CN109705749A - A kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal and preparation method thereof - Google Patents
A kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal and preparation method thereof Download PDFInfo
- Publication number
- CN109705749A CN109705749A CN201811560572.XA CN201811560572A CN109705749A CN 109705749 A CN109705749 A CN 109705749A CN 201811560572 A CN201811560572 A CN 201811560572A CN 109705749 A CN109705749 A CN 109705749A
- Authority
- CN
- China
- Prior art keywords
- melt adhesive
- hot melt
- adhesive film
- fabric
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Abstract
The present invention discloses a kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, including 20-40 parts of maleic anhydride stem grafting polyolefin, 20-50 parts of ethylene copolymer, 5-25 parts of thermoplastic elastomer (TPE), 5-20 parts of tackifier, 0-10 parts of filler and 0.3-5 parts of auxiliary agent.Hot melt adhesive film of the present invention, instead of traditional liquid glue, so that bonding process environmental protection odorlessness, this kind of hot melt adhesive film can solve metal simultaneously and glass-fiber-fabric bonds bad problem, in particular for the bonding of aluminium foil and glass-fiber-fabric, mean peel strength between hot melt adhesive film and glass-fiber-fabric is 2.0N/mm, and adhesion strength is high, pollution-free, odorlessness and easy for construction；Invention additionally discloses a kind of preparation methods of hot melt adhesive film, and preparation process is simple, and raw material and equipment are easy to get, and are produced on a large scale.
Description
Technical field
The invention belongs to hot melt adhesive film technical fields, and in particular to a kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal
And preparation method thereof.
Background technique
The metal application Nian Jie with glass-fiber-fabric is more and more wider.Mainly pass through epoxy between metal material and glass-fiber-fabric at present
The liquid glues such as glue, polyurethane adhesive directly bond.Although liquid glue directly can reach adhesive effect, liquid by cold painting
Glue contains volatile materials, not only pollutes environment, and also have certain harm to operator.
Hot melt adhesive film is a kind of solvent-free solid gum, does not have volatile matter, therefore pollution-free, to human body also fanout free region.
Hot melt adhesive process operation is quick simultaneously, can be conducive to the extensive sharp work of factory with repetitive operation.Hot melt adhesive film has been at present
It gets application in metal and plastic bonding field.For example, Chinese patent CN107746680A discloses one kind for metalwork and modeling
The hot melt adhesive film of materials and parts bonding, which includes 12.00%-25.00% ethylene acrylic acid co polymer or acrylonitrile-acrylic acid
Copolymer, 20.00%-45.00% maleic anhydride graft copolymer, 15.00%-35.00% polyether polyurethane,
5.00%-20.00% linear low density polyethylene, 4.00%-8.00% heat stabilizer.This kind of hot melt adhesive has more excellent glue
Performance is connect, but is only applicable to the bonding of metal and plastics, bonding with polyester non-woven fabric for metal, adhesive effect is simultaneously
It is bad；Chinese invention patent CN101429413B discloses the double-layer composite hot melt adhesive film of a kind of metal and plastic bonding, by upper
The compound composition of lower bilayer glue film, lower layer's glue film attach release paper, and compound cutan is and gold with a thickness of 0.05mm~0.20mm, upper layer
Belong to the hot melt adhesive layer of bonding, with a thickness of the 30-60% of composite film thickness, lower layer is the hot melt adhesive layer bonded with plastics, thick
Degree is the 40~70% of composite film thickness, and lower layer attaches glaxin release paper.The invention is by the hot melt of two kinds of different adhesive properties
Together, and attach release paper prevents winding adhesion and glue film impaired to the modified direct combination of glue, reduces intermediate isolating layer
Using reducing compound cutan thickness, be once cast by coextrusion casting equipment or common casting apparatus be cast preparation twice and answers
Close glue film.This kind of hot melt adhesive film is suitable for the compoiste adhering of the plastics such as aluminium, stainless steel and other metal materials and ABS, PVC, PET.Together
Sample, for bonding between metal and glass-fiber-fabric, adhesive effect is bad.
Summary of the invention
The technical problem to be solved by the invention is to provide a kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal and its
Preparation method solves metal in the prior art and the bad technical problem of glass-fiber-fabric adhesive property.
