CN109669143B - Battery pack capacity evaluation method - Google Patents

Battery pack capacity evaluation method Download PDF

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CN109669143B
CN109669143B CN201910093911.6A CN201910093911A CN109669143B CN 109669143 B CN109669143 B CN 109669143B CN 201910093911 A CN201910093911 A CN 201910093911A CN 109669143 B CN109669143 B CN 109669143B
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battery pack
dynamic
voltage
pressure difference
value
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CN109669143A (en
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张玉乐
韩相帅
万正坤
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Avic Innovation Technology Research Institute Jiangsu Co ltd
China Aviation Lithium Battery Co Ltd
China Lithium Battery Technology Co Ltd
CALB Technology Co Ltd
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China Aviation Lithium Battery Co Ltd
China Aviation Lithium Battery Research Institute Co Ltd
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Abstract

The invention provides a battery pack capacity evaluation method, and belongs to the technical field of battery pack quality detection. The battery pack capacity evaluation method comprises the following steps: discharging the battery pack to be tested with the initial charge amount within a set range to cut-off voltage according to a set multiplying power, and determining a relation curve of the lowest monomer voltage and the discharge time and a relation curve of the lowest monomer voltage and the dynamic pressure difference in the discharge process; taking the dynamic pressure difference value corresponding to the common maximum inflection point on the two curves as a first characteristic voltage point dynamic pressure difference value, and taking the dynamic pressure difference value at the discharge cutoff position as a second characteristic voltage point dynamic pressure difference value; and comparing the obtained dynamic differential pressure values of the two characteristic voltage points with the corresponding qualified dynamic differential pressure standard value, and if the two dynamic differential pressure values do not exceed the corresponding qualified dynamic differential pressure standard value, indicating that the capacity of the battery pack to be tested is qualified. The battery pack capacity evaluation method can shorten evaluation time and reduce evaluation cost.

