CN109207079A - A kind of PVC film sheet material and its preparation process with metal adhesive - Google Patents

A kind of PVC film sheet material and its preparation process with metal adhesive Download PDF

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Publication number
CN109207079A
CN109207079A CN201811000853.XA CN201811000853A CN109207079A CN 109207079 A CN109207079 A CN 109207079A CN 201811000853 A CN201811000853 A CN 201811000853A CN 109207079 A CN109207079 A CN 109207079A
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China
Prior art keywords
film sheet
sheet material
pvc film
metal adhesive
pvc
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Pending
Application number
CN201811000853.XA
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Chinese (zh)
Inventor
肖传富
孙晓光
储江顺
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Shanghai Bangzhong Polymer Materials Co Ltd
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Shanghai Bangzhong Polymer Materials Co Ltd
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Priority to CN201811000853.XA priority Critical patent/CN109207079A/en
Publication of CN109207079A publication Critical patent/CN109207079A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0869—Acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/20—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
    • C09J2301/208—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive layer being constituted by at least two or more adjacent or superposed adhesive layers, e.g. multilayer adhesive
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/304—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/412—Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of microspheres

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
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  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention discloses a kind of with metal adhesive PVC film sheet material, including PVC film sheet material and composite hot melt adhesive, and composite hot melt adhesive includes and the hose lining of metal adhesive and outer layer glue Nian Jie with PVC the adhesive strength height of this kind of composite hot melt adhesive, good film-forming property；Furthermore invention additionally discloses a kind of preparation processes with the PVC film sheet material of metal adhesive, PVC film sheet material, hose lining, outer layer glue are respectively put into co-extrusion extruder main and auxiliaries to squeeze out, then the PVC film sheet material that hot melt adhesive is contained on surface is obtained by coextrusion casting, the preparation process can be directly compound by PVC film sheet material and hot melt adhesive, it avoids using release paper, preparation process is simple, and good with Bond Strength.