In order to solve the above technical problems, the technical solution adopted by the present invention: a kind of heat Nian Jie with glass-fiber-fabric for metal
Melten gel film, which is characterized in that including following raw material components and parts by weight:
Preferably, the maleic anhydride stem grafting polyolefin includes maleic anhydride grafted polyethylene, maleic anhydride grafting poly- third
Alkene, any one in maleic anhydride grafted ethene octene copolymer.
Preferably, the ethylene copolymer includes one of EVA, EEA, EMA and ethylene-dien terpolymer or any
Combination.It should be noted that ethylene-dien terpolymer includes ethylene-methyl acrylate-glyceryl methacrylate (E-
) or ethylene/n-butyl acrylate-glycidyl methacrylate (E-BA-GMA) etc. MA-GMA.
Preferably, the content of comonomer is 10%-40% in the ethylene copolymer.
Preferably, the thermoplastic elastomer (TPE) is selected from one of POE, POP, SIS, SEBS, EPDM, SBR, TPU or appoints
Meaning combination.
Preferably, the tackifier are terpene resin, phenolic aldehyde terpene resin, C5 hydrogenated petroleum resin, C5/C9 copolymer resins
In any one.
Preferably, the filler is any one in calcium carbonate, talcum powder, barium sulfate, white carbon black and kaolin.
Preferably, the mesh number of the filler is 2000-5000 mesh.
Preferably, the auxiliary agent includes antioxidant, ultraviolet dose, one of coupling agent and dispersing agent or any combination.
Wherein, antioxidant be one of antioxidant 1010, antioxidant 1076, antioxidant 168 or antioxidant B215 or
Any combination；Ultraviolet dose is any one in UV531, UV944, UV-P or UV327；Coupling agent is silanes, aluminic acid lipoprotein
Any one in class or titanate ester；Dispersing agent is atoleine, white oil, silicone oil, any one in naphthenic oil.
Invention additionally discloses a kind of preparation methods of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, which is characterized in that
Include the following steps:
(1) maleic anhydride stem grafting polyolefin is weighed according to the proportion, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug, is filled out
Material and auxiliary agent, then mix auxiliary agent with filler；
(2) it will be mixed in maleic anhydride stem grafting polyolefin, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug and step (1)
Raw material after conjunction further mixes, and extruding pelletization in extruder is added, and obtains hot-melt adhesive granules；
(3) hot melt adhesive film is prepared by blown film or curtain coating in the hot-melt adhesive granules in step (2).
Preferably, the extruder extrusion temperature is 150-190 DEG C；The temperature of the blown film or curtain coating is 130-160 DEG C.
Beneficial effects of the present invention: the present invention discloses a kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, instead of
Traditional liquid glue, so that bonding process environmental protection odorlessness, while this kind of hot melt adhesive film can solve metal and glass-fiber-fabric bonding not
Good problem, in particular for the bonding of aluminium foil and glass-fiber-fabric, the mean peel strength between hot melt adhesive film and glass-fiber-fabric is
2.0N/mm, adhesion strength is high, pollution-free, odorlessness and easy for construction；Invention additionally discloses one kind to be used for metal and glass
The preparation method of the hot melt adhesive film of cloth bonding, preparation process is simple, and raw material and equipment are easy to get, and are produced on a large scale.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment 1:
A kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, including following raw material components and parts by weight:
Wherein, maleic anhydride stem grafting polyolefin is maleic anhydride inoculated polypropylene, grafting rate 0.8%.
Ethylene copolymer is EVA, and the content of comonomer is 15% in EVA.
Thermoplastic elastomer (TPE) is the blend of POE and POP, and the weight proportion of POE and POP is 2:3.
Tackifier are terpene resin.
Filler is calcium carbonate, and the mesh number of filler is 3500 mesh.
Invention additionally discloses a kind of preparation methods of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, including walk as follows
It is rapid:
(1) maleic anhydride stem grafting polyolefin is weighed according to the proportion, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug, is filled out
Material, antioxidant and coupling agent, then mix antioxidant, coupling agent with filler；
(2) it will be mixed in maleic anhydride stem grafting polyolefin, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug and step (1)
Raw material after conjunction further mixes, and extruding pelletization in extruder is added, and obtains hot-melt adhesive granules；Wherein, extruder squeezes out temperature
Degree is 170-190 DEG C；
(3) hot melt adhesive film is prepared by blown film in the hot-melt adhesive granules in step (2), wherein blown film or curtain coating
Temperature is 130-150 DEG C.