Description

Battery pack capacity evaluation method
Technical Field
The invention relates to a battery pack capacity evaluation method, and belongs to the technical field of battery pack quality detection.
Background
The existing battery pack capacity evaluation method is in a full-charge state when the battery is discharged, so that the battery pack needs to be fully charged before discharging, and the discharge capacity is the actual capacity of the battery pack, so that the time spent in the evaluation process is too long. Meanwhile, charging and discharging are required to be completed on power charging and discharging working condition equipment, and the cost of the power charging and discharging working condition equipment is high. Therefore, the existing battery capacity evaluation method takes long time and requires high cost.
Disclosure of Invention
The invention aims to provide a battery pack capacity evaluation method to solve the problems of long time and high cost of battery pack capacity evaluation at present.
In order to achieve the above object, the present invention provides a battery pack capacity evaluation method, including the steps of:
1) discharging the battery pack to be tested with the initial charge amount within a set range to cut-off voltage according to a set multiplying power, and determining a relation curve of the lowest monomer voltage and the discharge time and a relation curve of the lowest monomer voltage and the dynamic pressure difference in the discharge process;
2) taking the dynamic pressure difference value corresponding to the common maximum inflection point on the two curves as a first characteristic voltage point dynamic pressure difference value, and taking the dynamic pressure difference value at the discharge cutoff position as a second characteristic voltage point dynamic pressure difference value;
3) and comparing the obtained dynamic differential pressure values of the two characteristic voltage points with corresponding dynamic differential pressure qualified standard values, and if the two dynamic differential pressure values do not exceed the corresponding dynamic differential pressure qualified standard values, indicating that the capacity of the battery pack to be tested is qualified, wherein the dynamic differential pressure qualified standard values are determined according to the full-charge and full-discharge capacity evaluation data of the battery pack.
The battery pack capacity evaluation method has the beneficial effects that: the method is used for evaluating the capacity of the battery pack, and the battery pack is not required to be in a full-charge state when being discharged, so that the process of fully charging the battery pack is saved, and the evaluation time is shortened; in addition, special power charging and discharging working condition equipment is not needed, so that the cost is reduced.
In order to obtain a qualified standard value of the dynamic pressure difference so as to judge whether the capacity of the battery pack to be tested is qualified or not, as an improvement of the above battery pack capacity evaluation method, the obtaining process of the qualified standard value of the dynamic pressure difference is as follows:
A. extracting at least 100 sets of battery packs, and discharging to cut-off voltage according to a set multiplying power after each set of battery pack is fully charged;
B. acquiring a characteristic voltage point dynamic voltage difference value of each battery pack in a discharging process, wherein each group comprises a corresponding first characteristic voltage point dynamic voltage difference value and a corresponding second characteristic voltage point dynamic voltage difference value;
C. and calculating the average value of the dynamic voltage difference values of the first characteristic voltage point and the average value of the dynamic voltage difference values of the second characteristic voltage point in the obtained dynamic voltage difference values of the characteristic voltage points of each battery pack, and respectively taking the set proportion of each average value as the qualified standard value of the dynamic voltage difference of the first characteristic voltage point and the qualified standard value of the dynamic voltage difference of the second characteristic voltage point.
In order to make the obtained qualified standard value of the dynamic pressure difference more reasonable, the value range of the set proportion in the step C is 105-120 percent as another improvement of the battery pack capacity evaluation method.
In order to evaluate whether the capacity of the battery pack is qualified or not under the condition that the battery pack is not required to be fully charged so as to reduce the evaluation time, as a further improvement of the battery pack capacity evaluation method, the set range is 30% -70%.
Drawings
Fig. 1 is a flow chart of a battery capacity evaluation method according to an embodiment of the invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail with reference to the accompanying drawings and specific embodiments.
The method for evaluating the capacity of the battery pack is described in detail below by taking a power lithium battery pack as an example. The power lithium battery pack is formed by selecting monomer cells meeting the capacity required by customers. After the power lithium battery pack is formed by connecting the single battery cells in series and in parallel, the pack capacity has a certain attenuation relative to the single capacity, so that the rated capacity of each single battery cell forming the power lithium battery pack needs to meet the customer requirements, and the calculation is carried out according to the standard that the rated capacity of the single battery cell is equal to the capacity of the power lithium battery pack multiplied by 102 percent when the rated capacity of the single battery cell is calculated.
Referring to fig. 1, the battery capacity evaluating method includes the steps of:
step 1: according to the discharge process test data of the battery pack to be tested, a corresponding relation curve of the discharge time and the lowest single voltage (namely, a relation curve of the lowest single voltage and the discharge time) and a corresponding relation curve of the lowest single voltage and the dynamic pressure difference (namely, a relation curve of the lowest single voltage and the dynamic pressure difference) are determined.
In this embodiment, the battery pack to be tested, the initial charge of which is within the range of 30% SOC to 70% SOC (i.e., within the set range), is discharged to the cut-off voltage according to the 1C magnification (i.e., the set magnification), the discharging process may be performed on the battery rack, the voltage value of each single battery cell in the discharging process of the battery pack to be tested is collected by the battery management group, and the maximum value and the minimum value among the voltage values of all the single battery cells in the discharging process of the battery pack to be tested are calculated. Wherein, the minimum value is used as the lowest monomer voltage, and the difference between the maximum value and the minimum value is used as the dynamic pressure difference. Drawing a scatter diagram of the lowest monomer voltage and the discharge time by using an EXCEL tool, determining a corresponding relation curve (marked as a T-Vmin curve) of the discharge time and the lowest monomer voltage, drawing a scatter diagram of the dynamic pressure difference and the lowest monomer voltage, and determining a corresponding relation curve (marked as a Vmin-DVDiff curve) of the lowest monomer voltage and the dynamic pressure difference.
In other embodiments, the setting range of the initial charge of the battery pack to be tested, the setting magnification during discharging, and the cut-off voltage can be adjusted according to actual conditions.
Step 2: and determining the characteristic voltage point dynamic pressure difference values (including a first characteristic voltage point dynamic pressure difference value and a second characteristic voltage point dynamic pressure difference value) according to the slopes and slope change rates of the T-Vmin curve and the Vmin-DVDiff curve.
In the discharging process, when the charge capacity of the battery pack to be tested is in a 10% SOC-0% SOC interval, the voltage of each monomer battery core is rapidly reduced, a very obvious inflection point is formed on a T-Vmin curve, and the slope of the T-Vmin curve is rapidly increased. Meanwhile, because the rapid reduction rates of the cell voltages of the single cells are not consistent, an obvious inflection point is also formed on the Vmin-DVDiff curve. In this embodiment, the voltage value at the common maximum inflection point on the two curves is used as the first characteristic voltage point, and the dynamic voltage difference value corresponding to the common maximum inflection point on the two curves is used as the first characteristic voltage point dynamic voltage difference value (i.e., the dynamic voltage difference value corresponding to the first characteristic voltage point).
As the depth of discharge continues to increase, the slope of the two curves continues to increase until the discharge cutoff voltage. In this embodiment, the voltage value at the discharge cutoff point is used as the second characteristic voltage point, and the dynamic voltage difference value at the discharge cutoff point is used as the second characteristic voltage point dynamic voltage difference value (i.e., the dynamic voltage difference value corresponding to the second characteristic voltage point).
And step 3: and (3) formulating a characteristic voltage point dynamic differential pressure judgment standard (comprising a qualified standard value of the dynamic differential pressure of the first characteristic voltage point and a qualified standard value of the dynamic differential pressure of the second characteristic voltage point) by combining the full charge and full discharge capacity evaluation data of the power lithium battery pack.
In this embodiment, 100 sets of power lithium battery packs (hereinafter referred to as battery packs) are selected, and after each set of battery pack is fully charged, the battery packs are discharged to a cut-off voltage according to a 1C magnification (i.e., a set magnification).
And (3) acquiring a first characteristic voltage point dynamic voltage difference value and a second characteristic voltage point dynamic voltage difference value in the discharging process of each set of battery pack by utilizing the step (1) and the step (2) to obtain 100 sets of characteristic voltage point dynamic voltage difference values.
Calculating the average value of the dynamic voltage difference values of the first characteristic voltage point in the obtained 100 groups of dynamic voltage difference values of the characteristic voltage points, and taking 105 percent (namely a set proportion) of the average value as a qualified dynamic voltage difference standard value of the first characteristic voltage point; similarly, calculating the average value of the dynamic voltage difference values of the second characteristic voltage point in the obtained 100 groups of dynamic voltage difference values of the characteristic voltage point, and taking 105% of the average value as the qualified dynamic voltage difference standard value of the second characteristic voltage point respectively.
As another embodiment, when the dynamic differential pressure qualified standard value is determined, the set multiplying power when the battery pack is discharged and the set proportion of the dynamic differential pressure value average of the first and second characteristic voltage points may all be adjusted according to actual conditions, for example, the set proportion may be selected from a range of 105% to 120%.
As another embodiment, in order to make the obtained dynamic differential pressure qualified standard value more conform to the actual situation, more than 100 sets of evaluation data of the full charge and full discharge capacity of the power lithium battery pack may be selected as required to calculate the dynamic differential pressure qualified standard value.
And 4, step 4: and judging whether the capacity of the battery pack to be tested is qualified or not according to the characteristic voltage point dynamic pressure difference judgment standard.
And (3) comparing the first characteristic voltage point dynamic pressure difference value and the second characteristic voltage point dynamic pressure difference value of the battery pack to be tested obtained in the step (2) with corresponding dynamic pressure difference qualified standard values respectively, and if the first characteristic voltage point dynamic pressure difference value and the second characteristic voltage point dynamic pressure difference value do not exceed the corresponding dynamic pressure difference qualified standard values, indicating that the capacity of the battery pack to be tested is qualified.
In the embodiment, whether the capacity of the battery pack is qualified or not is evaluated according to the dynamic voltage difference value of the two characteristic voltage points in the discharging process of the battery pack, and the problems that the evaluation of the capacity of the battery pack takes long time and the required equipment and labor cost are high are solved.

