CN109694757A - A kind of alcohol radical liquid fuel and preparation method thereof - Google Patents

A kind of alcohol radical liquid fuel and preparation method thereof Download PDF

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Publication number
CN109694757A
CN109694757A CN201910127002.XA CN201910127002A CN109694757A CN 109694757 A CN109694757 A CN 109694757A CN 201910127002 A CN201910127002 A CN 201910127002A CN 109694757 A CN109694757 A CN 109694757A
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parts
liquid fuel
alcohol
stabilizer
reaction kettle
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Inventor
张秀君
孔永平
陈荣霞
李法香
张环平
余坤明
燕腾飞
曹会敏
刘建付
王素勤
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Zhengzhou Star Creation Energy Technology Co Ltd
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Zhengzhou Star Creation Energy Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1216—Inorganic compounds metal compounds, e.g. hydrides, carbides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/125—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/1258—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof hydrogen peroxide, oxygenated water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/26—Organic compounds containing phosphorus
    • C10L1/2608—Organic compounds containing phosphorus containing a phosphorus-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)

Abstract

The invention belongs to alcohol-based fuel technical fields, it is related to a kind of alcohol radical liquid fuel and preparation method thereof, which is made of the raw material of following weight parts: 60-90 parts of methanol, 10-20 parts of ethyl alcohol, 3-7 parts of methyl cyclopentadiene trihydroxy manganese, 5-20 parts of acetone, 5-10 parts of isopropanol, 0.2-0.6 parts of dimethyl ether .5-5 parts of hydrogen peroxidase 10,0.3-1.5 parts of potassium permanganate, 0.2-0.5 parts of ferrocene, 0.5-0.8 parts of corrosion inhibitor, 5-10 parts of water, 5-15 parts of stabilizer, 1-3 parts of deodorant.The present invention is mixed technique by multistage and prepares alcohol radical liquid fuel, improves mixing efficiency, stirs evenly, obtained product appearance color is limpid bright, is not easy to be layered, and performance is more stable, and product quality has reached alcohol radical liquid fuel national standard.