Embodiment 2:
A kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, including following raw material components and parts by weight:
Wherein, maleic anhydride stem grafting polyolefin is maleic anhydride grafted linear low density polyethylene, grafting rate 1.0%.
Ethylene copolymer includes the blend of EVA and EEA, and the weight ratio of EVA and EEA is 2:1, is wherein copolymerized in EVA
The content of monomer is that the content of 20%, EEA comonomer is 18%.
Thermoplastic elastomer (TPE) is the blend of SIS and TPU, and the weight proportion of SIS and TPU is 1:1.
Tackifier are phenolic aldehyde terpene resin.
Filler is talcum powder, and the mesh number of filler is 2800 mesh.
Invention additionally discloses a kind of preparation methods of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, including walk as follows
It is rapid:
(1) maleic anhydride stem grafting polyolefin is weighed according to the proportion, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug, is filled out
Material, antioxidant and coupling agent, then mix antioxidant, coupling agent with filler；
(2) it will be mixed in maleic anhydride stem grafting polyolefin, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug and step (1)
Raw material after conjunction further mixes, and extruding pelletization in extruder is added, and obtains hot-melt adhesive granules；Wherein, extruder squeezes out temperature
Degree is 170-190 DEG C；
(3) hot melt adhesive film is prepared by blown film in the hot-melt adhesive granules in step (2), wherein blown film or curtain coating
Temperature is 130-150 DEG C.
Embodiment 3:
A kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, including following raw material components and parts by weight:
Wherein, maleic anhydride stem grafting polyolefin includes maleic anhydride grafted ethene octene copolymer, grafting rate 0.5%.
Ethylene copolymer is ethylene/n-butyl acrylate-glycidyl methacrylate, wherein n-butyl acrylate
Content is 10%, and the content of glycidyl methacrylate is 15%.
Thermoplastic elastomer (TPE) is SEBS.
Tackifier are C5/C9 copolymer resins.
Filler is barium sulfate, and the mesh number of filler is 2500 mesh.
Invention additionally discloses a kind of preparation methods of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, including walk as follows
It is rapid:
(1) maleic anhydride stem grafting polyolefin is weighed according to the proportion, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug, is filled out
Material, antioxidant and coupling agent, then mix antioxidant, coupling agent with filler；
(2) it will be mixed in maleic anhydride stem grafting polyolefin, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug and step (1)
Raw material after conjunction further mixes, and extruding pelletization in extruder is added, and obtains hot-melt adhesive granules；Wherein, extruder squeezes out temperature
Degree is 160-180 DEG C；
(3) hot melt adhesive film is prepared by blown film in the hot-melt adhesive granules in step (2), wherein blown film or curtain coating
Temperature is 140-160 DEG C.
Embodiment 4:
A kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, including following raw material components and parts by weight:
Wherein, maleic anhydride stem grafting polyolefin is maleic anhydride grafted high density polyethylene, grafting rate 1.5%.
Ethylene copolymer is the blend of EVA and EMA, and the weight ratio of EVA and EMA is 2:3, is wherein copolymerized in EVA single
The content of body is that the content of comonomer in 15%, EMA is 10%.
Thermoplastic elastomer (TPE) is SBR.
Tackifier are C5 hydrogenated petroleum resin.
Filler is kaolin, and the mesh number of filler is 4500 mesh.
Invention additionally discloses a kind of preparation methods of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, including walk as follows
It is rapid:
(1) maleic anhydride stem grafting polyolefin is weighed according to the proportion, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug, is filled out
Material, antioxidant, ultraviolet dose, coupling agent and dispersing agent, then by antioxidant, ultraviolet dose, coupling agent and dispersing agent with
Filler is mixed；
(2) it will be mixed in maleic anhydride stem grafting polyolefin, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug and step (1)
Raw material after conjunction further mixes, and extruding pelletization in extruder is added, and obtains hot-melt adhesive granules；Wherein, extruder squeezes out temperature
Degree is 150-170 DEG C；
(3) hot melt adhesive film is prepared by blown film in the hot-melt adhesive granules in step (2), wherein blown film or curtain coating
Temperature is 140-160 DEG C.