Description

A kind of PVC film sheet material and its preparation process with metal adhesive
Technical field
The invention belongs to PVC film sheet material and its processing and manufacturing technologies, and in particular to a kind of PVC with metal adhesive Thin-film sheet and its preparation process.
Background technique
Metal and the application that plastics directly bond are more and more wider, the bonding especially between sheet metal and PVC plastic, more It applies come more in electronics industry, machinery industry, building trade etc..Currently, PVC plastic and metal needs to be added liquid glue or Person's hot melt adhesive is bonded.Liquid glue contains volatile materials, not only pollutes environment, and also have certain danger to operator Evil；Furthermore liquid glue process operation is inconvenient, therefore the utilization of liquid glue in the industry is gradually reduced.Hot melt adhesive film is solvent-free Solid, volatile matter is not had, therefore pollution-free, to human body also fanout free region；Hot melt adhesive process operation is quick simultaneously, can repeat Operation, is conducive to the extensive sharp work of factory.It has existed in the prior art some for metal and plastic bonding Hot melt adhesive.PVC plastic is usually prepared separately with hot melt adhesive, and PVC plastic, hot melt adhesive and metal are passed through layer again when in use Press or pressing machine equipment are bonded.Since existing hot melt adhesive viscosity is higher, during hot melt adhesive is prepared separately It needs to be added release paper to be isolated, this results in process to complicate, while also adding preparation cost, while this kind of heat The adhesive effect of melten gel is simultaneously bad.
Summary of the invention
The technical problem to be solved by the invention is to provide a kind of PVC film sheet materials and its preparation work with metal adhesive PVC and hot melt adhesive can be directly bonded by skill during the preparation process, avoid being isolated using release paper, relatively change preparation process, drop Low production cost.
In order to solve the above technical problems, the technical solution adopted by the present invention: a kind of PVC film sheet material with metal adhesive, It is characterized by comprising PVC film sheet material and composite hot melt adhesive, the PVC film sheet material include following raw material components and Parts by weight:
The composite hot melt adhesive include with the hose lining of metal adhesive and the outer layer glue Nian Jie with PVC,
The hose lining includes following raw material components and its parts by weight:
The outer layer glue includes following raw material components and its parts by weight:
Wherein, for ethylene copolymer at 190 DEG C, 2.16Kg melt index is 2-20g/10min.
Preferably, the heat stabilizer is one of calcium ricinoleate, calcium stearate, zinc stearate or magnesium stearate or several Kind；The plasticizer is castor oil-base polyester plasticizer, and the castor oil-base polyester plasticizer is selected from P-RA-HHPAs, P-RA- MAs, P-RA-SAAs or P-RA-ECHs；The filler is CaCO3、AL2O3、SiO2One or more of；The lubricant is One or more of tristerin, stearic amide, paraffin, polyethylene wax；The dispersing agent is phthalate dispersion Agent or dispersant B YK-P104S.
Preferably, the polyethylene graft polymers are in maleic anhydride grafted polyethylene or acrylic acid-grafted polyethylene One or any combination, wherein the grafting rate of polyethylene graft polymers be 0.5-2%.
Preferably, the polyethylene is one of LDPE, LLDPE, HDPE or any combination.
Preferably, the maleic anhydride grafts are maleic anhydride grafted polyethylene, maleic anhydride grafted ethene acetic acid second Alkene copolymer, maleic anhydride grafted ethene acrylate copolymer, maleic anhydride grafted ethene octene copolymer, wherein maleic acid The grafting rate of acid anhydride graft is 0.5-2.0%.
Preferably, the ethylene copolymer is one of EVA, EEA, EBA and terpolymer of ethylene or any Combination.
Preferably, the co-monomer content in ethylene copolymer described in outer layer glue is 20-40 parts.
Preferably, one of described thermoplastic elastomer (TPE) POE, TPU, NBR, POP, SIS, SEBS, EPDM, SBR or appoint Meaning combination.
Preferably, the tackifier are terpene resin, phenolic aldehyde terpene resin, C5 hydrogenated petroleum resin, C5/C9 copolymer resins One of or any combination.
Preferably, the antioxidant is antioxidant 1010, antioxidant 1076, irgasfos 168, antioxidant 264, antioxidant One of B215 or any combination.
Preferably, the anti ultraviolet agent is selected from one of UV531, UV327, UV944, UV770 or any combination.
A kind of preparation process with the PVC film sheet material of metal adhesive, it is characterised in that: the following steps are included:
(1) it according to a kind of proportion with the PVC film sheet material of metal adhesive described in claim 1~8 any one, chooses Raw material,
(2) PVC film sheet material addition high mixer is uniformly mixed, co-extrusion is then added and squeezes out machine host, extrusion temperature is 150-200℃；
(3) raw material of hose lining is added to the first co-extrusion extruder subsidiary engine, extrusion temperature is 150-200 DEG C；
(4) raw material of outer layer glue is added to the second co-extrusion extruder subsidiary engine, extrusion temperature is 130-190 DEG C；
(5) step (2), (3), (4) are prepared thin with the PVC of metal adhesive by co-extrusion extruder coextrusion casting Film sheet, die head temperature are 150-200 DEG C.
Beneficial effects of the present invention: the present invention discloses a kind of and metal adhesive PVC film sheet material, including PVC film piece Material and composite hot melt adhesive, composite hot melt adhesive include with the hose lining of metal adhesive and the outer layer glue Nian Jie with PVC, this kind is compound The adhesive strength height of hot melt adhesive, good film-forming property；Furthermore invention additionally discloses a kind of preparations with the PVC film sheet material of metal adhesive PVC film sheet material, hose lining, outer layer glue are respectively put into co-extrusion extruder main and auxiliaries and squeezed out, then passed through by technique Coextrusion casting obtains the PVC film sheet material that hot melt adhesive is contained on surface, which can be directly by PVC film sheet material and hot melt Glue is compound, avoids using release paper, and preparation process is simple, and good with Bond Strength.
Detailed description of the invention
Fig. 1 is the structural schematic diagram with the PVC film sheet material of metal adhesive；
Appended drawing reference in figure, 1-PVC thin-film sheet；2- outer layer glue；3- hose lining.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
A kind of PVC film sheet material with metal adhesive, including PVC film sheet material and composite hot melt adhesive, as shown in Figure 1, Wherein,
PVC film sheet material P1
PVC film sheet material P2
Composite hot melt adhesive includes and the hose lining of metal adhesive and the outer layer glue Nian Jie with PVC, wherein
Hose lining A1
Hose lining A2
Outer layer glue B1
Outer layer glue B2
A kind of preparation process with the PVC film sheet material of metal adhesive, comprising the following steps:
(1) proportion of the PVC film sheet material according to a kind of with metal adhesive, chooses raw material, in present embodiment, choose P, And the raw material in A1 or A2 and B1 or B2；
(2) high mixer is added in the raw material in P to be uniformly mixed, co-extrusion is then added and squeezes out machine host, extrusion temperature is 150-200℃；In present embodiment, extrusion temperature is 160-180 DEG C；
(3) raw material in A1 or A2 is added to the first co-extrusion extruder subsidiary engine, extrusion temperature is 150-200 DEG C；This reality It applies in mode, extrusion temperature is 160-180 DEG C；
(4) raw material in B1 or B2 is added to the second co-extrusion extruder subsidiary engine, extrusion temperature is 130-190 DEG C；This reality It applies in mode, extrusion temperature is 130-160 DEG C；
(5) step (2), (3), (4) are prepared thin with the PVC of metal adhesive by co-extrusion extruder coextrusion casting Film sheet, die head temperature are 150-200 DEG C, and in present embodiment, die head temperature is 170-200 DEG C.
Adhesive effect comparison:
A kind of PVC film sheet material with metal adhesive, experimental condition is 150 DEG C, 3~10s of hot pressing under 0.5~1.5MPa, Test 180 ° of peel strengths, it is as follows with the bonding result of metal aluminum sheet: by 1,2 or 3,4 or 5,6 or 7,8 comparison it is found that 2,4,6, 8 with it is relatively complete after aluminium sheet removing, and 1,3,5,7 with it is slightly remaining after aluminium sheet removing.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.