Description

A kind of alcohol radical liquid fuel and preparation method thereof
Technical field
The invention belongs to alcohol-based fuel technical field, it is related to a kind of alcohol radical liquid fuel and preparation method thereof.
Background technique
As being constantly progressive for society has entered into a new rank in history with economic fast development, the paces of the mankind Section, consequent is more and more problem.Such as the problems such as energy shortage and environmental pollution is not only to chemical industry The challenge of proposition, the challenge that even more current entire international community is initiated.Biomass energy comes as the fourth largest source After coal, petroleum, the three macrofossil energy of natural gas.Biomass energy is with quantity is big, widely distributed, reproducibility is strong, low dirt The features such as dye is one of the main force for substituting fossil energy.In recent years, due to the shadow by the energy shortagess such as petroleum and rise in price It rings, for the energy security for guaranteeing this country, countries in the world are all actively taking a series of action, greatly developing biomass energy.
Alcohol radical liquid fuel is a kind of novel renewable liquid fuel, is fired for domestic cooking fuel and Industrial Boiler Material, there is wide development space.As the representative of novel new energy, the development of alcohol radical liquid fuel has extremely important society It can benefit and historic significance.
Current alcohol radical liquid fuel is also to have based on methanol that a small amount of industrial alcohol is added mostly, and generally existing quality is not Stablize, the problems such as calorific value is low, volatile, therefore, China had put into effect many policies and regulations in succession and clearly encouraged to develop in recent years Alcohol radical liquid fuel, and a kind of suitable preparation method is looked for also at the most important thing.
Summary of the invention
The purpose of the present invention is to provide a kind of alcohol radical liquid fuels and preparation method thereof, solve existing alcohol-group liquid combustion Expect low existing calorific value, unstable quality and it is volatile the problems such as, and without raffinate, smoke dust, without carbon distribution, nothing in combustion process The pernicious gases such as sulfur dioxide.
To achieve the above object, the invention adopts the following technical scheme:
The present invention provides a kind of alcohol radical liquid fuel, is made of the raw material of following weight parts: 60-90 parts of methanol, ethyl alcohol 10-20 Part, 3-7 parts of methyl cyclopentadiene trihydroxy manganese, 5-20 parts of acetone, 5-10 parts of isopropanol, 0.2-0.6 parts of dimethyl ether, hydrogen peroxide 0.5-5 parts, 0.3-1.5 parts of potassium permanganate, 0.2-0.5 parts of ferrocene, 0.5-0.8 parts of corrosion inhibitor, 5-10 parts of water, stabilizer 5-15 parts, 1-3 parts of deodorant.
Preferably, it is made of the raw material of following weight parts: 80 parts of methanol, 15 parts of ethyl alcohol, methyl cyclopentadiene trihydroxy manganese 5 Part, 10 parts of acetone, 7 parts of isopropanol, 0.4 part of dimethyl ether, 3 parts of hydrogen peroxide, 1 part of potassium permanganate, 0.3 part of ferrocene, corrosion suppression 0.7 part of preparation, 7 parts of water, 10 parts of stabilizer, 2 parts of deodorant.
Preferably, the corrosion inhibitor includes methylenediphosphonate, ethyl acetate and six methylenes that mass ratio is 3:2:5 Urotropine.
Preferably, the stabilizer is selected from di-tert-butyl p-cresol, isobutyl amine, dibutyl hydroxy toluene or butylhydroxy Any one component and the mixture that any one group is grouped as in linseed oil or cottonseed oil in anisole, in stabilizer Mass ratio between above two component is 3:2.
Preferably, the deodorant is industrial essence.
The present invention also provides a kind of preparation methods of alcohol radical liquid fuel, comprising the following steps:
Step a: being added stabilizer in reaction kettle A, and heating is uniformly mixed, and it is spare that stabilizer is made；
Step b: first sequentially added in proportion in reaction kettle B methanol, ethyl alcohol, dimethyl ether, methyl cyclopentadiene trihydroxy manganese and Water is thoroughly mixed uniformly；Sequentially add isopropanol, acetone, hydrogen peroxide and permanganic acid in proportion in reaction kettle B again Potassium is thoroughly mixed uniformly；
Step c: the mixture in reaction kettle B is poured into reaction kettle A, and corrosion inhibitor, two are sequentially added in reaction kettle A Luxuriant iron, stabilizer and deodorant, stir about 30-60 minutes, sealing stood 3-5 hours at normal temperature, obtained alcohol-group liquid combustion Material.