Embodiment 5:
A kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, including following raw material components and parts by weight:
Wherein, maleic anhydride stem grafting polyolefin is maleic anhydride inoculated polypropylene, grafting rate 1.2%.
Ethylene copolymer is EMA, and the content of comonomer is 20% in EMA.
Thermoplastic elastomer (TPE) is the blend of SIS and SEBS, and the weight proportion of SIS and SEBS is 1:1.
Tackifier are terpene resin.
Filler is talcum powder, and the mesh number of filler is 3000 mesh.
Invention additionally discloses a kind of preparation methods of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, including walk as follows
It is rapid:
(1) maleic anhydride stem grafting polyolefin is weighed according to the proportion, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug, is filled out
Material, antioxidant, ultraviolet dose, coupling agent and dispersing agent, then by antioxidant, ultraviolet dose, coupling agent and dispersing agent with
Filler is mixed；
(2) it will be mixed in maleic anhydride stem grafting polyolefin, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug and step (1)
Raw material after conjunction further mixes, and extruding pelletization in extruder is added, and obtains hot-melt adhesive granules；Wherein, extruder squeezes out temperature
Degree is 160-180 DEG C；
(3) hot melt adhesive film is prepared by blown film in the hot-melt adhesive granules in step (2), wherein blown film or curtain coating
Temperature is 140-160 DEG C.
Hot melt adhesive film prepared by embodiment 1-5 is coated on glass-fiber-fabric, is tested according to standard tension machine, peel strength is such as
Following table:
As seen from the above table, it is tested according to standard tension machine, the mean peel strength between hot melt adhesive film and glass-fiber-fabric is
The adhesive strength of 2.0N/mm, surface hot melt adhesive of the present invention are high.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain
Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.
Claims (10)
1. a kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, which is characterized in that including following raw material components and weight
Part:
2. a kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal according to claim 1, which is characterized in that the Malaysia
Acid anhydride-grafted polyolefin includes maleic anhydride grafted polyethylene, maleic anhydride inoculated polypropylene, maleic anhydride grafted ethene octene
Any one in copolymer.
3. a kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal according to claim 1, which is characterized in that the ethylene
Copolymer includes one of EVA, EEA, EMA and ethylene-dien terpolymer or any combination.
4. a kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal according to claim 1, which is characterized in that the thermoplastic
Property elastomer be selected from one of POE, POP, SIS, SEBS, EPDM, SBR, TPU or any combination.
5. a kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal according to claim 1, which is characterized in that the thickening
Agent is terpene resin, phenolic aldehyde terpene resin, C5 hydrogenated petroleum resin, any one in C5/C9 copolymer resins.
6. a kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal according to claim 1, which is characterized in that the filler
For any one in calcium carbonate, talcum powder, barium sulfate, white carbon black and kaolin.
7. a kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal according to claim 6, which is characterized in that the filler
Mesh number be 2000-5000 mesh.
8. a kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal according to claim 1, which is characterized in that the auxiliary agent
Including antioxidant, ultraviolet dose, one of coupling agent and dispersing agent or any combination.
9. a kind of preparation of the hot melt adhesive film Nian Jie with glass-fiber-fabric for metal described in a kind of -8 any one according to claim 1
Method, which comprises the steps of:
(1) weigh according to the proportion maleic anhydride stem grafting polyolefin, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug, filler, with
And auxiliary agent, then auxiliary agent is mixed with filler；
It (2) will be after mixing in maleic anhydride stem grafting polyolefin, ethylene copolymer, thermoplastic elastomer (TPE), thickening drug and step (1)
Raw material further mix, and extruding pelletization in extruder is added, obtains hot-melt adhesive granules；
(3) hot melt adhesive film is prepared by blown film or curtain coating in the hot-melt adhesive granules in step (2).
