antistatic;The additional amount of ultra-fine copper wire is mentioned High 10 times or more the requirements that just can achieve antistatic standard.
The sample dust-proof effect of embodiment 1 is fine, and being stained with dust quantity can achieve the requirement of GB17956-2000, and comparative example 3- 5 sample is stained with the standard that dust quantity test is unable to reach garment for clean room.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (6)

1. one kind is dust-proof to take polyester fabric, which is characterized in that using dust-proof antistatic polyester fiber as raw material, described is dust-proof anti- Electrostatic polyester fiber includes the raw material of following weight percent:
Anti-static electricity modifying agent 0.2-0.5%
Dust-proof inorganic agent 0.2-0.5%
Molybdenum disulfide 0.5-1%
Polyester slice surplus.
2. dust-proof as described in claim 1 take polyester fabric, which is characterized in that in the anti-static electricity modifying agent, each original The weight percent of material are as follows:
Ultra-fine copper wire 10-15%
Graphene 0.05-0.2%
Calcined shell powder 50-60%
Gelatin surplus.
3. dust-proof polyester fabric is taken as claimed in claim 2, which is characterized in that the diameter of the ultra-fine copper wire is 0.012-0.015mm。
4. dust-proof polyester fabric is taken as claimed in claim 2, which is characterized in that the partial size of the calcined shell powder is 10-50μm。
5. dust-proof as described in claim 1 take polyester fabric, which is characterized in that in the dust-proof inorganic agent, each raw material Weight percent are as follows:
Nano-titanium dioxide 1-3%
Polystyrene 8-12%
Lanthana 0.02-0.05%
Ethyl acetate surplus.
6. a kind of dust-proof preparation method for taking polyester fabric, which is characterized in that carry out as steps described below:
A, after shell being milled and being cleaned with dilute hydrochloric acid, water is dried under the conditions of 100-120 DEG C, 350-400 DEG C of roasting is cold But, calcined shell powder is obtained;And mix calcined shell powder with ultra-fine copper wire and graphene, it dry grinds, obtains mixture;
B, use gelatin to coat mixture as softgel shell, form microcapsules, as anti-static electricity modifying agent;
C, microcapsules and molybdenum disulfide are added in the polyester slice of molten condition, after mixing, by polyester slice in spinning High speed spinning is made as-spun fibre on machine, and in spinning process, using air-jet device, from up and down, four direction is simultaneously to fibre Spray dust-proof inorganic agent in dimension table face;Specific spinning process condition are as follows: 280-300 DEG C of spinning temperature, spinning speed 1200- 1300m/min obtains terylene as-spun fibre;
D, as-spun fibre is carried out shaping using parallel drafting machine, dustproof static-proof electricity polyester fiber can be obtained;
E, dustproof static-proof electricity polyester fiber obtains dust-proof taking polyester fabric by woven fabric, arrangement, sizing, coating, drying.
CN201811492490.6A 2018-12-07 2018-12-07 One kind is dust-proof to take polyester fabric and preparation method thereof Pending CN109706538A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811492490.6A CN109706538A (en) 2018-12-07 2018-12-07 One kind is dust-proof to take polyester fabric and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811492490.6A CN109706538A (en) 2018-12-07 2018-12-07 One kind is dust-proof to take polyester fabric and preparation method thereof

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Publication Number Publication Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111088550A (en) * 2019-12-19 2020-05-01 湖州旧馆四发服装砂洗厂 Preparation and dyeing method of anti-static polyester fabric

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CN101074502A (en) * 2006-05-16 2007-11-21 东丽纤维研究所(中国)有限公司 Endurable polyester anti-static fibre and its production
CN101362821A (en) * 2008-09-26 2009-02-11 江苏中鲈科技发展股份有限公司 PTT polyester chip and method for preparing antistatic PTT polyester fibres
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111088550A (en) * 2019-12-19 2020-05-01 湖州旧馆四发服装砂洗厂 Preparation and dyeing method of anti-static polyester fabric
CN111088550B (en) * 2019-12-19 2022-08-16 潮州市雅达绣衣有限公司 Preparation and dyeing method of anti-static polyester fabric

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Application publication date: 20190503

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