Compared with prior art, the beneficial effects of the present invention are:
1. the present invention optimizes combination to components such as methanol, ethyl alcohol, methyl cyclopentadiene trihydroxy manganese, dimethyl ether, water, make to fire Expect that component is scientific, reasonable, substantially increases the calorific value and stability of alcohol radical liquid fuel；Present invention adds stabilizers, wherein Linseed oil oleic acid rich in, linoleic acid, linolenic acid, can achieve with di-tert-butyl p-cresol and dissolve each other well, not only The stability that alcohol radical liquid fuel can be increased prevents from being layered, and can also improve the calorific value and flash temperature of fuel；Utilize methyl Cyclopentadiene trihydroxy manganese has the alcohol radical liquid fuel prepared good anti-as high-octane rating additive and anti-knock agent Quick-fried performance, while fuel consumption is also reduced, save the energy；A certain amount of water is added in fuel, improves alcohol-group liquid The flash temperature of fuel, to reduce the risk of kindling.
2. preparation method of the present invention is multistage mixing technique, mixing efficiency is improved, is stirred evenly, obtained product Appearance color is limpid bright, is not easy to be layered, and performance is more stable, and product quality has reached alcohol radical liquid fuel national standard, burning In the process without raffinate, smoke dust, without carbon distribution, without pernicious gases such as sulfur dioxide, meet environmental requirement.
Specific embodiment
The following examples are intended to illustrate the invention, but is not used to limit the scope of protection of the present invention.Unless otherwise specified, real Apply the conventional means that technological means used in example is well known to those skilled in the art.Test method in following embodiments, such as It is conventional method without special instruction.
Embodiment one
A kind of alcohol radical liquid fuel is made of the raw material of following weight parts: 60 parts of methanol, 10 parts of ethyl alcohol, methyl cyclopentadiene three 3 parts of hydroxyl manganese, 5 parts of acetone, 5 parts of isopropanol, 0.2 part of dimethyl ether .5 parts of hydrogen peroxidase 10,0.3 part of potassium permanganate, ferrocene 0.2 Part, 0.5 part of corrosion inhibitor, 5 parts of water, 5 parts of stabilizer, 1 part of industrial essence.It is 3:2 that wherein corrosion inhibitor, which includes mass ratio: 5 methylenediphosphonate, ethyl acetate and hexa；Stabilizer be mass ratio be 3:2 di-tert-butyl p-cresol and The mixture of linseed oil composition.
The preparation method of above-mentioned alcohol radical liquid fuel the following steps are included:
Step a: being added linseed oil in reaction kettle A, is heated to 300 DEG C, it is equal that di-tert-butyl p-cresol mixing is added after cooling It is even, it is spare that stabilizer is made；
Step b: first sequentially added in proportion in reaction kettle B methanol, ethyl alcohol, dimethyl ether, methyl cyclopentadiene trihydroxy manganese and Water is thoroughly mixed uniformly；Sequentially add isopropanol, acetone, hydrogen peroxide and permanganic acid in proportion in reaction kettle B again Potassium is thoroughly mixed uniformly；
Step c: the mixture in reaction kettle B is poured into reaction kettle A, and corrosion inhibitor, two are sequentially added in reaction kettle A Luxuriant iron, stabilizer and deodorant, stir about 30-60 minutes, sealing stood 3-5 hours at normal temperature, obtained alcohol-group liquid combustion Material.
Embodiment two
A kind of alcohol radical liquid fuel is made of the raw material of following weight parts: 80 parts of methanol, 15 parts of ethyl alcohol, methyl cyclopentadiene three 5 parts of hydroxyl manganese, 10 parts of acetone, 7 parts of isopropanol, 0.4 part of dimethyl ether, 3 parts of hydrogen peroxide, 1 part of potassium permanganate, 0.3 part of ferrocene, 0.7 part of corrosion inhibitor, 7 parts of water, 10 parts of stabilizer, 2 parts of industrial essence.It is 3 that wherein corrosion inhibitor, which includes mass ratio: Methylenediphosphonate, ethyl acetate and the hexa of 2:5；Stabilizer is the isobutyl amine and linseed that mass ratio is 3:2 The mixture of oil composition.
The preparation method of above-mentioned alcohol radical liquid fuel the following steps are included:
Step a: being added linseed oil in reaction kettle A, is heated to 300 DEG C, isobutyl amine is added after cooling and is uniformly mixed, be made steady It is spare to determine agent；