10. a kind of preparation method of the hot melt adhesive film Nian Jie with glass-fiber-fabric for metal, feature exist according to claim 9
In the extruder extrusion temperature is 150-190 DEG C；The temperature of the blown film or curtain coating is 130-160 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811560572.XA CN109705749A (en) | 2018-12-20 | 2018-12-20 | A kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811560572.XA CN109705749A (en) | 2018-12-20 | 2018-12-20 | A kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109705749A true CN109705749A (en) | 2019-05-03 |
Family
ID=66256048
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811560572.XA Withdrawn CN109705749A (en) | 2018-12-20 | 2018-12-20 | A kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109705749A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110699013A (en) * | 2019-11-04 | 2020-01-17 | 巢进化学(上海)有限公司 | Hot melt adhesive for bonding metal and plastic and preparation method thereof |
| CN111040661A (en) * | 2019-12-27 | 2020-04-21 | 上海邦中高分子材料股份有限公司 | Hot melt adhesive film for bonding TPO (thermoplastic polyolefin) waterproof coiled material and metal plate and preparation method thereof |
| CN111063483A (en) * | 2019-11-29 | 2020-04-24 | 上海蓝昊电气江苏有限公司 | Low-temperature-resistant mobile flexible cable for open-pit mine and wrapping tape thereof |
| CN111231451A (en) * | 2020-01-16 | 2020-06-05 | 江苏凯伦建材股份有限公司 | Film-coated metal plate |
| CN112060744A (en) * | 2020-09-02 | 2020-12-11 | 星光印刷（苏州）有限公司 | Magnet piece and base material composite imprinting process method based on thermoplastic adhesive film |
| CN112778945A (en) * | 2020-12-25 | 2021-05-11 | 上海邦中高分子材料股份有限公司 | Special bonding resin for PVC (polyvinyl chloride) film and preparation method thereof |
| CN112795332A (en) * | 2020-12-25 | 2021-05-14 | 上海邦中高分子材料股份有限公司 | Hot melt adhesive film for bonding PVC (polyvinyl chloride) waterproof coiled material and metal plate and preparation method thereof |
| CN112795331A (en) * | 2020-12-25 | 2021-05-14 | 上海邦中新材料有限公司 | Hot melt adhesive film for high-adhesion-strength nanometer heat insulation tile and preparation method thereof |
| CN112831283A (en) * | 2020-12-25 | 2021-05-25 | 上海邦中高分子材料股份有限公司 | Hot melt adhesive film for bonding melamine paper and metal plate and preparation method thereof |
| CN115093807A (en) * | 2022-06-23 | 2022-09-23 | 东莞市学诚塑胶制品有限公司 | High-molecular adhesive film and production process thereof |
| CN115287003A (en) * | 2022-08-04 | 2022-11-04 | 广东汇齐新材料有限公司 | Composite hot melt adhesive film for metal bonding and preparation method thereof |
| CN116023882A (en) * | 2022-12-26 | 2023-04-28 | 广州鹿山新材料股份有限公司 | Adhesive resin for oxford fabric and aluminum foil composite film, and preparation method and application thereof |
-
2018
- 2018-12-20 CN CN201811560572.XA patent/CN109705749A/en not_active Withdrawn
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110699013A (en) * | 2019-11-04 | 2020-01-17 | 巢进化学(上海)有限公司 | Hot melt adhesive for bonding metal and plastic and preparation method thereof |
| CN111063483A (en) * | 2019-11-29 | 2020-04-24 | 上海蓝昊电气江苏有限公司 | Low-temperature-resistant mobile flexible cable for open-pit mine and wrapping tape thereof |
| CN111040661A (en) * | 2019-12-27 | 2020-04-21 | 上海邦中高分子材料股份有限公司 | Hot melt adhesive film for bonding TPO (thermoplastic polyolefin) waterproof coiled material and metal plate and preparation method thereof |
| CN111231451A (en) * | 2020-01-16 | 2020-06-05 | 江苏凯伦建材股份有限公司 | Film-coated metal plate |
| CN112060744A (en) * | 2020-09-02 | 2020-12-11 | 星光印刷（苏州）有限公司 | Magnet piece and base material composite imprinting process method based on thermoplastic adhesive film |
| CN112795332A (en) * | 2020-12-25 | 2021-05-14 | 上海邦中高分子材料股份有限公司 | Hot melt adhesive film for bonding PVC (polyvinyl chloride) waterproof coiled material and metal plate and preparation method thereof |
| CN112778945A (en) * | 2020-12-25 | 2021-05-11 | 上海邦中高分子材料股份有限公司 | Special bonding resin for PVC (polyvinyl chloride) film and preparation method thereof |