Claims (9)

1. a kind of and metal adhesive PVC film sheet material, it is characterised in that: including PVC film sheet material and composite hot melt adhesive, institute Stating PVC film sheet material includes following raw material components and parts by weight:
The composite hot melt adhesive include with the hose lining of metal adhesive and the outer layer glue Nian Jie with PVC,
The hose lining includes following raw material components and its parts by weight:
The outer layer glue includes following raw material components and its parts by weight:
Wherein, for ethylene copolymer at 190 DEG C, 2.16Kg melt index is 2-20g/10min.
2. a kind of PVC film sheet material with metal adhesive according to claim 1, it is characterised in that: described polycthylene grafted Polymer is one of maleic anhydride grafted polyethylene or acrylic acid-grafted polyethylene or any combination, wherein polyethylene The grafting rate of graft polymers is 0.5-2%.
3. a kind of PVC film sheet material with metal adhesive according to claim 1, it is characterised in that: the polyethylene is One of LDPE, LLDPE, HDPE or any combination.
4. a kind of PVC film sheet material with metal adhesive according to claim 1, it is characterised in that: the maleic anhydride connects Branch object is maleic anhydride grafted polyethylene, ethylene-vinylacetate grafting maleic anhydride copolymer, maleic anhydride grafted ethene propylene Acid ester copolymer, maleic anhydride grafted ethene octene copolymer, wherein the grafting rate of maleic anhydride grafts is 0.5-2.0%.
5. a kind of PVC film sheet material with metal adhesive according to claim 1, it is characterised in that: the ethylene copolymer For one of EVA, EEA, EBA and the terpolymer of ethylene or any combination.
6. a kind of PVC film sheet material with metal adhesive according to claim 1, it is characterised in that: second described in outer layer glue Alkene copolymer is 20-40 parts.
7. a kind of PVC film sheet material with metal adhesive according to claim 1, it is characterised in that: the thermoplastic elastic One of body POE, TPU, NBR, POP, SIS, SEBS, EPDM, SBR or any combination.
8. a kind of PVC film sheet material with metal adhesive according to claim 1, it is characterised in that: the tackifier are terpene One of olefine resin, phenolic aldehyde terpene resin, C5 hydrogenated petroleum resin, C5/C9 copolymer resins or any combination.
9. a kind of preparation process with the PVC film sheet material of metal adhesive described in a kind of -8 any one according to claim 1, It is characterized in that: the following steps are included:
(1) it according to a kind of proportion with the PVC film sheet material of metal adhesive described in claim 1~8 any one, chooses former Material,
(2) PVC ingredient addition high mixer is uniformly mixed, co-extrusion is then added and squeezes out machine host, extrusion temperature 150-200 ℃；
(3) raw material of hose lining is added to the first co-extrusion extruder subsidiary engine, extrusion temperature is 150-200 DEG C；
(4) raw material of outer layer glue is added to the second co-extrusion extruder subsidiary engine, extrusion temperature is 130-190 DEG C；
(5) the PVC film piece with metal adhesive is prepared by co-extrusion extruder coextrusion casting in step (2), (3), (4) Material, die head temperature are 150-200 DEG C.
CN201811000853.XA 2018-08-30 2018-08-30 A kind of PVC film sheet material and its preparation process with metal adhesive Pending CN109207079A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111016201A (en) * 2019-11-21 2020-04-17 安徽汇吉科技有限公司 Production line and production method of gold-plastic composite board
CN114479682A (en) * 2022-01-04 2022-05-13 江苏凯伦建材股份有限公司 Hot melt adhesive film for bonding metal and PVC (polyvinyl chloride) and preparation method thereof
CN115891354A (en) * 2022-10-20 2023-04-04 江阴宝柏新型包装材料有限公司 High-gloss high-interlayer-fastness aluminum-plastic sheet and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101429413A (en) * 2008-11-18 2009-05-13 广州市鹿山化工材料有限公司 Double-layer composite hot melt adhesive film for bonding metal and plastic

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101429413A (en) * 2008-11-18 2009-05-13 广州市鹿山化工材料有限公司 Double-layer composite hot melt adhesive film for bonding metal and plastic

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111016201A (en) * 2019-11-21 2020-04-17 安徽汇吉科技有限公司 Production line and production method of gold-plastic composite board
CN114479682A (en) * 2022-01-04 2022-05-13 江苏凯伦建材股份有限公司 Hot melt adhesive film for bonding metal and PVC (polyvinyl chloride) and preparation method thereof
WO2023130722A1 (en) * 2022-01-04 2023-07-13 江苏凯伦建材股份有限公司 Hot melt adhesive film for bonding metal and pvc, and preparation method therefor
CN114479682B (en) * 2022-01-04 2024-06-11 江苏凯伦建材股份有限公司 Hot melt adhesive film for bonding metal and PVC and preparation method thereof
CN115891354A (en) * 2022-10-20 2023-04-04 江阴宝柏新型包装材料有限公司 High-gloss high-interlayer-fastness aluminum-plastic sheet and preparation method thereof

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