Step b: first sequentially added in proportion in reaction kettle B methanol, ethyl alcohol, dimethyl ether, methyl cyclopentadiene trihydroxy manganese and Water is thoroughly mixed uniformly；Sequentially add isopropanol, acetone, hydrogen peroxide and permanganic acid in proportion in reaction kettle B again Potassium is thoroughly mixed uniformly；
Step c: the mixture in reaction kettle B is poured into reaction kettle A, and corrosion inhibitor, two are sequentially added in reaction kettle A Luxuriant iron, stabilizer and deodorant, stir about 30-60 minutes, sealing stood 3-5 hours at normal temperature, obtained alcohol-group liquid combustion Material.
Alcohol radical liquid fuel performance manufactured in the present embodiment is as follows: alcohol content >=70%, density (20 DEG C) 0.80-0.83g/ cm3, mechanical admixture < 0.02%, < -30 DEG C of condensation point, 200 DEG C of ignition temperature >, pH value 6-8, total sulfur content < 0.01%, low-heat Value > 21000kJ/kg, -30 DEG C not stratified, reaches the requirement of " alcohol radical liquid fuel " standard GB/T 16663-1996.
Embodiment three
A kind of alcohol radical liquid fuel is made of the raw material of following weight parts: 90 parts of methanol, 20 parts of ethyl alcohol, methyl cyclopentadiene three 7 parts of hydroxyl manganese, 20 parts of acetone, 10 parts of isopropanol, 0.6 part of dimethyl ether, 5 parts of hydrogen peroxide, 1.5 parts of potassium permanganate, ferrocene 0.5 Part, 0.8 part of corrosion inhibitor, 10 parts of water, 15 parts of stabilizer, 3 parts of industrial essence.Wherein corrosion inhibitor includes mass ratio For the methylenediphosphonate, ethyl acetate and hexa of 3:2:5；Stabilizer is the dibutyl hydroxy that mass ratio is 3:2 The mixture of toluene and cottonseed oil composition.
The preparation method of above-mentioned alcohol radical liquid fuel the following steps are included:
Step a: being added cottonseed oil in reaction kettle A, is heated to 300 DEG C, dibutyl hydroxy toluene is added after cooling and is uniformly mixed, It is spare that stabilizer is made；
Step b: first sequentially added in proportion in reaction kettle B methanol, ethyl alcohol, dimethyl ether, methyl cyclopentadiene trihydroxy manganese and Water is thoroughly mixed uniformly；Sequentially add isopropanol, acetone, hydrogen peroxide and permanganic acid in proportion in reaction kettle B again Potassium is thoroughly mixed uniformly；
Step c: the mixture in reaction kettle B is poured into reaction kettle A, and corrosion inhibitor, two are sequentially added in reaction kettle A Luxuriant iron, stabilizer and deodorant, stir about 30-60 minutes, sealing stood 3-5 hours at normal temperature, obtained alcohol-group liquid combustion Material.
Example IV
A kind of alcohol radical liquid fuel is made of the raw material of following weight parts: 90 parts of methanol, 20 parts of ethyl alcohol, methyl cyclopentadiene three 7 parts of hydroxyl manganese, 20 parts of acetone, 10 parts of isopropanol, 0.6 part of dimethyl ether, 5 parts of hydrogen peroxide, 1.5 parts of potassium permanganate, ferrocene 0.5 Part, 0.8 part of corrosion inhibitor, 10 parts of water, 15 parts of stabilizer, 3 parts of industrial essence.It is 3 that wherein corrosion inhibitor, which includes mass ratio: Methylenediphosphonate, ethyl acetate and the hexa of 2:5；Stabilizer is the butylated hydroxy anisole that mass ratio is 3:2 With the mixture of linseed oil composition.
The preparation method of above-mentioned alcohol radical liquid fuel the following steps are included:
Step a: being added linseed oil in reaction kettle A, is heated to 300 DEG C, it is equal that butylated hydroxy anisole mixing is added after cooling It is even, it is spare that stabilizer is made；
Step b: first sequentially added in proportion in reaction kettle B methanol, ethyl alcohol, dimethyl ether, methyl cyclopentadiene trihydroxy manganese and Water is thoroughly mixed uniformly；Sequentially add isopropanol, acetone, hydrogen peroxide and permanganic acid in proportion in reaction kettle B again Potassium is thoroughly mixed uniformly；
Step c: the mixture in reaction kettle B is poured into reaction kettle A, and corrosion inhibitor, two are sequentially added in reaction kettle A Luxuriant iron, stabilizer and deodorant, stir about 30-60 minutes, sealing stood 3-5 hours at normal temperature, obtained alcohol-group liquid combustion Material.
The embodiment of the above, only presently preferred embodiments of the present invention, is only used to explain the present invention, not limit The scope of the present invention processed to those of ordinary skill in the art certainly can be according to skill disclosed in this specification Art content makes other embodiments easily by way of replacing or changing, therefore all made in the principle of the present invention Changes and improvements etc., should be included in scope of the present invention patent.