| CN112795331A (en) * | 2020-12-25 | 2021-05-14 | 上海邦中新材料有限公司 | Hot melt adhesive film for high-adhesion-strength nanometer heat insulation tile and preparation method thereof |
| CN112831283A (en) * | 2020-12-25 | 2021-05-25 | 上海邦中高分子材料股份有限公司 | Hot melt adhesive film for bonding melamine paper and metal plate and preparation method thereof |
| CN115093807A (en) * | 2022-06-23 | 2022-09-23 | 东莞市学诚塑胶制品有限公司 | High-molecular adhesive film and production process thereof |
| CN115287003A (en) * | 2022-08-04 | 2022-11-04 | 广东汇齐新材料有限公司 | Composite hot melt adhesive film for metal bonding and preparation method thereof |
| CN116023882A (en) * | 2022-12-26 | 2023-04-28 | 广州鹿山新材料股份有限公司 | Adhesive resin for oxford fabric and aluminum foil composite film, and preparation method and application thereof |
| CN116023882B (en) * | 2022-12-26 | 2023-08-18 | 广州鹿山新材料股份有限公司 | Adhesive resin for oxford fabric and aluminum foil composite film, and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109705749A (en) | A kind of hot melt adhesive film Nian Jie with glass-fiber-fabric for metal and preparation method thereof | |
| CN101429413B (en) | Double-layer composite hot melt adhesive film for bonding metal and plastic | |
| CN103205210B (en) | High-temperature-resistant hot melt adhesive membrane for aluminum honeycomb boards, and preparation method thereof | |
| CN109666432A (en) | A kind of multi-layer co-extruded plastic composite pipe hot melt adhesive and preparation method thereof | |
| CN109207073A (en) | A kind of three layers of composite hot melt adhesive film and its processing technology for metal and polar functionalities plastic bonding | |
| CN106085309B (en) | Automobile floor leather melt pressure sensitive glue composition and preparation method thereof | |
| CN109749688A (en) | A kind of hot melt adhesive Nian Jie with polyester non-woven fabric for metal and preparation method thereof | |
| CN104497929B (en) | A kind of special binding resin of aluminium-plastic panel and preparation method thereof | |
| CN109705590B (en) | Self-healing self-adhesive rubber asphalt, preparation method thereof and self-adhesive rubber asphalt waterproof coiled material | |
| CN108192522B (en) | HDPE chemical bonding type self-adhesion waterproofing membrane | |
| RU2008109007A (en) | POWDER COATING COMPOSITION FOR COATING SURFACES OF THERMOPLASTIC COMPOSITES | |
| WO2001018141A1 (en) | Low activation temperature adhesive composition with high peel strength and cohesive failure | |
| TW201124496A (en) | Adhesive assembly tape for interior finishing | |
| CN105602478A (en) | Self-adhesive polyethylene protective film and preparation method of self-adhesive layer thereof | |
| CN106009171A (en) | Non-asphalt-based high polymer self-adhered waterproof membrane with high peel strength and preparation method of non-asphalt-based high polymer self-adhered waterproof membrane | |
| CN104284958A (en) | Adhesive sheet | |
| CN114479709B (en) | Polyolefin pre-laid waterproof coiled material and preparation method thereof | |
| US5854356A (en) | Polymers for release films on surfaces containing pressure-sensitive adhesives | |
| CN106883493A (en) | A kind of CPS prespreadings waterproof roll and preparation method thereof | |
| CN106827746A (en) | A kind of multi-layer co-extruded compound mould release membrance | |
| CN109397820A (en) | A kind of composite membrane containing EAA, LDPE and LLDPE, preparation method and application | |
| CN114479682A (en) | Hot melt adhesive film for bonding metal and PVC (polyvinyl chloride) and preparation method thereof | |
| CN109207079A (en) | A kind of PVC film sheet material and its preparation process with metal adhesive | |
| JPH04236288A (en) | Hot melt adhesive composition | |
| CN109207074A (en) | A kind of composite hot melt adhesive Nian Jie with PVC for metal and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190503 |
|
| WW01 | Invention patent application withdrawn after publication |