CN109691442A

CN109691442A - Mixed-powder type chloro-calcium hyperoxide water-purifying disinfection sanitizer

Info

Publication number: CN109691442A
Application number: CN201710987592.4A
Authority: CN
Inventors: 向兵
Original assignee: Chengdu Bugee Technology Co Ltd
Current assignee: Chengdu Bugee Technology Co Ltd
Priority date: 2017-10-21
Filing date: 2017-10-21
Publication date: 2019-04-30

Abstract

The invention discloses mixed-powder type chloro-calcium hyperoxide sterilizing agent prescriptions, it belongs to fine chemistry industry or inorganic bio technical field, also belongs to biomedical engineering technology field.Dilution when PE is packed or the mixed-powder type chloro-calcium hyperoxide water-purifying of cartridge carton uses by water mixes, it releases chlorine peroxide and plays the role of the water purification sterilizing of strength, warehousing, toilet can also be placed in and be sustained technique and sterilizing according to it, using very convenient, to human body and ecological environment without any teratogenesis, mutagens and carcinogenic illeffects.

Description

Mixed-powder type chloro-calcium hyperoxide water-purifying disinfection sanitizer

Technical field: mixed-powder type chloro-calcium hyperoxide (Intermixing power of chlorine or Calcium peroxide, is abbreviated as PCD) disinfection sanitizer, it is a kind of water quality cleansing agent chemically obtained or is used for The sterilizing of warehousing, hospital and toilet etc..Therefore, this hair belongs to fine chemistry industry or inorganic bio technical field, Also belong to biomedical engineering technology field.

Background technique: chlorine peroxide and calper calcium peroxide are strong oxidizers.CaO₂Odorless, tasteless is decomposed in humid air, It is commonly used for fungicide, preservative, antiferment and seed disinfectant etc.: Cl0₂(CD) claim chlorine dioxide more, be after quick lime, drift Forth generation water disinfectant after white powder, strong chlorine oil, it has rapid, thorough killing to make bacterium, virus, mould etc. With, have no the report in relation to the bacterium that develops drug resistance so far because so far not yet discovery can resist its oxidation without being killed Microorganism, and CD on higher animal cells structure without influence, teratogenesis, mutagens and carcinogenesis does not occur.Therefore, WHO refers to It is set to A1 level security disinfectant, oneself has multiphase to react to produce ClO₂Patent report (Marck Lipsztajn, Etobicoke, Canada.chlorine dioxide generating process. United States Patent, US005676920A, oct.14,1997), and using stable ClO 2 solution as major antibacterial thimerosal ingredient compared with More preparation method (Luxianfeng Environmental Protection Science & Technology Co., Ltd., Beijing.The production method of high purity chlorine dioxide food additives.Invention Patent application publication number CN 1195642A).But so far there is not yet the report of PCD disinfection sanitizer, the sterilizing energy of PCD Power is stronger, and use scope is wider, and cost is relatively low and uses very convenient.

Summary of the invention: the object of the present invention is to firstly, be configured to a kind of chlorine peroxide disinfection sanitizer of solid shape, make Storing is very convenient with use, while cost is again low, can push away use extensively；Secondly, by means of chlorine peroxide and calper calcium peroxide it Between synergism, make the better effect of sterilizing, and use scope is wider.

Used technical measures are as follows to achieve the purpose of the present invention:

1. being mixed by following proportion (wt.%) using sulphur silicon, villaumite and calper calcium peroxide as raw material, forming PCD disinfection sanitizer:

The sulphur silicon of proportional quantity intersects with 3 to 7 layers of villaumite point to be stacked, centre CaO₂Dry powder or the fillers such as diatomite and sandstone point Every respectively being intake gas vent there are 2-6 θ 2-3mm up and down with biodegradable plastic is packed or cartridge carton:

2. sulphur silicon is to absorb the concentrated sulfuric acid with diatomite by 1:0.20-0.50 weight ratio, at loose powdery admittedly and it is divided into layer 2-3； Villaumite is mixed by sodium chlorate and sodium chloride by 1: 0.35-0.70 weight ratio, is divided into layer 2-4, is used Ca0₂Dry powder or diatom Soil makes to be not in contact with each other without reacting with sandstone with the separation of sulphur silicon:

3. using fresh Ca0₂Suspension scene absorbs CIO₂, that is, it is made by Cl0₂The CaO being saturated₂Powder.Fresh CaO₂Suspension It is that will contain 100g CaCI₂Coolant liquid, be added drop-wise to 6% H of 600ml under stiring₂O₂With H composed by 300m1 concentrated ammonia liquor₂O₂- NH₃·H₂It is made in O mixed liquor.

Below in conjunction with example, the invention will be further described.

Example 1, water-purifying sterilizing agent.

It takes 15.8m1 concentrated sulfuric acid 15g diatomite to absorb, at powdery is loosely consolidated, half amount is respectively taken to be pressed into the wide X of 2 stratifications respectively In the X3.8 of thick x high=6.1 X10.5cm press mold carton or biodegradable starch-resin polybag, and it is pressed into 3 layers respectively 50g villaumite is (by 32g NaCIO₃It is mixed with 18g NaCI) intersect and stacks, intermediate diatomite or sandstone separate, every box or every bag Material always weighs about 100g, before putting into fish pond shrimp ponds, tears upper lower sealing off, i.e., mixes and released about immediately by the dilution of water The CIO of 20g or so₂, launching 100 packets can make 10 mu of shrimp ponds of depth of water 1.5m containing 0.2g/m³CIO₂, spot in aquaculture pond can be killed Black gill disease caused by the arcs seedling bacterial diseases such as the rotten eye of prawn etc., black leg and water quality deterioration etc. is saved, journey is deteriorated according to water quality and prawn disease Degree can suitably increase concentration, i.e. increasing injected volume can dramatically increase water oxygen level simultaneously, be advantageous to forming for prawn.

Example 2 is sustained disinfection sanitizer.

32ml concentrated sulfuric acid 18g diatomite is taken to absorb.At loosely admittedly powdery, be divided into 3 parts paving be 30X7cm thin paper on, with The 50g villaumite that also paving is 3 layers on identical size thin paper is (by 30g NaCIO₃With 15gNaCI and 5g CaO₂Powder is mixed) intersect It stacks, is then rolled into cylindrical shape, be placed in the PE polybag of buckle mouth or in carton.4 boxes or every bag of material gross weight 100g, contain PCD 20g, for l0m³Space sterilizing.

Claims

1. one kind using sulphur silicon, villaumite and calper calcium peroxide as raw material, is mixed by following proportion (wt.%), forms mixed-powder type chloro-calcium Peroxide disinfection sanitizer:

The other fillers of sulphur silicon villaumite calper calcium peroxide.

2. disinfectant according to claim 1, which is characterized in that sulphur silicon is to use the concentrated sulfuric acid by 1:0.2-0.5 weight ratio Diatomite absorbs, at loose powdery admittedly.

3. disinfectant according to claim 1, which is characterized in that villaumite (presses 1:0.35-0.70 by sodium chlorate and sodium chloride Weight ratio mixes) and sulphur silicon between with calper calcium peroxide dry powder or the classes filler such as sandstone and diatomite separation, make in solid-state When be not in contact with each other and do not react.

4. disinfectant according to claim 1, which is characterized in that (under stiring will with fresh calper calcium peroxide suspension 100g CaCI₂Coolant liquid is added drop-wise to 600m16% H₂O₂With the H of mono- concentrated ammonia liquor of 300m composition₂O₂-NH_3.H₂Shape in O mixed liquor At) chlorine peroxide is absorbed, then low-temperature vacuum drying is at powder.