Claims (6)

1. a kind of alcohol radical liquid fuel, which is characterized in that be made of the raw material of following weight parts: 60-90 parts of methanol, ethyl alcohol 10- 20 parts, 3-7 parts of methyl cyclopentadiene trihydroxy manganese, 5-20 parts of acetone, 5-10 parts of isopropanol, 0.2-0.6 parts of dimethyl ether, peroxidating 0.5-5 parts of hydrogen, 0.2-0.5 parts of ferrocene, 0.5-0.8 parts of corrosion inhibitor, 5-10 parts of water, is stablized 0.3-1.5 parts of potassium permanganate 5-15 parts of agent, 1-3 parts of deodorant.
2. a kind of alcohol radical liquid fuel according to claim 1, which is characterized in that be made of the raw material of following weight parts: 80 parts of methanol, 15 parts of ethyl alcohol, 5 parts of methyl cyclopentadiene trihydroxy manganese, 10 parts of acetone, 7 parts of isopropanol, 0.4 part of dimethyl ether, peroxide Change 3 parts of hydrogen, 1 part of potassium permanganate, 0.3 part of ferrocene, 0.7 part of corrosion inhibitor, 7 parts of water, 10 parts of stabilizer, 2 parts of deodorant.
3. a kind of alcohol radical liquid fuel according to claim 1 or 2, which is characterized in that the corrosion inhibitor includes matter Amount is than methylenediphosphonate, ethyl acetate and the hexa for 3:2:5.
4. a kind of alcohol radical liquid fuel according to claim 1 or 2, which is characterized in that the stabilizer is selected from two uncles In butyl paracresol, isobutyl amine, dibutyl hydroxy toluene or butylated hydroxy anisole any one component and be selected from linseed oil Or the mixture that any one group is grouped as in cottonseed oil, the mass ratio in stabilizer between above two component are 3:2.
5. a kind of alcohol radical liquid fuel according to claim 1 or 2, which is characterized in that the deodorant is industrial essence.
6. a kind of described in any item preparation methods of alcohol radical liquid fuel of claim 1 ~ 5, which is characterized in that including following step It is rapid:
Step a: being added stabilizer in reaction kettle A, and heating is uniformly mixed, and it is spare that stabilizer is made；
Step b: first sequentially added in proportion in reaction kettle B methanol, ethyl alcohol, dimethyl ether, methyl cyclopentadiene trihydroxy manganese and Water is thoroughly mixed uniformly；Sequentially add isopropanol, acetone, hydrogen peroxide and permanganic acid in proportion in reaction kettle B again Potassium is thoroughly mixed uniformly；
Step c: the mixture in reaction kettle B is poured into reaction kettle A, and corrosion inhibitor, two are sequentially added in reaction kettle A Luxuriant iron, stabilizer and deodorant, stir about 30-60 minutes, sealing stood 3-5 hours at normal temperature, obtained alcohol-group liquid combustion Material.
CN201910127002.XA 2019-02-20 2019-02-20 A kind of alcohol radical liquid fuel and preparation method thereof Pending CN109694757A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110724568A (en) * 2019-11-07 2020-01-24 郑虎 Methanol matrix mixed clean liquid fuel and preparation method thereof
CN112920864A (en) * 2021-02-07 2021-06-08 深圳蓝诺清洁能源科技有限公司 Alcohol-based liquid fuel and preparation method thereof
CN113046141A (en) * 2019-12-27 2021-06-29 安徽宝钻环境科技有限公司 Manufacturing process of precious drilling liquid fuel

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1667094A (en) * 2005-04-08 2005-09-14 谷宝龙 Alcohol-base liquid fuel
CN101144036A (en) * 2006-09-11 2008-03-19 温小琳 Alcohol group liquid fuel
CN101392194A (en) * 2008-10-28 2009-03-25 天津市益环化工有限公司 Alcohol-base liquid fuel and preparation method thereof
CN103122263A (en) * 2013-01-30 2013-05-29 秦如新 Fuel additive and clean low-carbon fuel with same
CN103980957A (en) * 2014-04-04 2014-08-13 黄利 Novel alcohol-based liquid fuel and preparation method thereof
CN106978220A (en) * 2017-03-14 2017-07-25 东莞市普吉新能源有限公司 Alcohol radical liquid fuel and preparation method
CN107118816A (en) * 2017-07-08 2017-09-01 湖北文理学院 A kind of composite gasoline additive
CN107267228A (en) * 2017-07-08 2017-10-20 湖北文理学院 A kind of composite gasoline

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1667094A (en) * 2005-04-08 2005-09-14 谷宝龙 Alcohol-base liquid fuel
CN101144036A (en) * 2006-09-11 2008-03-19 温小琳 Alcohol group liquid fuel
CN101392194A (en) * 2008-10-28 2009-03-25 天津市益环化工有限公司 Alcohol-base liquid fuel and preparation method thereof
CN103122263A (en) * 2013-01-30 2013-05-29 秦如新 Fuel additive and clean low-carbon fuel with same
CN103980957A (en) * 2014-04-04 2014-08-13 黄利 Novel alcohol-based liquid fuel and preparation method thereof
CN106978220A (en) * 2017-03-14 2017-07-25 东莞市普吉新能源有限公司 Alcohol radical liquid fuel and preparation method
CN107118816A (en) * 2017-07-08 2017-09-01 湖北文理学院 A kind of composite gasoline additive
CN107267228A (en) * 2017-07-08 2017-10-20 湖北文理学院 A kind of composite gasoline

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110724568A (en) * 2019-11-07 2020-01-24 郑虎 Methanol matrix mixed clean liquid fuel and preparation method thereof
CN113046141A (en) * 2019-12-27 2021-06-29 安徽宝钻环境科技有限公司 Manufacturing process of precious drilling liquid fuel
CN112920864A (en) * 2021-02-07 2021-06-08 深圳蓝诺清洁能源科技有限公司 Alcohol-based liquid fuel and preparation method thereof

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Application publication date: 20190430