Claims (4)

1. A battery pack capacity evaluation method is characterized by comprising the following steps:
1) discharging the battery pack to be tested with the initial charge amount within a set range to cut-off voltage according to a set multiplying power, and determining a relation curve of the lowest monomer voltage and the discharge time and a relation curve of the lowest monomer voltage and the dynamic pressure difference in the discharge process; the dynamic pressure difference is the difference value between the maximum value and the minimum value of all the single cell voltage values in the discharging process of the battery pack to be tested;
2) taking the dynamic pressure difference value corresponding to the common maximum inflection point on the two curves as a first characteristic voltage point dynamic pressure difference value, and taking the dynamic pressure difference value at the discharge cutoff position as a second characteristic voltage point dynamic pressure difference value;
3) and comparing the obtained dynamic differential pressure values of the two characteristic voltage points with corresponding dynamic differential pressure qualified standard values, and if the two dynamic differential pressure values do not exceed the corresponding dynamic differential pressure qualified standard values, indicating that the capacity of the battery pack to be tested is qualified, wherein the dynamic differential pressure qualified standard values are determined according to the full-charge and full-discharge capacity evaluation data of the battery pack.
2. The battery pack capacity evaluation method according to claim 1, wherein the obtaining of the dynamic pressure difference qualification value is as follows:
A. extracting at least 100 sets of battery packs, and discharging to cut-off voltage according to a set multiplying power after each set of battery pack is fully charged;
B. acquiring a characteristic voltage point dynamic pressure difference value of each battery pack in a discharging process, wherein the characteristic voltage point dynamic pressure difference value of each battery pack comprises a first characteristic voltage point dynamic pressure difference value and a second characteristic voltage point dynamic pressure difference value which correspond to each other;
C. and calculating the average value of the dynamic voltage difference values of the first characteristic voltage point and the average value of the dynamic voltage difference values of the second characteristic voltage point in the obtained dynamic voltage difference values of the characteristic voltage points of each battery pack, and respectively taking the set proportion of each average value as the qualified standard value of the dynamic voltage difference of the first characteristic voltage point and the qualified standard value of the dynamic voltage difference of the second characteristic voltage point.
3. The battery pack capacity evaluation method according to claim 2, wherein the value range of the ratio set in step C is 105% to 120%.
4. The battery pack capacity evaluation method according to claim 1, wherein the set range is 30% to 70%.
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